CN100589789C - Shampoo composition for removing dandruff and relieving itching - Google Patents
Shampoo composition for removing dandruff and relieving itching Download PDFInfo
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- CN100589789C CN100589789C CN200710135783A CN200710135783A CN100589789C CN 100589789 C CN100589789 C CN 100589789C CN 200710135783 A CN200710135783 A CN 200710135783A CN 200710135783 A CN200710135783 A CN 200710135783A CN 100589789 C CN100589789 C CN 100589789C
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- surfactant
- shampoo
- shampoo composite
- dandruff
- climbazole
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Abstract
The invention discloses an anti-dandruff shampoo composition for relieve itching, which comprise water, cosmetically acceptable carrier constituents suitable for hairs and the following components (byweight percent): climbazole 0. 01-1. 5%, triclosan 0. 01-0. 5%, allantion 0. 01-0. 5%.
Description
Technical field
The present invention relates to a kind of shampoo composition for removing dandruff and relieving itching.
Background technology
The dandruff and head pruritus are the bothersome problems that many adults run in daily life, and this is not only because the dandruff and head pruritus bring embarrassment to people in daily life, and because the scratching meeting that head pruritus causes further causes damage to hair and scalp.The reason that produces the dandruff is a lot, with sebum and the symbiotic microorganism of skin, particularly good fat fungus, is considered to produce the main cause of the dandruff.
Anti-dandruff dose anti-dandruff principle is exactly to suppress and kill good fat fungus on the scalp.Anti-dandruff dose that makes an addition at present in the shampoo has sulfur, salicylic acid, menthol, coal tar, ketoconazole, selenium sulfide, resorcinol, quaternary ammonium salt compound, lauroleic acid derivant, vitamin E amino-acid ester, hexachlorobenzene hydroxyquinoline, polyvinylpyrrolidone-iodine, Zinc Pyrithione (ZPT), climbazole, Octopirox etc.In most of shampoos, main anti-dandruff dose of using has Zinc Pyrithione (ZPT), Octopirox and climbazole at present, and their anti-dandruff effect mainly shows as stronger sterilization and bacteriostasis, also can resist seborrhea simultaneously.
Climbazole has another name called active climbazole, diazolones, and chemical name is 1-(4-chlorophenoxy)-3.3-dimethyl-1-(imidazoles-1-yl)-2-butanone, its molecular formula C
15H
17O
2N
2CL is called as the efficient anti-dandruff and itching-relieving agent of the second filial generation.Climbazole has unique antibacterial action, especially ovum circle scurf sporeformer, Candida albicans, bran scall Pseudomonas fungus there is inhibitory action, it can be blocked dandruff by the modes such as hydrolysis, antioxidation and decompose hydroperoxide of sterilization, inhibition lipase and produce, thereby reach the effect of effective removing scurf and relieving itching, become one of first-selected antibacterial of cosmeticses of everyday use such as medium-to-high grade shampoo, fancy soap, medicated soap, medicated toothpaste and rinse liquid.Chinese patent application number is 02113805, and publication number is 1378834, and name is called one of anti-dandruff composition in " environment protection type strong shampoo " and is climbazole, and other anti-dandruff composition is a Chinese herbal medicine Radix rumicis acetosae active component.Climbazole and Chinese herbal medicine Radix rumicis acetosae active component are as anti-dandruff dose of compound use in the above-mentioned patent; but Chinese herbal medicine extract cost height, and use climbazole separately as anti-dandruff dose, life-time service can cause anti-dandruff effect to descend; in addition, single increase climbazole consumption has certain stimulation to scalp.
Triclosan has another name called triclosan DP300, clean U.S. is new, and chemical name is 2,4,4 '-three chloro-2 '-dihydroxy diphenyl ethers, and its molecular formula is C
12H
7O
2C
13, have wide spectrum, efficiently, outstanding advantage such as polluted product, no any penetrating odor not, gram positive bacteria, gram negative bacteria, fungus, yeast, virus etc. are all had extensively, kill efficiently and inhibitory action.Application number is 02109200, and publication number is 1378834, and the main sterilization component that name is called " disinfecting, sterilizing and skin-protecting liquid " is triclosan and ethanol.Application number is 02113896, and publication number is 1387838, and name is called one of composition in " green medicinal body wash " and is triclosan.
