CN100445327C - Preparation method and application of ceiba fiber in spinning and weave field - Google Patents
Preparation method and application of ceiba fiber in spinning and weave field Download PDFInfo
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- CN100445327C CN100445327C CNB2006100781410A CN200610078141A CN100445327C CN 100445327 C CN100445327 C CN 100445327C CN B2006100781410 A CNB2006100781410 A CN B2006100781410A CN 200610078141 A CN200610078141 A CN 200610078141A CN 100445327 C CN100445327 C CN 100445327C
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- bombax cotton
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Abstract
The invention relates to an assistant agent, ceiba fiber treated by the assistant agent, the treating method, the manufacturing method and application of the ceiba fiber in spinning and textile, belonging to spinning technology area. Said assistant agent comprises 30-55 parts of acrylate, 30-50 parts of amylum, 15-25 parts of polyvinyl alcohol, and 150-600 parts of water. The former treating method of said ceiba fiber is that every components of said assistant agent are mixed to form mixed solution of assistant agent; the mixed solution is heated to 60-80DEG C; ceiba fiber with 30-35 times weight of the mixed solution is added and mixed evenly; the ceiba fiber is treated in self-formation for 10-20 minutes by the water steam with 80DEG C in mixing material room so that the mixed solution of assistant agent sprays on the surface of ceiba fiber in uniformity and it is dried; the former treatment is finished. After said treatment burr is formed on the surface of ceiba fiber and cohesive force can be enhanced greatly. The ceiba fiber not only can be spun with other fiber together but also spun by itself.
Description
Technical field
The present invention relates to a kind of auxiliary agent, the bombax cotton of handling through this auxiliary agent and locate existing method, and the application of this bombax cotton in yarn fabric belong to textile technology field.
Background technology
At present, in the textile fabric raw material, green, the pure natural fiber fabric more and more is subjected to people and praises highly, China is in the textile exports ratio that increases year by year in recent years, the ratio of pure natural " vegetable fibre " fabric has occupied absolute predominance, yet because the limitation of traditional natural plant raw material own characteristic, make this series products, the added value of finished product is very low, behind in a large amount of outlets, we have not only paid a large amount of cheap labours, and have also paid a large amount of cheap starting material simultaneously, and these characteristics also make this class textile product in innovation and breakthrough significant limitation be arranged.
Cotton is purposes one of the most conventional raw material, belong to natural plant fibre, in the today of advocating green, pure natural fiber fabric, more and more be subjected to people's favor, but because of the limitation of himself characteristic and condition, as: heat retention, the flexibility, fiber glossiness and elasticity is relatively poor, non-watertight, damp proof, fiber proportion is heavier or the like, so its value-added content of product is not very high, and when cotton content is above above 50%, also to be subjected to the restriction of textile quotas during outlet.
Flaxen fiber, also belong to natural plant fibre, people still the Application and Development of making great efforts it, but its limitation in the textile fabric fabric applications is bigger, the stiff no flexibility of flaxen fiber, fiber glossiness, heat retention are relatively poor, so its product flexibility, feel, color and luster, heat retention of producing are poorer.
Bombax cotton is a kind of fiber not too known in textile industry, is in the fruit that is grown on the wild natural phant of a kind of Ochnaceae class (tree) of subtropical zone, and is very similar to cotton.Its fiber surface is smooth, glossiness is fabulous, and it is a kind of natural high hollow, ultra-fine fibre.Past since people to bombax cotton research seldom, and the kapok kind that each investigator adopted also is not quite similar, therefore every indexs such as the fiber fineness of different bibliographical informations, length are all variant.The contriver is by a large amount of collections, detection, research work, and by the different seeds in the different places of production, home and abroad are added up, contrast, study, every index of different seeds is substantially in following scope; Bombax cotton length 8～34mm, average 15～25mm.Fiber stage casing diameter 18～45 μ m, average 30～36 μ m.Linear density 0.4～0.7dtex.Wall thickness 0.5～2 μ m, fiber fineness is 0.9～3.2dtex, ultimate fibre density only is 0.29g/cm
3, and cotton fibre is 1.53g/cm
3The relative torsional stiffness of bombax cotton is 71.5 * 10
-4CN.cm
2/ tex
2, bigger than going back of glass fibre.This makes twisting efficiency reduce, and because of staple length is short, intensity is low, the surface is too smooth, cohesive force is relatively poor, therefore is difficult to spin resultant yarn with traditional Yarn spinning method again, and this is the major reason that causes never using well in the past bombax cotton.
