CN100462410C - Environmental-protection soybean oil offset metal ink - Google Patents
Environmental-protection soybean oil offset metal ink Download PDFInfo
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- CN100462410C CN100462410C CNB2006100081964A CN200610008196A CN100462410C CN 100462410 C CN100462410 C CN 100462410C CN B2006100081964 A CNB2006100081964 A CN B2006100081964A CN 200610008196 A CN200610008196 A CN 200610008196A CN 100462410 C CN100462410 C CN 100462410C
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- oil
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- soybean oil
- soya
- blue
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- 239000003549 soybean oil Substances 0.000 title claims abstract description 46
- 235000012424 soybean oil Nutrition 0.000 title claims abstract description 46
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 21
- 239000002184 metal Substances 0.000 title claims abstract description 21
- 239000003921 oil Substances 0.000 claims abstract description 34
- 235000019198 oils Nutrition 0.000 claims abstract description 34
- 238000007639 printing Methods 0.000 claims abstract description 32
- 239000002904 solvent Substances 0.000 claims abstract description 23
- 239000003208 petroleum Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 21
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 17
- 239000002383 tung oil Substances 0.000 claims abstract description 17
- OIAUFEASXQPCFE-UHFFFAOYSA-N formaldehyde;1,3-xylene Chemical compound O=C.CC1=CC=CC(C)=C1 OIAUFEASXQPCFE-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920000180 alkyd Polymers 0.000 claims abstract description 14
- -1 alkyl phenol Chemical compound 0.000 claims abstract description 13
- 239000004411 aluminium Substances 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910001112 rose gold Inorganic materials 0.000 claims abstract description 6
- 239000000976 ink Substances 0.000 claims description 83
- 244000068988 Glycine max Species 0.000 claims description 26
- 235000010469 Glycine max Nutrition 0.000 claims description 26
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- 229910000906 Bronze Inorganic materials 0.000 claims description 12
- 239000010974 bronze Substances 0.000 claims description 12
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 claims description 12
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 11
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 5
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- 230000001070 adhesive effect Effects 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 3
- DUIOKRXOKLLURE-UHFFFAOYSA-N 2-octylphenol Chemical compound CCCCCCCCC1=CC=CC=C1O DUIOKRXOKLLURE-UHFFFAOYSA-N 0.000 claims description 3
- ZPUCINDJVBIVPJ-LJISPDSOSA-N cocaine Chemical compound O([C@H]1C[C@@H]2CC[C@@H](N2C)[C@H]1C(=O)OC)C(=O)C1=CC=CC=C1 ZPUCINDJVBIVPJ-LJISPDSOSA-N 0.000 claims description 3
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- 239000010940 green gold Substances 0.000 claims description 3
- 229920000642 polymer Polymers 0.000 claims description 3
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 3
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 claims 1
- 239000011814 protection agent Substances 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 5
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract description 4
- 230000004048 modification Effects 0.000 abstract description 4
- 238000012986 modification Methods 0.000 abstract description 4
- 238000009835 boiling Methods 0.000 abstract description 3
- RZJRJXONCZWCBN-UHFFFAOYSA-N octadecane Chemical compound CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 abstract description 3
- 229940038384 octadecane Drugs 0.000 abstract description 2
- 244000046052 Phaseolus vulgaris Species 0.000 abstract 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000470 constituent Substances 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000010931 gold Substances 0.000 abstract 1
- 229910052737 gold Inorganic materials 0.000 abstract 1
- 238000007645 offset printing Methods 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 18
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 15
- 239000003981 vehicle Substances 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 238000002844 melting Methods 0.000 description 8
- 239000002002 slurry Substances 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000006136 alcoholysis reaction Methods 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 238000006482 condensation reaction Methods 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
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- 238000005260 corrosion Methods 0.000 description 2
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- 239000004615 ingredient Substances 0.000 description 2
- 239000002932 luster Substances 0.000 description 2
- RFKJHQXSLBUONF-UHFFFAOYSA-N methyl blue free acid Chemical compound C1=CC(S(=O)(=O)O)=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=NC=2C=CC(=CC=2)S(O)(=O)=O)C=2C=CC(NC=3C=CC(=CC=3)S(O)(=O)=O)=CC=2)C=C1 RFKJHQXSLBUONF-UHFFFAOYSA-N 0.000 description 2
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- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 240000004528 Catalpa ovata Species 0.000 description 1
- 235000010005 Catalpa ovata Nutrition 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
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- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- TVZPLCNGKSPOJA-UHFFFAOYSA-N copper zinc Chemical compound [Cu].[Zn] TVZPLCNGKSPOJA-UHFFFAOYSA-N 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
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- 238000012360 testing method Methods 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
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Abstract
The invention relates to environmental protection type soybean oil offset printing metal printing ink. It uses china wood oil/soybean oil low molecular copolymer, alkyl phenol modification xylene formaldehyde resin, and long oil length bean oil/ isophthalic acid alkyd resin as main film forming matter which forms printing ink connecting material with soybean oil, low arene high boiling point petroleum solvent, organic alumina gel, and metallic pigment preservative agent 1-amino group octadecane. The printing ink connecting material cooperates with the metallic pigment to make blue-gold, red-gold, blue-red-gold, and aluminium ink according to material constituent weight percentage.
