CN100528914C - 负载型助催化剂的制备 - Google Patents

负载型助催化剂的制备 Download PDF

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Publication number
CN100528914C
CN100528914C CNB2004800419359A CN200480041935A CN100528914C CN 100528914 C CN100528914 C CN 100528914C CN B2004800419359 A CNB2004800419359 A CN B2004800419359A CN 200480041935 A CN200480041935 A CN 200480041935A CN 100528914 C CN100528914 C CN 100528914C
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CN
China
Prior art keywords
aryl
polymerization
alkyl
group
dichloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB2004800419359A
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English (en)
Chinese (zh)
Other versions
CN1922217A (zh
Inventor
N·塞德尔
B·里希特
R·克拉策尔
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Basell Polyolefine GmbH
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Basell Polyolefine GmbH
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Publication date
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Publication of CN1922217A publication Critical patent/CN1922217A/zh
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Publication of CN100528914C publication Critical patent/CN100528914C/zh
Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
CNB2004800419359A 2003-12-23 2004-12-22 负载型助催化剂的制备 Expired - Fee Related CN100528914C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP03029734 2003-12-23
EP03029734.5 2003-12-23
US60/541,667 2004-02-03

Publications (2)

Publication Number Publication Date
CN1922217A CN1922217A (zh) 2007-02-28
CN100528914C true CN100528914C (zh) 2009-08-19

Family

ID=37779308

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2004800419359A Expired - Fee Related CN100528914C (zh) 2003-12-23 2004-12-22 负载型助催化剂的制备

Country Status (7)

Country Link
US (1) US7442667B2 (enExample)
EP (1) EP1697432B1 (enExample)
JP (1) JP4794461B2 (enExample)
KR (1) KR20060118563A (enExample)
CN (1) CN100528914C (enExample)
BR (1) BRPI0418117B1 (enExample)
WO (1) WO2005063831A2 (enExample)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8076259B2 (en) * 2007-10-04 2011-12-13 Basell Polyolefine Gmbh Process for the preparation of catalyst paste and products thereof
EP2172493A1 (en) * 2008-10-02 2010-04-07 Total Petrochemicals Research Feluy Activating supports based on perfluorinated boronic acids
CN108610441B (zh) * 2016-12-13 2021-08-03 中国石油天然气股份有限公司 负载型烯烃聚合助催化剂及其制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5414180A (en) * 1993-07-14 1995-05-09 Phillips Petroleum Company Organo-aluminoxy product and use
JP3378073B2 (ja) * 1994-02-23 2003-02-17 三菱化学株式会社 熱可塑性エラストマー重合粒子並びにその製造法
JPH07292019A (ja) * 1994-04-28 1995-11-07 Mitsubishi Chem Corp オレフィン重合用触媒およびオレフィン重合体の製造法
ES2164774T3 (es) 1994-08-03 2002-03-01 Exxonmobil Chem Patents Inc Composicion catalitica ionica soportada.
US5939347A (en) 1995-01-25 1999-08-17 W.R. Grace & Co. -Conn. Supported catalytic activator
DE19710615A1 (de) 1997-03-14 1998-09-17 Studiengesellschaft Kohle Mbh Organochrom-Verbindungen enthaltende Katalysatoren und ihre Verwendung in der Alkenpolymerisation
WO1998004570A1 (de) 1996-07-30 1998-02-05 Studiengesellschaft Kohle Mbh Organochrom-verbindungen enthaltende katalysatoren und ihre verwendung in der alkenpolymerisation
KR100536794B1 (ko) 1996-11-15 2005-12-14 바셀 테크놀로지 캄파니 비이브이 복소환 메탈로센 및 중합 촉매
CN1264869C (zh) 1997-08-21 2006-07-19 住友化学工业株式会社 改性粒子 ,用其制成的载体 ,用其制成的烯烃聚合用催化剂成分 ,用其制成的烯烃聚合用催化剂以及烯烃聚合物制备方法
DE19744102A1 (de) * 1997-10-06 1999-04-15 Targor Gmbh Katalysatorsystem
DE19757540A1 (de) 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
DE19935592A1 (de) 1999-08-02 2001-02-08 Elenac Gmbh Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation
KR20010086047A (ko) 1999-09-29 2001-09-07 고오사이 아끼오 입체규칙성 α-올레핀 중합용 촉매 및 입체규칙성α-올레핀 중합체의 제조방법
US6759361B2 (en) * 2001-06-04 2004-07-06 Equistar Chemicals, Lp Aluminoboronate activators for single-site olefin polymerization catalysts
JP2005538245A (ja) 2002-07-15 2005-12-15 バーゼル、ポリオレフィン、ゲゼルシャフト、ミット、ベシュレンクテル、ハフツング 担体を有する触媒組成物の製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
IMPROVING THE PERFORMANCE OFHETEROGENEOUSBORANE COCATALYSTS BYPRETREATMENT OF THESILICA SUPPORT WITHALKYLALUMINUM COMPOUNDS. CHAROENCHAIDET S ET AL.MACROMOLECULAR:RAPID COMMUNICATIONS,Vol.23 No.7. 2002 *

Also Published As

Publication number Publication date
EP1697432A2 (en) 2006-09-06
BRPI0418117B1 (pt) 2015-10-13
CN1922217A (zh) 2007-02-28
JP2007515531A (ja) 2007-06-14
WO2005063831A2 (en) 2005-07-14
EP1697432B1 (en) 2014-01-15
US20070149387A1 (en) 2007-06-28
JP4794461B2 (ja) 2011-10-19
WO2005063831A3 (en) 2005-12-08
KR20060118563A (ko) 2006-11-23
BRPI0418117A (pt) 2007-04-17
US7442667B2 (en) 2008-10-28

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Granted publication date: 20090819