CN1009728B - 供陶瓷材料用的金属氧化物粉末的制备方法 - Google Patents
供陶瓷材料用的金属氧化物粉末的制备方法Info
- Publication number
- CN1009728B CN1009728B CN87100401A CN87100401A CN1009728B CN 1009728 B CN1009728 B CN 1009728B CN 87100401 A CN87100401 A CN 87100401A CN 87100401 A CN87100401 A CN 87100401A CN 1009728 B CN1009728 B CN 1009728B
- Authority
- CN
- China
- Prior art keywords
- alcoholate
- metal
- organic compound
- water
- hydrolysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000843 powder Substances 0.000 title claims abstract description 38
- 238000000034 method Methods 0.000 title claims abstract description 28
- 229910044991 metal oxide Inorganic materials 0.000 title claims abstract description 18
- 150000004706 metal oxides Chemical class 0.000 title claims abstract description 18
- 229910010293 ceramic material Inorganic materials 0.000 title abstract description 3
- 229910052751 metal Inorganic materials 0.000 claims abstract description 27
- 239000002184 metal Substances 0.000 claims abstract description 27
- 230000002378 acidificating effect Effects 0.000 claims abstract description 17
- 230000007062 hydrolysis Effects 0.000 claims abstract description 16
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 16
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 25
- 229910052726 zirconium Inorganic materials 0.000 claims description 8
- -1 zirconium alkoxides Chemical class 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 230000001476 alcoholic effect Effects 0.000 claims description 3
- 239000008240 homogeneous mixture Substances 0.000 claims description 3
- 238000010899 nucleation Methods 0.000 claims description 2
- 230000006911 nucleation Effects 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract description 8
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 25
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 12
- 150000001735 carboxylic acids Chemical class 0.000 description 11
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 11
- 229910001928 zirconium oxide Inorganic materials 0.000 description 11
- 239000000919 ceramic Substances 0.000 description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 7
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 7
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 239000005642 Oleic acid Substances 0.000 description 7
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 7
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 7
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 7
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 5
- 125000001931 aliphatic group Chemical group 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000005639 Lauric acid Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000002152 aqueous-organic solution Substances 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 238000005119 centrifugation Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 230000035800 maturation Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 238000006424 Flood reaction Methods 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000014121 butter Nutrition 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/14—Methods for preparing oxides or hydroxides in general
- C01B13/32—Methods for preparing oxides or hydroxides in general by oxidation or hydrolysis of elements or compounds in the liquid or solid state or in non-aqueous solution, e.g. sol-gel process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