Description
Technical field
What the present invention relates to a kind of IPC classification C09D, C09F field is applicable to the soybean oil offset metal ink that is applied in the flexographic ink low-melting ink vehicle, especially a kind of environmental-protection soybean oil offset metal ink.
Background technology
Offset metal ink is compared with general coloured glue printing ink, has glittering metalluster, is mainly used in packing and decorating printing, to beautifying packing, improves commodity value, and immeasurable effect is arranged.But contain 35～40% high point petroleum solvent in this class printing ink, be equivalent to the over-head distillate and the solar oil tail fraction of aviation kerosene.Contain more multiring aromatic hydrocarbon substance in this petroleum solvent, wherein contain the carcinogenic composition of intensive as: 3,4-benzo pyrrole, 3-nitro benzo ketone etc., residual quantity is big on printed matter, the survival time is long, to children still is that the grownup can cause health harm, also is the environomental pollution source of printing ink production and use.
With soybean oil this not only environmental protection but also the non-renewable petroleum solvent of reproducible resource replacement, contemporary for the abundant dry vegetable oil (oleum lini, Chinese catalpa wet goods) of resource, be the eco-friendly measure that is beneficial to man.But the soybean oil that how to make semi-drying oils reaches in printing ink that dry set speed is fast, printing performance good, becomes the key of problem.In open source literature that can be for reference, as: CN1415673A, CN1410495A, CN0310748A, CN1239123A, CN1079488A and CN14720282A all never ipsilateral disclosed the autonomous innovation scheme that the contriver provides with regard to the problems referred to above, and used for reference on the current printing ink market and to have utilized the soybean oil manufacturing not only to meet environment protection requirement but also can reach printing ink accomplished fact and the research and development advantage that printing technology requires.Even if given prominence to compliance with environmental protection requirements and printing technology requirement, but be reflected in aspect ink formulations, the manufacturing process wait slowly such as main low-melting ink vehicle, auxiliary low-melting ink vehicle, soybean oil drying problem and how appropriately use have also to exist on a series of technical measures of auxiliary agent of unusual effect and update and perfect space.