Compare with " synthon " with some other " natural fiber ", bombax cotton is the environment-friendly materials of real pure natural.Silk cotton tree never to fertilize, agricultural chemicals, also never damaged by worms, " bombax cotton " self has unique mildew-resistant, protection against the tide, waterproof, mothproof characteristics.Degree of hollowness is up to 80%-90%, make it have very strong heat retention and the ability of keeping out the wind (heat retention is 1.8 times of duck's down), and the degree of hollowness of the up-to-date hi-tech fiber of human development has only 25%-50% (so it might become human optimal heat insulating material formed), and superfine linear density 0.4-0.7dtex only is 1/2 of a cotton fiber, is the thinnest in the world present natural superfine fiber.Its proportion is little more a lot of than cotton fibre, owing to do not absorb water under its light specific gravity, hollow ratio height, cold water state, the fabric of making of its drying in the sun that dries in the air is fast, and can be easy to carry, and for sleeping in the open night and China south moist winter, is best warming, damp proof good merchantable brand.It does not have any stimulation and detrimentally affect to human body skin, and ultra-fine, soft and smooth fiber makes that it is soft, warm, sliding suitable, comfortable, belongs to top grade in the natural fiber material, in the today of advocating natural materials the application in the textile fabric is had fabulous prospect.
But short just because of bombax cotton length, linear density is low, the smooth obvolvent rate variance of fiber surface, intensity are low, fiber proportion kicks the beam and is difficult to spin resultant yarn, so be difficult to it is carried out as real textile materials the making of textiles all the time all the time; Clearly even " can only can not make textile materials " in the macropaedia as weighting material with its qualitative description.So the application of past bombax cotton in textiles almost is blank.Once the someone utilized cotton or synthon and its blending in recent years, but can only spin coarse yarn, and its intensity is very poor, bar is done inequality, finally is difficult to form mass-producing product or commodity.Therefore, in traditional textile technology and method, bombax cotton can not further be processed always.At present, only have Japan big and spin the kapok and the cotton blended fabric of company's exploitation, its bombax cotton content is at 30%-50%, and the blending yarn count is 8
S, 10
S, 20
SCoarse yarn, and the coarse yarn below 20 of Nigeria's bombax cotton and cotton fibre 50%-50% blending; And all documents are all emphasized singly can not realize that with pure the spinning of bombax cotton bombax cotton and cotton fibre blending can not realize that bombax cotton is more than 50%.Kapok and numb blending, also not seeing has successful case, and utilizes " animal fibre " and " bombax cotton " blending resultant yarn, has no precedent record especially.
Summary of the invention
The auxiliary agent that the object of the present invention is to provide a kind of bombax cotton in the spinning pre-treatment, to use.
The spinning pre-treating process that provides a kind of bombax cotton to use above-mentioned auxiliary agent is provided.
Another purpose of the present invention provides a kind of spinning bombax cotton that above-mentioned treatment process obtains of using.
A further object of the present invention provides a kind of application of bombax cotton in yarn fabric that obtains after above-mentioned auxiliary agent is handled.
Described auxiliary agent is made of following parts by weight of component:
Acrylate 30-55
Starch 30-50
Polyvinyl alcohol 15-25
Water 150-600.
Described auxiliary agent preferably is made of following parts by weight of component:
Acrylate 35-45
Starch 35-45
Polyvinyl alcohol 20
Water 250-350.
In the above-mentioned auxiliary agent, most preferably constitute by following parts by weight of component:
Acrylate 40
Starch 40
Polyvinyl alcohol 20
The preferred butyl acrylate of described acrylate.
Described polyvinyl alcohol preferred molecular weight is the PVA of 500-1500.
Among the present invention, the spinning pre-treating process that described bombax cotton is used above-mentioned auxiliary agent is: each component of above-mentioned auxiliary agent is mixed, form the auxiliary agent mixed solution, mixed solution is heated to 60-80 ℃, adds the bombax cotton of 30-35 times of weight of mixed solution, mix, in the batch mixing room with 80 ℃ water vapour, bombax cotton is carried out semidefinite form handled 10-20 minute, make the auxiliary agent mixed solution be sprayed at bombax cotton surface and dry uniformly, pre-treatment is promptly finished.Then the yarn that is spun into is sent into drying room and under 100 ℃ temperature, carried out yarn count typing processing.
Bombax cotton is through above-mentioned processing, and the surface forms burr, and cohesive force is strengthened greatly, not only can carry out mix spinning smoothly with other fibers, can also carry out pure bombax cotton spinning separately.
