CN101133008B - 从1,1,1,3,3,3-六氟丙烷非催化法生产1,1,3,3,3-五氟丙烯 - Google Patents

从1,1,1,3,3,3-六氟丙烷非催化法生产1,1,3,3,3-五氟丙烯 Download PDF

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Publication number
CN101133008B
CN101133008B CN2005800375571A CN200580037557A CN101133008B CN 101133008 B CN101133008 B CN 101133008B CN 2005800375571 A CN2005800375571 A CN 2005800375571A CN 200580037557 A CN200580037557 A CN 200580037557A CN 101133008 B CN101133008 B CN 101133008B
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China
Prior art keywords
pyrolysis
reactor
reaction zone
temperature
reaction
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Expired - Fee Related
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CN2005800375571A
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English (en)
Chinese (zh)
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CN101133008A (zh
Inventor
V·N·M·劳
A·C·西弗特
R·N·米勒
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EIDP Inc
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EI Du Pont de Nemours and Co
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/19—Fluorine; Hydrogen fluoride
    • C01B7/191—Hydrogen fluoride
    • C01B7/195—Separation; Purification
    • C01B7/196—Separation; Purification by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/38—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C21/00—Acyclic unsaturated compounds containing halogen atoms
    • C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
    • C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN2005800375571A 2004-10-29 2005-10-28 从1,1,1,3,3,3-六氟丙烷非催化法生产1,1,3,3,3-五氟丙烯 Expired - Fee Related CN101133008B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US62321004P 2004-10-29 2004-10-29
US60/623,210 2004-10-29
PCT/US2005/039169 WO2006050215A2 (en) 2004-10-29 2005-10-28 Non-catalytic manufacture of 1,1,3,3,3-pentafluoropropene from 1,1,1,3,3,3-hexafluoropropane

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201010143775A Division CN101792365A (zh) 2004-10-29 2005-10-28 共沸或共沸类组合物、分离氟化氢的方法和分离1,1,3,3,3-五氟丙烯的方法

Publications (2)

Publication Number Publication Date
CN101133008A CN101133008A (zh) 2008-02-27
CN101133008B true CN101133008B (zh) 2011-11-23

Family

ID=36319717

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2005800375571A Expired - Fee Related CN101133008B (zh) 2004-10-29 2005-10-28 从1,1,1,3,3,3-六氟丙烷非催化法生产1,1,3,3,3-五氟丙烯
CN201010143775A Pending CN101792365A (zh) 2004-10-29 2005-10-28 共沸或共沸类组合物、分离氟化氢的方法和分离1,1,3,3,3-五氟丙烯的方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CN201010143775A Pending CN101792365A (zh) 2004-10-29 2005-10-28 共沸或共沸类组合物、分离氟化氢的方法和分离1,1,3,3,3-五氟丙烯的方法

Country Status (5)

