CN101074540A

CN101074540A - Underwear, pants and socks with physical antibacterial and deodorization functions and their productions

Info

Publication number: CN101074540A
Application number: CN 200710111663
Authority: CN
Inventors: 陈炎武
Original assignee: Individual
Current assignee: Individual
Priority date: 2006-08-11
Filing date: 2007-06-08
Publication date: 2007-11-21

Abstract

This invention relates to clothes and its production process, especially for the underwear, trousers, socks with the physical antibacterial and odour-off ability. This invention immerse the underwear, trousers, socks in the solution with silicone quaternary ammonium salt, borneol, spices, and then Dry, crush, wash, dry again, one antibacterial omentum of silicone quaternary ammonium in molecular level form in the underwear, trousers, socks with percentage of 0.5-5%, by which the respiratory enzymes on which the pathogenic microorganisms rely do not work, so that the microorganisms suffocate. This invention removes smell and bacteria of underwear, trousers, socks, it prevents the incidence of skin and ringworm diseases and it has no side-effect to human being.

Description

A kind of physical antibacterial eliminate the unusual smell underwear, trousers, socks and production technology thereof

Technical field

The present invention relates to a kind of production technology of producing human dressing, especially relate to underwear, trousers, socks and production technology thereof that a kind of physical antibacterial eliminates the unusual smell.

Technical background

The disclosed antibacterial deodorizing dressing of existing market, the overwhelming majority is various perfume, the spray that utilizes chemical analysis to make, be actually to carry out and cover peculiar smell with fragrance, the chemical analysis of converting bactericide and so on that has, also can play certain bactericidal action, but it is not firm that it combines with clothing, and the time that stops on clothing is short, and washing back antibacterials and fragrance promptly do not exist.

Summary of the invention

For overcoming the deficiency that prior art exists, the object of the present invention is to provide and a kind ofly utilize mechanism that physical antibacterial eliminates the unusual smell promptly: utilize the pathogenic microorganism that has with the organosilicon quaternary ammonium salt energy adsoption band negative electrical charge of positive charge to produce huge strong electrostatic interaction, the respiratory enzyme that pathogenic microorganism is depended on for existence is ineffective and underwear, trousers, socks and production technology thereof that mechanism death by suffocation is made, bacterium on the underwear that it can effectively be removed, trousers and the socks and peculiar smell, and has good permeability, strong adhesion, the function that can prevent disease of skin.

The mechanism of action of the present invention is: the underwear after physical antibacterial eliminates the unusual smell solution soaking, trousers, socks are solidificated in the stealthy antibiotic isolated netted film of the molecular level that forms the non-macroscopic view of non-medicine on the clothing after drying-squeezing-washing-drying-integer again, antibiotic nethike embrane is medical macromolecular materials, its organosilicon quaternary ammonium salt base Cationic functional groups links with article with the form of chemical bond, in the formed molecular level nethike embrane of article surface structure, not cutaneous physiological function, build-in attribute such as metabolic function and immunologic function, has stealthy dressing effect, the unique chemical bond is closed mode, can the long period rest on article surface.Organosilicon quaternary ammonium salt base Cationic functional groups, electronegative pathogenic microorganism there is powerful suction-operated, surpasses the freedom of movement of constraint pathogenic microorganism, suppress its respiratory function, ineffective and the death by suffocation of the respiratory enzyme that makes bad existence, thus play the effect that bactericidal eliminates the unusual smell.

In order to achieve the above object, technical scheme of the present invention is achieved like this: a kind of physical antibacterial eliminate the unusual smell underwear, trousers, socks and production technology thereof, it is characterized in that: with a kind of physical antibacterial underwear, trousers, socks production technology production that eliminates the unusual smell, make and remain with organosilicon quaternary ammonium salt on it, its percent retention is 0.5-5%.