Allantoin is called as counter-stimulus, and chemical name is an imidazole alkane-2 between the 1-urea groups, the 4-diketone, and its molecular formula is C
4H
6N
4O
3Allantoin helps to alleviate the uncomfortable and skin irritation reaction of the components of cosmetics such as surfactant, oils, acid and base material of fancy soap and abluent as counter-stimulus, eliminate allergic phenomenas such as general red, coarse, the erythema of skin.Application number is 01138372, and publication number is 1429539, and name is called one of composition in " a kind of prescription of vitamin E cream " and is allantoin.Also used allantoin in the patent " green medicinal body wash ".
In the existing shampoo composite, shampoo product with anti-dandruff and itching-relieving efficacies is existing a lot of on market, but its anti-dandruff effect is desirable mostly not to the utmost, and obvious to the stimulation damaging action of hair and scalp, and the removing scurf and relieving itching effect of the existing shampoo product in market can't satisfy the demands of consumers.
Summary of the invention
The inventor finds by a large amount of tests, together be applied in shampoo according to certain percentage by weight is composite climbazole, triclosan and three kinds of materials of allantoin, can make full use of three's characteristics, the excellent balance that reach anti-dandruff, antipruritic, reduces scalp irritation has reduced the anti-dandruff dose of zest that scalp is produced when increasing the removing scurf and relieving itching effect.
The shampoo composite that the purpose of this invention is to provide a kind of new removing scurf and relieving itching, composite by climbazole, triclosan and allantoin three, improved the effect of removing scurf and relieving itching, alleviated scalp irritation simultaneously, the excellent balance that reach anti-dandruff, antipruritic, reduces scalp irritation.
For achieving the above object, the invention provides a kind of new shampoo composition for removing dandruff and relieving itching, comprise water, be applicable to acceptable carrier component and following component by weight percentage in the cosmetic of hair: climbazole, 0.01%～1.5%; Triclosan, 0.01%～0.5%; Allantoin, 0.01%～0.5%.
Above-mentioned three kinds of composition preferred weight percent are: climbazole, 0.2%～1.0%; Triclosan, 0.05%～0.4%; Allantoin, 0.05%～0.3%.
Above-mentioned three kinds of compositions most preferably percentage by weight are: climbazole is 0.5%～0.8%, and triclosan is 0.2%～0.3%, and allantoin is 0.1%～0.2%.
The acceptable carrier component comprises surfactant and optional components in the above-mentioned cosmetic that is applicable to hair.
Surfactant comprises that one or more last acceptable and suitable parts of making up are used for the cleaning surfactant of hair, be selected from least a in anionic detersive surfactant, amphoteric surfactant and the non-ionic surface active agent, preferred anionic detersive surfactant.The content of surfactant is 5%～50% (w/w), preferred 10%～30% (w/w), most preferably 18% (w/w).
Described anion surfactant comprises following at least a: alkylsulfonate; alkyl sulfate; acylated amino salt; polyoxyethylene alkyl ether sulfate salt; alkylbenzenesulfonate; N-acyl group-N methyl taurine salt; alpha-alefinically sulfonate; the higher fatty acids sulfonated ester; the alkyl ether acetate; the polyoxyethylene alkyl ether acetate; fatty acid soaps; alkyl phosphate salt; the N-lauroyl glutamate; N-palmityl glutamate, Glu; N-lauroyl-Ethylglycocoll salt; N-Hamposyl L salt and N-myristoyl-Beta-alanine salt.
Described zwitterionic surfactant comprises following at least a: alkyl betaine-type surfactant, amido betaine type surfactant, sulfobetaines type surfactant, hydroxyl sulfo betaine type surfactant, amidosulfobetaines type surfactant, phosphoric acid betaine type surfactant, imidazolinium betaine type surfactant, alanine type surfactant and amino acid type surfactant.
Described ionic surfactant pack is drawn together following at least a: polyoxyethylene fatty acid ester, polyoxyethylene hydrogenated Oleum Ricini, polyoxyethylene dehydration Pyrusussuriensis (sugar) alcohol fatty acid ester, polyoxy fatty acid glyceride, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene glycol, fatty acid distribution of coconut oil alkane alcohol amide, sucrose fatty acid ester, alkylglycoside, alkyl glycerol base glucoside and methyl glucoside fatty acid ester.Wherein, preferred polyethylene glycol mono stearate, decyl glyceryl monolaurate, single Tridocosanoin, polyoxyethylene lauryl ether, polyoxyethylene 8 stearate ether, polyoxyethylene mountain Yu acid ether, polyoxyethylene (160) polyoxypropylene (30) glycol, alkylglycoside, or the like.