- C01G25/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Nanotechnology (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Composite Materials (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Physics & Mathematics (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8600833 | 1986-01-20 | ||
| FR86.00833 | 1986-01-20 | ||
| FR8600833A FR2593166A1 (fr) | 1986-01-20 | 1986-01-20 | Procede de fabrication d'une poudre d'oxyde metallique pour materiaux ceramiques et poudre de zircone obtenue par ce procede. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN87100401A CN87100401A (zh) | 1987-08-05 |
| CN1009728B true CN1009728B (zh) | 1990-09-26 |
Family
ID=9331352
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN87100401A Expired CN1009728B (zh) | 1986-01-20 | 1987-01-20 | 供陶瓷材料用的金属氧化物粉末的制备方法 |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US4830993A (enExample) |
| EP (1) | EP0238103B1 (enExample) |
| JP (1) | JPS62171901A (enExample) |
| KR (1) | KR870007057A (enExample) |
| CN (1) | CN1009728B (enExample) |
| AT (1) | ATE74878T1 (enExample) |
| AU (1) | AU586323B2 (enExample) |
| CA (1) | CA1288573C (enExample) |
| DE (1) | DE3778187D1 (enExample) |
| DK (1) | DK26487A (enExample) |
| ES (1) | ES2031116T3 (enExample) |
| FR (1) | FR2593166A1 (enExample) |
| GR (1) | GR3004672T3 (enExample) |
| NO (1) | NO172845C (enExample) |
Families Citing this family (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1197794B (it) * | 1986-07-31 | 1988-12-06 | Montedison Spa | Procedimento per la preparazione di panticelle fini di ossidi metallici |
| BE1001832A4 (fr) * | 1987-03-26 | 1990-03-20 | Solvay | Procede pour la fabrication d'une poudre d'oxydes metalliques mixtes, et poudres d'oxydes metalliques mixtes. |
| FR2617151B1 (fr) * | 1987-06-29 | 1990-10-12 | Solvay | Procede pour la fabrication d'une poudre d'oxydes metalliques mixtes, et poudres d'oxydes metalliques mixtes |
| DE3736686A1 (de) * | 1987-10-29 | 1989-05-11 | Fraunhofer Ges Forschung | Verfahren zur herstellung von monodispersen keramischen pulvern |
| BE1001780A4 (fr) * | 1988-06-13 | 1990-03-06 | Solvay | Procede pour la fabrication de cristaux de titanate de baryum et/ou de strontium et cristaux de titanate de baryum et/ou de strontium. |
| FR2633605B1 (fr) * | 1988-07-01 | 1991-07-12 | Rhone Poulenc Chimie | Procede de preparation d'oxyde de titane et d'articles a base d'oxyde de titane |
| CA1326122C (en) * | 1988-10-05 | 1994-01-18 | Fawzy Gamaleldin Sherif | Process for forming metal oxide powders from the metal alkoxide |
| FR2639341B1 (fr) * | 1988-11-18 | 1991-02-01 | Solvay | Procede pour la fabrication d'une poudre comprenant au moins un oxyde metallique, et poudre d'oxyde de zirconium |
| BE1004293A3 (fr) * | 1989-07-20 | 1992-10-27 | Solvay | Procede de fabrication d'un composite d'oxydes metalliques, poudres composites d'oxydes metalliques et materiaux ceramiques. |
| BE1004604A4 (fr) * | 1990-11-08 | 1992-12-22 | Solvay | Procede de fabrication d'une poudre d'oxydes metalliques mixtes. |
| US5254638A (en) * | 1991-03-25 | 1993-10-19 | The Reagents Of The University Of California | Composite materials of interpenetrating inorganic and organic polymer networks |
| ES2041596B1 (es) * | 1992-03-31 | 1994-06-16 | Consejo Superior Investigacion | Procedimiento continuo de preparacion de polvos fluorescentes constituodos por una matriz oxidica dopada con colorantes organicos. |
| US5312571A (en) * | 1993-01-07 | 1994-05-17 | Norton Company | Shaped bodies and the production thereof |
| DE4337643C1 (de) * | 1993-11-04 | 1995-08-03 | Rwe Dea Ag | Verfahren zur Herstellung von in Wasser dispergierbaren Tonerdehydraten böhmitischer Struktur und Verwendung derselben |
