CN100379400C - 抗皱化妆品袋 - Google Patents
抗皱化妆品袋 Download PDFInfo
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- CN100379400C CN100379400C CNB038041278A CN03804127A CN100379400C CN 100379400 C CN100379400 C CN 100379400C CN B038041278 A CNB038041278 A CN B038041278A CN 03804127 A CN03804127 A CN 03804127A CN 100379400 C CN100379400 C CN 100379400C
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- bag
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
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- A47K7/00—Body washing or cleaning implements
- A47K7/02—Bathing sponges, brushes, gloves, or similar cleaning or rubbing implements
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Abstract
一种用于清洁表面的制品，所述制品包括由多个壁组成的曲线袋，其中至少一个壁是透水的，并且至少一个壁由至少一种无纺缠结纤维网组成，所述纤维缠结方向与网的主长轴垂直。一种通过水活化产生气体的起泡清洁剂组合物，其是一种无水干燥的固体，所述组合物容纳在袋中，和通过产生气体，所述袋壁向外膨胀。缠结纤维在次轴的方向取向以使产品使用时起皱最少。
Description
本发明涉及一种包含起泡干粉的可膨胀袋，所述的起泡干粉能活化放出气体以使所述袋向外膨胀。
传统上在市场出售的清洁制品呈肥皂条、淋浴凝胶和摩丝的形式，其中的泡沫通过机械和气溶胶喷射器得到。消费者采用机械方式帮助形成泡沫并通过擦洗物理除去灰尘。今年来，洗涤织物通常采用这种方式。
洗涤新方式具有巨大的消费者吸引力。例如，表面活性剂和调理剂组合物已经以层的方式加入如在美国专利6280757(McAtee等人)公开的带孔擦拭品中。如在美国专利6066607(Gordon等人)中公开的开孔海绵通过提高起泡的速度和质量以使淋浴凝胶产生泡沫。
美国专利5980931(Fowler等人)公开了一种基本上干质、一次性的个人护理品，其中表面活性剂体系在一种水不溶性无纺布或相似基质上干燥。已经报道了一种第二代双层小毛巾。参见WO 00/42961(Smith)，WO 01/08542(Cen等人)，WO 01/08640(Smith等人)，WO 01/08641(Lorenzi等人)，WO 01/08655(Phipps等人)，WO01/08656(Lorenzi等人)，WO 01/08657(Lorenzi等人)和WO01/08658(Cawkwell人)，其中都公开了一次性的个人清洁小毛巾，所述的小毛巾至少在一个一层为高膨体片的双层织物上具有起泡表面活性剂。消费者期望能够将小毛巾放置于水中产生表面活性剂泡。
