CN102863846A - Single-component water-based glass screen-printing ink - Google Patents
Single-component water-based glass screen-printing ink Download PDFInfo
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- CN102863846A CN102863846A CN2011101917688A CN201110191768A CN102863846A CN 102863846 A CN102863846 A CN 102863846A CN 2011101917688 A CN2011101917688 A CN 2011101917688A CN 201110191768 A CN201110191768 A CN 201110191768A CN 102863846 A CN102863846 A CN 102863846A
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Abstract
The invention provides a single-component water-based glass screen-printing ink, comprising the following components in percentage by weight: 58-84% of modified water-based acrylic resin, 0.5-1% of dispersing agent, 0.5-2% of surface active agent, 0.3-1.5% of organic silicon defoaming agent, 0.5-2% of leveling agent, 0.3-2% of gas-phase silicon dioxide, 1-2% of siloxane coupling agent, 0.5-1.8% of polyethylene wax, 4-30% of water-based pigment, 5-10% of enclosed curing agent, 0.2-2% of PH-value regulating agent and 3-5% of deionized water. The single-component water-based glass screen-printing ink has no emission of toxic gas when in use so as to be environment-friendly without pollution.
Description
Technical field
The present invention relates to technical field of ink, particularly a kind of single-component water-based glass cross printing-ink.
Background technology
Glass cross printing-ink on the market, solvent-borne type single-component glass ink, two component printing ink etc. all contain a large amount of organic solvents, such as ketone, stupid class etc. in its composition.Have a large amount of organic solvent volatile emission in air when printing, to environment, be unfavorable for environmental protection, be unfavorable for the healthy of operator, two component printing ink also cause the large reason of waste.
Summary of the invention
The invention provides a kind of single-component water-based glass cross printing-ink that emits without toxic gas.
To achieve these goals, the invention provides following technical scheme:
A kind of single-component water-based glass cross printing-ink according to weight percent, comprising:
Modified aqueous acrylic acid resin: 58-84%
Dispersion agent: 0.5-1%
Tensio-active agent: 0.5-2%
Silicone antifoam agent: 0.3-1.5%
Flow agent: 0.5-2%
Aerosil: 0.3-2%
Siloxanes coupling agent: 1-2%
Polyethylene wax: 0.5-1.8%
Water-based paint: 4-30%
Blocked curing agent: 5-10%
PH value conditioning agent: 0.2-2%
Deionized water: 3-5%.
Preferably, described dispersion agent comprises: triethyl hexyl phosphoric acid and tripoly phosphate sodium STPP.
Preferably, described tensio-active agent comprises: carboxylic acid, sulfonic acid, sulfuric acid and amino acid.
Preferably, described flow agent comprises esters of acrylic acid and fluorocarbon class.
Preferably, described siloxanes coupling agent comprises: two-(the silica-based propyl group of γ-triethoxy) tetrasulfide and epoxy group(ing).
Preferably, described water-based paint comprises: permanent yellow, charcoal blacks and water-soluble titanium white powder.
Preferably, described blocked curing agent comprises: aliphatie diamine and aliphatic polyamine.
Preferably, described pH value conditioning agent comprises: Sodium hexametaphosphate 99 and yellow soda ash, sulfurous gas.
By implementing above technical scheme, has following technique effect: single-component water-based glass cross printing-ink provided by the invention, what adopt is that modified aqueous acrylic acid is as carrier, blocked curing agent in can be good at filling a prescription together makes print film produce reticulated structure in the process of being heated by the effect of siloxanes coupling agent, can be adsorbed in firmly glass surface, glass is produced sticking power, other material in its prescription all has with modified aqueous acrylic acid good avidity is arranged, after mixing with the modified aqueous acrylic acid resin, can adopt the tap water infinite dilution, the condition that can meet screen printing ink fully, owing in whole prescription, all there not being ketone, stupid class organic solvent, so in construction process, just there is not the discharging of organic solvent, reduced the discharging of VOC (volatile organic compounds), meet the requirement of environmental protection.
Embodiment
Technical scheme for a better understanding of the present invention, the below describes embodiment provided by the invention in detail.