| US7569285B2 (en) * | 1996-10-17 | 2009-08-04 | The Trustees Of Princeton University | Enhanced bonding layers on titanium materials |
| US6146767A (en) * | 1996-10-17 | 2000-11-14 | The Trustees Of Princeton University | Self-assembled organic monolayers |
| US7507483B2 (en) * | 1997-02-04 | 2009-03-24 | Jeffrey Schwartz | Enhanced bonding layers on native oxide surfaces |
| US7815963B2 (en) * | 1996-10-17 | 2010-10-19 | The Trustees Of Princeton University | Enhanced bonding layers on titanium materials |
| US7396594B2 (en) * | 2002-06-24 | 2008-07-08 | The Trustees Of Princeton University | Carrier applied coating layers |
| US6645644B1 (en) | 1996-10-17 | 2003-11-11 | The Trustees Of Princeton University | Enhanced bonding of phosphoric and phosphoric acids to oxidized substrates |
| US6265025B1 (en) | 1999-09-16 | 2001-07-24 | Lockheed Martin Energy Research Corporation | Method for the production of ultrafine particles by electrohydrodynamic micromixing |
| US20060194008A1 (en) * | 1999-09-22 | 2006-08-31 | Princeton University | Devices with multiple surface functionality |
| JP2002362909A (ja) * | 2001-06-05 | 2002-12-18 | Nippon Shokubai Co Ltd | 低原子価金属酸化物系粒子の製法 |
| JP2006517463A (ja) * | 2003-02-11 | 2006-07-27 | プリンストン ユニヴァーシティ | 表面に結合した、有機酸を用いた単分子層 |
| JP2004256377A (ja) * | 2003-02-27 | 2004-09-16 | Nippon Shokubai Co Ltd | 金属酸化物膜の製造方法 |
| US7067169B2 (en) * | 2003-06-04 | 2006-06-27 | Chemat Technology Inc. | Coated implants and methods of coating |
| CA2629600C (en) * | 2005-11-14 | 2011-11-01 | Biomet 3I, Inc. | Deposition of discrete nanoparticles on an implant surface |
| WO2009097218A1 (en) | 2008-01-28 | 2009-08-06 | Biomet 3I, Llc | Implant surface with increased hydrophilicity |
| US8641418B2 (en) * | 2010-03-29 | 2014-02-04 | Biomet 3I, Llc | Titanium nano-scale etching on an implant surface |
| WO2013142118A1 (en) | 2012-03-20 | 2013-09-26 | Biomet 3I, Llc | Surface treatment for an implant surface |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR672002A (fr) * | 1928-03-27 | 1929-12-21 | Titanium Pigment Co Inc | Composés de titane et leur procédé de fabrication |
| CA980330A (en) * | 1972-02-28 | 1975-12-23 | Continental Oil Company | Process for preparing clear bright oleaginous aluminum dispersions |
| US4501818A (en) * | 1983-07-05 | 1985-02-26 | Norton Company | Process for the preparation of ceramic powders |
| CH666965A5 (de) * | 1983-08-30 | 1988-08-31 | Cerberus Ag | Verfahren zur herstellung von materialien fuer gassensoren. |
| US4543341A (en) * | 1983-12-23 | 1985-09-24 | Massachusetts Institute Of Technology | Synthesis and processing of monosized oxide powders |
| US4605631A (en) * | 1984-03-19 | 1986-08-12 | Norton Company | Advanced preparation of ceramic powders |
| JPS60246254A (ja) * | 1984-05-16 | 1985-12-05 | 大日本インキ化学工業株式会社 | 複合セラミツクス粉末の製造法 |
| US4741894A (en) * | 1986-06-03 | 1988-05-03 | Morton Thiokol, Inc. | Method of producing halide-free metal and hydroxides |
| US4943316A (en) * | 1986-12-30 | 1990-07-24 | Hallsworth & Associates Pty. Limited | Relating to the formation of metal alkoxides and metal powders by the use of microwave radiation |
| FR2617151B1 (fr) * | 1987-06-29 | 1990-10-12 | Solvay | Procede pour la fabrication d'une poudre d'oxydes metalliques mixtes, et poudres d'oxydes metalliques mixtes |
-
1986
- 1986-01-20 FR FR8600833A patent/FR2593166A1/fr active Pending
-
1987
- 1987-01-05 CA CA000526633A patent/CA1288573C/fr not_active Expired - Fee Related
