CN100408325C

CN100408325C - Decorative melamine laminated floor covering material and its making method

Info

Publication number: CN100408325C
Application number: CNB991076605A
Authority: CN
Inventors: 成在浣; 朴东根; 金英岐; 闵日泓
Original assignee: LG Chemical Co Ltd
Current assignee: LG Corp
Priority date: 1998-12-08
Filing date: 1999-05-03
Publication date: 2008-08-06
Anticipated expiration: 2019-05-03
Also published as: TWI228077B; JP2000170361A; KR20000047383A; KR100579841B1; TW200300010A; CN1256200A; TWI226851B

Abstract

To provide a decorative floor covering material and its manufacturing method and especially to provide a melamine sheet-laminated decorative PVC floor covering material having the excellent surface physical properties and also to provide its manufacturing method. A decorative floor covering material is composed of a base layer 100 and a balance layer 140 which is laid between melamine resin-impregnated papers 150 or under the base layer 100, and the balance layer 140 comprises of a material selected out of a sheet, a web or a nonwoven fabric. In the decorative floor covering material which is made up by joining an accumulated body formed by placing the balance layer, improving the adhesive strength between the resin-impregnated layer and the PVC resin layer, and since the fibers between the balance layer and the balance layer intensify the strength of entire matrix, curling before or after execution of work or bending occurring during transportation can be decreased.

Description

Ornamental melamine laminated floor covering material and manufacture method thereof

The present invention relates to ornamental floor covering and manufacture method thereof, specifically, relate to and decorate melamine laminated PVC floor covering, it is to form with the melamine sheet material lamination on the PVC plate with excellent physical property; The present invention also relates to make the method for this material.

The floor covering that is used for the commodity building now generally is smooth stone material or PVC brick and other material, as shown in Figure 1.In large quantities of building such as market and office building, stone floor material such as marble and granite are the materials of the most common use.Though this class stone material product durability is good, because of costing an arm and a leg, has now developed some substitutes.

The PVC brick product of having developed has two-tone marbling, and is similar with lithotome.These PVC bricks be crushed to that various erose material is suppressed or continuously compacting form, produce the PVC plate that one deck has two or more tones thus, obtain marbling effect shown in Figure 2.But, because therefore excessive use filler in the manufacture process is restricted in the natural sex degree of color and configuration aspects.

In order to improve the shortcoming of this respect, now developed ornamental polyvinyl chloride resin floor covering, as shown in Figure 3, it has laid printed layer on the PVC plate.

The represented this decorative floor cladding material that is bonded into by the compacting of one pile of material of Fig. 3 comprise lay successively following which floor: produce the base layer 1 that product thickness and levelling reconciliation of inventory are used; The printed layer 2 of representing decorative effect on the base layer 1 with art pattern; The hyaline layer 3 that protection printed layer 2 patterns are used; Make product have the face coat 4 of resistance tocrocking and scratch resistance; And under basic unit 1, be used for the balance layer 5 of adjustment.If base layer 1 itself can be regulated the balance of this floor covering, then balance layer 5 can save.

The manufacture method of above-mentioned traditional decorative floor cladding material comprises following step:

It is thick that the resin mixture of soft pvc or hard PVC is calendered to 2-3mm, makes base layer 1;

Manufacturing is layered on printed layer 2 and the hyaline layer 3 on the base layer 1, and is layered on the balance layer 5 under the base layer 1;

On the polyvinyl chloride resin sheet material, carry out drying after printing natural tone decorative pattern or the wooden tone pattern with photolithography or transfer method and make printed layer 2, the thickness of this polyvinyl chloride resin sheet material is 0.08-0.15mm, form with soft or the calendering of hard PVC compound, contain 10-20 weight % titanium oxide in the compound and make it to have good covering power;

Make hyaline layer 3 with the transparent PVC resin film that 0.1-0.95mm is thick, it is by rolling soft or the hard PVC resin mixture forms;

Soft or the calendering of hard PVC resin mixture are made the balance layer 5 of 0.32-0.95mm;

Printed layer 2, hyaline layer 3 and balance layer 5 are laminated on the base layer 1, this laminating method be with a press complete on the base layer above-mentioned printed layer that makes 2 and hyaline layer 3 and base layer 1 transfer put balance layer 5 after, carry out hot pressing; And

Be cured formation face coat 4 with ultraviolet ray after on hyaline layer 3, being coated with the face finish that 5-60 μ m principal component is urethanes or acrylate, form face coat 4 with heat cure or ultraviolet curing after perhaps being coated with a kind of main component and being urethanes or acrylate on hyaline layer 3, making thickness thus is the decorative floor cladding material of 2.5-5.0mm.

Though traditional decorative floor cladding material of making by above-mentioned this method is with low cost and easy for installation being widely used owing to it, because the face coat on its top layer not antipollution or anti scuffing thereby damage easily not.As a result, the frequent place of those dealings is with regard to contaminated or scratch, thereby it reduces in architectural purposes.

Afterwards, use a kind of decorative floor cladding material melamine resin, that superficial layer has high rigidity that do not have, solved above-mentioned these problems.Figure 4 and 5 are represented some traditional floor coverings like this.

Fig. 4 represents the cutaway view of the disclosed decorative laminate of european patent application No.0561086A1.This decorative laminate comprises the veneer 14 of phenolic resin adhesion layer 12, melamine resin impregnate layer 13 and melamine resin dipping, and they are layered on the polyvinyl chloride resin layer 11 successively.

Fig. 5 represents the cutaway view of the disclosed laminated material of Japanese publication No.Heisei 9-123366.This laminated material comprises the veneer 34 of a hot melt film 32, a stencil paper 33 and melamine resin dipping, and they are laminated on rubber or the thermoplastic resin 31.

The decorative floor cladding material of the melamine resin impregnate layer that the usefulness of Figure 4 and 5 representative is traditional has solved surperficial scratch and pollution problems; this is owing to used the top layer of melamine resin as soaking melamine resin veneer 14; the protective clear layer 25 that a kind of cardboard that soaks melamine resin is made, and soak melamine resin veneer 34.But such decorative floor cladding material exists variety of issue, and the adhesive strength of adhesive layer that for example is used for bonding this one deck that soaks melamine resin and this one deck of polyvinyl chloride resin is poor.

In addition, decorative laminate shown in Figure 4 has the following problem: because the adhesion strength of the compatibility difference of the polyvinyl chloride resin of the phenolic resins of phenolic resin adhesion layer 12 and the following surface and PVC layer 11 of this layer thereby this adhesive layer 12 is poor, when and when being picked up with the edge clamping of decorative laminate, its central area will be damaged, and this is because it does not have the hard sheet material of this layer can compensate the fragility of melamine resin under external impacts.

In addition, the laminated material of Fig. 5 has following dimensional stability problem: comprise that hot melt film 32 wherein causes the contraction of this film itself when the temperature change as the adhesive layer between rubber or thermoplastic resin 31 and the bristol paper 33 owing to the increase of crystallization, and be difficult to keep balance according to the variation of temperature and humidity.

Fig. 1 also exists to traditional decorative floor cladding material shown in Figure 5 and curls and crooked problem, especially is lower than-10 ℃ and when being higher than 40 ℃ in temperature.This be base material itself not the heatproof degree change and cause because various different shrinkage factor and the expansion rate of layer under different temperatures and humidity of forming has nothing in common with each other.

The structure that for this reason must replenish matrix remedies these deficiencies.

The purpose of this invention is to provide a kind of ornamental polyvinyl chloride resin floor covering, and its manufacture method.This floor of the present invention cover material has improved performances such as anti scuffing and antipollution greatly, thereby has had some physical properties of crust because its superficial layer floods with melamine resin.

Another object of the present invention provides a kind of decorative floor cladding material that is formed by one pile of material heat pressure adhesive, it is thereby that a balance layer is clipped in the bonding strength that improves between the polyvinyl chloride resin layer below resin impregnate layer and this resin impregnate layer between this resin impregnate layer and the PVC layer, and this improvement because the fiber in the balance layer penetrates in overlay coating and the shop fixtures layer obtains.That is to say,, thereby make this resin impregnate layer and polyvinyl chloride resin layer reduce curling of taking place before and after the installation, also reduce the bending that takes place in the use because balance layer and inner fiber thereof have strengthened whole substrate.

The detailed description of making below in conjunction with accompanying drawing can more be expressly understood value of the present invention and advantage.Wherein:

Fig. 1 to Fig. 5 is the side cutaway view of the traditional decorative floor cladding material of expression; And

Fig. 6 to Figure 14 is the side cutaway view of expression decorative floor cladding material of the present invention.