Be applicable to the optional member of shampoo composite of the present invention, comprise that polysiloxanes conditioner, cationic polymer, suspending agent, antistatic additive, antioxidant, foam booster, viscosity modifier, thickening agent, PH regulator (for example sodium citrate, citric acid, succinic acid, phosphoric acid, sodium hydroxide and sodium carbonate), antiseptic, pigment, organic solvent or diluent, pearling agent, spice, aliphatic alcohol etc. are known or be effective to additional optional components among hair nursing or the personal care product.
In the shampoo composite of above-mentioned removing scurf and relieving itching, climbazole has inhibitory action to ovum circle scurf sporeformer, Candida albicans, bran scall Pseudomonas fungus, it can be by sterilization, suppress the modes such as hydrolysis, antioxidation and decompose hydroperoxide of lipase and block the dandruff generation, thereby reach the effect of effective removing scurf and relieving itching; The triclosan sterilization mechanism is to be adsorbed in bacteria cell wall earlier, and then the penetration cell wall, with lipid, the proteins react in the Cytoplasm, produces irreversible denaturation, killing bacteria.Therefore bactericidal effect good, have quick-acting effects; Allantoin helps to alleviate the uncomfortable and skin irritation reaction of components of cosmetics such as surfactant, oils and acid, base material as counter-stimulus, eliminates allergic phenomenas such as general red, coarse, the erythema of skin.
The combination of each component of shampoo composite of above-mentioned removing scurf and relieving itching and the above-mentioned weight percentage ranges of each component, be that the inventor passes through to test in a large number to determine, combinations thereof and percentage range make the present invention strengthen the removing scurf and relieving itching effect, reduced zest simultaneously to scalp, thus the excellent balance that reaches anti-dandruff, antipruritic, reduces scalp irritation.
Shampoo composite of the present invention can by any known or other effectively be applicable to technology preparation of shampoo, the method that prepare shampoo composite of the present invention comprises conventional preparation and hybrid technology, specifically preparation method is referring to embodiment.
Shampoo composite of the present invention uses with the usual manner of cleaning and conditioning hair or skin.Its consumption can use as required flexibly.
The specific embodiment
Further specify the present invention below by embodiment and Comparative Examples, but they not limitation of the invention.Except as otherwise noted, the percentage ratio that is adopted among the present invention all is weight percentage.Preparation shampoo embodiment
Among the following embodiment, I and V are the preparation embodiment of shampoo composite of the present invention, and II, III, IV, VI, VII, VIII are Comparative Examples.
The method for preparing shampoo composite in embodiment and the Comparative Examples (seeing Table 1) suitably is as follows: join in the blending tank of strap clamp cover to whole ammonium lauryl sulfate (25%wt solution) about 1/3, under slowly stirring, be heated to about 70 ℃ to 80 ℃, form surfactant solution.In this jar, add coconut oleoyl amine monoethanol ammonium and ethylene glycol stearate, disperse.In this mixer, then add hexadecyltrimethylammonium chloride, climbazole, triclosan and allantoin and carry out fusion, add antiseptic then.Said mixture is cooled to about 25 ℃ to about 40 ℃, is collected in the finished product jar.In the finished product jar, under agitation, add remaining ammonium lauryl sulfate and other component, to guarantee the thing that is uniformly mixed.After adding all components, can in mixture, add additional viscosity modifier and pH regulator agent as required, to regulate product viscosity and pH to required degree.
The composition of the various shampoo composites of table 1.
Effect embodiment
Effect evaluation method for embodiment is: will prepare example I respectively with Comparative Example II, III, IV test specimens as a comparison, the preparation EXAMPLE V respectively with Comparative Examples VI, VII, VIII test specimens as a comparison, issue test crowd (each 50 people) contrast respectively and use, the tester all is that the dandruff is more and with the personnel of head pruritus.
