CN1278015A - Electric contact material alloy based on silver-titanium and prodn. process therefor - Google Patents
Electric contact material alloy based on silver-titanium and prodn. process therefor Download PDFInfo
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- CN1278015A CN1278015A CN 99114275 CN99114275A CN1278015A CN 1278015 A CN1278015 A CN 1278015A CN 99114275 CN99114275 CN 99114275 CN 99114275 A CN99114275 A CN 99114275A CN 1278015 A CN1278015 A CN 1278015A
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Abstract
The present invention relates to an electric contact material based on silver-titanium and its production technology. The production technological method is as follows: silver ingot and titanium and one or several of zinc, tungsten, copper, bismuth or nickel are put in smelting furnace to smelt and cast into ingot; or mix silver powder, titanium powder, zinc, copper, bismuth or nickel powder and press into ingot, then calcine under high temperature and cold processing, extrude into bar under high temperature and cold-process to obtain silver-titanium electric contact wire material with good processability, low price and high reilability.
Description
The present invention relates to a kind of contact material and production technique thereof based on silver-titanium.It is mainly used in makes bimetal composite rivet contact, is widely used in high power relay.
Along with the develop rapidly of automobile, aircraft industry, the consequent is more and more higher to the requirement of automobile, the employed high power relay of aircraft.The contact material of rly. often adopts Ag-Ni alloy, Ag-SnO alloy, Pd-Cu alloy etc.The Ag-Ni alloy is widely used owing to its manufacturing process maturation.But this material only is applicable to the rly. that requirement is lower, can not satisfy the requirement of the rly. that reliability is higher, carrying capacity is big.Ag SnO alloy, it has satisfied the requirement of most of rly.s to contact material, but its material in being processed into the process of contact moment hardness hard, easily split, thereby poor processability, the consumption mould is many, every mould can only be processed several thousand contacts, contact production cost height.And the contact resistance instability, work reliability is poor.Often adopt the Pd-Cu alloy as contact material to the high rly. of reliability requirement, but this material is very expensive, about 40,000 yuan of per kilograms, therefore, how developing the new contact material that processing characteristics is good, cost is low, reliability is good again, is rly. industry questions of common interest.
The object of the present invention is to provide a kind of processing characteristics is good, cost is low, reliability is high again new contact material and production technique thereof.
The object of the present invention is achieved like this: a kind of contact material based on silver-titanium, it is to contain titanium in silver matrix.
The share of titanium is the per-cent of 0.5~10.5 weight in the material of the present invention, and the share of silver is 89.5~99.5 weight percents (with respect to the gross weights of material).
Also contain a kind of of the zinc, tungsten, copper, bismuth or the nickel that account for total amount 0.1~1.5% or several in the material of the present invention.
Producing and manufacturing technique of the present invention is:
-a kind of of silver ingot, titanium and zinc, tungsten, copper, bismuth or nickel or several are placed smelting furnace melting and ingot casting; Or with silver powder, titanium valve, and powder such as zinc, tungsten, copper, bismuth or nickel a kind of or several mix and briquetting, at high temperature sintering and cold working;
-at high temperature push slivering;
-can obtain silver-titanium through drawing and electrically contact wire rod.
The temperature of the high temperature extruding of production technique of the present invention is 820 °~960 ℃.Be preferably 840 °~900 ℃.Be preferably 860 °~880 ℃
Compare with existing contact material, the present invention adds titanium and forms silver-titanium alloy material in silver matrix, and hardness is even in being processed into the process of contact, can not ftracture, thereby good processability, the consumption mould is few, and every mould can be processed a hundreds of thousands of contact, the contact production cost is low, contact resistance is stable, the work reliability height, and material price is low, its material is about 2000 yuan of per kilograms, is 1/20 of palladium-silver alloy contact material.
Fig. 1 is technological process of production figure of the present invention.
Fig. 2 is one embodiment of the invention technological process of production figure.
Below in conjunction with accompanying drawing the present invention is made a detailed description:
The present invention is a kind of contact material based on silver-titanium, and it is to contain titanium in silver matrix.The share of titanium is the per-cent of 0.5~10.5 weight in the material, and the share of silver is 89.5~99.5 weight percents (with respect to the gross weights of material).
Also contain a kind of of the zinc, tungsten, copper, bismuth or the nickel that account for total amount 0.1~1.5% or several in the material of the present invention.Be preferably a kind of of 0.5~1% zinc, tungsten, copper, bismuth or nickel or several.
The share of zinc is 0.1~0.5% in the material of the present invention; The share of tungsten is 0.1~0.3%; The share of copper is 0.1~0.8%; The share of bismuth is 0.1~0.5%; The share of nickel is 0.1~0.5% (with respect to the material gross weight).