Ornamental polyvinyl chloride resin cladding material of the present invention is to be bonded with a kind of ply of paper 150 that is layered on the dipping melamine resin above the polyvinyl chloride resin base layer 100.This floor covering also comprises a balance layer 140, it be bonded to base layer 100 and be soaked with between the ply of paper 150 of melamine resin or base layer below.The material of this balance layer is to be selected from sheet material, textile fabric and non-woven fibre.

This decoration of PVC resin floor cladding material also can be clipped in tack coat 130 between balance layer 140 and the base layer 100 bonding and make with a kind of.

The present invention also provides a kind of method of making this ornamental polyvinyl chloride resin floor covering, comprises following step: polyvinyl chloride resin is made base layer 100 by calendering; With fiberglass braided or be pressed into bottom 110; Paper is made the ply of paper 150 of resin dipping with melamine resin dipping back drying while semi-solid preparation; And after being layered on base layer 100 and Tetefol layer 150 on the bottom 110 that glass fibre is a matrix successively with a press at 10-80kg/cm ²Under pressure and the 120-180 ℃ temperature hot pressing 10-40 minute.

This polyvinyl chloride resin floor covering is bonding with the balance layer 140 between the ply of paper 150 of base layer 100 and resin dipping, this balance layer is textile fabric, non-woven fibre or cotton-shaped sheet material, makes by being selected from following these materials: the mixture of the mixture of the scrim nonwoven fabric of natural fiber, polyester, glass fibre, glass fibre, glass fibre and polyester fiber, natural fiber and glass fibre, paper pulp and paper.

The method of decoration of PVC resin floor cladding material that the present invention also provides a kind of manufacturing to comprise base layer 100, the bottom below base layer 100 110, adhesive layer 130, balance layer 140 and covers the Tetefol layer 150 of base layer 100.This method comprises following step:

A) on base layer 100, be coated with 80-300g/m ²Adhesive or lay binder film, make adhesive layer 130 thus;

B) laying the resin impregnate layer on the adhesive layer of step a) is that HPL (high-pressure laminated plate) uses pressing plate at 130-160 ℃ of temperature and 10-30kg/cm this HPL sheet material and base layer afterwards ²Pressure down compacting 10-20 minute is bonding and make laminate, and wherein HPL sheet material upwards contains balance layer 140, sandwich layer 151, decorative layer 152 and protective clear layer 153 successively; And

C) under the laminate of step b), lay after the bottom 110 gained one laminate materials at room temperature and 10-30kg/cm ²Pressure was suppressed 15-30 minute down.

The present invention also provides a kind of manufacturing to have the method for the decoration of PVC resin floor cladding material of balance layer 140, adhesive layer 130, base layer 100 and resin impregnate layer 150 (from top to bottom successively).This method comprises following step:

A) on base layer 100, be coated with 80-300g/m ²Adhesive and make adhesive layer 130;

B) on the adhesive phase of step a), lay after the resin impregnate layer of HPL (high-pressure laminated plate) this HPL sheet material and base layer 100 usefulness pressing plates at 130-160 ℃ of temperature and 10-30kg/cm ²Pressure is 10-30 minute bonding laminate of making of compacting down, and wherein HPL sheet material comprises sandwich layer 151, decorative layer 152 and protective clear layer 153 (from the bottom up successively);

C) at the laminate bottom surface of step b) coating 80-300g/m ²Adhesive make another adhesive layer 130; And

D) below the adhesive layer 130 of step c), lay balance layer 140 afterwards at room temperature and 3-8kg/cm ²Pressure down compacting made in 4-24 hour the decorative floor cladding material or

I) lay balance layer 140, base layer 100, bonding laminate 130, sandwich layer 151, decorative layer 152 and protective clear layer 153 (making progress successively); Then

Ii) gather into folds above-mentioned with hot press which floor at 130-160 ℃ of temperature and 10-30kg/cm ²Under the pressing plate of pressure hot pressing 10-20 minute, cooling at room temperature then, thus make the decorative floor cladding material.

Sheet material or film preferably a kind of combination of polymers of the material of above-mentioned adhesive layer or a kind of curtain coating, calendering or T shape mold forming.This combination of polymers is selected from chloroprene resin, acrylonitrile-butadiene rubber, acrylic resin, polyester, carbamate, rubber, vinylite and epoxy resin; This curtain coating, calendering or the sheet material of T shape mold forming or film are acrylic resin, resin modified phenol resin, the urethane resin of the ethylene vinyl acetate resin that is selected from amide resin, ethylene vinyl acetate resin, modification, acrylic resin, modification, the urethane resin and the epoxy resin of modification.

Balance layer 140 preferably is that textile fabric, non-woven fibre or the cotton-shaped sheet material of base-material made sheet material with the natural fiber.This textile fabric and non-woven fibre are selected from glass fibre, carbon fiber, PET (poly terephthalic acid second two ferment esters), polypropylene, polyester and nylon.

The ply of paper 150 of above-mentioned impregnating resin can comprise protective clear layer 153; Decorative layer 152; And sandwich layer 151 (downward successively).

Above-mentioned dipping the ply of paper 150 of resin also can comprise decorative layer 152 and sandwich layer 151 (downward successively).

The another kind of structure of the ply of paper 150 of above-mentioned impregnating resin can comprise protective clear layer 153 and the decorative layer of laying successively 152 downwards.

It is the ply of paper 150 that contains the melamine resin dipping that comprises protective clear layer 153 successively downwards that this ornamental polyvinyl chloride resin floor covering also has another structure; Balance layer 140; Printed layer 120; Base layer 100; And bottom 110.

It is the ply of paper 150 that contains the impregnating resin that comprises protective clear layer 153, decorative layer 152 and sandwich layer 151 successively downwards that this ornamental polyvinyl chloride resin floor covering has another kind of structure again; Balance layer 140; Adhesive layer 130; Base layer 100; With bottom 110.

It is the ply of paper (comprising protective clear layer 153, decorative layer 152 and sandwich layer 151) that contains impregnating resin successively downwards that this ornamental polyvinyl chloride resin floor covering also has another kind of structure again; Balance layer 140; Sandwich layer 151; Adhesive layer 130; Base layer 100; With bottom 110.

It is to contain the ply of paper 150 (comprising protective clear layer 153, decorative layer 152 and sandwich layer 151) that floods melamine resin successively downwards that this ornamental polyvinyl chloride resin floor covering also has another structure; Adhesive layer 130; Base layer 150; Adhesive layer 130; With balance layer 140.

Above-mentioned protective clear layer 153 is the plain paper of pitch based fiber preferably, and it is with 25-61g/m ²There is the cellulose paper of homodisperse wear-resistant silica or aluminium oxide to flood under 130-150 ℃ of temperature, to carry out drying and semi-solid preparation simultaneously after the melamine resin of 200-800 weight % of this veneer paper weight and makes.

Above-mentioned decorative layer 152 is the facing paper of impregnating resin preferably, and it is with 80-120g/m ²The photomechanical printing cellulose paper of titanium oxide (being facing paper) carries out drying and semi-solid preparation simultaneously and makes after having flooded the resin that is lower than this facing paper weight 100 weight % under 130-150 ℃ of temperature.Described resin is selected from melamine resin, mylar, diallyl phthalate ester resin and phenolic resins.

Above-mentioned sandwich layer 151 preferably is selected from following this different materials: will be lower than 198g/m ²The brown paper of the impregnated phenolic resin made with the resin impregnating of the 20-100 weight % of this brown paper of brown paper; The all-glass paper of impregnated phenolic resin or scribble polyvinyl chloride resin or the all-glass paper of acrylic resin, it is with 40-160g/m ²All-glass paper apply with the phenolic resins of the 20-100 weight % of this all-glass paper and make; And the glass mat of impregnated phenolic resin or scribble polyvinyl chloride resin or the glass fibre of acrylic resin, it is with 40-160g/m ²Glass mat apply with the phenolic resins of the 20-60 weight % of this glass mat and make.

The Shore hardness of the base layer 100 of above-mentioned decoration of PVC resin floor cladding material is in the 50-100 scope, this base layer is that the degree of polymerization with 15-25 weight % is the polyvinyl chloride resin compound after mediating in banbury after barium-zinc family composition additive of the pearl filler of dioctyl phthalate plasticizer, 65-80 weight % of polyvinyl chloride resin, the 4-6 weight % of 700-1500 and 1-4 weight % mixes in dry-mixed machine or combined type blender, under 120-170 ℃, roll, can make the thick hard PVC resin of 1.6-4.6mm thus.