Among the present invention, when bombax cotton and cotton fibre or flax fiber blending, the blending rate of bombax cotton can access 32 up to 70%--45 high grade cotton yarn.When bombax cotton and when wool blended, the blending rate of bombax cotton can obtain the high grade cotton yarn more than 32 up to 65%.When bombax cotton and rabbit hair blending, realized bombax cotton 70%, the rabbit hair 20%, polyamide fibre 10% blending rate 21--32 medium yarn; When bombax cotton and the camel hair blending, realized the high grade cotton yarn more than 32 of bombax cotton 70%, camel hair 20%, polyamide fibre 10% blending rate.When bombax cotton and regenerated fiber mix spinning, utilize the characteristics of various regenerated fibers self, with its in varing proportions with the bombax cotton mix spinning, realized bombax cotton blending rate 21--45 middle and high yarn up to 70%--95%.When bombax cotton carries out separately pure spinning, realized that the pure ratio of spinning of bombax cotton is up to 100% 21--32 medium yarns.
All kinds of yarn counts of above-mentioned spinning become all kinds of pattern cloth, denim, khaki, VELVET, woolen material, swimming dress material through weaving, and can make bedclothes, carpet, wall cloth, family's decorations house ornamentation lining, industrial lining, clothes, dress ornament; Can " knitting " make all kinds of knitting inside and outside clothing, T-shirt lining, clothes, dress ornament; Can " weave " and make all kinds of sweaters, overcoat, clothes, dress ornament.
The invention provides bombax cotton and spin preceding pretreated auxiliary agent and pretreatment process method thereof, remedied the defective that bombax cotton can't spin because of light specific gravity, easy flyings, difficult one-tenth net, slivering, realized that the bombax cotton with 100% spins as raw material.By adopting the bombax cotton spinning, realized scale production, now can be spun into 45 high grade cotton yarn, and the yarn count bar is done evenly, can produce that various (woven, knitting, braiding) textile fabric, clothes, family spin, carpet, family's decorations house ornamentation lining, industrial textile, for important foundation has been established in the deeper from now on development and use of bombax cotton, broken traditional understanding to this technical field, broken through the taboo rule of macropaedia, filled up pure bombax cotton can not spinning and bombax cotton and other fiber blend can not realize spinning world's blank of high grade cotton yarn.Bombax cotton will produce immeasurable economic benefit and social benefit in the successful Application of textile field.It will create a world, domestic emerging weaving industry, form novel industrial chain in the textile industry.
The comprehensive cost of bombax cotton is lower than the cotton cost.Develop rapidly along with industrial economy, but the soil acreage under cultivation will be fewer and feweri, and cotton fiber must be planted among the limited farmland, therefore, the minimizing that can till the land will cause the output of cotton fiber also can reduce thereupon, the planting cost of cotton can be more and more higher, and the resource of cotton will become new problem.Bombax cotton is grown on the silk cotton tree of subtropics and Yunnan Province of China, Guangxi, Guangdong, Fujian one band; if a large amount of plantation silk cotton tree in the deserted mountain of China's southern area; both increase China's area of woods, afforested mountain forest, protected vegetation waterborne; saved limited farmland; can enliven poor mountain area economy again; increase the hill farmer income, once plantation is lifelong is benefited.
Simultaneously, by bombax cotton provided by the invention when making fabric, the ratio of bombax cotton surpasses 51%, and do not change textile fibrous property, therefore, do not limited by the textile quotas of the U.S. and European Union, the kapok textile exports can be country and exchanges a large amount of foreign exchanges for, and this also will make the textile industry that is subjected to quota " puzzlement " be benefited.
Description of drawings:
Fig. 1 is the insulation rate and square metre weight relationships of kapok fabric and common fabric
Fig. 2 is the air penetrability and square metre weight relationships of kapok fabric and common fabric
Embodiment:
Embodiment 1-6
| Catalogue | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 |
| Butyl acrylate/g | 30 | 50 | 35 | 45 | 40 | 30 |
| Starch/g | 50 | 35 | 45 | 40 | 30 | 40 |
| Polyvinyl alcohol/g | 18 (molecular weight 600) | 22 (molecular weight 1500) | 15 (molecular weight 800) | 25 (molecular weight 1000) | 20 (molecular weight 1200) | 20 (molecular weight 500) |
| Water/ |
350 | 300 | 150 | 600 | 250 | 200 |
| Heating temperature ℃ | 60 | 65 | 70 | 75 | 80 | 80 |
| Bombax cotton/Kg | 13.5 | 12.2 | 8.6 | 21.3 | 11.2 | 10.2 |
| The semidefinite form treatment time | 15 | 20 | 20 | 10 | 15 | 20 |
Each component of above-mentioned auxiliary agent is mixed, form the auxiliary agent mixed solution, mixed solution is heated to relevant temperature, the bombax cotton that adds certainweight, mix, in the batch mixing room,, bombax cotton is carried out the semidefinite form of corresponding time and handle with 80 ℃ water vapour, make the auxiliary agent mixed solution be sprayed at bombax cotton surface and dry uniformly, pre-treatment is promptly finished.
