CN100389058C - 负载型纳米硒及其制备方法 - Google Patents
负载型纳米硒及其制备方法 Download PDFInfo
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- CN100389058C CN100389058C CNB2005100502954A CN200510050295A CN100389058C CN 100389058 C CN100389058 C CN 100389058C CN B2005100502954 A CNB2005100502954 A CN B2005100502954A CN 200510050295 A CN200510050295 A CN 200510050295A CN 100389058 C CN100389058 C CN 100389058C
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- selenium
- mineral material
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- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 title claims abstract description 116
- 239000011669 selenium Substances 0.000 title claims abstract description 99
- 229910052711 selenium Inorganic materials 0.000 title claims abstract description 99
- 238000002360 preparation method Methods 0.000 title claims abstract description 21
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 44
- 239000011707 mineral Substances 0.000 claims abstract description 44
- 239000000463 material Substances 0.000 claims abstract description 43
- 238000001694 spray drying Methods 0.000 claims abstract description 9
- 150000003342 selenium Chemical class 0.000 claims abstract description 8
- 230000002829 reductive effect Effects 0.000 claims abstract description 5
- 239000002002 slurry Substances 0.000 claims description 30
- 239000000725 suspension Substances 0.000 claims description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 238000000034 method Methods 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000011734 sodium Substances 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 18
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 17
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 17
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 16
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 16
- 229960001545 hydrotalcite Drugs 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- 229910021536 Zeolite Inorganic materials 0.000 claims description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 14
- 239000010457 zeolite Substances 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000001488 sodium phosphate Substances 0.000 claims description 12
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 12
- 229910000406 trisodium phosphate Inorganic materials 0.000 claims description 12
- 235000019801 trisodium phosphate Nutrition 0.000 claims description 12
- 239000004113 Sepiolite Substances 0.000 claims description 10
- 230000018044 dehydration Effects 0.000 claims description 10
- 238000006297 dehydration reaction Methods 0.000 claims description 10
- 229910052624 sepiolite Inorganic materials 0.000 claims description 10
- 235000019355 sepiolite Nutrition 0.000 claims description 10
- 238000009775 high-speed stirring Methods 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 8
- 230000008569 process Effects 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 8
- 239000005543 nano-size silicon particle Substances 0.000 claims description 7
- 235000012239 silicon dioxide Nutrition 0.000 claims description 7
- 229920005552 sodium lignosulfonate Polymers 0.000 claims description 5
- 229960000892 attapulgite Drugs 0.000 claims description 4
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethyl mercaptane Natural products CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052625 palygorskite Inorganic materials 0.000 claims description 4
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 claims description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 3
- 239000012279 sodium borohydride Substances 0.000 claims description 3
- 235000019154 vitamin C Nutrition 0.000 claims description 2
- 239000011718 vitamin C Substances 0.000 claims description 2
- 239000011148 porous material Substances 0.000 abstract description 13
- 239000002245 particle Substances 0.000 abstract description 10