The bottom 110 of above-mentioned decorative floor cladding material be selected from impregnated phenolic resin, melamine resin or acrylic resin paper, weaven goods, flood or scribble polyvinyl chloride resin glass fibre non-woven fabric, soft polyvinyl chloride resin plate.Preferably, the material of this bottom (110) is paper or textile fabric and polyvinyl chloride resin dipping or the coated glass fibers non-woven fibre that is selected from phenolic resins, melamine resin, acrylic resin dipping.

Material with base layer 100 of 50-100 Shore hardness is selected from polyvinyl chloride resin, polyurethane, natural or synthetic rubber, vistanex, mylar or elastomer.

Below the present invention is done detailed explanation:

The present invention has introduced and has decorated with polyvinyl chloride resin floor covering and preparation method thereof.This decoration is one pile of stratified material to be carried out heat pressure adhesive with the press of high pressure form with the polyvinyl chloride resin floor covering.This pile stratified material be by balance layer is placed between resin impregnate layer and the polyvinyl chloride resin layer below the resin impregnate layer or with balance layer be placed on the polyvinyl chloride resin layer below make, by the fiber in the balance layer is penetrated in overlay coating and the shop fixtures layer (being in resin impregnate layer and the polyvinyl chloride resin layer) improve in the original relatively poor adhesion strength of resin impregnate layer and polyvinyl chloride resin interlayer and reduce take place to curl before and after installing and processing procedure in bend, this be because the fiber reinforcement in balance layer and the balance layer whole parent.

This balance layer not only plays balanced action, keeps conventional thickness constant and prevent from after installation to take place to curl, and plays a part to be limited in the transportation and bend, and has improved the bonding strength of resin impregnate layer and polyvinyl chloride resin base layer.

The pattern that decorative layer described above has is being represented the style style of decorating land used plate cladding material.

Sandwich layer described above will have certain thickness and impact resistance.This makes the upper and lower of bonding connection sandwich layer become possibility and it plays a part to be easy to make the HPL (high-pressure laminated plate) of resin impregnate layer and balance layer.

In Fig. 6～Fig. 9 represented decoration of the present invention with floor covering can be divided into Fig. 6～shown in Figure 8 by comprise glass fibre make the bottom 110 of substrate, base layer 100, balance layer 140 and contain the ply of paper 150 of resin dipping of decorative layer 152 and Fig. 9 shown in by not comprising that glass fibre makes the bottom 110 of substrate, base layer 100, printed layer 120, balance layer 140 and contain the ply of paper 150 of the resin dipping of decorative layer 152.The former is to use the ply of paper 150 of resin dipping of decorative layer 152 as the situation of the decorative effect of display layer, and the latter is to use the situation of printed layer 120 as the decorative effect of display layer.

This will describe in detail below:

The decoration of Fig. 6～Fig. 8 is a base layer 100 with the composition of floor covering; at the balance layer on the base layer 140, comprise and the ply of paper 150 of the resin dipping of decorative layer 152 (on balance layer) comprise that the ply of paper 150 of the resin dipping of decorative layer 152 is made up of sandwich layer 151, decorative layer 152 and protective clear layer 153 or is formed or be made up of decorative layer 152 and protective clear layer 153 by sandwich layer 151 and decorative layer 152 from bottom to top.

Fig. 6 is the cutaway view of decorating with floor covering; this decoration floor covering is made up of base layer 100, the balance layer 140 on base layer 100, the ply of paper 150 of resin dipping on balance layer and the bottom 110 that glass fibre is done substrate; wherein; the ply of paper of resin dipping is by sandwich layer 151 from bottom to top, and dress layer 152 and protective clear layer 153 are formed.

To describe one below and be used to make the embodiment of this decoration with floor covering.

At first, make base layer 100, this base layer will have the balance of certain thickness and adjustable restraining product.

The base layer 100 that sheet thickness is 1.6～4.mm is made in the calendering of polyvinyl chloride resin compound.Suitable calender temperature is 120～170 ℃.

At the polyvinyl chloride resin that with the degree of polymerization is 700～1500 100 weight %, dioctyl phthalate as 20～40 weight % of plasticizer, after mixing in blending machine and combined hybrid device as the barium zinc compound of 2～5 weight % of stabilizing agent with as the calcium carbonate of 200～700 weight % of filler, make the polyvinyl chloride resin compound by in banbury mixers, mediating.

Next step, the bottom 110 of the glass fibre matrix of manufacturing support substrate layer 100.

The bottom 110 of glass fibre matrix or be the glass fibre of braiding or the sheet material of glass fibre compacting as fabric, and to require the weight of per unit area be 20～100g/m ²

Be the balance layer of making between the ply of paper (150) that places base layer (100) and resin dipping (140) below.

By from natural fiber, polyester fiber, glass fibre, glass scrim nonwoven fabric (glassscrim), the mixture of glass fibre and polyester fiber, select a kind of fiber in the mixture of natural fiber and glass fibre etc., balance layer 140 is made textile fabric, non-woven fibre or cotton-shaped sheet material.The weight of these balance layer 140 per unit areas is 10～300g/m ²

Except fiber recited above, also can use paper pulp, paper etc.

Make the ply of paper 150 of resin dipping below, product has the performance of antipollution and damage resistant.The ply of paper 150 of resin dipping is by the sandwich layer 151 with certain thickness and adjustable product balance from bottom to top, and its artistic pattern can produce the decorative layer 152 of decorative effect and the protective clear layer 153 of protection decorative layer 152 recited above is formed.Can make respectively and position in order for every layer.

Per unit area weight is 100～200g/m ²Behind the resin impregnating of brown paper with 40～180 weight % (by the weight of per unit brown paper), with this sandwich layer 151 dry simultaneously and semi-solid preparation 1～3 minute under 30～150 ℃ furnace temperature.

This phenolic resins is the phenol of 30～46 weight %, and the formaldehyde of 46～30 weight %, 4～6 weight % is as the ethanol of solvent, the water of 2～5 weight %, and 15～5 weight % are as the mixture of the orthoresol of the amines catalyst of modifying agent and 3～8 weight %.

Per unit area weight is 80～120g/m ²Facing paper after with 60～160 weight % (by the weight of per unit facing paper) melamine resin dipping, this decorative layer 152 dry simultaneously and semi-solid preparation 1～5 minute under 80～150 ℃ furnace temperature.

This melamine resin is the melamine of 30～45 weight %, the formaldehyde of 40～20 weight %, 18～27 weight % are as the water of solvent, 1～5 weight % is as the diethylene glycol (DEG) or the acetylguanamine of modifying agent, and the NaOH of 1 weight % adjusting pH value and 10～2 weight % are as the mixture of the amines catalyst of curing agent.

Facing paper is a kind of like this paper: on blank sheet of paper, this blank sheet of paper is made by titanium oxide is added in the natural fiber with certain bristol paper, and the method for printing comprises photolithography etc.

In per unit area weight is 20～50g/m ²Behind the melamine resin dipping of veneer paper with 200～400 weight % (by the weight of per unit veneer paper), with this protective clear layer 153 dry simultaneously and semi-solid preparation 1～5 minute under 100～150 ℃ furnace temperature.

This melamine resin is the melamine of 30～45 weight %, the formaldehyde of 40～20 weight %, 18～27 weight % are as the water of solvent, 1～5 weight % is as the diethylene glycol (DEG) or the acetylguanamine of modifying agent, 1 weight % regulates the NaOH of pH value and 10～2 weight % mixture as the amines catalyst of curing agent, with used identical of decorative layer recited above 152.

Veneer paper is highly refined cellulose paper.

After form decorating with floor covering every layer and being created respectively; decoration floor covering of the present invention is with base layer 100; balance layer 140 and by sandwich layer 151; the ply of paper 150 of the resin dipping that decorative layer 152 and protective clear layer 153 formed is layered on glass fibre in order do on the bottom 110 of substrate after; by at 120～180 ℃, 10～80kg/cm ²Heating and the condition of pressurization under these layers were suppressed simultaneously 10～40 minutes and were made.

When carrying out hot pressing with press; the bottom 110 that glass fibre is done substrate sees through base layer 100 and makes base layer 100 obtain enhancing; the fiber of balance layer 140 enters the levels (being the ply of paper 150 of resin dipping and the base layer 100 of polyvinyl chloride resin layer) of balance layer 140; the ply of paper 150 and the base layer 100 of while binding resin dipping; sandwich layer 151, decorative layer 152 and the protective clear layer 153 of semi-solid preparation are solidified fully, and especially painted one-tenth becomes transparent as the milky protective clear layer 153 of typing paper by compacting under the condition of semi-solid preparation.