另一种途径在美国专利6063390(Farrell等人)中公开，其中记载了一种具有含有起泡清洁剂组合物的袋状结构的擦洗品。所述袋壁中至少一个是透水的。当用水润湿时，组合物中的酸性物质和碱性物质组分起泡产生二氧化碳，并从表面活性剂组分中产生大量的泡沫。通过起泡作用形成鼓起的“垫子”。
EP 0836842B1(Moore等人)公开了椭圆形一次性无纺布清洁用品。所述清洁用品由水缠结纤维组成，其中缠结的方向与椭圆主轴方向平行。
长条形袋特别适宜于握紧；它们在人体功效学上更适于手。对于本发明，起泡袋体系的目标是易于握紧。
由无纺材料制成的袋所面临的一个问题是它们易于起皱。当干的起泡组合物被水活化，所产生的气体充满袋而成为鼓起的垫子形状。袋壁的变形导致垫子外形实质上起皱。不管是美观的还是人体功效学的原因，起皱都是不需要的。
相应地，本发明的一个目的就是提供一种具有活化起泡清洁体系的化妆品，其通过起泡气体而引起所述产品膨胀但避免其变形和起皱。
值得注意的是，此后公开的发明较其目的或所要解决的技术问题要宽。
根据一个方面，提供了清洁表面用制品，所述制品包括：
-由多个壁组成的曲线袋，其中至少一个壁是透水的，并且至少一个壁由至少一种无纺缠结纤维网组成，所述纤维缠结方向与网的主长轴垂直；和
-一种通过水活化产生气体的起泡清洁剂组合物，其是一种无水干燥的固体，所述组合物在袋中，和通过产生气体，所述袋壁向外膨胀。
通过附图，本发明的进一步的目的、特性和优点将变得更明显，其中：
-图1是椭圆袋的第一种实施方案的平面透视图；
-图2是图1中示出的第一种实施方案沿2-2方向的剖视图；
-图3是根据本发明的袋的第二种实施方案的正面视图；
-图4是根据本发明的袋的第三种实施方案的正面视图；和
-图5是根据本发明的袋的第四种实施方案的正面视图。
目前，已经发现当无纺布网中的纤维具有适当朝向时，其形成的袋壁能够避免起皱的问题。通过水活化起泡组合物释放气体，所述袋壁向外膨胀。至少部分袋壁上由缠结纤维取向形成的网允许体系延展，因此避免变形和任何实质上的起皱。
图1示出第一种实施方案，其中所述袋是椭圆形。
袋2具有由第一织边网4和第二熔喷复合网6构成的袋壁，后者与高膨体片8接合。形成网4和网6的网是无纺缠结纤维基体。图2以剖面图的最佳方式示出数个网组成的壁，腔10在第一和第二网4、6之间，用来束缚粉状起泡组合物12。网4和6沿周边轨迹14超声密封以确保粉末组合物不会损失。
袋2由纵向主轴M和横向次轴N限定，所述主轴比次轴长。
图3具有是本发明的第二种实施方案。其示出月牙形的袋16。主轴和次轴，(M’和N’)，在图上标出。
图4示出根据本发明的第三种实施方案。袋22的一边具有正弦曲线形24和对面边直线形26。主轴和次轴定义为M”和N”。
图3和图4提供特别有益的曲线边，因为它们具有相对于椭圆形来说比较容易握，并且不易滑的外形。然而，具有如18和28的凹边的形状的起皱问题。
图5示出第四种实施方案。袋32在主轴M”’的末端有一个直边36和对面末端是一个圆边34。次轴N”’横贯主轴。
当袋2被水浸湿时，产生大量的泡沫，与洗涤棒起泡大致相同。从形体上看，所述袋被构造成适宜人手的椭圆形从而模拟洗涤棒。
所述的术语“主轴”指的是纵向或长的方向，并定义为与袋纵向中心线平行的方向。通常，主轴与制备网的加工方向(MD)重合。换句活说，当纤维放置后，在MD运动中它们远离沉积源被运送成网。术语“次轴”指的是横向或宽的方向，并定义为与袋纵向中心线垂直的方向。通常次轴与制备网的MD正交的横向(CD)重合。