Country Link
US (1) US20060094911A1 (https=)
EP (1) EP1805124A2 (https=)
JP (1) JP2008518938A (https=)
CN (2) CN101133008B (https=)
WO (1) WO2006050215A2 (https=)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7388117B2 (en) * 2005-11-01 2008-06-17 E.I. Du Pont De Nemours And Company Azeotrope compositions comprising 1,2,3,3,3-pentafluoropropene and hydrogen fluoride and uses thereof
US7476771B2 (en) * 2005-11-01 2009-01-13 E.I. Du Pont De Nemours + Company Azeotrope compositions comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
CN101351537B (zh) 2005-11-01 2013-09-25 纳幕尔杜邦公司 包含不饱和氟化烃的溶剂组合物
ES2642570T3 (es) * 2006-02-28 2017-11-16 The Chemours Company Fc, Llc Composiciones azeotrópicas que comprenden compuestos fluorados para aplicaciones de limpieza
US8377327B2 (en) * 2006-06-27 2013-02-19 E I Du Pont De Nemours And Company Tetrafluoropropene production processes
JP2009542650A (ja) * 2006-06-27 2009-12-03 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー テトラフルオロプロペン製造方法
US7803975B2 (en) * 2006-07-13 2010-09-28 E.I. Du Pont De Nemours And Company Process for separating a fluoroolefin from HF by liquid-liquid extraction
GB0614927D0 (en) * 2006-07-27 2006-09-06 Ineos Fluor Holdings Ltd Separation process
ES2450945T3 (es) * 2006-08-24 2014-03-25 E. I. Du Pont De Nemours And Company Procedimientos para la separación de fluoroolefinas a partir de fluoruro de hidrógeno por destilación azeotrópica
CN101535223A (zh) * 2006-09-05 2009-09-16 纳幕尔杜邦公司 用于制备氟烃的纯化工艺和方法
EP2069273B1 (en) 2006-09-08 2018-02-21 The Chemours Company FC, LLC Azeotrope compositions comprising 1,1,1,2,3-pentafluoropropene and hydrogen fluoride and uses thereof
KR101397113B1 (ko) 2006-10-03 2014-05-19 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. 탄소수 3-6의 (하이드로)플루오로알켄의 생성을 위한 탈수소할로겐화 방법
CN101528645B (zh) * 2006-10-31 2013-10-30 纳幕尔杜邦公司 氟丙烷、卤代丙烯以及2-氯-3,3,3-三氟-1-丙烯与hf的共沸组合物和1,1,1,2,2-五氟丙烷与hf的共沸组合物的制备方法
TW200844075A (en) * 2006-10-31 2008-11-16 Du Pont Processes for the production of fluoropropanes and halopropenes
CN101610987A (zh) * 2006-10-31 2009-12-23 纳幕尔杜邦公司 含有2,3,3,3-四氟丙烯和/或1,2,3,3-四氟丙烯的组合物及其制备方法
GB0625214D0 (en) * 2006-12-19 2007-01-24 Ineos Fluor Holdings Ltd Process
US8101672B2 (en) * 2007-12-13 2012-01-24 Honeywell International Inc. Azeotrope-like compositions of 1,1,2,3,3-pentafluoropropene
KR102136117B1 (ko) * 2008-02-21 2020-07-22 더 케무어스 컴퍼니 에프씨, 엘엘씨 공비 증류에 의한 플루오르화수소로부터의 1,3,3,3-테트라플루오로프로펜의 분리 방법
CA2736437A1 (en) * 2008-10-27 2010-06-03 E.I. Du Pont De Nemours And Company Conversion of hydrofluorochloropropanes to fluoropropenes
US8697922B2 (en) 2008-10-27 2014-04-15 E I Du Pont De Nemours And Company Conversion of 2-chloro-1,1,1,2-tetrafluoropropane to 2,3,3,3-tetrafluoropropene
US8203022B2 (en) * 2008-10-27 2012-06-19 E I Du Pont De Nemours And Company Conversion of 2-chloro-1,1,1,2-tetrafluoropropane to 2,3,3,3-tetrafluoropropene
CN102227395A (zh) * 2008-11-13 2011-10-26 苏威氟有限公司 氢氟烯烃、氢氟烯烃的制造以及使用氢氟烯烃的方法
WO2016025288A1 (en) * 2014-08-14 2016-02-18 The Chemours Company Fc, Llc Process for the production of e-1,3,3,3-tetrafluoropropene (hfc-1234ze) by dehydrofluorinatiokl
WO2017104829A1 (ja) * 2015-12-16 2017-06-22 旭硝子株式会社 ハイドロフルオロオレフィンの製造方法
CN111094503B (zh) * 2017-09-11 2022-04-01 科慕埃弗西有限公司 包含氟化氢和含氟烃的共沸组合物
CN114375287B (zh) * 2019-09-12 2024-07-30 关东电化工业株式会社 具有＝cf2或＝chf的结构的氟烯烃的精制方法、以及高纯度氟烯烃及其制造方法
TW202430495A (zh) 2022-10-03 2024-08-01 日商關東電化工業股份有限公司 氟烯烴之製造方法
CN116003210A (zh) * 2022-11-30 2023-04-25 三明市海斯福化工有限责任公司 一种偏氟乙烯单体的制备方法及偏氟乙烯单体

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3397248A (en) * 1964-05-15 1968-08-13 Du Pont Process for the preparation of hexafluoropropene
DE1906206A1 (de) * 1968-12-28 1970-10-08 Fluorwerke Dohna Verfahren zur Herstellung von Fluoralkenen
JPH0967281A (ja) * 1995-09-01 1997-03-11 Daikin Ind Ltd １，１，１，３，３−ペンタフルオロプロペンの製造方法及び１，１，１，３，３−ペンタフルオロプロパンの製造方法
DE69812901T2 (de) * 1997-01-31 2003-11-06 E.I. Du Pont De Nemours And Co., Wilmington Katalytische herstellung von pentafluorpropenen
US5945573A (en) * 1997-01-31 1999-08-31 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,3,3-pentafluoropropane
US6376727B1 (en) * 1997-06-16 2002-04-23 E. I. Du Pont De Nemours And Company Processes for the manufacture of 1,1,1,3,3-pentafluoropropene, 2-chloro-pentafluoropropene and compositions comprising saturated derivatives thereof
US6031141A (en) * 1997-08-25 2000-02-29 E. I. Du Pont De Nemours And Company Fluoroolefin manufacturing process
US6583328B1 (en) * 1999-04-05 2003-06-24 Pcbu Services, Inc. Method for the preparation of 1,1,1,3,3-pentafluoropropene and 1,1,1,3,3-pentafluoropropane
US6703533B1 (en) * 1999-08-20 2004-03-09 E. I. Du Pont De Nemours And Company Preparation of selected fluoroolefins
US20020032356A1 (en) * 2000-07-14 2002-03-14 Gelblum Peter Gideon Synthesis of perfluoroolefins

Also Published As

Publication number Publication date
US20060094911A1 (en) 2006-05-04
JP2008518938A (ja) 2008-06-05
CN101133008A (zh) 2008-02-27
EP1805124A2 (en) 2007-07-11
WO2006050215A3 (en) 2007-05-18
WO2006050215A2 (en) 2006-05-11
CN101792365A (zh) 2010-08-04

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Granted publication date: 20111123

Termination date: 20131028