A kind of single-component water-based glass cross printing-ink that the invention process provides, it comprises according to weight percent: modified aqueous acrylic acid resin: 58-84%; Dispersion agent: 0.5-1%; Tensio-active agent: 0.5-2%; Silicone antifoam agent: 0.3-1.5%; Flow agent: 0.5-2%; Aerosil: 0.3-2%; Siloxanes coupling agent: 1-2%; Polyethylene wax: 0.5-1.8%; Water-based paint: 4-30%; Blocked curing agent: 5-10%; PH value conditioning agent: 0.2-2%; Deionized water: 3-5%.
In above-described embodiment, preferably, described dispersion agent comprises: triethyl hexyl phosphoric acid and tripoly phosphate sodium STPP.Described tensio-active agent comprises: carboxylic acid, sulfonic acid, sulfuric acid and amino acid.Described flow agent comprises esters of acrylic acid and fluorocarbon class.Described siloxanes coupling agent comprises: two-(the silica-based propyl group of γ-triethoxy) tetrasulfide and epoxy group(ing).Described water-based paint comprises: permanent yellow, charcoal blacks and permanent bordeaux water-soluble titanium white powder.Described blocked curing agent comprises: aliphatie diamine and aliphatic polyamine.Described pH value conditioning agent comprises: Sodium hexametaphosphate 99, yellow soda ash and sulfurous gas.
Embodiment one (to make the single-component water-based white glass screen printing ink of 100KG as example):
Get: modified aqueous acrylic acid resin 58KG; Tripoly phosphate sodium STPP 0.5KG; Sulfonic acid 0.5KG; Silicone antifoam agent 0.3KG; Esters of acrylic acid 0.5KG; Aerosil 0.3KG; Two-(the silica-based propyl group of γ-triethoxy) tetrasulfide 1KG, polyethylene wax 0.5KG, water-soluble titanium white powder 30KG, aliphatie diamine 5KG, Sodium hexametaphosphate 99 0.2KG, deionized water 3KG, with above material in order the limit edged mix, be ground to fineness below 2.5U through three-roller, restir is evenly packed.
Embodiment two (to make the single-component water-based purple glass screen printing ink of 100KG as example):
Get: modified aqueous acrylic acid resin 84KG, triethyl hexyl phosphatase 11 KG, carboxylic acid 2KG, silicone antifoam agent 1.5KG, fluorocarbon class 2KG, aerosil 2KG, two-(the silica-based propyl group of γ-triethoxy) tetrasulfide 2KG, polyethylene wax 1.8KG, permanent yellow 4KG, aliphatie diamine 10KG; PH value conditioning agent 2KG, deionized water 5KG, with above material in order the limit edged mix, be ground to fineness below 2.5U through three-roller, restir is evenly packed.
Embodiment three (to make the single-component water-based black glass screen printing ink of 100KG as example):
Get: modified aqueous acrylic acid resin 84KG, tripoly phosphate sodium STPP 1KG, amino acid 2KG, silicone antifoam agent 1.5KG, fluorocarbon class 2KG, aerosil 2KG, epoxy group(ing) 2KG, polyethylene wax 1.8KG, carbon black pigment 8KG, aliphatic polyamine 10KG, sulfurous gas 2KG, deionized water 5KG, with above material in order the limit edged mix, be ground to fineness below 2.5U through three-roller, restir is evenly packed.
This single-component water-based glass cross printing-ink has that strong adhesion, hardness are high, a performance of ethanol-tolerant wiping, anti-butanone wiping, water boiling resistance, acidproof, alkaline-resisting these seven aspects:
1), strong adhesion: by the print film surface being carried out the test of hundred lattice, adopt the 3M600 adhesive tape to be adjacent to, with the rapid pull-up of miter angle, and repeat 3 subsurfaces China ink layer without coming off.
2), hardness is high: adopt the Chinese pencil of 3H on the print film surface, streak from the surface with 500G power, to China ink layer without vestige.
3), ethanol-tolerant is wiped examination: adopt sticking spirituous cloth waste to wipe back and forth 100 nothings of examination at the printing ink layer back and forth with 1000G power and come off.
4), anti-butanone wiping: adopt the cloth waste be stained with butanone with 1000G power the printing ink layer back and forth 100 nothings of wiping come off.
5), water boiling resistance: the printed matter that prints is positioned in 100 ℃ of water temperatures boiled 1 hour, do not come off.
