CN101092531A - Low temperature solidified glass printing ink in single constituent - Google Patents
Low temperature solidified glass printing ink in single constituent Download PDFInfo
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- CN101092531A CN101092531A CN 200710025255 CN200710025255A CN101092531A CN 101092531 A CN101092531 A CN 101092531A CN 200710025255 CN200710025255 CN 200710025255 CN 200710025255 A CN200710025255 A CN 200710025255A CN 101092531 A CN101092531 A CN 101092531A
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Abstract
This invention discloses a single-component low-temperature-curing glass ink for decorating glass panel. The glass ink is composed of waterborne acrylic resin as the active component, coupler, defoamer, organic pigment, and water as the viscosity adjuster. The glass ink is prepared by: mixing the above raw materials, grinding and stirring. The single-component low-temperature-curing glass ink utilizes water as the diluting agent to adjust the viscosity, thus is harmless to human body, and is environmentally friendly.
Description
Technical field
The present invention relates to a kind of low temperature solidified glass printing ink in single constituent that the ambetti panel uses that is used for.
Background technology
Utilizing silk-screen fabrication techniques glass decoration pattern for many years, mainly be the solvent type ink that adopts high temperature sintering printing ink and low-temperature curing, but the printing ink of these two kinds of processes patterns and use all has many deficiencies.Adopt high temperature sintering printing ink, the deficiency that its technology exists is: (1) high temperature: 600 ℃ of-800 ℃ of sintering, and a large amount of energy of meeting loss causes cost of manufacture too high, and market competitiveness is not strong; (2) because in the high-temperature sintering process, coal combustion and produce flyash produces a large amount of pollutions to environment; (3) make principle based on high temperature sintering, the design producing fineness is not high, and printing ink use mineral dye, and colour vividness is not high, and color effect is less than the printing ink of pigment dyestuff; (4) pigment mainly uses high temperature to contain lead oxides in the inorganic high-temp fired-ink, for human body serious murder by poisoning is arranged, so its application all has been subjected to strict restriction in many aspects.
The solvent type ink of low-temperature curing gets up in the base growth of fired-ink, in solidification value, no small progress is arranged on the choices of raw materials, but in Environmental awareness intensive today day by day, its drawback has progressively displayed:
(1) there is harm in used solvent to HUMAN HEALTH in the production;
(2) solvent evaporates pollutes not environmental protection to environment in air;
(3) at present in order to reach the effect of low-temperature curing, adopt multi-component system mostly.Many components printing ink is extremely inconvenience in use, and solidifying agent is active high, and effective storage life is short, causes a large amount of wastes aborning, has increased production cost.
Summary of the invention
At the problems referred to above, the invention provides a kind of water and do the low temperature solidified glass printing ink in single constituent that thinner is regulated viscosity, harmless, be a kind of environmental protection printing ink.
Technical scheme of the present invention is as follows: low temperature solidified glass printing ink in single constituent, it is an active ingredient with the water-borne acrylic resin, is auxiliary material with coupling agent, defoamer etc., is mixed with pigment dyestuff, with water as viscosity modifier, through prepare burden, grind, stir finished product printing ink.
The proportioning of each component is as follows: water-borne acrylic resin 75-85 part; Coupling agent 1-4 part; Defoamer 1-3 part; Flow agent 1-3 part; Pigment dyestuff 7-8 part; Inorganic fillings 8-12 part.
Coupling agent is a silane coupling agent; Inorganic fillings can adopt barium sulfate or lime carbonate etc.
The invention has the beneficial effects as follows: 1. this printing ink is that water is cooked thinner adjusting viscosity, and is nontoxic, and human body is not had injury, is a Green Product.2. water is cooked thinner, and in short supply at petroleum resources is today, plays aim of saving, improves the market competitiveness.Product in use, water oil two class half tones are general, for the printing house facilitates, also reduced unnecessary waste.4. convenient transportation reduces the danger in the transportation, saves transportation cost.
Embodiment
Low temperature solidified glass printing ink in single constituent, it is an active ingredient with the water-borne acrylic resin, is auxiliary material with coupling agent, defoamer etc., is mixed with pigment dyestuff, with water as viscosity modifier, through prepare burden, grind, stir finished product printing ink.
The proportioning of each component is as follows: water-borne acrylic resin 75-85 part; Coupling agent 1-4 part; Defoamer 1-3 part; Flow agent 1-3 part; Pigment dyestuff 7-8 part; Inorganic fillings 8-12 part.
Coupling agent can adopt silane coupling agent; Inorganic powder such as barium sulfate or lime carbonate etc. are as stopping composition.
Its principle of work is as follows: in the low-temperature bake process, produce self-crosslinking between the resin, so just played without solidifying agent in purpose of adhering on glass.
Using method of the present invention: water is opened printing ink rare to needed printing viscosity, printing screen plate: 180 orders, solidification value: 180 ℃ of * 8 ' or 160 ℃ of * 20.
The performance index that low temperature solidified glass printing ink in single constituent reaches are as follows:
1. sticking power test (3M adhesive tape, the test of hundred lattice): 100/100
2. anti-alcohol test (95% ethanol): 200 times
3. anti-acetone test: 100 times
4. acid proof test (5% sulfuric acid): 24 hours
5. alkali resistance test (5% sodium hydroxide): 16 hours
6. water boiling resistance (100 ℃ of boiling water): 2 hours, do not come off
This product is along with the time can be more and more stronger at firmness on glass, and a week reaches maximum firmness.