Summary of the invention
For solve in the environmental-protection soybean oil offset metal ink metallic pigment such as copper bronze (copper zinc alloy), aluminium silver powder (aluminium powder) can be because of corrosion variable color obfuscation, and petroleum solvent produced pollution problem, the present invention adopts the sylvic oil of modified by alkyl phenol xylene formaldehyde resin preparation as main low-melting ink vehicle, it has water-fast, chemical-resistant resistance and electrical insulating property, and gloss greatly, can not corroding metal pigment, with other resins good consistency is arranged; Adopt long-oil-length soya-bean oil/isophthalic alkyd resin as auxiliary low-melting ink vehicle, to improve low-melting ink vehicle to the wettability of metallic pigment and the rheological property of printing ink; Form one deck molecule tunic with 1-amino octadecane on the metallic pigment surface, make air and metallic pigment isolated, thereby anti-sealing and airborne oxygen and carbon dioxide are protected its glittering metalluster to the corrosion of metallic pigment.This printing ink is main solvent with the soybean oil, only carries out the China ink adjustment with a spot of low aromatic hydrocarbons petroleum solvent (aromaticity content≤1.0%).Metallic pigment (or pigment slurry) and above-mentioned environmental-protection soybean oil offset metal ink low-melting ink vehicle are disperseed through thorough mixing, promptly become the high-quality printing ink that is applicable to sheet-fed offset machine printing expensive goods.For this reason; the present invention addresses the above problem the technical scheme of being taked: a kind of environmental-protection soybean oil offset metal ink; the low-molecular(weight)polymer (A) that comprises soybean oil and soybean oil and tung oil in the material component of its printing ink; modified by alkyl phenol xylene formaldehyde resin (B); long-oil-length soya-bean oil/isophthalic alkyd resin (C); organoaluminum gelifying agent (D); as 1 of metal protection agent-amino octadecane (E) and metallic pigment (copper bronze; aluminium-silver slurry), described printing ink can be made blue or green bronze ink respectively by the material component weight percent; red bronze ink; blue or green red bronze ink and Yin Mo.Their combination raw materials separately number by weight percentage are respectively: see Table 1
Table 1:
| Material name | Blue or green gold China ink | Red gold China ink | Blue or green red gold China ink | Yin Mo |
| Tung oil/soya-bean oil hangs down molecule multipolymer (A) | 20.7 | 20.7 | 20.7 | 20.7 |
| Modified by alkyl phenol xylene formaldehyde resin (B) | 3.8 | 3.8 | 3.8 | 3.8 |
| Long-oil-length soya-bean oil/isophthalic alkyd resin (C) | 10.9 | 10.9 | 10.9 | 10.9 |
| Refined soybean oil | 11.9 | 11.9 | 11.9 | 11.9 |
| Low aromatic hydrocarbons high point petroleum solvent | 4.7 | 4.7 | 4.7 | 4.7 |
| Organoaluminum gelifying agent (D) | 0.5 | 0.5 | 0.5 | 0.5 |
| 1-amino octadecane (E) | 0.8 | 0.8 | 0.8 | 0.8 |
| Blue or green light copper bronze | 45.0 | 31.7 | ||
| Ruddiness copper bronze | 1.7 | 46.7 | 15.0 | |
| The floated aluminium-silver slurry | 46.7 | |||
| Add up to | 100.0 | 100.0 | 100.0 | 100.0 |
The non-environmentally friendly machine of prior art ex hoc genus anne relatively, substantive distinguishing features that the present invention had and significant technical progress principal reaction are in the following aspects:
(1), the present invention uses the low molecule multipolymer (A) through tung oil modification by copolymerization soybean oil, make the soybean oil of semi-drying oil have the dried level of the oleum lini of similar siccative oil, and with the petroleum solvent that soybean oil has replaced major part to contain hazardous substance, promptly having used a small amount of high point petroleum solvent also is aromatic hydrocarbons content extremely low (≤1%).Its safety and characteristic of environmental protection are fairly obvious.
(2), the present invention hangs down molecule multipolymer (A) with the extremely low modified by alkyl phenol xylene formaldehyde resin (B) of acid number, long-oil-length soya-bean oil/isophthalic alkyd resin (C) and tung oil/soya-bean oil, the offset metal ink low-melting ink vehicle that is combined into, its water tolerance, chemical proofing, electrical insulating property are good, and, can keep the metalluster of printing ink the long period to metallic pigment non-corrosiveness almost.
(3), the present invention has selected the outstanding effect ink addition agent: a kind of chelating type organoaluminum gelifying agent (D), can improve the viscosity of printing ink and increase viscosity hardly, make that the printing ink set speeds up, the transfer printing performance is better, ink film gloss is bigger, printability is excellent; A kind of metallic pigment surface protectant 1-amino octadecane (E) makes the glittering metalluster of ink film more lasting, and the printing ink package stability obviously improves.
Description of drawings
Fig. 1 is preparation technology's schema of the environmental-protection soybean oil offset metal ink that the present invention relates to.
Embodiment
The present invention relates to a kind of environmental-protection soybean oil offset metal ink, comprise the ink vehicle that low molecule multipolymer (A), modified by alkyl phenol xylene formaldehyde resin (B), long-oil-length soya-bean oil/isophthalic alkyd resin (C) and organoaluminum gelifying agent (D), the 1-amino octadecane (E) with soybean oil and soybean oil and tung oil, low aromatic hydrocarbons petroleum solvent combination refining form in the material component of its printing ink; With blue or green light, ruddiness copper bronze and floated aluminium-silver slurry is metallic pigment.Described printing ink can be made blue or green bronze ink, red bronze ink, blue or green red bronze ink, aluminium ink respectively by the material component weight percent.Their combination raw materials separately number by weight percentage are respectively:
The blue or green red Jin Moyinmo of the red gold China ink of the blue or green gold China ink of material name
Tung oil/soya-bean oil hangs down molecule multipolymer (A) 20.7 20.7 20.7 20.7
Modified by alkyl phenol xylene formaldehyde resin (B) 3.8 3.8 3.8 3.8
Long-oil-length soya-bean oil/isophthalic alkyd resin (C) 10.9 10.9 10.9 10.9
Refined soybean oil 11.9 11.9 11.9 11.9
Low aromatic hydrocarbons high point petroleum solvent 4.7 4.7 4.7 4.7
Organoaluminum gelifying agent (D) 0.5 0.5 0.5 0.5
1-amino octadecane (E) 0.8 0.8 0.8 0.8
Blue or green light copper bronze 45.0 31.7
Ruddiness copper bronze 1.7 46.7 15.0
Floating type aluminium-silver slurry 46.7
In this example, the method for making of ink vehicle is:
(1), low molecule multipolymer (A) preparation of tung oil/soybean oil:
To make with extra care tung oil and refined soybean oil with 25: 75 ratio of weight percent, drop into reactor, with rare gas element (or N2 or CO2 gas) protection; heat up and stirring; 250～260 ℃ of insulation polymerizations, reach till 80～120mpas/25 ℃ to multipolymer viscosity, filter discharging.
(2), the preparation of xylene formaldehyde resin:
Used dimethylbenzene can be m-xylene or xylol, and the fastest with the m-xylene reaction in xylol, the relative response velocity ratio of a position, ortho position, paraxylene and formaldehyde is 11: 3: 2.Dimethylbenzene and formaldehyde are in the presence of sulfuric acid (or acetate, phosphoric acid, hydrochloric acid), and the mol ratio of dimethylbenzene and formaldehyde is 1: 1.2～1.8, generate xylene formaldehyde resin through condensation reaction.
Formulation examples:, see Table 2 in weight part
Table 2
| Material name | Ingredient proportion |
| Dimethylbenzene (first) | 38.5 |
| Formaldehyde 37% | 31.3 |
| The vitriol oil 98% | 11.6 |
| Dimethylbenzene (second batch) | 18.6 |
| Add up to: | 100.0 |
Working method:
Formaldehyde is packed in the reactor, and chuck and condenser lead to water coolant, under agitation drip the vitriol oil, keep adding first dimethylbenzene below 50 ℃, put the chuck water coolant and feed and be steam heated to that material keeps refluxing static layering 8 hours to boiling in the still.Emit spent acid, add second batch of dimethylbenzene and wash, after pH value is neutrality, wash once abundant static minute water again.After treating that water is put only, resin liquid is filtered, in reactor, dimethylbenzene is taken off in underpressure distillation, and outlet temperature is no more than 150 ℃, till absence of liquid steams, is cooled to about 80 ℃, filters the storage vessel of packing into.