6), acidproof: as the finished product that prints to be put into 5% hydrochloric acid soln soak to take out in 24 hours and do not come off.
7), alkali resistance: the finished product that prints is put into 5% sodium hydroxide solution soak to take out in 24 hours and do not come off.
The above a kind of single-component water-based glass cross printing-ink that the embodiment of the invention is provided is described in detail, for one of ordinary skill in the art, thought according to the embodiment of the invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (8)
1. a single-component water-based glass cross printing-ink is characterized in that, according to weight percent, comprising:
Modified aqueous acrylic acid resin: 58-84%
Dispersion agent: 0.5-1%
Tensio-active agent: 0.5-2%
Silicone antifoam agent: 0.3-1.5%
Acrylate flow agent: 0.5-2%
Aerosil: 0.3-2%
Siloxanes coupling agent: 1-2%
Polyethylene wax: 0.5-1.8%
Water-based paint: 4-30%
Blocked curing agent: 5-10%
PH value conditioning agent: 0.2-2%
Deionized water: 3-5%.
2. single-component water-based glass cross printing-ink as claimed in claim 1 is characterized in that, described dispersion agent comprises: triethyl hexyl phosphoric acid and tripoly phosphate sodium STPP.
3. single-component water-based glass cross printing-ink as claimed in claim 1 is characterized in that, described tensio-active agent comprises: carboxylic acid, sulfonic acid, sulfuric acid and amino acid.
4. single-component water-based glass cross printing-ink as claimed in claim 1 is characterized in that, described flow agent comprises esters of acrylic acid and fluorocarbon class.
5. single-component water-based glass cross printing-ink as claimed in claim 1 is characterized in that, described siloxanes coupling agent comprises: two-(the silica-based propyl group of γ-triethoxy) tetrasulfide and epoxy group(ing).
6. single-component water-based glass cross printing-ink as claimed in claim 1 is characterized in that, described water-based paint comprises: permanent yellow, charcoal blacks and water-soluble titanium white powder.
7. single-component water-based glass cross printing-ink as claimed in claim 1 is characterized in that, described blocked curing agent comprises: aliphatie diamine and aliphatic polyamine.
8. single-component water-based glass cross printing-ink as claimed in claim 1 is characterized in that, described pH value conditioning agent comprises: Sodium hexametaphosphate 99 and yellow soda ash, sulfurous gas.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2011101917688A CN102863846A (en) | 2011-07-08 | 2011-07-08 | Single-component water-based glass screen-printing ink |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011101917688A CN102863846A (en) | 2011-07-08 | 2011-07-08 | Single-component water-based glass screen-printing ink |
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| CN102863846A true CN102863846A (en) | 2013-01-09 |
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| CN2011101917688A Pending CN102863846A (en) | 2011-07-08 | 2011-07-08 | Single-component water-based glass screen-printing ink |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103242705A (en) * | 2013-04-25 | 2013-08-14 | 深圳市美丽华油墨涂料有限公司 | ITO (Indium Tin Oxide) conductive glass temporary protection printing ink and preparation method thereof |
| CN103342922A (en) * | 2013-07-30 | 2013-10-09 | 新乡市雯德翔川油墨有限公司 | All vegetable oil high-speed planographic printing ink |
| CN103509406A (en) * | 2013-07-23 | 2014-01-15 | 王景泉 | Aqueous decorative ink for glass printing and preparation method thereof |
| CN103666024A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠天光传感器有限公司 | High-printability printing ink and preparation method thereof |
| CN104194488A (en) * | 2014-08-28 | 2014-12-10 | 南昌来捷尔新材料技术有限公司 | Single-component waterborne glass ink and preparation method thereof |