Fig. 7 is the cutaway view of decorating with floor covering, and it comprises base layer 100, the balance layer 140 on base layer 100, and the ply of paper 150 of the resin dipping on balance layer 140, the ply of paper 150 of this resin dipping is made up of sandwich layer 151 and decorative layer 152.

Except the ply of paper 150 of resin dipping was made up of sandwich layer 151 and decorative layer 152, it was very similar to the method for Fig. 6 with the method for PVC floor covering to make this decoration.

That is to say, decorate composition with floor covering, it is base layer 100, glass fibre is made the bottom 110 of substrate, balance layer 140 and comprise that the sandwich layer 151 and the ply of paper 150 of the resin dipping of decorative layer 152 are manufactured respectively after, decoration floor covering of the present invention is with base layer 100, balance layer 140 and be laid on glass fibre in order and do on the bottom 110 of substrate by the ply of paper 150 that the resin that sandwich layer 151 and decorative layer 152 are formed floods after, by at 120～180 ℃, 10～80kg/cm ²Condition under suppress these layers recited above 10～40 minutes and make simultaneously.

Fig. 8 is the cutaway view of decorating with floor covering; it comprises base layer 100; balance layer 140 on base layer 100; the ply of paper of the resin dipping on balance layer 140 and the bottom 110 that the glass fibre below base layer 100 is done substrate, the ply of paper 150 of this resin dipping is made up of decorative layer 152 and protective clear layer 153 from bottom to top.

Except the ply of paper 150 of resin dipping was made up of decorative layer 152 and protective clear layer 153, it was very similar to the method for the sort of material of shop drawings 6 with the method for floor covering to make this decoration.

That is to say; at each composition of decorating with floor covering; be base layer 100, glass fibre bottom 110, the balance layer 140 of doing substrate and comprise that the decorative layer 152 and the ply of paper 150 of the resin dipping of protective clear layer 153 are manufactured respectively after; decoration floor covering of the present invention is after being laid on glass fibre in order with base layer 100, balance layer 140 with by the ply of paper 150 that the resin that decorative layer 152 and protective clear layer 153 are formed floods and doing on the bottom 110 of substrate; by at 120～180 ℃, 10～80kg/cm ²Condition under suppressed simultaneously 10～40 minutes and make.

Decorate among Fig. 9 with floor covering and comprise base layer 100, printed layer 120, balance layer 140, do not comprise the ply of paper 150 of resin dipping of decorative layer and the bottom 110 that the glass fibre below base layer 100 is done substrate.The ply of paper 150 of this resin dipping is made up of protective clear layer 153.

Making this decoration comprises with the method for floor covering and makes the Tetefol layer 150 of forming the base layer 100 decorated with floor covering, bottom 110, balance layer 140 that glass fibre is done substrate and comprising protective clear layer 153.

Also to make the printed layer 120 that demonstrates the artistic pattern decorative effect.

This printed layer 120 is by comprising printing processes such as photolithography or transfer printing, prints after being printed on certain pattern on the polyvinyl chloride resin sheet and makes.

The polyvinyl chloride resin sheet material is by the polyvinyl chloride resin compound being rolled, being made into the sheet material that thickness is 0.07～0.20mm.Suitable calender temperature is 150～190 ℃.

This polyvinyl chloride resin compound is at the polyvinyl chloride resin that is 700～3000 100 weight %, as the dioctyl phthalate of 10～30 weight % of plasticizer, as 2～5 weight % barium zinc compounds of stabilizing agent with the degree of polymerization, have as pigment good covering power 10～30 weight % titanium oxide and mix in blending machine and combined hybrid device as the calcium carbonate of 0～50 weight % of filler after, in banbury mixers, mediate the back and get.

After decoration is manufactured respectively with the composition of floor covering; decoration floor covering of the present invention is base layer 100, printed layers 120, balance layer 140 and the Tetefol layer 150 that contains protective clear layer 153 to be placed in order after glass fibre does on the bottom 110 of substrate, by at 10～80kg/cm ², suppressed simultaneously under 120～180 ℃ the condition which floor 10～40 minutes recited above and make.

After carrying out hot pressing with press; the glass fibre that glass fibre is done in the bottom 110 of substrate penetrates basalis 100 and base layer 100 is enhanced; the fiber of balance layer 140 penetrates the levels of balance layer 140; be the ply of paper 150 of resin dipping and the printed layers 120 of polyvinyl chloride resin layer; the ply of paper 150 and the printed layers 120 of while binding resin dipping, the protective clear layer 153 of semi-solid preparation becomes transparent by compacting.

Decorate with in the floor covering at Fig. 6～Fig. 9, for balance support layer 140, playing the adhesive effect between the ply of paper 150 of base layer 100 and resin dipping or between the ply of paper 150 of printed layers 120 and resin dipping, adhesive phase can described in the above base layer 100 and balance layer 140 between form or between printed layers 120 and balance layer 140, form.This will describe in Figure 10～Figure 13.

A kind of in the polyurethane resin of acrylic resin, resin modified phenol resin, polyurethane resin or modification by calendering or the molded vinyl alcohol vinyl acetate resin that is selected from amide resin, ethylene vinyl acetate resin, modification of T shape, acrylic resin, modification makes the thick sheet material of 0.02～0.2mm with this adhesive phase 130.

Figure 10 is the cutaway view of decorating with floor covering, and its adhesive phase 130 is to form between Fig. 6 decorates with the base layer 100 of floor covering and balance layer 140.

Figure 11 is the cutaway view of decorating with floor covering, and its adhesive phase 130 is to form between Fig. 7 decorates with the base layer 100 of floor covering and balance layer 140.

Figure 12 is the cutaway view of decorating with floor covering, and its adhesive phase 130 is to form between Fig. 8 decorates with the base layer 100 of floor covering and balance layer 140.

Figure 13 is the cutaway view of decorating with floor covering, and its adhesive phase 130 is to form between Fig. 9 decorates with the base layer 100 of floor covering and balance layer 140.

Making of the present invention another kind of manufacture method of decorating with floor covering represented among Figure 10 comprises: by with 80～300g/m ²The adhesive film that applies or lay 0.05～0.2mm thickness on base layer 100, form after the adhesive phase 130, the protective clear layer of the resin impregnate layer of balance layer, sandwich layer, decorative layer and HPL (high-pressure laminating material) sheet material is layered on the adhesive phase 130 from bottom to top; Make the bonding laminate of HPL and base layer 100 by under high temperature and pressure, suppressing; And after bottom being laid under the laminate, by in room temperature, 10～30kg/cm ²Pressure down compacting made in 15～30 minutes to decorate and use floor covering.

Above the described required condition that is used for lamination HPL and base layer be: 130～160 ℃ of platen temperatures, pressure are 10～30kg/cm ², the press time is 10～20 minutes, cool to room temperature after compacting.

Figure 14 is that the present invention decorates the cutaway view with a floor covering embodiment, and it is by the scraps of paper being impregnated with the adhesive phase 130 of resin modified phenol resin etc.; the scraps of paper are impregnated with the sandwich layer 151 of phenolic resins; the stamp scraps of paper are impregnated with the decorative layer 152 of melamine resin; the protective clear layer 153 that the scraps of paper are impregnated with melamine resin is layered on the PVC base layer 100 and from the bottom to top by will be by melamine resin or phenolic resins; the balance layer 140 that the glass fibre of the scraps of paper of resin modified phenol resin or acrylic resin dipping or polyvinyl chloride resin dipping or non-woven fibre or soft PVC sheet are made is layered on the following of PVC base layer 100 and makes.

Decoration among Fig. 6～Figure 14 of the present invention is 2.0～5.0mm with the thickness requirement of floor covering.

Though the present invention has done detailed description with reference to preferred embodiment, those skilled in the art will suitably make various changes and replacement and do not break away from design of the present invention and the scope of being stated in the claim of enclosing to this.

Embodiment 1

(preparation of base layer 100)

To include the Corvic of 100 weight portions, the dioctyl phthalate of 36 weight portions, the barium zinc compound of 3 weight portions and the pre-composition of 500 weight portion calcium carbonate join in the mixer and mix therein.

Mixture is joined in the banbury mixers and mediates therein.Be by compacting and make the smooth mode of mixture produce the base layer 100 that thickness is 2.6mm in 130 ℃～160 ℃ the calender in a temperature then.

(preparation of bottom 110)

Every square metre is that the bottom 110 of fiberglass batts of 30 grams prepares by glass fibre is suppressed.

(preparation of balance layer 140)

Every square metre is that the balance layer 140 of sheet materials of 30 grams is to make with cotton-shaped natural fiber.

