CN100437857C - Machining technique of silver/copper double composite strip material - Google Patents

Machining technique of silver/copper double composite strip material Download PDF

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CN100437857C
CN100437857C CNB200610123758XA CN200610123758A CN100437857C CN 100437857 C CN100437857 C CN 100437857C CN B200610123758X A CNB200610123758X A CN B200610123758XA CN 200610123758 A CN200610123758 A CN 200610123758A CN 100437857 C CN100437857 C CN 100437857C
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silver
composite strip
copper
metal oxide
band
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CN1971789A (en
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林羽锦
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SINO-1 ELECTRICAL CONTACTS ALLOY CO LTD
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Abstract

This invention relates to electricity materials technique field and to one silve to copper double compound band process method, which comprises the following steps: firstly grinding the silver metal oxidation with one thin siver band to form silver metal oxidation or silver compound materials; grinding silver metal oxidation and silver compound band through its top silver band layer and copper band heat grinding through heat compound band for annealing.

Description

A kind of processing technology of silver/copper double composite strip material
Technical field:
The present invention relates to the electric contact material technical field, refer in particular to a kind of processing technology of silver/copper double composite strip material.
Background technology:
Electric contact is the contact element of appliance switch, instrument and meter, it mainly bears the effect of connection and breaking current, it has decisive role to the safe operation of electrical equipment, in the material of producing electric contact, siluer metal oxide (as siller tin oxide AgSnO2, Agcdo AgCdO) material is owing to have anti-preferably electrical wear, resistance fusion welding and conductivity are used widely in low-voltage electrical apparatus.The two-sided composite material of silver tin/copper oxide is the new function material that is combined by special combination process by siluer metal oxide and two kinds of materials of copper, it had both kept the main characteristic of siluer metal oxide and base material copper, can obtain the not available performance of stock blend by complex effect again, silver, the anti-electrical wear of performance silver contact had both been saved, advantage such as resistance fusion welding and conductivity, can improve mechanical performance again, be an important joint silver technology.
Yet the bond strength of siluer metal oxide and copper is relatively poor, therefore, need have corresponding special process to process just and can make both strong bonded together, complements each other, and takes into account each other.At present domestic aspect composite material primary study the bar of yellow gold and oxygen-free copper compound, face is compound, there are indivedual factories testing the compound of siluer metal oxide and copper, the mode of production is for welding the edge of the siluer metal oxide plate ingot of 20mm and thick copper ingot two materials with argon arc welding earlier, then with heavy reduction rolling under the roughing mill, again through diffusion annealing repeatedly, the rolling combination that reaches different metal.This mode of production can not large-scale production, can only process the very little band of a segment length at every turn, utilizes this kind technology not process continuously, and production efficiency is extremely low.And along with the extensive use of electronic product, the demand of electric contact also increases day by day, and market prospects are very optimistic, but at present domestic production technology production efficiency is extremely low, the band poor bonding strength, and compound fastness is poor, and its production cost is high, can not satisfy the demand of existing market far away.
Summary of the invention:
The objective of the invention is to provide a kind of processing technology of silver/copper double composite strip material at the deficiencies in the prior art, this kind processing technology can process the silver/copper double composite strip material of rolling continuously, realize large-scale production, the production efficiency height, production cost is low, and the silver/copper double composite strip material bond strength height that is processed, compound fastness are good.