| CN104263069A (en) * | 2014-08-29 | 2015-01-07 | 湖南新力华纳米科技有限公司 | Water-based thermosetting glass printing ink and preparation method thereof |
| CN104327598A (en) * | 2014-10-17 | 2015-02-04 | 东莞市锐鹰陶瓷玻璃原料有限公司 | Baked-type water-based environmentally-friendly printing ink |
| CN105153800A (en) * | 2015-07-08 | 2015-12-16 | 合肥旭阳铝颜料有限公司 | One-component mirror surface sliver ink |
| CN105802404A (en) * | 2016-04-26 | 2016-07-27 | 安徽康瑞鑫电子科技有限公司 | Wire-covering enamel |
| CN106987174A (en) * | 2017-04-19 | 2017-07-28 | 广州大学 | A kind of water-soluble mobile phone faceplate glass protection ink |
| CN109852136A (en) * | 2018-12-28 | 2019-06-07 | 湖南松井新材料股份有限公司 | One-component ink and water-based ink coating for 3C glass |
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| CN101092531A (en) * | 2007-07-19 | 2007-12-26 | 王兆进 | Low temperature solidified glass printing ink in single constituent |
| CN101284965A (en) * | 2007-04-10 | 2008-10-15 | 樊官保 | Water-based intaglio ink equal to plate engraving ink and uses thereof |
| CN101392043A (en) * | 2008-11-10 | 2009-03-25 | 王兆进 | Method for preparing resin for high water resistant waterborne glass ink |
| CN102040881A (en) * | 2009-10-21 | 2011-05-04 | 刘立新 | Etching and plating resist ink of hydrophobic printed circuit board |
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| CN101284965A (en) * | 2007-04-10 | 2008-10-15 | 樊官保 | Water-based intaglio ink equal to plate engraving ink and uses thereof |
| CN101092531A (en) * | 2007-07-19 | 2007-12-26 | 王兆进 | Low temperature solidified glass printing ink in single constituent |
| CN101392043A (en) * | 2008-11-10 | 2009-03-25 | 王兆进 | Method for preparing resin for high water resistant waterborne glass ink |
| CN102040881A (en) * | 2009-10-21 | 2011-05-04 | 刘立新 | Etching and plating resist ink of hydrophobic printed circuit board |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103242705A (en) * | 2013-04-25 | 2013-08-14 | 深圳市美丽华油墨涂料有限公司 | ITO (Indium Tin Oxide) conductive glass temporary protection printing ink and preparation method thereof |
| CN103509406A (en) * | 2013-07-23 | 2014-01-15 | 王景泉 | Aqueous decorative ink for glass printing and preparation method thereof |
| CN103342922A (en) * | 2013-07-30 | 2013-10-09 | 新乡市雯德翔川油墨有限公司 | All vegetable oil high-speed planographic printing ink |
| CN103666024A (en) * | 2013-11-18 | 2014-03-26 | 蚌埠天光传感器有限公司 | High-printability printing ink and preparation method thereof |
| CN104194488A (en) * | 2014-08-28 | 2014-12-10 | 南昌来捷尔新材料技术有限公司 | Single-component waterborne glass ink and preparation method thereof |
| CN104263069B (en) * | 2014-08-29 | 2016-07-06 | 湖南新力华纳米科技有限公司 | A kind of aqueous thermosetting glass printing ink and preparation method thereof |
| CN104263069A (en) * | 2014-08-29 | 2015-01-07 | 湖南新力华纳米科技有限公司 | Water-based thermosetting glass printing ink and preparation method thereof |
| CN104327598A (en) * | 2014-10-17 | 2015-02-04 | 东莞市锐鹰陶瓷玻璃原料有限公司 | Baked-type water-based environmentally-friendly printing ink |
| CN105153800A (en) * | 2015-07-08 | 2015-12-16 | 合肥旭阳铝颜料有限公司 | One-component mirror surface sliver ink |
| CN105153800B (en) * | 2015-07-08 | 2019-02-26 | 合肥旭阳铝颜料有限公司 | A kind of one-component mirror-like silver ink |
| CN105802404A (en) * | 2016-04-26 | 2016-07-27 | 安徽康瑞鑫电子科技有限公司 | Wire-covering enamel |
| CN106987174A (en) * | 2017-04-19 | 2017-07-28 | 广州大学 | A kind of water-soluble mobile phone faceplate glass protection ink |
| CN106987174B (en) * | 2017-04-19 | 2020-10-23 | 广州大学 | Water-soluble mobile phone panel glass protection ink |
| CN109852136A (en) * | 2018-12-28 | 2019-06-07 | 湖南松井新材料股份有限公司 | One-component ink and water-based ink coating for 3C glass |
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Application publication date: 20130109 |