- 1987-01-06 US US07/000,767 patent/US4830993A/en not_active Expired - Fee Related
- 1987-01-07 ES ES198787200017T patent/ES2031116T3/es not_active Expired - Lifetime
- 1987-01-07 DE DE8787200017T patent/DE3778187D1/de not_active Expired - Fee Related
- 1987-01-07 AT AT87200017T patent/ATE74878T1/de active
- 1987-01-07 EP EP87200017A patent/EP0238103B1/fr not_active Expired - Lifetime
- 1987-01-10 KR KR870000144A patent/KR870007057A/ko not_active Ceased
- 1987-01-19 JP JP62009785A patent/JPS62171901A/ja active Pending
- 1987-01-19 NO NO870217A patent/NO172845C/no unknown
- 1987-01-19 DK DK026487A patent/DK26487A/da not_active Application Discontinuation
- 1987-01-20 CN CN87100401A patent/CN1009728B/zh not_active Expired
- 1987-02-26 AU AU69274/87A patent/AU586323B2/en not_active Ceased
-
1992
- 1992-05-22 GR GR920400993T patent/GR3004672T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK26487A (da) | 1987-07-21 |
| ATE74878T1 (de) | 1992-05-15 |
| CN87100401A (zh) | 1987-08-05 |
| NO172845C (no) | 1993-09-15 |
| AU6927487A (en) | 1988-09-15 |
| AU586323B2 (en) | 1989-07-06 |
| NO172845B (no) | 1993-06-07 |
| NO870217D0 (no) | 1987-01-19 |
| KR870007057A (ko) | 1987-08-14 |
| CA1288573C (fr) | 1991-09-10 |
| NO870217L (no) | 1987-07-21 |
| FR2593166A1 (fr) | 1987-07-24 |
| US4830993A (en) | 1989-05-16 |
| GR3004672T3 (enExample) | 1993-04-28 |
| EP0238103A1 (fr) | 1987-09-23 |
| JPS62171901A (ja) | 1987-07-28 |
| EP0238103B1 (fr) | 1992-04-15 |
| DK26487D0 (da) | 1987-01-19 |
| ES2031116T3 (es) | 1992-12-01 |
| DE3778187D1 (de) | 1992-05-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1009728B (zh) | 供陶瓷材料用的金属氧化物粉末的制备方法 | |
| DE3041762C2 (de) | Verfahren zur Herstellung eines Polysilans und dessen Verwendung zur Herstellung eines siliciumcarbidhaltigen keramischen Materials | |
| DE69304695T2 (de) | Verfahren zur herstellung anorganischer gele | |
| DE3688910T2 (de) | Polysilasane und verwandte verbindungen, verfahren und verwendungen. | |
| Abe et al. | Preparation of continuous zirconia fibres from polyzirconoxane synthesized by the facile one-pot reaction | |
| CN1030393A (zh) | 混合金属氧化物粉末制造方法及混合金属氧化物粉末 | |
| CH648323A5 (de) | Verfahren zur herstellung eines polysilanes. | |
| CN87102385A (zh) | 新的陶瓷、金属陶瓷或金属粉末的组合物及其生产方法 | |
| CN109890755B (zh) | 表面修饰埃洛石、表面修饰埃洛石的制造方法和催化反应 | |
| DE4127354A1 (de) | Granulat auf basis von siliciumcarbidpulver und siliciumcarbidkeramik | |
| JPH0816003B2 (ja) | 無機酸化物の製造方法 | |
| DE3751408T2 (de) | Schleifpartikel aus Aluminiumoxid/Aluminiumoxinitrid/4.Nebengruppe-Metallnitrid erhalten nach einem Sol-Gel-Verfahren. | |
| CN1088688C (zh) | 带有疏水化表面的陶瓷粉末及制备方法和用途 | |
| EP0601405B1 (de) | Polymere Borosilazane und Alumosilazana, Verfahren zu ihrer Herstellung sowie deren Verwendung | |
| DE69706496T2 (de) | Siliciumkarbidfaser mit ausgezeichneter Alkalibeständigkeit und Verfahren zu Ihrer Herstellung | |
| CN1168785C (zh) | 纳米氧化锆粉体的制备方法 | |
| DE3500962A1 (de) | Verfahren zur herstellung eines sinterkoerpers aus siliciumcarbid | |
| CN1398923A (zh) | 改性的超细氧化锌及其制备方法 | |
| DE69427457T2 (de) | Yttrium-enthaltendes Verbundpulver, gesinterter Verbundwerkstoff, und Verfahren zu dessen Herstellung | |
| JP2001031415A (ja) | 珪酸カルシウム系あるいはシリカ系多孔質成形体 | |
| CN1096420C (zh) | 稀士氧化物的生产方法及由此获得的稀土氧化物 | |
| DE4116523A1 (de) | Verfahren zur herstellung von (alpha)-al(pfeil abwaerts)2(pfeil abwaerts)o(pfeil abwaerts)3(pfeil abwaerts) | |
| JPS6374905A (ja) | 球状の金属酸化物粉末及び製造方法 | |
| CN88101743A (zh) | 一种混合金属氧化物粉末的制备方法和混合金属氧化物粉末 | |
| JPH0653564B2 (ja) | 六方晶窒化硼素の高純度化方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |