CN101090948A - 酸性染料混合物 - Google Patents
酸性染料混合物 Download PDFInfo
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- CN101090948A CN101090948A CNA2006800016107A CN200680001610A CN101090948A CN 101090948 A CN101090948 A CN 101090948A CN A2006800016107 A CNA2006800016107 A CN A2006800016107A CN 200680001610 A CN200680001610 A CN 200680001610A CN 101090948 A CN101090948 A CN 101090948A
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- 239000000203 mixture Substances 0.000 title claims abstract description 78
- 239000000980 acid dye Substances 0.000 title abstract description 6
- 239000000975 dye Substances 0.000 claims abstract description 181
- 238000004043 dyeing Methods 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000004952 Polyamide Substances 0.000 claims abstract description 10
- 239000002657 fibrous material Substances 0.000 claims abstract description 10
- 229920002647 polyamide Polymers 0.000 claims abstract description 10
- 238000004519 manufacturing process Methods 0.000 claims abstract description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 22
- 239000001257 hydrogen Substances 0.000 claims description 22
- 229910052736 halogen Inorganic materials 0.000 claims description 14
- 150000002367 halogens Chemical class 0.000 claims description 14
- 238000012505 colouration Methods 0.000 claims description 12
- 150000002431 hydrogen Chemical class 0.000 claims description 12
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 11
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 5
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 229910052728 basic metal Inorganic materials 0.000 claims description 4
- 150000003818 basic metals Chemical class 0.000 claims description 4
- 125000000043 benzamido group Chemical group [H]N([*])C(=O)C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 4
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052700 potassium Chemical group 0.000 claims description 2
- 239000011591 potassium Chemical group 0.000 claims description 2
- 239000011734 sodium Chemical group 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 238000007639 printing Methods 0.000 abstract description 3
- 159000000000 sodium salts Chemical group 0.000 description 8
- 239000000463 material Substances 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 3
- 229920002292 Nylon 6 Polymers 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052731 fluorine Inorganic materials 0.000 description 3
- 239000011737 fluorine Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 2
- 239000001045 blue dye Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 239000001048 orange dye Substances 0.000 description 2
- 230000000176 photostabilization Effects 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- USFZMSVCRYTOJT-UHFFFAOYSA-N Ammonium acetate Chemical class N.CC(O)=O USFZMSVCRYTOJT-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 240000007817 Olea europaea Species 0.000 description 1
- 235000019257 ammonium acetate Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010014 continuous dyeing Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- -1 isobutyl- Chemical group 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000001043 yellow dye Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0096—Multicolour dyeing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0051—Mixtures of two or more azo dyes mixture of two or more monoazo dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
- C09B67/0055—Mixtures of two or more disazo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/02—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes
- D06P1/04—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes not containing metal
- D06P1/06—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes not containing metal containing acid groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/021—Material containing basic nitrogen using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/06—Material containing basic nitrogen containing amide groups using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/14—Wool
- D06P3/16—Wool using acid dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/241—Polyamides; Polyurethanes using acid dyes
Abstract
本发明涉及有关染红色的酸性染料混合物，其包括式(I)的染料与至少一种式(II)的染料；还涉及其制造方法及用其染色和印染天然或合成聚酰胺纤维材料的方法。
Description
技术领域
本发明涉及酸性染料领域。
现有技术
酸性染料是公知的，并可用来染色和印染天然和合成的聚酰胺纤维材料。
文件US 4,537,598；US 5,090,964；US 5,131,919和US 6,443,998都记述了染红色的酸性染料混合物，其也可用来染色和印染聚酰胺纤维，且适合以三原色技术来组合染色。
不过，已知的染料和染料混合物都分别具有在染房中的应用性以及染后材料的坚牢性方面的一些缺点。
发明内容
本发明的目的是提供改良的酸性染料的染红色混合物，其适合用来从水性染浴染色或印染天然或合成聚酰胺纤维材料，且显示良好的上染性(exhaustion)，尤其是在与其它染料组合时，特别是小浴比(shortliquor)，具有非常好的均染和坚牢度，尤其是耐光性。
本发明涉及染料混合物，其包含式(I)染料：
其中M为氢、碱金属、铵离子或当量的碱土金属，
与至少一种式(II)染料
其中
R1为氢；(C1-C8)-烷基；经卤素取代的(C1-C8)-烷基；卤素；苯甲酰胺基；在苯环中经卤素取代的苯甲酰胺基；-SO2-苯基；在苯环中经(C1-C8)-烷基取代的-SO2-苯基；-SO2-O-苯基；
1-氮杂环庚烷-N-磺酰基；或式(III)的基团
其中R4为(C1-C8)-烷基；(C3-C8)-环烷基；苯基，或经(C1-C8)-烷基取代的苯基；且R5为氢或(C1-C8)-烷基；
R2为氢、卤素、(C1-C8)-烷基或为式(IV)的基团
其中R6为氢、甲基或乙基；且R7为(C1-C8)-烷基、苯基或-CO-O-(C3-C8)-环烷基；
R3为氢、卤素或(C1-C8)-烷基；
M为氢、碱金属、铵离子或等当量的碱土金属，
其中式(II)不包括式(I)染料，且
排除包含式(I)染料和式(II)染料的如下这样的混合物，其中R1为三氟甲基且R2和R3两者皆为氢；以及式(II)的染料，其中R1为式(III)的基团，其中R4为环己基，R5为甲基，且R2和R3两者皆为氢；并且
排除由式(I)染料和式(II)染料组成的如下这样的混合物，其中R1为三氟甲基且R2和R3两者皆为氢。
(C1-C8)-烷基可为直链或支链，并且是例如甲基、乙基、正丙基、异丙基、正丁基、异丁基、叔丁基、戊基、己基、庚基或辛基。优选(C1-C4)-烷基，如甲基、乙基、正丙基和正丁基。
(C3-C8)-环烷基优选环己基。
卤素优选氟、氯和溴。因此，经卤素取代的(C1-C8)-烷基优选被氟、氯或溴所取代。特别优选的经卤素取代的(C1-C8)-烷基为三氟甲基。
替代R2或R3的卤素优选氟、氯和溴，且特别优选氯。