Technical indicator: non-volatile part〉95%, hydroxy radical content〉4%
(3) long-oil-length soya-bean oil/isophthalic alkyd resin (C) preparation:
Formulation examples:, see Table 3 in weight part
Table 3
| Material name | Ingredient proportion |
| Refined soybean oil (one) | 52.500 |
| Industry glycerol (content 〉=96%) | 11.000 |
| Lithium hydroxide (reagent) | 0.023 |
| M-phthalic acid | 22.000 |
| Zinc oxide (industrial goods superfine) | 0.029 |
| Low aromatic hydrocarbons high point petroleum solvent | 10.000 |
| Refined soybean oil (two) | 4.500 |
Working method:
Refined soybean oil (one), industry glycerol are weighed up in the input reactor by formula ratio, start stirring, heat temperature raising.When temperature of charge to 180 ℃, add lithium hydroxide, continue to be warming up to 238-242 ℃ of insulation alcoholysis, liquid level leads to CO
2Or N
2Protection.Be incubated sampling in 30 minutes and survey the methyl alcohol tolerance, detect once every sampling in 15 minutes later on, until the transparent end-point of alcoholysis that is of 1:2 methyl alcohol (25 ℃).Stop logical CO
2Or N
2, slowly gradation adds m-phthalic acid, adds in about 1 hour.Add zinc oxide, be warming up to 268-272 ℃ with 1-1.5 hour then, liquid level leads to CO
2Or N
2Protection is incubated sampling detecting acid number and viscosity after 2 hours.When acid number reaches below the 10mg KOH/g, when viscosity reaches 3000-4000mPaS/35 ℃, will hang down aromatic hydrocarbons high point petroleum solvent and refined soybean oil (two) immediately and add, regulate viscosity to set quota, it is qualified to be.Discharging is filtered in the storage vessel.
Above-mentioned Synolac (C) technical indicator is as follows:
Viscosity 4000-6000mPaS/35 ℃
Acid number≤10mg KOH/g
Color and luster≤#10 Jia Shi look;
(4) ink vehicle preparation:
In the ink vehicle preparation, at first be with the xylene formaldehyde resin modified by alkyl phenol, alkylphenol can be selected for use right-tertiary butyl phenol (PTBP), right-special octyl phenol (POP), right-nonyl phenol (PNP), right-4-dodecylphenol (PDDP), also available dihydroxyphenyl propane carries out modification or uses the mixed phenol modification.Made modified by alkyl phenol xylene formaldehyde resin (B) hangs down molecule multipolymer (A), long-oil-length soya-bean oil/isophthalic alkyd resin (C) at soybean oil and low aromatic hydrocarbons high point petroleum solvent (aromaticity content≤1.0% with tung oil/soya-bean oil, 270 ℃～310 ℃ of boiling ranges) mix in, and add organoaluminum gelifying agent (D) and 1-amino octadecane (E) and handle, promptly make most important component-ink vehicle among the present invention.
Formulation examples:, see Table 4 in weight part
Table 4
| Material name | Example 1 | Example 2 | Example 3 |
| Low aromatic hydrocarbons high point petroleum solvent () | 4.5 | 4.5 | 4.5 |
| Refined soybean oil (one) | 1.0 | 1.0 | 1.0 |
| Xylene formaldehyde resin | 25.5 | 25.5 | 25.5 |
| Right-tertiary butyl phenol (PTBP) | 14.5 | 7.5 | |
| Right-special octyl phenol (POP) | 19.9 | 6.0 | |
| Dihydroxyphenyl propane | 2.0 | ||
| Tosic acid (catalyzer) | 0.055 | 0.055 | 0.055 |
| Long-oil-length soya-bean oil/isophthalic alkyd resin (C) | 7.0 | 7.0 | 7.0 |
| Tung oil/soya-bean oil hangs down molecule multipolymer (A) | 21.0 | 15.6 | 20.0 |
| Organoaluminum gelifying agent (D) | 1.0 | 1.0 | 1.0 |
| Low aromatic hydrocarbons height strokes a petroleum solvent (two) | 10.0 | 10.0 | 10.0 |
| Refined soybean oil (two) | 15.0 | 15.0 | 15.0 |
| 1-amino octadecane (E) | 1.5 | 1.5 | 1.5 |
| Add up to | 101.055 | 101.055 | 101.055 |
Working method:
In being furnished with the reactor of horizontal condenser, add low aromatic hydrocarbons high point petroleum solvent (), refined soybean oil (), xylene formaldehyde resin, alkylphenol or mixed phenol, catalyzer tosic acid successively, close charge cavity, open reactor → horizontal condenser → water receptor → Atmosphere System passage, with all the other valves on the reactor and water susceptor bottom valve Close All.Heat temperature raising is opened stirring, logical condenser cooling water during to 60～70 ℃ of temperature in the kettle.When temperature rises to 90 ℃, observe cases of dehydration, as it is normal to dewater, continues to heat up and carry out condensation reaction, 3 weight parts that dewater approximately continue to be warming up to 160 ℃, keep 160～170 ℃ of temperature 1 hour, stop heating, and the water in the water susceptor is emitted.Carry out remaining moisture content of vacuum removal and low-molecular material then, about 15 minutes of time.Remove negative pressure in the still, add long-oil-length soya-bean oil/isophthalic alkyd resin (C), tung oil/soya-bean oil low-molecular(weight)polymer (A) and diluted organoaluminum gelifying agent (D), in 165～170 ℃ of insulation reaction 30 minutes (annotate: organoaluminum gelifying agent and refined soybean oil Dilution ratio are 1: 4 weight part).Add low aromatic hydrocarbons high point petroleum solvent (two), remaining refined soybean oil (two) and 1-amino octadecane (E) at last, stir.Sampling detects, and the filtered while hot discharging storage vessel of packing in qualified back is the ink vehicle among the present invention.
