CN101003644A - 一种用于水性复膜胶的非有机硅消泡剂 - Google Patents
一种用于水性复膜胶的非有机硅消泡剂 Download PDFInfo
- Publication number
- CN101003644A CN101003644A CN 200610161576 CN200610161576A CN101003644A CN 101003644 A CN101003644 A CN 101003644A CN 200610161576 CN200610161576 CN 200610161576 CN 200610161576 A CN200610161576 A CN 200610161576A CN 101003644 A CN101003644 A CN 101003644A
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- CN
- China
- Prior art keywords
- defoamer
- oil
- antifoaming agent
- agent
- froth breaking
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002518 antifoaming agent Substances 0.000 title claims abstract description 19
- 239000003292 glue Substances 0.000 title claims abstract description 19
- 229920001296 polysiloxane Polymers 0.000 title claims description 12
- 239000002131 composite material Substances 0.000 title 1
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 16
- 239000003921 oil Substances 0.000 claims abstract description 12
- 238000003756 stirring Methods 0.000 claims abstract description 11
- 239000002480 mineral oil Substances 0.000 claims abstract description 9
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 9
- 229920000570 polyether Polymers 0.000 claims abstract description 9
- 150000001408 amides Chemical class 0.000 claims abstract description 8
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000006229 carbon black Substances 0.000 claims abstract description 4
- 238000001816 cooling Methods 0.000 claims abstract description 4
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- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 3
- 239000000194 fatty acid Substances 0.000 claims abstract description 3
- 229930195729 fatty acid Natural products 0.000 claims abstract description 3
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 3
- 239000002184 metal Substances 0.000 claims abstract description 3
- 239000011347 resin Substances 0.000 claims abstract description 3
- 229920005989 resin Polymers 0.000 claims abstract description 3
- 239000013530 defoamer Substances 0.000 claims description 42
- -1 amine hydroxybenzenes Chemical class 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 15
- 239000012752 auxiliary agent Substances 0.000 claims description 14
- 238000009413 insulation Methods 0.000 claims description 13
- 239000012939 laminating adhesive Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- 235000019198 oils Nutrition 0.000 claims description 11
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
- 239000000600 sorbitol Substances 0.000 claims description 8
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 7
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 6
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 6
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000005642 Oleic acid Substances 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 6
- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical class CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 claims description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical class 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 4
- 239000001593 sorbitan monooleate Substances 0.000 claims description 4
- 235000011069 sorbitan monooleate Nutrition 0.000 claims description 4
- 229940035049 sorbitan monooleate Drugs 0.000 claims description 4
- 239000001587 sorbitan monostearate Substances 0.000 claims description 4
- 235000011076 sorbitan monostearate Nutrition 0.000 claims description 4
- 229940035048 sorbitan monostearate Drugs 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- 239000013543 active substance Substances 0.000 claims description 3
- 238000010276 construction Methods 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 2
- 235000021355 Stearic acid Nutrition 0.000 claims description 2