Bombax cotton is through above-mentioned processing, and the surface forms burr, and cohesive force is strengthened greatly, not only can carry out mix spinning smoothly with other fibers, can also carry out pure bombax cotton spinning separately.The yarn that is spun into is sent into drying room under 100 ℃ temperature, carry out yarn count typing processing.
Bombax cotton and the cotton fibriia blending of using embodiment 1 to obtain, the blending rate of bombax cotton obtains 32 up to 70%--45 high grade cotton yarns.
The bombax cotton that use embodiment 2 obtains and wool blended, the blending rate of bombax cotton can obtain the high grade cotton yarn more than 32 up to 65%.
The bombax cotton and the rabbit hair blending that use embodiment 3 to obtain have obtained bombax cotton 70%, the rabbit hair 20%, polyamide fibre 10% blending rate 21--32 medium yarns.
Bombax cotton and the camel hair blending of using embodiment 4 to obtain have obtained bombax cotton 70%, camel hair 20%, polyamide fibre 10% blending rate 32--45 high grade cotton yarns.
The bombax cotton and the regenerated fiber mix spinning that use embodiment 5 to obtain have obtained bombax cotton blending rate 21 up to 70%--95%--45 middle and high yarns.
The pure bombax cotton spinning of using embodiment 6 to obtain has obtained bombax cotton up to 100% 21--32 medium yarns.
Embodiment 7
The bombax cotton that embodiment 2-6 is obtained under equal conditions spins, tests, and calculating mean value, the result is as follows: 1, strength test contrast:
Cotton yarn brute force is＞8.8CN/tex
Kapok yarn brute force is＞8.2CN/tex
2, yarn count strip dry uniformity variant coefficient test comparison:
Cotton strip dry uniformity variant coefficient (CV%) 11.0
Kapok strip dry uniformity variant coefficient (CV%) 11.24
3, kapok yarn and cotton yarn diameter test comparison:
Cotton 0.357mm
Kapok 0.371mm
Embodiment 8
The bombax cotton that Application Example 1 obtains is made underwear under the same conditions, compares with the cotton underwear, and data are as follows:
1, the cotton cold-proof underwear detects data:
Heat transfer coefficient (w/m
2. ℃) 3.3
Clo value (CLO) 0.17
Warming rate 24
2, the kapok cold-proof underwear detects data:
Heat transfer coefficient (w/m
2. ℃) 6.024
Clo value (CLO) 1.072
Warming rate 43.99
Embodiment 9
Lining and four seasons clothes made from bombax cotton in a word, its products characteristics is light, soft, comfortable, smooth, bright-coloured, antistatic, easy entanglement not, moisture absorption, not mouldly do not eat into, and acid and alkali-resistance under the normal temperature is real green natural environmentfriendly products.
Be bombax cotton and cotton and other fiber every detection data in making all kinds of cold-proof underwears below, for reference:
China's industry standard regulation, the warming rate of thermal cloth must not be less than 30%.And the serial kapok high-efficiency thermal protection underwear of our company's exploitation has good warmth retention effect, warming rate mean value about 50%, is better than cashmere, eider down.Thermal-conduction resistance is higher more than 20% than cotton product, and thermal-convection resistance is 2-3 a times of cotton product, and warming rate is advanced in the world.Moisture vapor transmission, softness, comfort level are better than all-cotton fabric; Have soft-touch, warm (the similar cashmere of sense of touch difference and the woolen difference of ultra-fine kapok and textile product) moisture absorption, lead wet, elasticity, comfortable several big characteristics:
1. insulation rate is (according to standard GB 1048-89, utilize YG606 type plate type fabric heat-insulation instrument test) mainly reflect the heat-conductive characteristic of lining, compare with polyester-cotton blend product with cotton as can be seen, the insulation rate of kapok cold-proof underwear obviously improves, and this illustrates its conduction heat office.(see figure 1)
2. Air permenbility reflects the performance of keeping out the wind (the present domestic heat loss through convection performance or the performance of keeping out the wind that does not have instrument to examine lining specially of lining, weigh the performance of keeping out the wind of lining herein with Y561 type air permeability tester), Air permenbility is bigger, and the heat loss through convection amount is bigger, and the performance of keeping out the wind is poor more.Obviously, the heat loss through convection amount of kapok cold-proof underwear is starkly lower than cotton and polyester-cotton blend control sample, illustrates that the performance of keeping out the wind is fine.