Described physical antibacterial eliminate the unusual smell underwear, trousers, socks and production technology thereof, its organosilicon quaternary ammonium salt is synthetic by tertiary amine and chlorine footpath radical siloxane, and its synthetic equation is: (CH ₃O) ₃Si (CH ₃) ₃Cl+C ₁₈H ₃₇N (CH ₃) ₃→ [(CH ₃O) ₃-Si (CH ₃) ₃-N (CH ₃) ₃-C ₁₈H ₃₇] ⁺CL ^-Described chlorocarbon radical siloxane and catalyst add in the reactor → and heating → add the excessive chlorocarbon radical siloxane of tertiary amine → mensurations tertiary amine → decompression distillation → recovery separates and catalyst separation → organosilicon quaternary ammonium salt with tertiary amine → reaction generation thing; That is to say: chlorocarbon radical siloxane and catalyst are added in the reactor, after stirring and being warmed up to 120 ℃, slowly drip tertiary amine, after control reaction temperature is no more than 155 ℃, in 2～5 hours, tertiary amine is added, and 120 ℃～155 ℃ the reaction 24 hours after, tertiary amine is measured in sampling, when its free content＜0.06%/ml, carry out decompression distillation, reclaim excessive chlorocarbon radical siloxane and tertiary amine, to react and produce thing and catalyst separation, to obtain lurid oily filter body promptly: organosilicon quaternary ammonium salt, then organosilicon quaternary ammonium salt solution is put into holding vessel, static 24 hours are standby.

The described physical antibacterial underwear that eliminates the unusual smell, trousers, socks and production technology thereof, it is used to produce the physical antibacterial underwear that eliminates the unusual smell, trousers, the solution of socks is made up of organosilicon quaternary ammonium salt+borneol+spices+distilled water, its weight ratio is, organosilicon quaternary ammonium salt: borneol: spices: distilled water=3～9%+0.5～2%+0.05～0.2%+90～96%, select medical distilled water 90～96% by weight proportion for use, organosilicon quaternary ammonium salt 3～9%, borneol 0.5～2%, spices 0.05～0.2%, earlier medical distilled water is added in the blender, again organosilicon quaternary ammonium salt is slowly added in the blender, continue to stir 2 hours, after sample analysis organosilicon quaternary ammonium salt content is 0.5～9.29%, add borneol again and continue to stir 1 hour, add spices again, continue to stir 1 hour, put into the finished product holding vessel, leave standstill after 24 hours standby; Its production technology is: with underwear, perhaps underpants, perhaps socks put into the solution that leaves standstill after 24 hours soak 2 hours → squeeze out 130～160 ℃ of baking ovens of solution → put into through squeezer dry → to put into clear water again and wash → oven dry → integer → packing → finished product (physical antibacterial eliminate the unusual smell underwear, trousers, socks) again.

Advantage of the present invention is a sound construction, good permeability, and strong adhesion helps the breathing of human body skin and human body is had no side effect.The present invention keeps on article such as underwear, trousers, socks for a long time, and deodorizing effectively is antibiotic, prevents the generation of disease of skin, beriberi, the ringworm of the foot.

The specific embodiment

Chlorocarbon siloxanes and catalyst are added in the reactor by 1.4: 0.02 molar ratio ingredients, stir and slowly be warming up to 120 ℃, slowly drip mol ratio and be 1 tertiary amine.Control reaction temperature is no more than 140 ℃, in 3 hours, tertiary amine is added, and under 130 ℃ temperature, reacted 24 hours, tertiary amine is measured in sampling, contain when it is free＜0.06% the time, carry out decompression distillation, reclaim excessive chlorocarbon radical siloxane and tertiary amine, follow isolate reactant and catalyst (catalyst can use repeatedly), to obtain lurid oily liquids is organosilicon quaternary ammonium salt, then organic brick silicon quaternary ammonium salt is put into the storage jar, static 24 hours, select medical distilled water 93.96% by weight, organosilicon quaternary ammonium salt 5%, borneol 1%, spices 0.1%, earlier medical distilled water is added in the container, again organosilicon quaternary ammonium salt is slowly added temperature in proportion and close in the device, stirred 2 hours, after getting material and analyzing organosilicon quaternary ammonium salt content and be 5%, add borneol more in proportion, continue to stir 1 hour, and added spices more in proportion and continue to stir 1 hour, promptly become the physical antibacterial solution that eliminates the unusual smell, at last solution is put into the finished product holding vessel, left standstill after 24 hours standby.

According to what of clothing, select a certain amount of physical antibacterial solution that eliminates the unusual smell to put into container, after underwear or underpants or socks are put into solution and soak 2 hours, pull out to be put into and solution is extruded in the squeezer, again clothing is put in 135 ℃ the drying baker and dries, be put in the clear water again and wash, thereafter again through oven dry, integer obtains the clothing finished product that physical antibacterial eliminates the unusual smell after the flow processs such as packing, all production processes are carried out in clean level is 300,000 grades environment.