Production technique of the present invention is:
-with a kind of of silver ingot, titanium and zinc, tungsten, copper, bismuth or nickel or several meltings and ingot casting (Fig. 1); Or with silver powder, titanium valve, and powder such as zinc, tungsten, copper, bismuth or nickel a kind of or several mix and briquettings sintering and cold working at high temperature (Fig. 2);
-at high temperature push slivering;
-can obtain silver-titanium through drawing and electrically contact wire rod.
The high temperature sintering of production technique of the present invention and the temperature of extruding are 820 °~960 ℃.Be preferably 840 °~900 ℃.Be preferably 860 °~880 ℃.
Be several embodiments of the present invention below:
Example 1: take by weighing the 15Kg silver ingot, place medium-frequency induction furnace to melt, add the 1Kg titanium subsequently, after homogenizing, billet and deepfreeze are cast in scarfing cinder, cut cast gate and remove surface impurity, billet of harvest type is at the web that is squeezed under 800~960 ℃ the high temperature about φ 6mm, through being drawn into the wire product of φ 1.3~5.0mm.
Example 2: take by weighing the 15.5Kg silver ingot, place medium-frequency induction furnace to melt, add the 0.5kg titanium subsequently, after homogenizing, billet and deepfreeze are cast in scarfing cinder, cut cast gate and remove surface impurity, billet of harvest type is at the web that is squeezed under 840~900 ℃ the high temperature about φ 6mm, through being drawn into the wire product of φ 1.3~5.0mm.
Example 3: take by weighing the 15.5Kg silver ingot, place medium-frequency induction furnace to melt, add 0.4Kg titanium, 0.016Kg zinc, 0.064Kg nickel, 0.02kg copper subsequently successively, processing condition are with example 2.
Example 4: take by weighing the 15.45Kg silver ingot, place medium-frequency induction furnace to melt, add 0.4Kg titanium, 0.016Kg zinc, 0.064Kg nickel, 0.048Kg copper subsequently successively, 0.016kg tungsten, processing condition are with example 2.
Example 5: take by weighing 14.82kg silver powder, add the 1.16kg titanium valve subsequently, place V-mixer evenly mixed after, briquetting is molded under 800~960 ℃ of high temperature carries out sintering and cold working, under 800~960 ℃ of high temperature, be squeezed into web then, through being drawn into the wire product of φ 1.3~5.0mm.
Example 6: take by weighing 15.5kg silver powder, add the 0.56kg titanium valve subsequently, place V-mixer evenly mixed after, briquetting is molded under 840~900 ℃ of high temperature carries out sintering and cold working, under 840~900 ℃ of high temperature, be squeezed into web then, through being drawn into the wire product of φ 1.3~5.0mm.
Example 7: take by weighing 15.3kg silver powder, add 0.5kg titanium valve, 0.016kg zinc powder, 0.064kg nickel powder, 0.02kg copper powder subsequently, processing condition are with example 6.
Example 8: take by weighing 15.4kg silver powder, add 0.4kg titanium valve, 0.016kg zinc powder, 0.064kg copper powder, 0.064 nickel powder, 0.016kg tungsten powder subsequently successively, processing condition are with example 6.
Claims (13)
1, a kind of contact material based on silver-titanium is characterized in that it is to contain titanium in silver matrix.
2. a kind of contact material according to claim 1 based on silver-titanium, the share that it is characterized in that titanium in the material is 0.5~10.5 weight percent, the share of silver is 89.5~99.5% weight percents (with respect to the gross weights of material).
3, a kind of contact material based on silver-titanium according to claim 2 is characterized in that containing in the material a kind of of the zinc, tungsten, copper, bismuth or the nickel that account for gross weight 0.1~1.5% (weight percent) or several.
4, a kind of contact material based on silver-titanium according to claim 3 is characterized in that containing in the material a kind of of the zinc, tungsten, copper, bismuth or the nickel that account for gross weight 0.5~1.% (weight percent) or several.
5, a kind of contact material based on silver-titanium according to claim 3, the share that it is characterized in that zinc in the material are 0.1~0.5 weight percent (with respect to the gross weight of material).
6, a kind of contact material based on silver-titanium according to claim 3, the share that it is characterized in that tungsten in the material are 0.1~0.3 weight percent (with respect to the gross weight of material).
7, a kind of contact material based on silver-titanium according to claim 3, the share that it is characterized in that copper in the material are 0.1~0.8 weight percent (with respect to the gross weight of material).
8, a kind of contact material based on silver-titanium according to claim 3, the share that it is characterized in that bismuth in the material are 0.1~0.5 weight percent (with respect to the gross weight of material).