According to identical method hair washing, every kind of shampoo used for two weeks when the tester used the shampoo sample.The people of half uses a kind of shampoo wherein earlier, second half people uses another kind of shampoo earlier, for example, when I and II contrast test sample, 25 people are at the last fortnight I shampoo on probation, two weeks of back are tried out II shampoo, and 25 people are at the last fortnight II shampoo on probation in addition, and two weeks of back are tried out I shampoo.The tester according to oneself feel mark, wherein antipruritic effect is that the time that begins according to head pruritus and the degree of head pruritus are marked, anti-dandruff effect is to mark according to what and size of dandruff.Standards of grading adopt 7 fens systems, and 1 minute the poorest, and 7 minutes best, and mark is high more good more.
The various shampoo composite results of use of table 2. are estimated
| Evaluation index (7 fens systems.1 minute the poorest, and 7 minutes best, and mark is high more good more) |
The little scoring.Standards of grading adopt 7 fens systems, and 1 minute the poorest, and 7 minutes best, and mark is high more good more.
The various shampoo composite results of use of table 2. are estimated
Claims (8)
1, a kind of shampoo composite of removing scurf and relieving itching comprises water, is applicable to acceptable carrier component and following component by weight percentage in the cosmetic of hair: climbazole, 0.01%～1.5%; Triclosan, 0.01%～0.5%; Allantoin, 0.01%～0.5%.
2, according to the described shampoo composite of claim 1, climbazole wherein, 0.2%～1.0%; Triclosan, 0.05%～0.4%; Allantoin, 0.05%～0.3%.
3, according to the described shampoo composite of claim 2, wherein climbazole is 0.5%～0.8%, and triclosan is 0.2%～0.3%, and allantoin is 0.1%～0.2%.
4, according to claim 1 or 2 or 3 described shampoo composites, the acceptable carrier component comprises surfactant and optional components in the described cosmetic that is applicable to hair.
5, according to the described shampoo composite of claim 4, wherein 5%～50% of surfactant comprise shampoo composite gross weight.
6, according to the described shampoo composite of claim 4, wherein 10%～30% of surfactant comprise shampoo composite gross weight.
7, according to the described shampoo composite of claim 4, wherein 18% of surfactant comprise shampoo composite gross weight.
8, according to the described shampoo composite of claim 5, wherein surfactant is at least a in anionic detersive surfactant, amphoteric surfactant and the non-ionic surface active agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710135783A CN100589789C (en) | 2007-08-16 | 2007-08-16 | Shampoo composition for removing dandruff and relieving itching |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710135783A CN100589789C (en) | 2007-08-16 | 2007-08-16 | Shampoo composition for removing dandruff and relieving itching |
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| Publication Number | Publication Date |
|---|---|
| CN101129301A CN101129301A (en) | 2008-02-27 |
| CN100589789C true CN100589789C (en) | 2010-02-17 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710135783A Expired - Fee Related CN100589789C (en) | 2007-08-16 | 2007-08-16 | Shampoo composition for removing dandruff and relieving itching |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106176337A (en) * | 2016-07-07 | 2016-12-07 | 黄献疆 | A kind of shampoo and preparation technology thereof |
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Non-Patent Citations (6)
| Title |
|---|
| 关于去头屑香波. 虞瑞尧等.《药物与人》，第11卷第3期. 1998 |
| 关于去头屑香波. 虞瑞尧等.《药物与人》，第11卷第3期. 1998 * |
| 洗发、护发产品功能添加剂. 袁立新等.《日用化学品科学》，第29卷第2期. 2006 |
| 洗发、护发产品功能添加剂. 袁立新等.《日用化学品科学》，第29卷第2期. 2006 * |
| 防脱发生发香波的配方研究. 施昌松等.《日用化学品科学》，第28卷第12期. 2005 |
| 防脱发生发香波的配方研究. 施昌松等.《日用化学品科学》，第28卷第12期. 2005 * |
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| CN101129301A (en) | 2008-02-27 |
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Effective date of registration: 20161010 Address after: Hamburg Germany No. 48 D-20253 Street Una Patentee after: BEIERSDORF AG Address before: The British Virgin Islands, Lalude town overseas business center No. 957 mailbox Patentee before: Shengfeng Group Co.,Ltd. |
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Granted publication date: 20100217 Termination date: 20200816 |
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