(preparation of decorative layer 152)

The decorative layer 152 of melamine resin impregnated sheets of paper is at the liquid melamine resin dipping 80g/m with 100 weight % (by the weight of per unit facing paper) ²Printed decoration paper after, by being that dry simultaneously and semi-solid preparation prepared in 2～3 minutes in 120 ℃～140 ℃ the stove in temperature, this liquid melamine resin is the melamine of 37 weight portions, the formaldehyde of 33 weight portions, the water of 25 weight portions, the pre-composition of the amine base catalyst of the diethylene glycol (DEG) of 1 weight portion and 3.7 weight portions.

(preparation of protective clear layer 153)

The protective clear layer 153 of melamine resin impregnated sheets of paper is at the liquid melamine resin dipping 38g/m with 250 weight % (by the weight of per unit veneer paper) ²Veneer paper after, by being that dry simultaneously and semi-solid preparation prepared in 2～3 minutes in 120 ℃～140 ℃ the stove in temperature, this liquid melamine resin is the melamine of 37 weight portions, the formaldehyde of 33 weight portions, the water of 25 weight portions, the pre-composition of the amine base catalyst of the diethylene glycol (DEG) of 1 weight portion and 3.7 weight portions.

(preparation of Corvic floor covering (Fig. 8))

After the scraps of paper 150 of the resin dipping of laying bottom 110, base layer 100, balance layer 140 and forming by decorative layer 152 and protective clear layer 153; Corvic floor covering shown in Figure 8 is in forcing press; with 130～140 ℃ press temperature, 40kg/cm ²Pressure suppress simultaneously and heated all layers 20～30 minutes and make.

Embodiment 2

(preparation of base layer 100)

Mixture is joined in the banbury mixers and mediates therein.Be to flatten by compacting and with mixture in 130 ℃～160 ℃ the calender to produce the base layer 100 that thickness is 2.6mm in a temperature then.

(preparation of bottom 110)

(preparation of printed layers 120)

With including the degree of polymerization is 1000 100 weight portion Corvics, and 20 weight portion dioctyl phthalates, the barium zinc compound of 3 weight portions, the pre-composition of 20 parts by weight of titanium oxide and 10 weight portion calcium carbonate join in the mixer and mix therein.

Mixture is joined in the banbury mixers and mediates therein.Be by compacting and make the smooth mode of mixture produce the Corvic sheet that thickness is 0.10mm in 170 ℃～180 ℃ the calender in a temperature then.

The printed layer 120 of melamine resin impregnated sheets of paper is printed a pattern by dry on the Corvic sheet and photolithography and is prepared.

(preparation of balance layer 140)

Every square metre is that 30 balance layer 140 sheet materials that restrain are to prepare by natural fiber being pressed into cotton-shaped sheet material.

(preparation of protective clear layer 153)

At liquid melamine resin dipping 38g/m with 250 weight % (by the weight of per unit veneer paper) ²Veneer paper after; the protective clear layer 153 of melamine resin impregnated sheets of paper is by being that dry simultaneously and semi-solid preparation prepared in 2～3 minutes in 120 ℃～140 ℃ the stove in temperature; this liquid melamine resin is the melamine of 37 weight portions; the formaldehyde of 33 weight portions; the water of 25 weight portions, the pre-composition of the amine base catalyst of the diethylene glycol (DEG) of 1 weight portion and 3.7 weight portions.

(preparation of Corvic floor covering (Fig. 9))

With bottom 110, base layer 100, printed layers 120; after the scraps of paper 150 of balance layer 140 and the resin dipping be made up of protective clear layer 153 are placed; Corvic floor covering shown in Figure 9 be with all layers in forcing press, with 130～140 ℃ press temperature, 40kg/cm ²Pressure suppress simultaneously and heat and prepared in 20～30 minutes.

Embodiment 3

(preparation of base layer 100)

Mixture is joined in the banbury mixers and mediates therein.Be by compacting mixture to be flattened in 130 ℃～160 ℃ the calender to produce the base layer 100 that thickness is 2.6mm in a temperature then.

(preparation of bottom 110)

(preparation of adhesive phase 130)

Prepare the sheet material adhesive phase 130 that thickness is 0.07mm by the calendering amide resin.

(preparation of balance layer 140)

Every square metre is that balance layer 140 sheet materials of 30 grams are to fold and prepare by natural fiber being pressed into one.

(preparation of sandwich layer 151)

At liquid phenolic resin dipping 80g/m with 60 weight % (by the weight of per unit brown paper) ²Brown paper after, the sandwich layer 151 of the resin impregnating scraps of paper is by being that dry simultaneously and semi-solid preparation prepared in 2～3 minutes in 100～120 ℃ the stove in temperature, this liquid phenolic resin is the phenol of 43 weight portions, the formaldehyde of 33 weight portions, the ethanol of 5 weight portions, the water of 3 weight portions, the pre-composition of the amine strain base catalyst of 3.7 weight portions and the orthoresol of 6 weight portions.

(preparation of decorative layer 152)

The decorative layer 152 of melamine resin impregnated sheets of paper is at the liquid melamine resin dipping 80g/m with 100 weight % (according to the weight of facing paper) ²Printed decoration paper after, by being that dry simultaneously and semi-solid preparation prepared in 2～3 minutes in 120 ℃～140 ℃ the stove in temperature, this liquid melamine resin is the melamine of 37 weight portions, the formaldehyde of 33 weight portions, the water of 25 weight portions, the pre-composition of the amine base catalyst of the diethylene glycol (DEG) of 1 weight portion and 3.7 weight portions.

(preparation of protective clear layer 153)

The protective clear layer 153 of melamine resin impregnated sheets of paper is at the liquid melamine resin dipping 38g/m with 250 weight % (according to the weight of veneer paper) ²Veneer paper after, by being that dry simultaneously and semi-solid preparation prepared in 2～3 minutes in 120 ℃～140 ℃ the stove in temperature, this liquid melamine resin is the melamine of 37 weight portions, the formaldehyde of 33 weight portions, the water of 25 weight portions, the pre-composition of the amine base catalyst of the diethylene glycol (DEG) of 1 weight portion and 3.7 weight portions.

(preparation of Corvic floor covering (Figure 10))

Corvic floor covering shown in Figure 10 is with bottom 110, base layer 100, adhesive phase 130; balance layer 140 and by sandwich layer 151; after the scraps of paper 150 of the resin dipping that decorative layer 152 and protective clear layer 153 are formed are completed; by in forcing press; with 130～140 ℃ platen temperature, 40kg/cm ²Pressure suppress simultaneously and heated all layers 20～30 minutes and prepare.

Embodiment 4

(preparation of base layer 100)

To include the Corvic of 25～15 weight portions, the dioctyl phthalate plasticizer of 6～4 weight portions, the barium zinc compound stabilizing agent of 4～1 weight portions and the pre-composition of 65～80 weight portion calcium carbonate join in the mixer and mix therein.

Mixture is joined in the banbury mixers and mediates therein.Be to flatten by compacting and with mixture in 130 ℃～160 ℃ the calender to produce the base layer 100 that thickness is 2～4mm in a temperature then.

(preparation of bottom 110)

To include the Corvic of 50～60 weight portions, the dioctyl phthalate plasticizer of 15～10 weight portions, the barium zinc compound stabilizing agent of 5～10 weight portions and the pre-composition of 30～20 weight portion calcium carbonate join in the mixer and mix therein.

Mixture is joined in the banbury mixers and mediates therein.Be to flatten by compacting and with mixture in 130 ℃～160 ℃ the calender to produce the bottom 110 that thickness is 0.05～0.5mm in a temperature then.

(preparation of balance layer 140)

Preparing every square metre is the polypropylene non-woven fibre balance layer 140 of 50 grams.

(preparation of sandwich layer 151)

The sandwich layer 151 of the resin impregnating scraps of paper is at the liquid phenolic resin dipping 80g/m with 60 weight % (according to the weight of brown paper) ²Brown paper after, by being that dry simultaneously and semi-solid preparation prepared in 2～3 minutes in 100～120 ℃ the stove in temperature, this liquid phenolic resin is the phenol of 43 weight portions, the formaldehyde of 33 weight portions, the ethanol of 5 weight portions, the water of 3 weight portions, the pre-composition of the amine base catalyst of 3.7 weight portions and the orthoresol of 6 weight portions.

(preparation of decorative layer 152)

(preparation of protective clear layer 153)

(preparation of high-pressure laminated plate)

High-pressure laminated plate is with balance layer 140 with by sandwich layer 151, after the Tetefol sheet 150 that decorative layer 152 and protective clear layer 153 are formed is completed, by in an open forcing press with 130～150 ℃ platen temperature, 55～100kg/cm ²Pressure suppress simultaneously and heat all layers and prepared in 20～30 minutes.