- 125000002252 acyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 239000002199 base oil Substances 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 239000002283 diesel fuel Substances 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 239000012467 final product Substances 0.000 claims description 2
- 239000000446 fuel Substances 0.000 claims description 2
- 239000000295 fuel oil Substances 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims description 2
- 239000003350 kerosene Substances 0.000 claims description 2
- 239000010721 machine oil Substances 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 229960003742 phenol Drugs 0.000 claims description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
- 239000003755 preservative agent Substances 0.000 claims description 2
- 230000002335 preservative effect Effects 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 229910000077 silane Inorganic materials 0.000 claims description 2
- 239000008117 stearic acid Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 125000003944 tolyl group Chemical group 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 238000010792 warming Methods 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 7
- 239000011248 coating agent Substances 0.000 abstract description 5
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- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 7
- 230000003254 anti-foaming effect Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 5
- 239000006185 dispersion Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 230000001680 brushing effect Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- 230000009471 action Effects 0.000 description 2
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- 239000003795 chemical substances by application Substances 0.000 description 2
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- 239000006260 foam Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000010008 shearing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000032798 delamination Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 206010016766 flatulence Diseases 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
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- 229920002545 silicone oil Polymers 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Landscapes
- Paper (AREA)
- Degasification And Air Bubble Elimination (AREA)
Abstract
Description
名称 | 消泡剂A | 消泡剂B | 对比消泡剂C |
100ml分散液的重量/g | 87.5 | 88.2 | 68.4 |
液体体积(ml) | 消泡剂A | 消泡剂B | 对比消泡剂C |
200 | 起始 | 起始 | 起始 |
250 | 5′00″ | 5′16″ | 3′15″ |
300 | 8′46″ | 9′06″ | 5′47″ |
350 | 10′32″ | 11′14″ | 6′32″ |
400 | 12′48″ | 12′56″ | 7′56″ |
450 | 14′39″ | 15′10″ | 8′23″ |
500 | 15′58″ | 16′10″ | 9′54″ |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006101615761A CN100487031C (zh) | 2006-12-29 | 2006-12-29 | 一种用于水性复膜胶的非有机硅消泡剂 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2006101615761A CN100487031C (zh) | 2006-12-29 | 2006-12-29 | 一种用于水性复膜胶的非有机硅消泡剂 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101003644A true CN101003644A (zh) | 2007-07-25 |
CN100487031C CN100487031C (zh) | 2009-05-13 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2006101615761A Expired - Fee Related CN100487031C (zh) | 2006-12-29 | 2006-12-29 | 一种用于水性复膜胶的非有机硅消泡剂 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100487031C (zh) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102120108A (zh) * | 2010-11-19 | 2011-07-13 | 苏州博纳化学科技有限公司 | 一种矿物油消泡剂的制备方法 |
CN102267150A (zh) * | 2011-06-30 | 2011-12-07 | 北京展辰化工有限公司 | 一种水性木材保护剂及其制备方法 |
CN102489047A (zh) * | 2011-12-06 | 2012-06-13 | 中国铝业股份有限公司 | 一种铝土矿浮选泡沫的消泡剂 |
CN103897628A (zh) * | 2012-12-28 | 2014-07-02 | 南通市晗泰化工有限公司 | 聚醚改性有机硅消泡剂及其制备方法 |
CN103897171A (zh) * | 2012-12-28 | 2014-07-02 | 南通市晗泰化工有限公司 | 一种改性聚醚 |
CN106811144A (zh) * | 2016-12-27 | 2017-06-09 | 广东中联邦精细化工有限公司 | 一种印刷材料专用消泡剂及其制备方法 |