- 238000009826 distribution Methods 0.000 abstract description 8
- 244000144972 livestock Species 0.000 abstract description 4
- 231100000053 low toxicity Toxicity 0.000 abstract description 4
- 238000005054 agglomeration Methods 0.000 abstract 1
- 230000002776 aggregation Effects 0.000 abstract 1
- 239000003674 animal food additive Substances 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 238000009837 dry grinding Methods 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 229940091258 selenium supplement Drugs 0.000 description 77
- 235000010755 mineral Nutrition 0.000 description 25
- 230000005540 biological transmission Effects 0.000 description 8
- 239000002086 nanomaterial Substances 0.000 description 8
- 241001465754 Metazoa Species 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 230000002354 daily effect Effects 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 235000013372 meat Nutrition 0.000 description 6
- 239000002105 nanoparticle Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 241000287828 Gallus gallus Species 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000011160 research Methods 0.000 description 4
- 241000272525 Anas platyrhynchos Species 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 244000144977 poultry Species 0.000 description 3
- 241000276707 Tilapia Species 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- BVTBRVFYZUCAKH-UHFFFAOYSA-L disodium selenite Chemical compound [Na+].[Na+].[O-][Se]([O-])=O BVTBRVFYZUCAKH-UHFFFAOYSA-L 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000011835 investigation Methods 0.000 description 2
- 229940087654 iron carbonyl Drugs 0.000 description 2
- 230000033458 reproduction Effects 0.000 description 2
- 229960001471 sodium selenite Drugs 0.000 description 2
- 239000011781 sodium selenite Substances 0.000 description 2
- 235000015921 sodium selenite Nutrition 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- RJFAYQIBOAGBLC-UHFFFAOYSA-N 2-amino-4-methylselanyl-butanoic acid Chemical compound C[Se]CCC(N)C(O)=O RJFAYQIBOAGBLC-UHFFFAOYSA-N 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000238553 Litopenaeus vannamei Species 0.000 description 1
- 229910001051 Magnalium Inorganic materials 0.000 description 1
- 235000008708 Morus alba Nutrition 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 231100000215 acute (single dose) toxicity testing Toxicity 0.000 description 1
- 238000011047 acute toxicity test Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- 230000006907 apoptotic process Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000009360 aquaculture Methods 0.000 description 1
- 244000144974 aquaculture Species 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000008827 biological function Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000013626 chemical specie Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000005906 dihydroxylation reaction Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000002124 endocrine Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000005556 hormone Substances 0.000 description 1
- 229940088597 hormone Drugs 0.000 description 1
- 231100000567 intoxicating Toxicity 0.000 description 1
- 230000002673 intoxicating effect Effects 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000002090 nanochannel Substances 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000001338 self-assembly Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
- 208000024877 white muscle disease Diseases 0.000 description 1
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Medicinal Preparation (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
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CNB2005100502954A CN100389058C (zh) | 2005-04-19 | 2005-04-19 | 负载型纳米硒及其制备方法 |