(preparation of adhesive phase 130)

Adhesive phase 130 be with solid concentration be polyurethane binder of 40 weight % by applicator roll with 65～150g/m ²Being coated in base layer (100) goes up and makes.

(preparation of Corvic floor covering (Figure 10))

With bottom 110; base layer 100 and by balance layer 140; sandwich layer 151; after the high-pressure laminating material that decorative layer 152 and protective clear layer 153 are formed is completed; the Corvic floor covering that 3.0mm shown in Figure 10 is thick is by in forcing press with all layers; with 80～120 ℃ platen temperature, 10～30kg/cm ²Pressure suppress simultaneously and heat and prepared in 15～30 minutes.

Embodiment 5

(preparation of base layer 100)

According to preparing base layer 100 with embodiment 4 described identical modes.

(preparation of bottom 110)

According to preparing bottom 110 with embodiment 4 described identical modes.

(preparation of balance layer 140)

According to preparing balance layer 140 with embodiment 4 described identical modes.

(preparation of sandwich layer 151)

The glass fibre scraps of paper that phenolic resins soaks are at the liquid phenolic resin dipping 40～160g/m with 40～60 weight % (by the weight of per unit all-glass paper) ²All-glass paper after, by being that dry simultaneously and semi-solid preparation prepared in 2～3 minutes in 100～120 ℃ the stove in temperature, this liquid phenolic resin is the phenol of 43 weight portions, the formaldehyde of 33 weight portions, the ethanol of 5 weight portions, the water of 3 weight portions, the pre-composition of the amine base catalyst of 3.7 weight portions and the orthoresol of 6 weight portions.Sandwich layer 151 is by overlapping the making of the glass fibre scraps of paper with two resin impregnatings.

(preparation of decorative layer 152)

According to preparing decorative layer 152 with embodiment 4 described identical modes.

(preparation of protective clear layer 153)

According to preparing protective clear layer 153 with embodiment 4 described identical modes.

(preparation of high-pressure laminated plate)

With balance layer 140 with by two sandwich layers 151, after the Tetefol sheet 150 that decorative layer 152 and protective clear layer 153 are formed is laid, high-pressure laminated plate be with all layers by in an open press power with 130～150 ℃ platen temperature, 55～100kg/cm ²Pressure suppress simultaneously and heat and prepared in 20～30 minutes.

(preparation of adhesive phase 130)

Preparation thickness is the acid amides film adhesive layer 130 of 0.10mm.

(preparation of Corvic floor cover (Figure 10))

With bottom 110; base layer 100; adhesive phase 130 and by balance layer 140; two sandwich layers 151; after the high-pressure laminated plate that decorative layer 152 and protective clear layer 153 are formed is laid; the Corvic floor covering that 3.0mm shown in Figure 10 is thick be with all layers in forcing press, with 100～140 ℃ platen temperature, 10～20kg/cm ²Pressure suppress simultaneously and heat and prepared in 15～30 minutes.

Embodiment 6

(preparation of base layer 100)

(preparation of bottom 110)

According to preparing bottom 110 with embodiment 4 described identical modes.

(preparation of balance layer 140)

(preparation of sandwich layer 151)

According to preparing the glass fibre scraps of paper of resin impregnating with the described identical mode of embodiment 5.

Sandwich layer 151 is to carry out overlapping the preparation by the glass fibre scraps of paper with two resin impregnatings.

(preparation of decorative layer 152)

(preparation of protective clear layer 153)

(preparation of high-pressure laminated plate)

With balance layer 140 with by two sandwich layers 151, after the Tetefol sheet 150 that decorative layer 152 and protective clear layer 153 are formed is laid, the high-pressure laminating material by in an open press with 130～150 ℃ platen temperature, 55～100kg/cm ²Pressure suppress simultaneously and heat all layers and prepared in 20～30 minutes.

(preparation of adhesive phase 130)

Preparation thickness is the epoxy resin film adhesive phase 130 of 0.10mm.

(preparation of Corvic floor covering (Figure 10))

With bottom 110; base layer 100; adhesive phase 130 and by balance layer 140; sandwich layer 151; after the high-pressure laminated plate that decorative layer 152 and protective clear layer 153 are formed is laid; the Corvic floor covering that 3.0mm shown in Figure 10 is thick passes through in forcing press, with 100～140 ℃ pressure and temp, 10～20kg/cm ²Pressure suppress simultaneously and heat all layers and prepared in 15～30 minutes.

Embodiment 7

(preparation of base layer 100)

The base layer 100 that preparation is identical with embodiment 4.

(preparation of bottom 110)

The bottom 110 that preparation is identical with embodiment 4.

(preparation of balance layer 140)

The balance layer 140 that preparation is identical with embodiment 4.

(preparation of sandwich layer 1)

The material of the sandwich layer 1 that preparation is identical with embodiment 4.

(preparation of sandwich layer 2)

The material of the sandwich layer 2 that preparation is identical with embodiment 5.

(preparation of decorative layer 152)

The decorative layer 152 that preparation is identical with embodiment 4.

(preparation of protective clear layer 153)

The protective clear layer 153 that preparation is identical with embodiment 4.

(decorating manufacturing) with the ground floor pressing plate

With base layer 100, sandwich layer 2, balance layer 140, sandwich layer 1, after decorative layer 152, protective clear layer 153 are layered on the bottom 110 in order, with forcing press at 10～30kg/cm ²Pressure, under 130～150 ℃ the temperature, by suppressing simultaneously and heating layer recited above and made the thick decoration floor covering of 3cm in 15～30 minutes.

Embodiment 8

Be prepared into size with floor covering be 400 * 400 * 3mm and it is placed in the thermostat after 24 hours at the decoration with top described embodiment 4, measures its crimpness.Relative humidity is fixed on 60 ± 5%.Measuring temperature is-10,23,30, and crimpness is illustrated in the table 1 in the time of 40 and 60 ℃, is 20,40,60 measuring humidity, and crimpness was presented in the table 2 in 80,95% o'clock.

Crimpness is calculated according to formula 1 described below:

[formula 1]

Length * 100 of curling (%)=camber/sample

Sample strip is handled 24 hours in thermostat after, sample strip is placed on the flat ground surface, camber is the measuring height in from ground to the turning point (place of sample strip bending).The bending of the Tetefol layer waviness of show sample represents with+value, and opposite depression is represented with-value.

[table 1]

In relative humidity is 60 ± 5% o'clock Temperature Influence

Temperature	Embodiment 4
Temperature	Embodiment 4	60℃	+3.80％
40℃	+2.50％	60℃	+3.80％
40℃	+2.50％	30℃	+0.75％
23℃	+0.15％	30℃	+0.75％
23℃	+0.15％	-10℃	-1.03％

[table 2]

The influence of humidity when temperature is 23 ± 2 ℃

Absolute humidity	Embodiment 4
Absolute humidity	Embodiment 4	20％	+0.36％
40％	+0.26％	20％	+0.36％
40％	+0.26％	60％	+0.15％
80％	+0.05％	60％	+0.15％
80％	+0.05％	95％	+0％

By result recited above as can be known, to place the decoration between the polyvinyl chloride resin base layer below resin impregnate layer and the resin impregnate layer be the variation of standing temperature and humidity with this floor covering to balance layer.

Embodiment 9

(preparation of base layer 100)

The base layer that preparation is identical with embodiment 4.

(preparation of balance layer 140)

The balance layer that preparation is identical with embodiment 4.

(preparation of sandwich layer 151)

The sandwich layer that preparation is identical with embodiment 4.

(preparation of decorative layer 152)

The decorative layer 152 that preparation is identical with embodiment 4.

(preparation of protective clear layer 153)

The protective clear layer 153 that preparation is identical with embodiment 4.

(preparation of high pressure zone material)

At each layer that will prepare above: after the protective clear layer 153 of Tetefol layer 150, decorative layer 152 and sandwich layer 151 are layered in the forcing press from top to bottom in order, at 55～100kg/cm ²Pressure, under 130～150 ℃ the temperature, these the lamination systems completed and heating were made HPL (high-pressure laminating material) in 20～30 minutes.

(preparation of adhesive phase 130)

Is that polyurethane binder of 40% is with 60～150g/m by using applicator roll with solids content ²Be coated on the base layer 100 recited above and prepare adhesive phase.