CN106807118A (zh) * | 2016-12-28 | 2017-06-09 | 广东中联邦精细化工有限公司 | 一种非有机硅高性能消泡剂及其制备方法 |
CN111888803A (zh) * | 2020-06-30 | 2020-11-06 | 浙江传化华洋化工有限公司 | 一种涂布用油酸酯改性有机硅消泡剂及其制备方法 |
CN112007386A (zh) * | 2020-09-01 | 2020-12-01 | 武汉思越化学技术有限公司 | 一种非有机硅消泡剂 |
CN114681958A (zh) * | 2020-12-31 | 2022-07-01 | 南京德俊新材料科技有限公司 | 一种水性涂料消泡剂及其制备方法 |
-
2006
- 2006-12-29 CN CNB2006101615761A patent/CN100487031C/zh not_active Expired - Fee Related
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102120108A (zh) * | 2010-11-19 | 2011-07-13 | 苏州博纳化学科技有限公司 | 一种矿物油消泡剂的制备方法 |
CN102267150A (zh) * | 2011-06-30 | 2011-12-07 | 北京展辰化工有限公司 | 一种水性木材保护剂及其制备方法 |
CN102267150B (zh) * | 2011-06-30 | 2013-07-31 | 北京展辰化工有限公司 | 一种水性木材保护剂及其制备方法 |
CN102489047A (zh) * | 2011-12-06 | 2012-06-13 | 中国铝业股份有限公司 | 一种铝土矿浮选泡沫的消泡剂 |
CN103897628A (zh) * | 2012-12-28 | 2014-07-02 | 南通市晗泰化工有限公司 | 聚醚改性有机硅消泡剂及其制备方法 |
CN103897171A (zh) * | 2012-12-28 | 2014-07-02 | 南通市晗泰化工有限公司 | 一种改性聚醚 |
CN106811144A (zh) * | 2016-12-27 | 2017-06-09 | 广东中联邦精细化工有限公司 | 一种印刷材料专用消泡剂及其制备方法 |
CN106807118A (zh) * | 2016-12-28 | 2017-06-09 | 广东中联邦精细化工有限公司 | 一种非有机硅高性能消泡剂及其制备方法 |
CN111888803A (zh) * | 2020-06-30 | 2020-11-06 | 浙江传化华洋化工有限公司 | 一种涂布用油酸酯改性有机硅消泡剂及其制备方法 |
CN111888803B (zh) * | 2020-06-30 | 2021-10-29 | 浙江传化华洋化工有限公司 | 一种涂布用油酸酯改性有机硅消泡剂及其制备方法 |
CN112007386A (zh) * | 2020-09-01 | 2020-12-01 | 武汉思越化学技术有限公司 | 一种非有机硅消泡剂 |
CN114681958A (zh) * | 2020-12-31 | 2022-07-01 | 南京德俊新材料科技有限公司 | 一种水性涂料消泡剂及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN100487031C (zh) | 2009-05-13 |
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Assignee: Chuzhou Sixin Science and Technology Co., Ltd. Assignor: Sixin Science & Technology Applied Inst. Co., Ltd., Nanjing City Contract fulfillment period: 2009.3.30 to 2026.12.28 Contract record no.: 2009320000673 Denomination of invention: Antifoaming agent of non-silicone in use for aqueous glue of composite film License type: Exclusive license Record date: 2009.4.23 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.3.30 TO 2026.12.28; CHANGE OF CONTRACT Name of requester: CHUZHOU SIXIN SCIENCE CO.,LTD. Effective date: 20090423 |
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Address after: Huang Jia Wei Road Nanjing City, Jiangsu province 210037 Xiaguan District No. 41-1 building B4-2 Patentee after: Sixin Science & Technology Applied Inst. Co., Ltd., Nanjing City Address before: 306, room 01, 210028 garden, 168 North Central Road, Xiaguan District, Jiangsu, Nanjing Patentee before: Sixin Science & Technology Applied Inst. Co., Ltd., Nanjing City |
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Address after: 210027, Nanjing, Jiangsu Province, Xiaguan Road, Shimonoseki District No. 199 Zijin venture special community building D11 Patentee after: Sixin Science & Technology Applied Inst. Co., Ltd., Nanjing City Address before: Huang Jia Wei Road Nanjing City, Jiangsu province 210037 Xiaguan District No. 41-1 building B4-2 Patentee before: Sixin Science & Technology Applied Inst. Co., Ltd., Nanjing City |
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Owner name: JIANGSU INSTITUTE OF FOUR NEW TECHNOLOGYAPPLICATIO Free format text: FORMER NAME: SIXIN SCIENCE + TECHNOLOGY APPLIED INST. CO., LTD., NANJING CITY |
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Address after: 210027 A22, 199 shogundong Road, Gulou District, Nanjing, Jiangsu. Patentee after: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD. Address before: 210027 Nanjing, Jiangsu, Gulou District, No. 199 shogundong Road, purple gold (Xiaguan) technology entrepreneurship special community D11 Patentee before: JIANGSU SIXIN SCIENTIFIC-TECHNOLOGICAL APPLICATION RESEARCH INSTITUTE CO., LTD. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090513 Termination date: 20171229 |
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CF01 | Termination of patent right due to non-payment of annual fee |