通常，无纺布在加工方向张力最强。本发明缠结的网设法在相对于MD方向提高CD方向的强度。然而，所得到的取向网在CD方向并没有必要具有比MD方向高的拉伸强度。但是拉伸强度之间的差别被缩小。例如，织边织物可在CD与MD拉伸强度比值约为1∶4下通过纤维沉积形成。随后的水缠结取向将比值提高到约1∶2。优选取向缠结纤维提高拉伸强度至少20％，更优选至少50％，和最优选CD对MD值至少为100％。
主轴的典型尺寸范围约为20-300毫米，优选约为30-100毫米。次轴的尺寸范围约为30-85毫米，优选约为20-50毫米。
本发明中纤维取向并不局限于任何特定的技术。实际上，任何本领域已知的技术都可应用以得到所需取向效果。
所述袋包括至少一个纤维缠结网。缠结纤维在与袋主轴垂直的方向缠结。优选制备缠结纤维的方法是利用已知的水缠结工艺。通过高能水射流横穿纤维物质以使纤维互锁形成的水缠结网坚固且耐用。其它高压流体可用来代替水。
虽然水缠结是优选的制备缠结网的方法，其它方法可用来代替。针刺法是可采用方法的一个例子。在此方法中，钩针刺入网中，钩住通过它的纤维束并因此在针刺区域接合。可采用的另一种方法是熔结法，其中的纤维是热塑性物质，或具有热塑性物质外层，并在离散的点通过热结合。通过该方法制备的网与水缠结法或针刺法制备的柔软度不同，并且有相当大的部分完全是松散纤维。
还有一种方法涉及纤维和化学粘合剂的混合物的湿法成网，有些如在造纸中所采用的方法。还有一种方法是疏理，其中切断纤维经剖开、清洗、排列并形成连续的未粘合网。然而，水缠结和化学的、热的、机械的粘合物质和疏理物质所代表的技术都可引入到本发明中，这些没有穷尽所有的可能性。其它技术如模压加工、起皱和开孔也能引入袋制备中。
网6可以是单个的熔喷网，但优选的是由多层接合的复合网。一种实施方案采用三层纺丝粘合/熔喷/纺丝粘合(SMS)和另一种采用四层代表纺丝粘合/熔喷/熔喷/纺丝粘合(SMMS)的结构。在这些系统中，熔喷纤维非常紧密，并且作为防止粉末流失的阻挡层。纺丝粘合层提供强度和柔软性。
所述熔喷网可以是任何由熔点约高于50℃的热塑性聚合物制备的网。优选的聚合物是制备熔喷网最常用的聚丙烯。其它适宜的聚合物包括聚(对苯二甲酸丁二醇酯)、聚己内酰胺、聚(对苯二甲酸乙二醇酯)和聚乙烯。
制备熔喷网的方法是本领域公知的，并且非常广泛的应用于制备无纺布商品。代表性的熔喷方法在1976年8月31日授予Buntin等人的美国专利3978185，1981年11月3日授予Meitner的美国专利4298649，和1978年7月11日授予Anderson等的美国专利4100324中公开，这些都在此引入作为参考。然而，应该理解，其它熔喷方法也能制备适宜于本发明目的的网。所述熔喷网能与其它支撑网接合或者层压，如纺丝粘合网，以赋予产品强度或者其它特性。
单片本发明的熔喷基质网的基本重量约为20-300克每平方米。优选基本重量约为80-250克，最优选的约为100-200克每平方米。
纺丝粘合需要通过向下的多重模孔挤出多种连续热塑性聚合物束到一移动表面上，挤出束在其上以随机分布方式收集。随机沉积的束随后在加热的辊隙间粘合以使所得到的连续纤维无纺布具有充分的完整性。熔喷网的特征是高强度/重量比，各向强度相同，多孔，和优良的抗磨损性。