替代R4的经取代的苯基优选被甲基取代。
M优选氢、钠或钾。
优选的式(II)染料为式(IIa)至(IIp)的染料
其中M如上面所定义。
一种优选的染料混合物包含式(I)染料和式(IIa)染料或式(IIm)染料。
另一种优选的染料混合物由式(I)染料与式(IIa)染料或式(IIm)染料组成。
还有一种优选的染料混合物包含式(I)染料与至少两种式(II)染料，其中之一为式(IIb)染料。还有一种优选的染料混合物包含式(I)染料与式(IIa)染料与式(IIb)或(IIm)染料。
本发明染料混合物包含优选量为5至95重量％的式(I)染料，以及优选量为95至5重量％的式(II)染料。本发明染料混合物包含特别优选量为40至80重量％的式(I)染料以及特别优选量为60至20重量％的式(II)染料。
本发明还涉及染料混合物，其包含90至99.99重量％的包含式(I)染料和至少一种式(II)染料的染料混合物，以及10至0.01重量％的一或多种调色剂。
调色剂为可以用来改变本发明染料混合物的色调以将其调整到某一色调标准的染料。
优选的调色剂为黄色、橙色或蓝色的酸性染料，或可与本发明染料混合物一起使用的其它黄色、橙色或蓝色染料。特别优选的调色剂为下面所提及的黄色、橙色和蓝色染料。
本发明还涉及制造本发明染料混合物的方法，其包括将所需量的式(I)染料与一种或多种式(II)染料机械混合。式(I)和(II)染料都是已知的，可购自市场或以本领域技术人员所知的方法生产。
本发明染料混合物适合用来以酸性染料领域中大量记载的应用方法染色和印染天然或合成聚酰胺纤维材料。所以，本发明也涉及一种使用本发明染料混合物染色和印染天然或合成聚酰胺纤维材料的方法。
优选的天然聚酰胺纤维材料为羊毛，而优选的合成聚酰胺纤维材料为尼龙材料，如尼龙-6和尼龙-6，6。
本发明染料混合物特别适合以三原色技术进行组合染色。根据本方法，将本发明染红色的混合物与适当的染蓝色的染料或染料混合物以及适当的染黄色的或染橙色的染料或染料混合物一起或混合使用。
所以，本发明也涉及一种天然或合成聚酰胺纤维材料的三原色染色和印染方法，其中本发明染料混合物与至少一种染蓝色的染料或染料混合物以及至少一种染黄色的或染橙色的染料或染料混合物一起使用。
优选的染蓝色的染料为式(IIIa)染料
其中R8为甲基或乙基，M如上所定义。
优选的式(IIIa)染料为式(IIIb)与(IIIc)染料
其它优选染蓝色的染料为式(IIId)至(IIIh)染料
其中M如上所定义；以及二种或多种式(IIIa)至(IIIh)染料的混合物。
优选的染黄色或染橙色的染料为式(IVa)至(IVh)染料
其中M如上所定义；以及二种或多种式(IVa)至(IVh)的染料混合物。
优选的染黄色或染橙色的混合物为包含式(IVa)染料和式(IVi)染料的混合物
其中M如上所定义。
包含式(IVa)染料和式(IVi)染料的混合物包含优选量为5至95重量％的式(IVa)染料及优选量为95至5重量％的式(IVi)染料。特别优选40至60重量％的式(IVa)染料和60至40重量％的式(IVi)染料。
使用本领域技术人员所知的常用浸染或连续染色与印染技术，本发明染料混合物在与染蓝色的染料和/或染黄色或染橙色的染料或其染料混合物合并使用时，显示出改进的色光一致染深性(On-tonebuild-up)。
在难染的纤维材料上，如高消光的、预热固化的微纤维，本发明因色光一致变色(On-tone fading)而显示出改良的耐光性。
实施例
实施例1
为制备包含式(I)染料与式(IIa)染料的染料混合物，将60份钠盐形式的式(I)染料和40份钠盐形式的式(IIa)染料均匀混合，得到100份染料混合物，后文中称为混合物A。
实施例2
为制备包含式(I)染料与式(IIm)染料的染料混合物，将25份钠盐形式的式(I)染料及75份钠盐形式的式(IIm)染料均匀混合，得到100份染料混合物，后面称为混合物B。
实施例3
为制备包含式(I)染料、式(IIa)染料及式(IIb)染料的染料混合物，将50份钠盐形式的式(I)染料、40份钠盐形式的式(IIa)染料及10份钠盐形式的式(IIb)染料均匀混合，得到100份的染料混合物，后文中称为混合物C。
实施例4
将10份尼龙-6，6材料(Helanca织物)置于200份含2克/升乙酸铵的水溶液(用乙酸调整到pH值5)中染色。所用染料为0.10％的实施例1染红色的混合物A，0.15％包含等摩尔量的式(IVa)染料和式(IVi)染料的染橙色的染料混合物，及0.12％式(IIIb)染蓝色的染料，所给量以Helanca织物的重量为基准。所有染料都以其钠盐形式使用。
在60℃至90℃温度下的染色时间为30至90分钟。其后，从染液中取出染过的尼龙-6，6织物，按一般方式冲洗并干燥。如此得到一片完全均染成棕色调的织物，没有任何与材料相关的条纹，且具有高度耐光性。
实施例5至11
分别用不同的染料和染料混合物重复实施例4，并使用下表中所给的量。所得全部染色件都完全均染且有高度耐光性。
| 实施例 | 所用染料 | 色调 |
| 5 | 0.035％的等摩尔式(IVa)和(IVi)染料的混合物0.023％混合物A0.063％的式(IIIb)染料 | 浅灰色 |
| 6 | 0.060％的等摩尔式(IVa)和(IVi)染料混合物0.005％混合物A0.075％的式(IIIb)染料 | 橄榄色 |
| 7 | 0.021％的等摩尔式(IVa)和(IVi)染料混合物0.027％混合物A0.020％的式(IIIb)染料 | 棕色 |
| 8 | 0.035％的等摩尔式(IVa)和(IVi)染料混合物0.023％混合物B0.063％的式(IIIb)染料 | 浅灰色 |
| 9 | 0.021％的等摩尔式(IVa)和(IVi)染料混合物0.027％混合物B0.020％的式(IIIb)染料 | 棕色 |
| 10 | 0.035％的等摩尔式(IVa)和(IVi)染料混合物0.023％混合物C0.063％的式(IIIb)染料 | 浅灰色 |
| 11 | 0.021％的等摩尔式(IVa)和(IVi)染料混合物0.027％混合物C0.020％的式(IIIb)染料 | 棕色 |
Claims (12)
1.染料混合物，其包含式(I)染料：
其中M为氢、碱金属、铵离子或等当量的碱土金属，与至少一种式(II)染料
其中