The present invention is in the mechanism of action of utilizing physical antibacterial to eliminate the unusual smell, clothings such as the underwear of making, trousers, socks, be subjected to the organosilicon quaternary ammonium salt electric field effects, the metabolic function of mycin can not be active in the cell membrane, is not that respiratory function is damaged, because membrane structure changes, it is deadly finally to cause the cell Dissolve things inside to leach, in the STU-AM of ten thousand/concentration solution, each bacterioid is survived nowhere, illustrates that solution bacterium greater than this concentration is in center of positive charge (N) fully and escapes and hide nowhere among surrounding.

The present invention can retain on the clothing after the processing for a long time, each washing clothes all can not washed off, through inventor's evidence, clothing after treatment up to wear mashed till, the function of its antibacterial deodorizing still can reach 98%, affords to use because the low modest ordinary people of price can both make.

The used catalyst of the present invention is well known to those skilled in the art, and no longer repeats here.

Claims

1, eliminate the unusual smell underwear, trousers, socks and production technology thereof of a kind of physical antibacterial is characterized in that: produce with eliminate the unusual smell underwear, trousers, socks production technology of a kind of physical antibacterial, make and remain with organosilicon quaternary ammonium salt on it, its percent retention is 0.5-5%.

2, eliminate the unusual smell underwear, trousers, socks and production technology thereof of physical antibacterial according to claim 2 is characterized in that: organosilicon quaternary ammonium salt is synthetic by tertiary amine and chlorine footpath radical siloxane, and its synthetic equation is: (CH ₃O) ₃Si (CH ₃) ₃Cl+C ₁₈H ₃₇N (CH ₃) ₃→ [(CH ₃O) ₃-Si (CH ₃) ₃-N (CH ₃) ₃-C ₁₈H ₃₇] ⁺CL ^-Described chlorocarbon radical siloxane and catalyst add in the reactor → and heating → add the excessive chlorocarbon radical siloxane of tertiary amine → mensurations tertiary amine → decompression distillation → recovery separates and catalyst separation → organosilicon quaternary ammonium salt with tertiary amine → reaction generation thing; That is to say: chlorocarbon radical siloxane and catalyst are added in the reactor, after stirring and being warmed up to 120 ℃, slowly drip tertiary amine, after control reaction temperature is no more than 155 ℃, in 2～5 hours, tertiary amine is added, and 120 ℃～155 ℃ the reaction 24 hours after, tertiary amine is measured in sampling, when its free content＜0.06%/ml, carry out decompression distillation, reclaim excessive chlorocarbon radical siloxane and tertiary amine, to react and produce thing and catalyst separation, to obtain lurid oily filter body promptly: organosilicon quaternary ammonium salt, then organosilicon quaternary ammonium salt solution is put into holding vessel, static 24 hours are standby.

3, the physical antibacterial according to claim 1 underwear that eliminates the unusual smell, trousers, socks and production technology thereof, it is characterized in that: describedly be used to produce the physical antibacterial underwear that eliminates the unusual smell, trousers, the solution of socks is made up of organosilicon quaternary ammonium salt+borneol+spices+distilled water, its weight ratio is, organosilicon quaternary ammonium salt: borneol: spices: distilled water=3～9%+0.5～2%+0.05～0.2%+90～96%, select medical distilled water 90～96% by weight proportion for use, organosilicon quaternary ammonium salt 3～9%, borneol 0.5～2%, spices 0.05～0.2%, earlier medical distilled water is added in the blender, slowly add organosilicon quaternary ammonium salt in the blender again, continue to stir 2 hours, after sample analysis organosilicon quaternary ammonium salt content is 0.5～9.29%, add borneol again and continue to stir 1 hour, add spices again, continue to stir 1 hour, put into the finished product holding vessel, leave standstill after 24 hours standby; Its production technology is: with underwear, perhaps underpants, perhaps socks put into the solution that leaves standstill after 24 hours soak 2 hours → squeeze out 130～160 ℃ of baking ovens of solution → put into through squeezer dry → to put into clear water again and wash → oven dry → integer → packing → finished product (physical antibacterial eliminate the unusual smell underwear, trousers, socks) again.