熔喷与纺丝粘合的区别在于，挤出聚合物束在沉积到收集表面之前被强迫气流切断并且分散成单个纤维。此外，纤维基本上通过空气冷却以致于其并不结晶和/或粘合在一起。网粘合以保持完整性和强度由单独的后续操作完成。
第二网6的最优选物质是可从Polyprop公司得到的无纺熔喷/纺丝粘合基质。
第一网4优选是一种纺丝或者是一种疏理/化学粘合无纺水不溶性物质。特别优选的是可从PGI公司得到的布NC008(Image Spun Lace)。
当前，一种高膨体片可作为水渗透壁。这里所用的“高膨体”指的是密度约为0.00005-0.1克/立方厘米的片，优选密度约为0.001-0.09克/立方厘米，厚度约为0.1-5厘米。
这里所用的“无纺”指的是层中不含有织成纺织物的纤维。术语“曲线”指的是组成袋的边中至少有一个是曲面。优选所述袋没有方角。
为本发明的目的，最优选的高膨体物质是Union Wadding公司出售的针刺复合物。
本发明的袋可通过下列方法制备：一个漏斗喷嘴向水平方向移动的取向无纺网上沉积限制量的起泡粉。下游一种近似的取向水缠结网自一辊展开并以上述方向移动，与第一网平行。此后，所述平行网和沉积的起泡粉末从一冲压装置下面通过，第一和第二网热密封在一起形成椭圆形，起泡粉末在网壁之间。此后，切割模具打孔输出热密封椭圆产品。
此后，一种或多种产品可在湿的不渗透外包装如箔衬袋中包装以抑制起泡体系在贮存中活化。
超声波焊接可用来代替第一和第二基质热密封在一起。线缝、施用胶水或其它闭合机制都可采用。
袋中组合物12的第一组分是一种酸性物质。适合该目的的是任何酸，优选的是呈干固体形式的那些。特别适宜的是C2-C20的有机一元或多元羧酸，特别是α-和β-羟基羧酸；C2-C20有机磷酸如植酸；C2-C20有机磺酸如甲苯磺酸；和过氧化物如过氧化氢。典型的羟基羧酸包括己二酸、戊二酸、琥珀酸、酒石酸、苹果酸、马来酸、乳酸、水杨酸和柠檬酸以及酸形成的内酯如葡糖酸内酯和葡糖二酸酯。最优选的是柠檬酸。适宜的酸性物质还有包覆酸。典型的包覆物质可包括水溶性合成或者天然聚合物如聚丙烯酸酯(如包覆聚丙烯酸)，纤维素胶质、聚氨酯和聚乙二醇聚合物。
术语“酸”指的是任何溶解在去离子水中浓度达到1％时pH值小于7，优选小于6.5，最优选小于5的任何物质。所述酸优选在25℃下为固体，即熔点不低于25℃。酸的浓度范围约为0.5-80wt％，优选约为10-65wt％，最优选约为20-45wt％，基于组合物的总重量。
袋中组合物的第二组分是碱性物质。所述碱性物质在与水和酸性物质接触时能够产生气体如二氧化碳、氮气或氧气，即起泡。适宜的碱性物质包括无水碳酸盐和碳酸氢盐，碱性过氧化物(例如过硼酸钠和过碳酸钠)和叠氮化物(例如叠氮化钠)。优选碱性物质是碳酸氢钠或碳酸氢钾。碱性物质的量约为1-80wt％，优选约为5-49wt％，更优选约为15-40wt％，最优选约为20-35wt％，基于组合物的总重量。
术语“无水”指的是水占组合物总重量的份数，不高于15wt％，优选约不高于5wt％和最优选不高于1wt％。水合的水不属于无水定义中的水。但是，优选最少化，以至消除任何水合水。
有利的酸性和碱性物质结合的量至少约为1.5wt％，优选约为40-95w t％，最优选约为60-80wt％，基于组合物的总重量。