R1为氢；(C1-C8)-烷基；经卤素取代的(C1-C8)-烷基；卤素；苯甲酰胺基；在苯环中经卤素取代的苯甲酰胺基；-SO2-苯基；在苯环中经(C1-C8)-烷基取代的-SO2-苯基；-SO2-O-苯基；
1-氮杂环庚烷-N-磺酰基；或式(III)的基团
其中R4为(C1-C8)-烷基；(C3-C8)-环烷基；苯基；或经(C1-C8)-烷基取代的苯基；且R5为氢或(C1-C8)-烷基；
R2为氢、卤素、(C1-C8)-烷基或式(IV)的基团
其中R6为氢、甲基或乙基；且R7为(C1-C8)-烷基、苯基或-CO-O-(C3-C8)-环烷基；
R3为氢、卤素或(C1-C8)-烷基；
M为氢、碱金属、铵离子或等当量的碱土金属；
其中式(II)不包含式(I)染料，且
排除包含式(I)染料和式(II)染料的如下这样的混合物，其中R1为三氟甲基且R2和R3两者皆为氢；以及式(II)染料，其中R1为式(III)的基团，式(III)中R4为环己基且R5为甲基；且R2和R3两者皆为氢，并且
排除由式(I)染料和式(II)染料组成的如下这样的混合物，其中R1为三氟甲基且R2和R3两者皆为氢。
2.根据权利要求1的染料混合物，其中M为氢、钠或钾。
3.根据权利要求1或2的染料混合物，其中式(II)染料选自由式(IIa)至(IIp)的染料
其中M的定义如上。
4.根据权利要求1或2的染料混合物，其包含式(I)染料和式(IIa)染料或式(IIm)染料。
5.根据权利要求1或2的染料混合物，其由式(I)染料和式(IIa)染料或式(IIm)染料所组成。
6.根据权利要求1或2的染料混合物，其包含式(I)染料和至少两种式(II)染料，其中之一为式(IIb)染料。
7.一种制造权利要求1的染料混合物的方法，其包括将所需量的式(I)染料和一种或多种式(II)染料机械混合。
8.一种天然或合成聚酰胺纤维材料的染色和印染方法，其中使用了权利要求1的染料混合物。
9.一种天然或合成聚酰胺纤维材料的三原色染色和印染方法，其中权利要求1的染料混合物，与至少一种染蓝色的染料或染料混合物以及至少一种染黄色或染橙色的染料或染料混合物一起使用。
10.根据权利要求9的方法，其中选自式(IIIb)至(IIIh)染料的染料
其中M的定义如权利要求1中所述；
或两种或多种式(IIIb)至(IIIh)染料的混合物，用作染蓝色的染料。
11.根据权利要求9的方法，其中选自式(IVa)至(IVh)染料的染料
其中M的定义如权利要求1中所述；
或两种或多种式(IVa)至(IVh)染料的混合物，用作染黄色的或染橙色的染料。
12.根据权利要求9的方法，其中式(IVa)染料和式(IVi)染料的混合物
其中M的定义如权利要求1中所述；
作为所述染黄色的或染橙色的染料。
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| Application Number | Priority Date | Filing Date | Title |
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| US65047505P | 2005-02-07 | 2005-02-07 | |
| US60/650,475 | 2005-02-07 |
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| CN101090948A true CN101090948A (zh) | 2007-12-19 |
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| US (2) | US8323358B2 (zh) |
| EP (1) | EP1848779A1 (zh) |
| JP (1) | JP2008530261A (zh) |
| KR (1) | KR101319074B1 (zh) |
| CN (1) | CN101090948A (zh) |
| CA (1) | CA2586610C (zh) |
| TW (1) | TW200636014A (zh) |
| WO (1) | WO2006082207A1 (zh) |
| ZA (1) | ZA200703507B (zh) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102421853A (zh) * | 2009-05-14 | 2012-04-18 | 科莱恩金融(Bvi)有限公司 | 有机化合物 |
| CN107345081A (zh) * | 2017-07-24 | 2017-11-14 | 北京泛博清洁技术研究院有限公司 | 裘皮用可循环染色酸性红色染料化合物及其合成与应用方法 |
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| US7527195B2 (en) * | 2005-04-11 | 2009-05-05 | Bill Me Later, Inc. | Method and system for risk management in a transaction |
| US20060229974A1 (en) * | 2005-04-11 | 2006-10-12 | I4 Licensing Llc | Method of extending credit to at least one consumer and method of processing a transaction between a consumer and a merchant |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| EP0127579B1 (de) * | 1983-05-25 | 1987-10-07 | Ciba-Geigy Ag | Verfahren zum Trichromie-Färben oder -Bedrucken |
| DE3578870D1 (de) * | 1984-11-08 | 1990-08-30 | Ciba Geigy Ag | Verfahren zum kontinuierlichen trichromie-faerben von synthetischen polyamidmaterialien. |