In sum, low temperature solidified glass printing ink in single constituent of the present invention is compared with solvent type ink, has reached every index of solvent type ink, is surpassing solvent type ink aspect the anti-pure and mild anti-acetone.
Claims (4)
1, low temperature solidified glass printing ink in single constituent, it is active ingredient with the water-borne acrylic resin, is auxiliary material with coupling agent, defoamer etc., is mixed with pigment dyestuff, with water as viscosity modifier, through prepare burden, grind, stir finished product printing ink.
2, low temperature solidified glass printing ink in single constituent according to claim 1 is characterized in that the proportioning of each component is as follows: water-borne acrylic resin 75-85 part; Coupling agent 1-4 part; Defoamer 1-3 part; Flow agent 1-3 part; Pigment dyestuff 7-8 part; Inorganic fillings 8-12 part.
3, low temperature solidified glass printing ink in single constituent according to claim 2 is characterized in that coupling agent is a silane coupling agent.
4, low temperature solidified glass printing ink in single constituent according to claim 2 is characterized in that inorganic fillings is barium sulfate or lime carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710025255 CN101092531A (en) | 2007-07-19 | 2007-07-19 | Low temperature solidified glass printing ink in single constituent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710025255 CN101092531A (en) | 2007-07-19 | 2007-07-19 | Low temperature solidified glass printing ink in single constituent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101092531A true CN101092531A (en) | 2007-12-26 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200710025255 Pending CN101092531A (en) | 2007-07-19 | 2007-07-19 | Low temperature solidified glass printing ink in single constituent |
Country Status (1)
| Country | Link |
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| CN (1) | CN101092531A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974264A (en) * | 2010-09-25 | 2011-02-16 | 深圳市华熙生物科技有限公司 | Night-gloss glass printing ink, preparation method and printing method on glass product |
| CN102702852A (en) * | 2012-06-13 | 2012-10-03 | 中山市中益油墨涂料有限公司 | UV ink for glass base material printing and preparation method thereof |
| CN102863846A (en) * | 2011-07-08 | 2013-01-09 | 南昌来捷尔新材料技术有限公司 | Single-component water-based glass screen-printing ink |
| CN104830154A (en) * | 2015-05-11 | 2015-08-12 | 蓝思科技（长沙）有限公司 | Water-soluble protective ink and preparation method thereof |
| WO2016197260A1 (en) * | 2015-06-09 | 2016-12-15 | 孟宪平 | Aqueous plastic gravure printing surface printing/composite ink, binder and preparation methods therefor |
| CN106752362A (en) * | 2017-03-10 | 2017-05-31 | 广东天龙油墨有限公司 | A kind of waterborne glass ink and preparation method thereof |
| CN116891651A (en) * | 2023-06-19 | 2023-10-17 | 深圳市东方硅源科技有限公司 | High-adhesion printing ink |
| US11952500B2 (en) | 2018-06-08 | 2024-04-09 | Kao Corporation | Aqueous gravure printing ink |
-
2007
- 2007-07-19 CN CN 200710025255 patent/CN101092531A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974264A (en) * | 2010-09-25 | 2011-02-16 | 深圳市华熙生物科技有限公司 | Night-gloss glass printing ink, preparation method and printing method on glass product |
| CN101974264B (en) * | 2010-09-25 | 2013-04-03 | 深圳市华熙生物科技有限公司 | Night-gloss glass printing ink, preparation method and printing method on glass product |
| CN102863846A (en) * | 2011-07-08 | 2013-01-09 | 南昌来捷尔新材料技术有限公司 | Single-component water-based glass screen-printing ink |
| CN102702852A (en) * | 2012-06-13 | 2012-10-03 | 中山市中益油墨涂料有限公司 | UV ink for glass base material printing and preparation method thereof |
| CN102702852B (en) * | 2012-06-13 | 2014-07-30 | 中山市中益油墨涂料有限公司 | UV ink for glass base material printing and preparation method thereof |
| CN104830154A (en) * | 2015-05-11 | 2015-08-12 | 蓝思科技（长沙）有限公司 | Water-soluble protective ink and preparation method thereof |
| WO2016197260A1 (en) * | 2015-06-09 | 2016-12-15 | 孟宪平 | Aqueous plastic gravure printing surface printing/composite ink, binder and preparation methods therefor |
| CN106752362A (en) * | 2017-03-10 | 2017-05-31 | 广东天龙油墨有限公司 | A kind of waterborne glass ink and preparation method thereof |
| US11952500B2 (en) | 2018-06-08 | 2024-04-09 | Kao Corporation | Aqueous gravure printing ink |
| CN116891651A (en) * | 2023-06-19 | 2023-10-17 | 深圳市东方硅源科技有限公司 | High-adhesion printing ink |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Taizhou kingfine printing material Co. Ltd Assignor: Wang Zhaojin Contract fulfillment period: 2009.6.18 to 2014.6.18 contract change Contract record no.: 2009320001124 Denomination of invention: Low temperature solidified glass printing ink in single constituent License type: Exclusive license Record date: 2009.7.16 |
|
| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.6.18 TO 2014.6.18; CHANGE OF CONTRACT Name of requester: TAIZHOU CITY MEIBANG DIGITAL PRINTING MATERIALS CO Effective date: 20090716 |
|
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Open date: 20071226 |