For achieving the above object, the present invention is achieved by the following technical solutions: it may further comprise the steps:
A, respectively silver band and siluer metal oxide band are carried out surface clean, remove its surperficial greasy dirt, oxide, again silver band and siluer metal oxide band are sent into a compound siluer metal oxide/silver-colored composite strip that becomes of hot-rolling mill hot rolling together, heating-up temperature is 300~800 ℃, tape running speed is 1.0~5.0m/min, band unwinding and rewinding tension range is 1~200KN, roll-force is 10~120 tons, the protective gas that shields is arranged in the thermal treatment zone, then again siluer metal oxide/silver-colored composite strip is annealed, annealing temperature is 400~600 ℃, annealing time is 0.2~1 hour, again it is sent into finishing mill after the annealing and carry out finish rolling system, anneal once more after the finish rolling system, annealing temperature is 40~600 ℃, annealing time is 0.2~1 hour, once more it being sent into finishing mill after the annealing, to carry out finished product rolling, at last it sent into banding machine and carry out itemize, and it is standby to make siluer metal oxide/silver-colored composite strip finished product;
B, copper strips is sent into groove milling equipment, on the upper and lower surfaces of copper strips, all mill out one with groove that siluer metal oxide/silver-colored composite strip is complementary;
C, respectively copper strips and the made siluer metal oxide/silver-colored composite strip two junction of A step are carried out surface clean, remove its surperficial greasy dirt, oxide;
D, copper strips after cleaning and two siluer metal oxide/silver-colored composite strips are sent into hot-rolling mill, and to carry out hot rolling compound, two siluer metal oxide/silver-colored composite strips lay respectively at the upper and lower surfaces of copper strips, siluer metal oxide/silver-colored composite strip is that the one side of silver and the bottom surface of copper strips groove are faying face, copper strips and siluer metal oxide/silver-colored composite strip heats through the positioner location and the spacing thermal treatment zone that enters, tape running speed is 1.0~5.0m/min, band unwinding and rewinding tension range is 1~200KN, heating-up temperature is 300~800 ℃, the reducing gas that shields is arranged in the thermal treatment zone, then the roll that is admitted on the hot-rolling mill of siluer metal oxide/silver-colored composite strip and copper strips is rolled, roll-force is 10~120 tons, two siluer metal oxide/silver-colored composite strips are embedded in the groove on copper strips two sides before entering roll respectively, copper strips and siluer metal oxide/silver-colored composite strip becomes silver/copper double composite strip material after rolling, at last this silver/copper double composite strip material is received to rolling;
E, silver/copper double composite strip material is annealed, annealing temperature is 400~600 ℃, and annealing time is 0.2~1 hour;
F, silver/copper double composite strip material is carried out surface clean, polishing and oven dry;
G, again silver/copper double composite strip material is sent into finishing mill and be rolled;
H, silver/copper double composite strip material is sent into banding machine at last and carried out itemize;
I, finished product.
Described groove milling equipment comprises that unreeling structure, rolling-up mechanism, three go up milling cutter, three following milling cutters and copper strips is positioned locating piece with spacing alignment, the described milling cutter of going up is positioned at the copper strips top, following milling cutter is positioned at the copper strips below, last milling cutter and following milling cutter cooperate in pairs, and the edge of a knife width of first, second, third pair of milling cutter is that broadening gradually is to requiring size.
Order is equipped with unreeling structure, band is positioned and spacing positioner, the thermal treatment zone, roll, rolling-up mechanism on the described hot-rolling mill, the described thermal treatment zone is the high-frequency electrical heating furnace, described positioner is two groups of locating wheels that limit band position and its position of scalable that are distributed in the band both sides, and every group of locating wheel has three.
Described locating piece is provided with big square hole and two confession small square holes that siluer metal oxide/silver-colored composite strip passes that a confession copper strips passes, two small square holes lay respectively at the both sides of big square hole, and the position of the groove of two small square holes and copper strips upper and lower surface is complementary.