Technical indicator is as follows:
Outward appearance: the transparent thick liquid of reddish-brown, do not have mechanical impurity, not water content;
Viscosity: 40000～80000mpas/25 ℃
Acid number :≤10mgKOH/g,
Color and luster :≤#14 Jia Shi look,
The method for making of environment-friendly type soybean offset metal ink is as follows:
Metallic pigment in the printing ink comprise: blue or green light copper bronze, ruddiness copper bronze and floated aluminium-silver slurry, copper bronze fineness 1200～1500 orders, water surface opacifying power 〉=7000cm
2/ g; Content of aluminium powder in the aluminium-silver slurry 〉=65%, screenings (45 μ m sieve aperture)≤1.0%, water surface opacifying power 〉=13500cm
2/ g.
Formulation examples:, see Table 5 in weight part
Table 5
| Material name | Blue or green bronze ink | Red bronze ink | Blue or green red bronze ink | Aluminium ink |
| Ink adhesive | 53.3 | 53.3 | 53.3 | 53.3 |
| Blue or green light copper bronze | 45.0 | 31.7 | ||
| Ruddiness copper bronze | 1.7 | 46.7 | 15.0 | |
| The floated aluminium-silver slurry | 46.7 | |||
| Add up to | 100.0 | 100.0 | 100.0 | 100.0 |
Working method:
Be weighed into ink adhesive in the batching mixing vessels, bucket is placed under the low speed butterfly paste mixer, (rotating speed 60～100rpm) slowly adds metallic pigment, stirs (about 30～40 minutes) after adding to open stirring.Sampling detects, and can pack after qualified.
Technology quality index is as follows:
Fineness: Jin Mo≤35 μ m, Yin Mo≤45 μ m
Degree of mobilization: Jin Mo 37～45mm/25 ℃, 34～44mm/25 ℃ in silver China ink
Viscosity: (400rpm, 32 ℃) 7.0～11.0
Color (scraping the sample contrast): approximate test sample
Content of vegetable oil such as soya-bean oil is 21～22% in the environmental-protection soybean oil offset metal ink that the present invention relates to, and aromaticity content is lower than 0.1%, its safety and environmental protection characteristic remarkable.Then print this product one time with this product China ink at the bottom of printing one deck earlier on the coated paper, perhaps, can reach quite satisfied effect with this product printing twice.Avoid using the strongly-acid fountain solution during printing as far as possible, preferably use alcohol edition-0 moistening liquid or slightly acidic fountain solution, space of a whole page moisture content should be controlled not too big, in case bad printing effect occurs.