(bonding)

At the ply of paper 150 of resin dipping be coated in after coating 130 on the matrix 100 places in order, ply of paper 150 that resin floods and matrix 100 working pressure machines are at 10～30kg/cm ²Pressure, under 80～120 ℃ the temperature, suppress and heated 15～30 minutes and bond together.

(preparation of adhesive phase 130)

Using applicator roll is that polyurethane binder of 40% is with 60～150g/m with solids content ²Be coated in base layer 100 (it and place the adhesive phase 130 between top described Tetefol layer 150 and the base layer 100 to bond together) below prepare another adhesive phase 130.

(decorating manufacturing) with floor cover (Figure 14)

After below balance layer 140 recited above being placed on base layer recited above, decoration shown in Figure 14 passes through at 8～30kg/cm with floor covering ²Pressure down compacting made in 4～24 hours.

Claims

1. ornamental polyvinyl chloride resin floor covering, be to be laid on polyvinyl chloride resin base layer (100) to go up the stratified material that the ply of paper (150) of dipping melamine resin makes and be bonded by compacting, this decoration of PVC resin floor cladding material comprises bottom that is layered on the bottom surface (110) and the balance layer (140) between the ply of paper (150) of base layer (100) and dipping melamine resin that is positioned under the base layer, and the material of this balance layer is to be selected from textile fabric and non-woven fibre.

2. the decoration of PVC resin floor cladding material of claim 1, wherein the material of this bottom (110) is paper or textile fabric and polyvinyl chloride resin dipping or the coated glass fibers non-woven fibre that is selected from phenolic resins, melamine resin or acrylic resin dipping.

3. the decoration of PVC resin floor cladding material of claim 1, wherein this floor covering is that the stratified material of making is bonded by compacting by placing the adhesive layer (130) between balance layer (140) and the base layer (100).

4. the decoration of PVC resin floor cladding material of claim 3, wherein this adhesive layer is a kind of polymer of mixing or the sheet material or the film of a kind of curtain coating, calendering or T shape mold forming, and the polymer of this mixing is selected from chloroprene resin, acrylonitrile-butadiene rubber, acrylic resin, polyester, urethanes, rubber, vinylite and epoxy resin; And this sheet material or film are acrylic resin, resin modified phenol resin, the urethane resin of the ethylene vinyl acetate resin that is selected from amide resin, ethylene vinyl acetate resin, modification, acrylic resin, modification, the urethane resin and the epoxy resin of modification.

5. the decoration of PVC resin floor cladding material of claim 1, wherein this textile fabric and non-woven fibre are made by natural fiber.

6. the decoration of PVC resin floor cladding material of claim 1, wherein said textile fabric is the yarn fabric of braiding, makes by being selected from following fiber: the yarn fabric that natural fiber, glass fibre, carbon fiber, PETG, polypropylene, polyester and nylon or the polyvinyl chloride resin made from the textile fabric of polyvinyl chloride resin dipping braiding flood.

7. the decoration of PVC resin floor cladding material of claim 1, wherein non-woven fibre is the non-woven fabric of braiding, makes by being selected from following fiber: the non-woven fabric that natural fiber, glass fibre, carbon fiber, poly terephthalic acid, glycol ester, polypropylene, polyester and nylon or the polyvinyl chloride resin made from the non-woven fibre of polyvinyl chloride resin dipping braiding flood.

8. the decoration of PVC resin floor cladding material of claim 1, wherein the ply of paper (150) of melamine resin dipping comprises and places successively downwards:

A) protective clear layer (153);

B) decorative layer (152); With

C) sandwich layer (151).

9. the decoration of PVC resin floor cladding material of claim 1, wherein the ply of paper (150) of melamine resin dipping comprises and places successively downwards:

A) decorative layer (152); With

B) sandwich layer (151).

10. the decoration of PVC resin floor cladding material of claim 1, wherein the ply of paper (150) of melamine resin dipping comprises and places successively downwards:

A) protective clear layer (153); With

B) decorative layer (152).

11. the decoration of PVC resin floor cladding material of claim 1 also contains and downwards places successively:

A) comprise the ply of paper (150) of the melamine resin dipping of protective clear layer (153);

B) balance layer (140);

C) printed layer (120);

D) base layer (100); With

E) bottom (110).

12. the decoration of PVC resin floor cladding material of claim 1 also contains and downwards places successively:

A) comprise the ply of paper (150) of the melamine resin dipping of hyaline layer (153), decorative layer (152) and sandwich layer (151);

B) balance layer (140);

C) adhesive layer (130);

D) base layer (100); With

E) bottom (110).

13. the decoration of PVC resin floor cladding material of claim 1 also contains and downwards places successively:

A) comprise the ply of paper (150) of the melamine resin dipping of protective clear layer (153), decorative layer (152) and sandwich layer (151);

B) balance layer (140);

C) sandwich layer (151);

D) adhesive layer (130);

E) base layer (100); With

F) bottom (110).

14. the decoration of PVC resin floor cladding material of claim 1 contains and downwards places successively:

The ply of paper (150) of the melamine resin dipping of a) forming by protective clear layer (153), decorative layer (152) and sandwich layer (151);

B) adhesive layer (130);

C) base layer (100);

D) adhesive layer (130); With

E) balance layer (140).

15. each decoration of PVC resin floor cladding material in claim 8 or 10 to 14, wherein protective clear layer (153) is the plain paper of pitch based fiber, it be by semi-solid preparation and dipping with wear-resistant silica and aluminium oxide with 25-61g/m ²The homodisperse cellulose paper of amount and make, contain the melamine resin of 200-800 weight % in the veneer paper of its per unit weight.

16. each decoration of PVC resin floor cladding material in claim 8 to 11 or 13 to 14, wherein decorative layer (152) is the facing paper of impregnating resin, and it is with 80-120g/m ²The photomechanical printing cellulose paper that contains titanium oxide is made by semi-solid preparation and dipping, and the content of resin is to be lower than 100% of this facing paper weight in the facing paper, and this resin is selected from melamine resin, mylar, diallyl phthalate ester resin or phenolic resins.

17. each decoration of PVC resin floor cladding material in the claim 8,9,11,13 or 14, its center core layer (151) is to be selected from: be impregnated with and be lower than 198g/m ²The brown paper of phenolic resins, wherein phenolic resins is the 20-100 weight % of this brown paper weight; The all-glass paper of impregnated phenolic resin or be coated with polyvinyl chloride resin or the all-glass paper of acrylic resin, they are that phenolic resins with the 20-100% of glass fibre weight applies 40-160g/m ²All-glass paper make; And the glass mat of impregnated phenolic resin or be coated with polyvinyl chloride resin or the glass fibre of acrylic resin, they are that phenolic resins with the 20-60% of glass fibre weight applies 40-160g/m ²Glass mat.

18. the decoration of PVC resin floor cladding material of claim 1, wherein the Shore hardness of base layer (100) is in the 50-100 scope.

19. a method of making decoration of PVC resin floor cladding material comprises following step: the polyvinyl chloride resin compound is made base layer (100) by calendering; With fiberglass braided one-tenth weaven goods or glass fibre is repressed and make bottom (110); Textile fabric or non-woven fibre is repressed and make balance layer (140); Dryly carry out semi-solid preparation simultaneously and make the ply of paper of impregnating resin (150) with in baking oven, carrying out after the melamine resin impregnated paper; And the ply of paper (150) of laying base layer (100), balance layer (140) and impregnating resin on fiberglass-based bottom (110) successively uses press at 10-80kg/cm afterwards ²Under pressure and the 120-180 ℃ temperature hot pressing 10-40 minute.

20. the method for the manufacturing decoration of PVC resin floor cladding material of claim 19, wherein the ply of paper of impregnating resin (150) comprises and downwards places successively:

A) protective clear layer (153), it is that veneer paper is made with carrying out drying and semi-solid preparation simultaneously after the liquid melamine resin dipping in baking oven;

B) decorative layer (152), it is to carry out drying and semi-solid preparation simultaneously after will the used for decorative paper liquid melamine resin dipping in baking oven and make; And

C) sandwich layer (151), it be with brown paper with after the liquid phenolic resin dipping in baking oven dry and semi-solid preparation form.

21. the method for the manufacturing decoration of PVC resin floor cladding material of claim 19, wherein the ply of paper of impregnating resin (150) comprises and downwards places successively:

A) decorative layer (152), it is to carry out drying and semi-solid preparation simultaneously after will the used for decorative paper liquid melamine resin dipping in baking oven and make; And

B) sandwich layer (151), it is that brown paper is formed with carrying out drying and semi-solid preparation simultaneously after the liquid phenolic resin dipping in baking oven.