Because the bond strength of siluer metal oxide and copper is relatively poor, and silver and copper can combine well, therefore, for overcoming this defective, the present invention is compound with siluer metal oxide band and thin silver band hot rolling earlier, forms siluer metal oxide/silver-colored composite strip, and siluer metal oxide/silver-colored composite strip is compound by silver-colored belt and copper strip hot rolling on it, the composite strip of producing had so both been saved silver, had good bond strength again; Described siluer metal oxide comprises siller tin oxide AgSnO2, Agcdo AgCdO etc., in addition, the present invention also all mills out a groove that can embed siluer metal oxide/silver-colored composite strip on the two sides of copper strips, before hot rolling is compound, earlier siluer metal oxide/silver-colored composite strip and copper strips are carried out surface clean, especially will be with the oxide on both faying faces, greasy dirts etc. are removed clean, strip surface oil thing, oxide is a key factor that influences its bond strength, therefore, strip surface oil thing, oxide, dirt must clean up, then siluer metal oxide/silver-colored composite strip and copper strips together being sent into hot-rolling mill, to carry out hot rolling compound again, positioner location on the hot-rolling mill guarantees that band is not offset in the conveying and the operation of rolling, keep straight line to carry band, siluer metal oxide/silver-colored composite strip is embedded before entering roll in the groove on copper strips two sides, enter roll again and be rolled and become silver/copper double composite strip material; Band on hot-rolling mill be earlier through the high-frequency electrical heating furnace heating to send into mill milling more compound, and band is carried continuously and is rolling, therefore, technology of the present invention can realize the continuous processing and the production of silver/copper double composite strip material, band after hot rolling is compound is again through following process such as annealing, to strengthen the atom diffusion at different metal interface, strengthen compound fastness, carry out finish rolling again and be made for the composite strip finished product.In sum, technology of the present invention is simple, can realize continuous production, the production efficiency height, and production cost is low, and the bond strength of the silver/copper double composite strip material that is processed is higher, and compound fastness is good.
Description of drawings:
Accompanying drawing 1 is the process chart of making siller tin oxide of the present invention/silver;
Accompanying drawing 2 is the process chart of making silver/copper double composite strip material of the present invention;
Accompanying drawing 3 is the structural representation of groove milling equipment of the present invention;
Accompanying drawing 4 is that copper strips of the present invention descends the structural representation after the two sides mills out groove thereon;
Accompanying drawing 5 is the structural representation of locating piece of the present invention;
Accompanying drawing 6 is the structural representation of hot-rolling mill of the present invention;
Accompanying drawing 7 is the structural representation of positioner of the present invention.
Embodiment:
For further prompting the present invention, be specifically described below in conjunction with accompanying drawing 1,2,3,4,5,6,7.
Copper strips 6 of the present invention is copper or copper alloy belt, has thin silver between siller tin oxide band 16 on the silver/copper double composite strip material of being produced and the copper strips 6 and is with 17 excessive layers, and its processing technology is as follows:
A, respectively to silver be with 17 and siller tin oxide band 16 band carry out surface clean, remove its surperficial greasy dirt, oxide, again silver is with 17 and siller tin oxide band 16 send into a compound siller tin oxide/silver-colored composite strip 15 that becomes of hot-rolling mill hot rolling together, the compound heating-up temperature of hot rolling is 300~800 ℃, tape running speed is 1.0~5.0m/min, roll-force is 10~120 tons, 10 have the protective gas that shields in the thermal treatment zone, then again siller tin oxide/silver-colored composite strip 15 is placed in the pit-type furnace and anneals, annealing temperature is 400~600 ℃, annealing time is 0.2~1 hour, again it is sent into finishing mill after the annealing and carry out finish rolling system, be placed in the pit-type furnace once more after the finish rolling system and anneal, annealing temperature is 400~600 ℃, and annealing time is 0.2~1 hour, and once more it being sent into finishing mill after the annealing, to carry out finished product rolling, at last it is sent into banding machine and carry out itemize, make siller tin oxide/silver-colored composite strip 15 finished products;
B, copper strips 6 is sent into groove milling equipment, on the upper and lower surfaces of copper strips 6, all mill out one with groove 9 that siller tin oxide/silver-colored composite strip 15 is complementary;
C, respectively copper strips 6 and the made siller tin oxide/silver-colored composite strip 15 of A step are carried out surface clean, remove its surperficial greasy dirt, oxide;
D, copper strips 6 after cleaning and two siller tin oxide/silver-colored composite strips 15 are sent into hot-rolling mill, and to carry out hot rolling compound, two siller tin oxide/silver-colored composite strips 15 lay respectively at the upper and lower surface of copper strips 6, siller tin oxide/silver-colored composite strip 15 is faying face for silver with 17 the one side and the bottom surface of copper strips 6 grooves 9, copper strips 6 and siller tin oxide/silver-colored composite strip 15 heats through the positioner location and the spacing thermal treatment zone 10 that enters, tape running speed is 1.0~5.0m/min, heating-up temperature is 300~800 ℃, the reducing gas that shields is arranged in the thermal treatment zone 10, then the roll 11 that is admitted on the hot-rolling mill of siller tin oxide/silver-colored composite strip 15 and copper strips 6 is rolled, roll-force is 10~120 tons, two siller tin oxide/silver-colored composite strips 15 are embedded in respectively before entering roll 11 in the groove 9 on copper strips 6 two sides, copper strips 6 and siller tin oxide/silver-colored composite strip 15 becomes silver/copper double composite strip material after rolling, at last with this silver/copper double composite strip material rolling;
E, silver/copper double composite strip material placed in the potoven anneal, annealing temperature is 400~600 ℃, and annealing time is 0.2~1 hour;
F, silver/copper double composite strip material is carried out surface clean, polishing and oven dry;
G, again silver/copper double composite strip material is sent into finishing mill and be rolled;
H, silver/copper double composite strip material is sent into banding machine at last and carried out itemize;
I, finished product.