| EP0387201B1 (de) * | 1989-03-10 | 1994-02-02 | Ciba-Geigy Ag | Farbstoffmischung und deren Verwendung |
| GB2236542B (en) * | 1989-10-06 | 1992-04-15 | Sandoz Ltd | Dye mixtures and their use in trichromatic dyeing processes |
| US5092906A (en) * | 1989-11-28 | 1992-03-03 | Ciba-Geigy Corporation | Anionic azo dye mixtures and their use for dyeing natural and synthetic polyamides |
| US5090964A (en) * | 1989-11-28 | 1992-02-25 | Ciba-Geigy Corporation | Red dye mixtures and their use: dyeing natural or synthetic polyamides |
| TW260694B (zh) * | 1993-10-28 | 1995-10-21 | Ciba Geigy | |
| TW314560B (zh) * | 1993-12-16 | 1997-09-01 | Ciba Sc Holding Ag | |
| ES2144305T3 (es) * | 1996-07-12 | 2000-06-01 | Ciba Sc Holding Ag | Procedimiento para la tintura o estampacion por tricromia. |
| EP0924266B1 (de) * | 1997-12-10 | 2003-01-22 | Ciba SC Holding AG | Farbstoffmischungen und deren Verwendung |
| TW472078B (en) * | 1997-12-10 | 2002-01-11 | Ciba Sc Holding Ag | A dye mixture comprising and a method for dyeing or printing natural or synthetic polyamide fiber materials |
| US6443998B1 (en) * | 2000-04-14 | 2002-09-03 | Shaw Industries, Inc. | Trichromatic fiber dyeing processes and compositions thereof |
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2006
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- 2006-02-01 WO PCT/EP2006/050601 patent/WO2006082207A1/en active Application Filing
- 2006-02-01 CA CA2586610A patent/CA2586610C/en not_active Expired - Fee Related
- 2006-02-01 KR KR1020077017181A patent/KR101319074B1/ko active IP Right Grant
- 2006-02-01 CN CNA2006800016107A patent/CN101090948A/zh active Pending
- 2006-02-01 JP JP2007553603A patent/JP2008530261A/ja not_active Withdrawn
- 2006-02-03 TW TW095103785A patent/TW200636014A/zh unknown
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102421853A (zh) * | 2009-05-14 | 2012-04-18 | 科莱恩金融(Bvi)有限公司 | 有机化合物 |
| CN102421853B (zh) * | 2009-05-14 | 2014-01-08 | 科莱恩金融(Bvi)有限公司 | 有机化合物 |
| CN107345081A (zh) * | 2017-07-24 | 2017-11-14 | 北京泛博清洁技术研究院有限公司 | 裘皮用可循环染色酸性红色染料化合物及其合成与应用方法 |
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| Publication number | Publication date |
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| JP2008530261A (ja) | 2008-08-07 |
| EP1848779A1 (en) | 2007-10-31 |
| CA2586610C (en) | 2013-06-25 |
| TW200636014A (en) | 2006-10-16 |
| KR101319074B1 (ko) | 2013-10-17 |
| US20060174426A1 (en) | 2006-08-10 |
| USRE47618E1 (en) | 2019-09-24 |
| US8323358B2 (en) | 2012-12-04 |
| CA2586610A1 (en) | 2006-08-10 |
| KR20070100764A (ko) | 2007-10-11 |
| WO2006082207A1 (en) | 2006-08-10 |
| ZA200703507B (en) | 2008-05-28 |
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