22. the method for the manufacturing decoration of PVC resin floor cladding material of claim 19, wherein the ply of paper of impregnating resin (150) comprises and downwards places successively:

A) protective clear layer (153), it is that veneer paper is made with carrying out drying and semi-solid preparation simultaneously after the liquid melamine resin dipping in baking oven; And

B) decorative layer (152), it is to carry out drying and semi-solid preparation simultaneously after will the used for decorative paper liquid melamine resin dipping in baking oven and make.

23. the method for the manufacturing decoration of PVC resin floor cladding material of claim 19, wherein the ply of paper of impregnating resin (150) contains: the veneer paper of the liquid melamine resin dipping of usefulness carries out dry and semi-solid preparation and the protective clear layer (153) that makes simultaneously in baking oven; A balance layer of placing printed layer below (140); And a printed layer (120), this printed layer is to be made the polyvinyl chloride resin sheet material, xeroxed or transfer printing on this polyvinyl chloride resin sheet material by polyvinyl chloride resin compound calendering, then the polyvinyl chloride resin sheet material of this stamp is carried out drying and makes.

24. the method for each manufacturing decoration of PVC resin floor cladding material among the claim 19-23, wherein balance layer (140) is textile fabric, non-woven fibre or the cotton-shaped sheet material of natural fiber base.

25. the method for each manufacturing decoration of PVC resin floor cladding material among the claim 19-23, wherein adhesive layer (130) is placed on below the balance layer (140), this adhesive layer (130) in the form of sheets, formed by resin calendering or T shape mold forming, this resin is selected from the urethane resin of acrylic resin, resin modified phenol resin, Benzocaine resin and modification of ethylene vinyl acetate resin, acrylic resin, the modification of amide resin, ethylene vinyl acetate resin, modification.

26. the method for the manufacturing decoration of PVC resin floor cladding material of claim 25, wherein balance layer (140) is textile fabric, non-woven fibre or the cotton-shaped sheet material of natural fiber base.

27. method of making decoration of PVC resin floor cladding material, this material contains the bottom (110) below base layer (100), the base layer (100), the ply of paper (150) of adhesive layer (130), balance layer (140) and impregnating resin above the base layer (100), and this method comprises following step:

A) go up coating 80-130g/m at base layer (100) ²Adhesive or lay an adhesive films and make adhesive layer (130);

B) on the adhesive layer of step (a), upwards lay after the high-pressure laminated plate sheet material this high-pressure laminated plate sheet material and base layer at 130-160 ℃ of temperature and 10-30kg/cm ²Compacting made it the bonding laminate of making in 10-20 minute on the pressing plate of pressure, and this high-pressure laminating sheet material comprises balance layer (140), sandwich layer (151), decorative layer (152) and protective clear layer (153); And

C) below the laminate of step (b), lay bottom (110) and the stratified material made at room temperature and 10-30kg/cm ²Under suppressed 15-30 minute.

28. the method for the manufacturing decoration of PVC resin floor cladding material of claim 27; wherein the high-pressure laminated plate of step (b) be successively to the upper berth after prepared balance layer, sandwich layer, decorative layer and the protective clear layer, be that 130-150 ℃ and pressure are 55-100kg/cm at platen temperature ²Under suppressed 15-30 minute and make.

29. the method for the manufacturing decoration of PVC resin floor cladding material of claim 27, wherein the material of balance layer (140) is selected from the paper of cotton-shaped sheet material, textile fabric, non-woven fibre and dipping melamine resin or phenolic resins.

30. the method for the manufacturing decoration of PVC resin floor cladding material of claim 29, wherein the material of textile fabric is selected from glass fibre, carbon fiber, PETG, polypropylene, polyester and nylon.

31. the method for the manufacturing decoration of PVC resin floor cladding material of claim 29, wherein the material of non-woven fibre is selected from glass fibre, carbon fiber, PETG, polypropylene, polyester and nylon.

32. the method for the manufacturing decoration of PVC resin floor cladding material of claim 27, wherein protective clear layer (153) is the plain paper of pitch based fiber, and it is with 25-61g/m ²The cellulose paper that is dispersed with wear-resistant silica or aluminium oxide with in temperature is 130-150 ℃ baking oven, carrying out dry simultaneously after the melamine resin of the 200-800 weight % of the veneer paper weight dipping and semi-solid preparation is made.

33. the method for the manufacturing decoration of PVC resin floor cladding material of claim 27, wherein decorative layer (152) is the facing paper of impregnating resin, and it is with 80-120g/m ²The photomechanical printing cellulose paper that contains titanium oxide be that used for decorative paper is lower than after the resin dipping of this facing paper weight 100 weight % at oven temperature be to carry out dry under 130-150 ℃ simultaneously and semi-solid preparation is made.

34. the method for the manufacturing decoration of PVC resin floor cladding material of claim 27, its center core layer (151) is to be selected from: the brown paper of impregnated phenolic resin, it is to be lower than 198g/cm ²Brown paper make with the resin impregnating of this brown paper weight 20-100 weight %; The all-glass paper of impregnated phenolic resin or be coated with polyvinyl chloride resin or the all-glass paper of acrylic resin, it is that phenolic resins with the 20-100 weight % of this glass fibre paper weight applies 40-160g/m ²All-glass paper make; And the glass mat of impregnated phenolic resin or be coated with polyvinyl chloride resin or the glass fibre of acrylic resin, they are that phenolic resins with the 20-60 weight % of this glass fibre weight applies 40-160g/m ²Glass mat make.

35. the method for the manufacturing decoration of PVC resin floor cladding material of claim 27, wherein the adhesive in the step (a) is a kind of polymer of mixing, and it is the composition of more than one polymer of selecting from chloroprene resin, butyronitrile resin, acrylic resin, polyester, urethanes, rubber, vinyl and epoxy resin.

36. the method for the manufacturing decoration of PVC resin floor cladding material of claim 27, wherein the adhesive films of step (a) is sheet material or the film that makes by curtain coating, calendering or T shape mold forming, and its material is selected from acrylic resin, resin modified phenol resin, the urethane resin of ethylene vinyl acetate resin, the modification of amide resin, ethylene vinyl acetate resin, modification, the urethane resin and the epoxy resin of modification.

37. a method of making decoration of PVC resin floor cladding material, this material is by base layer (100); Adhesive layer (130) and bottom (110) below this base layer (100); Form with the ply of paper (150) that is layered on adhesive layer (130), balance layer (140) and impregnating resin on the base layer (100), this method comprises following step:

A) on base layer (100), be coated with 80-300g/m ²Adhesive make adhesive layer (130) thus;

B) being 130-160 ℃ in temperature after the laying high-pressure laminated plate sheet material on step (a) adhesive layer is 10-30kg/cm with pressure ²Pressing plate down compacting made high-pressure laminated plate sheet material and the bonding laminate of base layer (100) thus in 10-20 minute, this high-pressure laminated plate sheet material upwards is made up of balance layer (140), the ply of paper (150) that comprises the impregnating resin of sandwich layer (151), decorative layer (152) and protective clear layer (153) successively;

C) on the laminate bottom surface of step (b), be coated with 80-300g/m ²Adhesive and make another adhesive layer (130); And

D) below the adhesive layer (130) of step (c), lay bottom layer (110) afterwards at room temperature and 3-8kg/cm ²Pressure compacting was down made the decorative floor cladding material in 4-24 hour.

38. a method of making decoration of PVC resin floor cladding material comprises following step:

A) make bottom (110), base layer (100), adhesive layer (130), balance layer (140), sandwich layer (151), decorative layer (152) and protective clear layer (153);

B) Manufactured following each layer upwards laid successively: bottom (110), base layer (100), adhesive layer (130), balance layer (140), sandwich layer (151), decorative layer (152) and protective clear layer (153);

C) with above-mentioned each that lays layer at 130-160 ℃ of temperature and 10-30kg/cm ²Pressing plate at room temperature cool off after hot pressing 10-20 minute and make decoration of PVC resin floor cladding material.

39. one kind contains the bottom (110) below a base layer (100), this base layer and the decoration of PVC resin floor cladding material of a ply of paper (150) that covers the impregnating resin on the base layer (100), a kind of decorative floor cladding material wherein contains:

A) base layer (100), the Shore hardness of its material is 50-100, this material is selected from polyvinyl chloride resin, polyurethane, natural or synthetic rubber, vistanex, mylar and elastomer; And

B) place balance layer (140) between base layer (100) and the impregnating resin layer (150), the material of this balance layer (140) is selected from the paper of cotton-shaped sheet material, textile fabric, non-woven fibre and dipping melamine resin or phenolic resins.