Claims (3)
1. environmental-protection soybean oil offset metal ink, it is characterized in that, comprise in the material component of described printing ink that with the low molecule multipolymer (A) of tung oil/soya-bean oil be main film forming substance, modified by alkyl phenol xylene formaldehyde resin (B) and long-oil-length soya-bean oil/isophthalic alkyd resin (C) are main film forming substance; Above-mentioned filmogen is in soybean oil and low aromatic hydrocarbons high point petroleum solvent; added organoaluminum gelifying agent (D) and metal protection agent 1-amino octadecane (E); prepared the connection material that is applicable to offset metal ink; described printing ink adds metallic pigment in connecting material; can make blue or green bronze ink, red bronze ink, blue or green red bronze ink, aluminium ink respectively by the material component weight percent, their combination raw materials separately number by mass percentage are respectively:
The blue or green red Jin Moyinmo of the red gold China ink of the blue or green gold China ink of material name
Tung oil/soya-bean oil low-molecular(weight)polymer (A) 20.7 20.7 20.7 20.7
Modified by alkyl phenol xylene formaldehyde resin (B) 3.8 3.8 3.8 3.8
Long-oil-length soya-bean oil/isophthalic alkyd resin (C) 10.9 10.9 10.9 10.9
Refined soybean oil 11.9 11.9 11.9 11.9
Low aromatic hydrocarbons high point petroleum solvent 4.7 4.7 4.7 4.7
Organoaluminum gelifying agent (D) 0.5 0.5 0.5 0.5
1-amino octadecane (E) 0.8 0.8 0.8 0.8
Blue or green light copper bronze 45.0--31.7---
Ruddiness copper bronze 1.7 46.7 15.0---
Floated aluminium-silver slurry-------46.7
2. environmental-protection soybean oil offset metal ink according to claim 1 is characterized in that, described ink adhesive, and its combination raw materials is respectively by weight:
Material name example 1 example 2 examples 3
Low aromatic hydrocarbons high point petroleum solvent () 4.5 4.5 4.5
Refined soybean oil (one) 1.0 1.0 1.0
Xylene formaldehyde resin 25.5 25.5 25.5
Right-tertiary butyl phenol (PTBP) 14.5 7.5
Right-special octyl phenol (POP) 19.9 6.0
Dihydroxyphenyl propane 2.0
Tosic acid 0.055 0.055 0.055
Long-oil-length soya-bean oil/isophthalic alkyd resin (C) 7.0 7.0 7.0
Tung oil/soya-bean oil hangs down molecule multipolymer (A) 21.0 15.6 20.0
Organoaluminum gelifying agent (D) 1.0 1.0 1.0
Low aromatic hydrocarbons high point petroleum solvent (two) 10.0 10.0 10.0
Refined soybean oil (two) 15.0 15.0 15.0
1-amino octadecane (E) 1.5 1.5 1.5
Add up to 101.055 101.055 101.055
3. environmental-protection soybean oil offset metal ink according to claim 1, it is characterized in that, in the low molecule multipolymer (A) of tung oil/soya-bean oil in the described ink adhesive, the weight percent of tung oil and soya-bean oil is 25: 75, and multipolymer viscosity is 80～120mpas/25 ℃.
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| CN101250351B (en) * | 2008-03-26 | 2011-08-10 | 中国印钞造币总公司 | Soybean oil based silk-screen ink |
| JP2011137098A (en) * | 2009-12-28 | 2011-07-14 | Matsui Kagaku Kk | Metal printing ink composition and printed metal plate using the same |
| CN102352152A (en) * | 2011-09-21 | 2012-02-15 | 周湛文 | Transfer printing color mirror ink |
| CN102382513A (en) * | 2011-09-21 | 2012-03-21 | 周湛文 | Gravure mirror ink |
| CN102382512A (en) * | 2011-09-21 | 2012-03-21 | 周湛文 | Pad printing mirror ink |
| CN102408785B (en) * | 2011-12-17 | 2013-01-23 | 张家港市威迪森油墨有限公司 | Soybean-oil-based offset printing metallic ink and preparation method thereof |
| CN102558960B (en) * | 2011-12-17 | 2013-11-27 | 张家港市威迪森油墨有限公司 | Colour printing gold ink and preparation method thereof |
| CN102532991A (en) * | 2011-12-17 | 2012-07-04 | 张家港市威迪森油墨有限公司 | Soybean oil-based offset printing ink binder and preparation method thereof |
| CN116855124A (en) * | 2023-07-24 | 2023-10-10 | 浙江亚厦装饰股份有限公司 | Lithographic printing ink and preparation method thereof |
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Non-Patent Citations (2)
| Title |
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| 大豆油树脂胶印油墨. 孙臣，凌云星.印刷技术，第30期. 2004 |
| 大豆油树脂胶印油墨. 孙臣，凌云星.印刷技术，第30期. 2004 * |
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