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CNB2005100502954A CN100389058C (zh) | 2005-04-19 | 2005-04-19 | 负载型纳米硒及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN1686789A CN1686789A (zh) | 2005-10-26 |
CN100389058C true CN100389058C (zh) | 2008-05-21 |
Family
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CNB2005100502954A Expired - Fee Related CN100389058C (zh) | 2005-04-19 | 2005-04-19 | 负载型纳米硒及其制备方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11090629B2 (en) | 2015-10-13 | 2021-08-17 | Regents Of The University Of Minnesota | Selenium nanomaterials and methods of making and using same |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100405924C (zh) * | 2006-03-29 | 2008-07-30 | 浙江大学 | 控缓释型镁的补镁饲料添加剂及其制备与使用方法 |
CN100364548C (zh) * | 2006-03-29 | 2008-01-30 | 浙江大学 | 控缓释型铁的补铁剂及其制备方法和用途 |
CN100364551C (zh) * | 2006-04-12 | 2008-01-30 | 浙江大学 | 负载型超细锌粉的补锌剂及制备方法和用途 |
US20110049045A1 (en) * | 2008-10-07 | 2011-03-03 | Brown University | Nanostructured sorbent materials for capturing environmental mercury vapor |
CN103027197A (zh) * | 2013-01-06 | 2013-04-10 | 杭州世博生物技术开发研究所有限公司 | 一种含纳米硒的矿物饲料添加剂及其制备方法和应用 |
WO2014202686A1 (fr) * | 2013-06-19 | 2014-12-24 | Pancosma S.A. | Nanoparticules de selenium elementaire et procede de preparation |
CN103445000B (zh) * | 2013-08-19 | 2015-05-06 | 广州天科生物科技有限公司 | 琼脂负载型饲料添加剂纳米硒及其制备方法 |
CN105968416B (zh) * | 2016-05-25 | 2019-01-18 | 吴琦 | 一种用于抗菌塑料的抗菌剂 |
CN106495105B (zh) * | 2016-10-17 | 2018-07-20 | 扬州大学 | 一种合成纳米硒材料的方法 |
CN110235997A (zh) * | 2017-12-25 | 2019-09-17 | 杭州皇冠农业生物工程技术研究中心有限公司 | 一种含纳米硒的矿物饲料添加剂及其制备方法和应用 |
CN108160085B (zh) * | 2018-01-16 | 2020-05-26 | 扬州大学 | 一种硅基纳米硒的制备方法 |
CN108523139A (zh) * | 2018-03-15 | 2018-09-14 | �吴 | 一种负氢离子硒元素补充剂及其制备方法 |
CN110003628A (zh) * | 2019-04-16 | 2019-07-12 | 刘伟 | 一种抗菌可降解塑料母粒及其制备方法 |
CN115430400A (zh) * | 2019-05-31 | 2022-12-06 | 贵州重力科技环保有限公司 | 一种原位纳米级硒非炭基脱汞吸附材料及其制备方法和应用 |
CN111213789A (zh) * | 2020-01-09 | 2020-06-02 | 四川吉隆达生物科技集团有限公司 | 纳米硒饲料添加剂及其制备方法 |
CN112088992A (zh) * | 2020-09-25 | 2020-12-18 | 中山市泰山饲料有限公司 | 一种快速致脆的罗非鱼配方饲料及其制备方法 |
CN112759456A (zh) * | 2021-01-22 | 2021-05-07 | 北部湾大学 | 一种固体硒肥及其制备方法 |
CN112956603B (zh) * | 2021-04-01 | 2021-10-12 | 联科华技术有限公司 | 一种可替代饲用纳米氧化锌的单原子锌添加剂及其制备方法 |
CN114532364B (zh) * | 2022-01-26 | 2022-11-11 | 中国科学院兰州化学物理研究所 | 一种利用油橄榄叶提取物制备纳米硒/凹凸棒石复合抗菌材料的方法 |
CN115259862B (zh) * | 2022-09-02 | 2023-05-05 | 西安理工大学 | 富硒陶瓷制品的硒元素长效缓释方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4548800A (en) * | 1982-08-02 | 1985-10-22 | Xerox Corporation | Process for selenium purification |
US4663141A (en) * | 1984-08-15 | 1987-05-05 | Mitsubishi Kinzoku Kabushiki Kaisha | Process for recovering or purifying selenium |
CN1184776A (zh) * | 1997-05-06 | 1998-06-17 | 合肥经济技术学院 | 活性红色单质硒的制备方法 |
CN1480391A (zh) * | 2002-09-06 | 2004-03-10 | 中国人民解放军军事医学科学院野战输 | 胶体纳米硒颗粒的制备方法 |
CN1519195A (zh) * | 2003-09-02 | 2004-08-11 | 浙江大学 | 制备纳米硒管的方法 |
-
2005
- 2005-04-19 CN CNB2005100502954A patent/CN100389058C/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4548800A (en) * | 1982-08-02 | 1985-10-22 | Xerox Corporation | Process for selenium purification |
US4663141A (en) * | 1984-08-15 | 1987-05-05 | Mitsubishi Kinzoku Kabushiki Kaisha | Process for recovering or purifying selenium |
CN1184776A (zh) * | 1997-05-06 | 1998-06-17 | 合肥经济技术学院 | 活性红色单质硒的制备方法 |
CN1480391A (zh) * | 2002-09-06 | 2004-03-10 | 中国人民解放军军事医学科学院野战输 | 胶体纳米硒颗粒的制备方法 |
CN1519195A (zh) * | 2003-09-02 | 2004-08-11 | 浙江大学 | 制备纳米硒管的方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11090629B2 (en) | 2015-10-13 | 2021-08-17 | Regents Of The University Of Minnesota | Selenium nanomaterials and methods of making and using same |
US11850568B2 (en) | 2015-10-13 | 2023-12-26 | Regents Of The University Of Minnesota | Selenium nanomaterials and methods of making and using same |
Also Published As
Publication number | Publication date |
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CN1686789A (zh) | 2005-10-26 |
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