9, a kind of contact material based on silver-titanium according to claim 3, the share that it is characterized in that nickel in the material are 0.1~0.5 weight percent (with respect to the gross weight of material).
10, a kind of production technique of the contact material based on silver-titanium is characterized in that its processing method is:
-a kind of of silver ingot, titanium and zinc, tungsten, copper, bismuth or nickel or several are placed smelting furnace melting and ingot casting; Or with silver powder, titanium valve and, powder mixes and briquettings such as zinc, tungsten, copper, bismuth or nickel, sintering and cold working at high temperature;
-at high temperature push slivering;
-can obtain silver-colored titanium through drawing and electrically contact wire rod.
11, the production technique of a kind of contact material based on silver-titanium according to claim 10, the temperature that it is characterized in that its high temperature sintering and extruding is 800 °~960 ℃.
12, the production technique of a kind of contact material based on silver-titanium according to claim 11, the temperature that it is characterized in that its high temperature sintering and extruding is 840 °~900 ℃.
13, the production technique of a kind of contact material based on silver-titanium according to claim 11, the temperature that it is characterized in that its high temperature sintering and extruding is 860 °~880 ℃.
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CN99114275A CN1091470C (en) | 1999-06-22 | 1999-06-22 | Electric contact material alloy based on silver-titanium and prodn. process therefor |
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CN99114275A CN1091470C (en) | 1999-06-22 | 1999-06-22 | Electric contact material alloy based on silver-titanium and prodn. process therefor |
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CN1278015A true CN1278015A (en) | 2000-12-27 |
CN1091470C CN1091470C (en) | 2002-09-25 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100437857C (en) * | 2006-11-24 | 2008-11-26 | 林羽锦 | Machining technique of silver/copper double composite strip material |
CN101831557B (en) * | 2010-05-14 | 2012-02-22 | 贵研铂业股份有限公司 | Method for preparing anti-natural ageing and softening high-purity silver material |
CN103611746A (en) * | 2013-12-08 | 2014-03-05 | 西安诺博尔稀贵金属材料有限公司 | Method for drawing silver-base alloy bar with high surface quality |
CN104357704A (en) * | 2014-10-27 | 2015-02-18 | 李博 | Nickel oxide dispersion-strengthened silver-based alloy and preparation method thereof |
CN104388737A (en) * | 2014-10-27 | 2015-03-04 | 李博 | Zinc oxide dispersion strengthened silver-based alloy and preparation method thereof |
CN104388735A (en) * | 2014-10-27 | 2015-03-04 | 李博 | Silver-based electric contact material and preparation method thereof |
CN106868333A (en) * | 2015-12-11 | 2017-06-20 | 靖江市海源新材料科技有限公司 | A kind of new electrical contact material |
CN110527863A (en) * | 2019-08-29 | 2019-12-03 | 西安工程大学 | A kind of preparation method of silver titanium contact material |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1033524C (en) * | 1994-09-06 | 1996-12-11 | 中国有色金属工业总公司昆明贵金属研究所 | Silver-tase alloy electric probe material |
-
1999
- 1999-06-22 CN CN99114275A patent/CN1091470C/en not_active Expired - Fee Related
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100437857C (en) * | 2006-11-24 | 2008-11-26 | 林羽锦 | Machining technique of silver/copper double composite strip material |
CN101831557B (en) * | 2010-05-14 | 2012-02-22 | 贵研铂业股份有限公司 | Method for preparing anti-natural ageing and softening high-purity silver material |
CN103611746A (en) * | 2013-12-08 | 2014-03-05 | 西安诺博尔稀贵金属材料有限公司 | Method for drawing silver-base alloy bar with high surface quality |
CN103611746B (en) * | 2013-12-08 | 2016-01-20 | 西安诺博尔稀贵金属材料有限公司 | A kind of Hubbing method of great surface quality silver-base alloy bar |
CN104357704A (en) * | 2014-10-27 | 2015-02-18 | 李博 | Nickel oxide dispersion-strengthened silver-based alloy and preparation method thereof |
CN104388737A (en) * | 2014-10-27 | 2015-03-04 | 李博 | Zinc oxide dispersion strengthened silver-based alloy and preparation method thereof |
CN104388735A (en) * | 2014-10-27 | 2015-03-04 | 李博 | Silver-based electric contact material and preparation method thereof |
CN106868333A (en) * | 2015-12-11 | 2017-06-20 | 靖江市海源新材料科技有限公司 | A kind of new electrical contact material |
CN110527863A (en) * | 2019-08-29 | 2019-12-03 | 西安工程大学 | A kind of preparation method of silver titanium contact material |
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CN1091470C (en) | 2002-09-25 |
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