In the above-mentioned hot rolling combination process, whether good coordination between its heating-up temperature, tape running speed, roll-force person coupling be the compound fastness of material key; And the unwinding and rewinding tension force of its band must be steadily, and the unwinding and rewinding tension force of band surely is to guarantee that band is straight, quantity-produced is crucial.Band must be selected suitable annealing temperature and time after hot rolling is compound, to strengthen the atom diffusion at different metal interface.
Groove milling equipment of the present invention comprise unreeling structure 1, rolling-up mechanism 2, three go up milling cutter 3, three following milling cutters 4 and copper strips 6 positioned locating piece 5 with spacing alignment, the described milling cutter 3 of going up is positioned at copper strips 6 tops, following milling cutter 4 is positioned at copper strips 6 belows, last milling cutter 3 and following milling cutter 4 cooperate in pairs, and the wide minimum of the edge of a knife of first pair of milling cutter, the edge of a knife width maximum of the 3rd pair of milling cutter, the edge of a knife width of these three pairs of milling cutters increases gradually.Promptly the edge of a knife width of first, second, third pair of milling cutter be broadening gradually to requiring size, process the groove 9 of required width one by one, the groove 9 accuracy tolerance minimums that this kind mode is processed make things convenient for the carrying out of subsequent technique.
Described locating piece 5 is provided with the both sides that a big square hole 18 and 14, two small square holes 14 of two small square holes lay respectively at big square hole 18, and copper strips 6 passes from big square hole 18, and the groove 9 of copper strips 6 upper and lower surfaces and the position of two small square holes 14 are complementary; Article two, siller tin oxide/15 of silver-colored composite strips pass from two small square holes 14 respectively, article two, small square hole 14 makes two siller tin oxides/silver-colored composite strip 15 can accurately fall in the groove 9 on copper strips 6 two sides before entering milling train 11, by milling train 11 rolling after, two siller tin oxide/15 of silver-colored composite strips are embedded in the groove 9 on copper strips 6 two sides.
Described hot-rolling mill is equipped with three unreeling structures 7 in proper order, band is positioned and spacing positioner, the thermal treatment zone 10, roll 11, a rolling-up mechanism 12, the described thermal treatment zone 10 is the high-frequency electrical heating furnace, described positioner is two groups of locating wheels 13 that are distributed in the band both sides, every group of locating wheel 13 has three, locating wheel 13 limits the band position, and its position of locating wheel 13 scalable, keep straight line to carry by these six locating wheels, 13 may command bands, guarantee that its quantity-produced carries out smoothly.
It only is preferred embodiment of the present invention that above institute is chatted, so all equivalences of doing according to the described structure of the present patent application claim, feature and principle change or decorate, is included in the present patent application claim.