3. moisture vapor transmission is the direct tolerance of the wet comfortableness of fabric, and the moisture vapor transmission of kapok and all-cotton fabric is suitable as can be seen for data from table, can illustrate also that theoretically two class formations are identical, water absorbability is identical, and the moisture vapor transmission of lining or wet comfortableness are suitable.So kapok and all-cotton fabric have similarly wet comfortableness, will never feel vexed steaming when wearing.Some people likes the wet comfortableness with Air permenbility reflection fabric, and in fact Air permenbility can not be directly corresponding with wet comfortableness, and for example a lot of polyester piece good Air permenbilities are high but wet comfortableness still is bad, and the people can feel vexed steaming.The opposite excessive warming effect of Air permenbility then can reduce.
Be that (in the serial kapok high-efficiency thermal protection underwear wherein two kinds) salient features with identical in structure cotton and polyester-cotton blend product is compared below:
The test index contrast table
Claims (9)
1, a kind of auxiliary agent is characterized in that, described auxiliary agent is made of following parts by weight of component:
Acrylate 30-55
Starch 30-50
Polyvinyl alcohol 15-25
Water 150-600.
2, auxiliary agent according to claim 1 is characterized in that, described auxiliary agent is made of following parts by weight of component:
Acrylate 35-45
Starch 35-45
Polyvinyl alcohol 20
Water 250-350.
3, auxiliary agent according to claim 2 is characterized in that, described auxiliary agent is made of following parts by weight of component:
Acrylate 40
Starch 40
Polyvinyl alcohol 20
Water 300.
According to claim 1,2 or 3 described auxiliary agents, it is characterized in that 4, described acrylate is a butyl acrylate.
According to claim 1,2 or 3 described auxiliary agents, it is characterized in that 5, described polyvinyl alcohol molecular weight is 500-1500.
6, a kind of application rights requires the bombax cotton pre-treating process of any described auxiliary agent of 1-5, it is characterized in that, described pre-treating process is: each component of auxiliary agent is mixed, form the auxiliary agent mixed solution, mixed solution is heated to 60-80 ℃, the bombax cotton that adds 30-35 times of weight of mixed solution, mix, in the batch mixing room with 80 ℃ water vapour, bombax cotton is carried out semidefinite form to be handled 10-20 minute, make the auxiliary agent mixed solution be sprayed at bombax cotton surface and dry uniformly, pre-treatment is promptly finished.
7, a kind of application rights requires the bombax cotton that 6 described treatment processs obtain, and it is characterized in that, described bombax cotton is through pre-treatment, and the surface forms burr, can carry out mix spinning smoothly with other fibers.
8, a kind of application rights requires the bombax cotton that 6 described treatment processs obtain, and it is characterized in that, described bombax cotton is through pre-treatment, and the surface forms burr, can carry out pure bombax cotton spinning separately.
9, claim 7 or 8 application of described bombax cotton in yarn fabric.
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|---|---|---|---|
| CNB2006100781410A CN100445327C (en) | 2005-12-31 | 2006-04-26 | Preparation method and application of ceiba fiber in spinning and weave field |
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| CN200510135675.8 | 2005-12-31 | ||
| CNB2006100781410A CN100445327C (en) | 2005-12-31 | 2006-04-26 | Preparation method and application of ceiba fiber in spinning and weave field |
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| CN100445327C true CN100445327C (en) | 2008-12-24 |
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Cited By (1)
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| CN102154752A (en) * | 2011-04-11 | 2011-08-17 | 南通纬纶纺织有限公司 | Ecological bombax cotton fiber and colored fiber blended knitting yarn and production technology thereof |
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| CN102277731B (en) * | 2011-06-07 | 2013-03-06 | 东华大学 | Friction-increasing and weighting agent and its preparation method and use in improvement of kapok fiber spinning performances |
| CN102586974A (en) * | 2012-03-16 | 2012-07-18 | 江阴市润兴纺织有限公司 | Kapok spinning processing method |
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| CN106835405A (en) * | 2016-11-14 | 2017-06-13 | 安徽省天助纺织科技有限公司 | A kind of mould proof deodorant towel containing bombax cotton regeneration cotton yarn textile material and preparation method thereof |
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