CN100494428C - 一种提取镓的生产方法 - Google Patents
一种提取镓的生产方法 Download PDFInfo
- Publication number
- CN100494428C CN100494428C CNB200710141488XA CN200710141488A CN100494428C CN 100494428 C CN100494428 C CN 100494428C CN B200710141488X A CNB200710141488X A CN B200710141488XA CN 200710141488 A CN200710141488 A CN 200710141488A CN 100494428 C CN100494428 C CN 100494428C
- Authority
- CN
- China
- Prior art keywords
- gallium
- mother liquid
- liquid filtrate
- carbon mother
- filtrate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title claims abstract description 67
- 229910052733 gallium Inorganic materials 0.000 title claims abstract description 67
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 34
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000012141 concentrate Substances 0.000 claims abstract description 19
- 239000013067 intermediate product Substances 0.000 claims abstract description 19
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 12
- 239000010881 fly ash Substances 0.000 claims abstract description 9
- 239000003245 coal Substances 0.000 claims abstract description 8
- 229910001570 bauxite Inorganic materials 0.000 claims abstract description 7
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 6
- 239000008151 electrolyte solution Substances 0.000 claims abstract description 6
- 238000001914 filtration Methods 0.000 claims abstract description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 239000000706 filtrate Substances 0.000 claims description 59
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 52
- 229910052799 carbon Inorganic materials 0.000 claims description 52
- 239000007788 liquid Substances 0.000 claims description 51
- 238000000034 method Methods 0.000 claims description 24
- 229910052782 aluminium Inorganic materials 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 15
- 239000004411 aluminium Substances 0.000 claims description 15
- 239000003513 alkali Substances 0.000 claims description 10
- 239000012065 filter cake Substances 0.000 claims description 8
- 238000000926 separation method Methods 0.000 claims description 8
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 238000004090 dissolution Methods 0.000 claims description 5
- 238000005868 electrolysis reaction Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- 239000012452 mother liquor Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract 3
- 239000002184 metal Substances 0.000 abstract 3
- 238000003763 carbonization Methods 0.000 abstract 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 9
- 239000011734 sodium Substances 0.000 description 9
- 229910052708 sodium Inorganic materials 0.000 description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 6
- 229910001195 gallium oxide Inorganic materials 0.000 description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical compound [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
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- Electrolytic Production Of Metals (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB200710141488XA CN100494428C (zh) | 2007-08-23 | 2007-08-23 | 一种提取镓的生产方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB200710141488XA CN100494428C (zh) | 2007-08-23 | 2007-08-23 | 一种提取镓的生产方法 |
Publications (2)
Publication Number | Publication Date |
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CN101130835A CN101130835A (zh) | 2008-02-27 |
CN100494428C true CN100494428C (zh) | 2009-06-03 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CNB200710141488XA Active CN100494428C (zh) | 2007-08-23 | 2007-08-23 | 一种提取镓的生产方法 |
Country Status (1)
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CN (1) | CN100494428C (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101864525A (zh) * | 2010-04-27 | 2010-10-20 | 中国神华能源股份有限公司 | 一种由粉煤灰提取镓的方法 |
CN101838738A (zh) | 2010-04-27 | 2010-09-22 | 中国神华能源股份有限公司 | 一种由粉煤灰提取镓的方法 |
RU2507280C1 (ru) * | 2012-07-23 | 2014-02-20 | Открытое Акционерное Общество "Челябинский цинковый завод" | Способ переработки цинксодержащих металлургических отходов |
CN111778413B (zh) * | 2020-07-03 | 2022-05-20 | 神华准能资源综合开发有限公司 | 一种基于树脂法从粉煤灰中提取镓的方法 |
CN112430737A (zh) * | 2020-10-29 | 2021-03-02 | 深圳市中金岭南有色金属股份有限公司丹霞冶炼厂 | 一种从萃取沉镓渣中回收镓的方法 |
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2007
- 2007-08-23 CN CNB200710141488XA patent/CN100494428C/zh active Active
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CN101130835A (zh) | 2008-02-27 |
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Effective date of registration: 20200429 Address after: 016012 Mengxi hi tech Industrial Park, Ordos City, Inner Mongolia Autonomous Region Patentee after: INNER MONGOLIA MENGXI ORDOS ALUMINUM CO.,LTD. Address before: 016016 the Inner Mongolia Autonomous Region Wuhai city Inner Mongolia Mengxi High Tech Group Co Ltd Patentee before: INNER MONGOLIA MENG XI HIGH-TECH GROUP Co.,Ltd. |
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Denomination of invention: A production method for extracting gallium Effective date of registration: 20211229 Granted publication date: 20090603 Pledgee: Ordos Bank Co.,Ltd. Qipanjing sub branch Pledgor: INNER MONGOLIA MENGXI ORDOS ALUMINUM CO.,LTD. Registration number: Y2021150000085 |
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Date of cancellation: 20220614 Granted publication date: 20090603 Pledgee: Ordos Bank Co.,Ltd. Qipanjing sub branch Pledgor: INNER MONGOLIA MENGXI ORDOS ALUMINUM CO.,LTD. Registration number: Y2021150000085 |
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Denomination of invention: A production method for extracting gallium Effective date of registration: 20220615 Granted publication date: 20090603 Pledgee: Ordos Bank Co.,Ltd. Qipanjing sub branch Pledgor: INNER MONGOLIA MENGXI ORDOS ALUMINUM CO.,LTD. Registration number: Y2022150000053 |
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Date of cancellation: 20230508 Granted publication date: 20090603 Pledgee: Ordos Bank Co.,Ltd. Qipanjing sub branch Pledgor: INNER MONGOLIA MENGXI ORDOS ALUMINUM CO.,LTD. Registration number: Y2022150000053 |
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Denomination of invention: A Production Method for Extracting Gallium Effective date of registration: 20230509 Granted publication date: 20090603 Pledgee: Ordos Bank Co.,Ltd. Qipanjing sub branch Pledgor: INNER MONGOLIA MENGXI ORDOS ALUMINUM CO.,LTD. Registration number: Y2023150000070 |
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Granted publication date: 20090603 Pledgee: Ordos Bank Co.,Ltd. Qipanjing sub branch Pledgor: INNER MONGOLIA MENGXI ORDOS ALUMINUM CO.,LTD. Registration number: Y2023150000070 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A production method for extracting gallium Granted publication date: 20090603 Pledgee: Ordos Bank Co.,Ltd. Qipanjing sub branch Pledgor: INNER MONGOLIA MENGXI ORDOS ALUMINUM CO.,LTD. Registration number: Y2024150000046 |
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