Claims (4)

1, a kind of processing technology of silver/copper double composite strip material, it is characterized in that: it may further comprise the steps:
A, respectively silver band and siluer metal oxide band are carried out surface clean, remove its surperficial greasy dirt, oxide, again silver band and siluer metal oxide band are sent into a compound siluer metal oxide/silver-colored composite strip that becomes of hot-rolling mill hot rolling together, heating-up temperature is 300~800 ℃, tape running speed is 1.0~5.0m/min, band unwinding and rewinding tension range is 1~200KN, roll-force is 10~120 tons, the protective gas that shields is arranged in the thermal treatment zone, then again siluer metal oxide/silver-colored composite strip is annealed, annealing temperature is 400~600 ℃, annealing time is 0.2~1 hour, again it is sent into finishing mill after the annealing and carry out finish rolling system, anneal once more after the finish rolling system, annealing temperature is 400~600 ℃, annealing time is 0.2~1 hour, once more it being sent into finishing mill after the annealing, to carry out finished product rolling, at last it sent into banding machine and carry out itemize, and it is standby to make siluer metal oxide/silver-colored composite strip finished product;
B, copper strips is sent into groove milling equipment, on the upper and lower surfaces of copper strips, all mill out one with groove that siluer metal oxide/silver-colored composite strip is complementary;
C, respectively copper strips and the made siluer metal oxide/silver-colored composite strip of A step are carried out surface clean, remove its surperficial greasy dirt, oxide;
D, copper strips after cleaning and two siluer metal oxide/silver-colored composite strips are sent into hot-rolling mill, and to carry out hot rolling compound, article two, siluer metal oxide/silver-colored composite strip lays respectively at the upper and lower surfaces of copper strips, siluer metal oxide/silver-colored composite strip is that the one side of silver and the bottom surface of copper strips groove are faying face, copper strips and siluer metal oxide/silver-colored composite strip heats through the positioner location and the spacing thermal treatment zone that enters, tape running speed is 1.0~5.0m/min, band unwinding and rewinding tension range is 1~200KN, heating-up temperature is 300~800 ℃, the reducing gas that shields is arranged in the thermal treatment zone, then siluer metal oxide/silver-colored composite strip and the copper strips roll that is admitted to hot-rolling mill is rolled, roll-force is 10~120 tons, article two, siluer metal oxide/silver-colored composite strip is embedded in the groove on copper strips two sides before entering roll respectively, copper strips and siluer metal oxide/silver-colored composite strip becomes silver/copper double composite strip material after rolling, at last with this silver/copper double composite strip material rolling;
E, silver/copper double composite strip material is annealed, annealing temperature is 400~600 ℃, and annealing time is 0.2~1 hour;
F, silver/copper double composite strip material is carried out surface clean, polishing and oven dry;
G, again silver/copper double composite strip material is sent into finishing mill and be rolled;
H, silver/copper double composite strip material is sent into banding machine at last and carried out itemize;
I, finished product.
2, the processing technology of a kind of silver/copper double composite strip material according to claim 1, it is characterized in that: described groove milling equipment comprises that unreeling structure, rolling-up mechanism, three go up milling cutter, three following milling cutters and copper strips is positioned locating piece with spacing alignment, the described milling cutter of going up is positioned at the copper strips top, following milling cutter is positioned at the copper strips below, last milling cutter and following milling cutter cooperate in pairs, and the edge of a knife width of first, second, third pair of milling cutter is that broadening gradually is to requiring size.
3, the processing technology of a kind of silver/copper double composite strip material according to claim 1, it is characterized in that: order is equipped with unreeling structure, band is positioned and spacing positioner, the thermal treatment zone, roll, rolling-up mechanism on the described hot-rolling mill, the described thermal treatment zone is the high-frequency electrical heating furnace, described positioner is two groups of locating wheels that limit band position and its position of scalable that are distributed in the band upper and lower surface, and every group of locating wheel has three.
4, the processing technology of a kind of silver/copper double composite strip material according to claim 2, it is characterized in that: described locating piece is provided with big square hole and two confession small square holes that siluer metal oxide/silver-colored composite strip passes that a confession copper strips passes, two small square holes lay respectively at the both sides of big square hole, and the position of the groove of two small square holes and copper strips upper and lower surface is complementary.
CNB200610123758XA 2006-11-24 2006-11-24 Machining technique of silver/copper double composite strip material Expired - Fee Related CN100437857C (en)

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