本发明组合物的进一步的最佳组分是表面活性剂，优选20℃下为干表面活性剂固体。本发明最优选的是椰油基羟乙基磺酸钠。其它有益的表面活性剂包括甲基椰油基牛磺酸钠、月桂酰基肌氨酸钠和月桂基硫酸钠。表面活性剂可以是阳离子的、阴离子的、非离子的、两性的、两性离子的以及它们的混合物。表面活性剂的量约为0.1-30wt％，优选约为1-30wt％，最优选约为8-20wt％，基于组合物的总重量。
可包括各种有益的皮肤试剂以提高用后特性。有利的是所述物质是无水干粉末。可选择的是所述物质可为沉积在粉末基质(硅酸钙或沸石)之上或其中的液体以得到流动性干粉末。有益的皮肤试剂包括若干种物质。这些包括润肤剂、防老化活性剂、抗菌剂和杀真菌剂、皮肤增白剂、遮光剂及其组合。有益的皮肤试剂占组合物总重量的量约为0.001-40wt％，优选约为0.1-20wt％，更优选约为0.5-10wt％，最优选约为1-5wt％。
润肤剂可以是自然的或合成的酯、硅油、烃、淀粉、脂肪酸及其混合物。典型的润肤剂的浓度约为0.1-35wt％，基于组合物的总重量。
硅油可分为挥发性和不挥发性的。这里所用的术语“挥发性”指的是室温下(25℃)具有可测量蒸汽压的那些物质。挥发性硅油优选选自含有3-9个，优选4-5个硅原子的环或直链聚二甲基硅氧烷。
直链挥发性硅氧烷在25℃下粘度一般约低于5厘沲，然而典型的环状物质的粘度约低于10厘沲。
适宜于用作润肤剂的不挥发性硅油包括聚烷基硅氧烷，聚烷基芳基硅氧烷和聚醚硅氧烷共聚物。本发明适用的基本不挥发性聚烷基硅氧烷包括，例如，25℃下粘度约为5-100000厘池的聚二甲基硅氧烷。用在本发明组合物中的不挥发性润肤剂优选是25℃下粘度约为10-400厘池的聚二甲基硅氧烷。
在酯润肤剂中：
(1)具有10-22个碳原子的脂肪酸的烯基或烷基酯。其例子包括新戊酸异二十醇酯，异壬基isonanonoate，肉豆蔻酸油醇酯，硬脂酸油醇酯，和油酸油醇酯。
(2)醚酯如乙氧化脂肪醇的脂肪酸酯。
(3)多羟基醇酯。乙二醇的单和双脂肪酸酯，二乙二醇的单和双脂肪酸酯，聚乙二醇(200-8000)的单和双脂肪酸酯，聚丙二醇2000单油酸酯，聚丙二醇2000单硬脂酸酯，乙氧基化丙二醇单硬脂酸酯，甘油基单和双脂肪酸酯，聚甘油醇多脂肪酸酯，乙氧基化甘油基单硬脂酸酯，1，3-丁二醇单硬脂酸酯，1，3-丁二醇双硬脂酸酯，聚氧乙烯多元醇脂肪酸酯，山梨糖醇脂肪酸酯，和聚氧乙烯山梨糖醇脂肪酸酯都是适宜的多羟基醇酯。
(4)蜡酯如蜂蜡，鲸蜡，十四烷基肉豆蔻酸酯，硬脂酸硬脂醇酯和山萮酸二十烷醇酯。
(5)固醇酯，其例子是胆固醇脂肪酸酯。
(6)甘油三酯，如葵花籽油，葵花籽油马来酸酯，聚棉籽酯，琉璃苣籽油和红花油。
适宜作为润肤剂的烃包括矿脂，矿物油，异石蜡烃和烃蜡如聚乙烯。
淀粉也是适宜的润肤剂。这类代表性的是木薯淀粉和阿拉伯半乳聚糖。
脂肪酸也是适宜的润肤剂。所述脂肪酸通常具有10-30个碳原子。这一类的例子有壬酸、月桂酸，肉豆蔻酸，棕榈酸，硬脂酸，异硬脂酸，羟基硬脂酸，油酸，亚油酸，蓖麻油酸，花生酸，山萮酸和芥酸。
防老化活性剂也是有益的皮肤试剂。此类中包括维生素，类维生素A及其组合。这些物质约占组合物总重量的0.001-20wt％。适宜的维生素包括抗坏血酸，维生素B6，维生素B12，维生素E以及它们的C1-C20酯。适宜的类维生素A包括视黄酸以及其C1-C22酯和盐，视黄醇和视黄醇的C1-C22脂肪酸酯包括视黄醇亚油酸酯。
另一类防老化活性剂是α-和β-羟基羧酸及其盐。该类代表性的是羟基乙酸，乳酸，苹果酸，羟基辛酸，水杨酸和它们的混合物以及其盐。适宜的盐是碱金属、铵和C1-C10烷醇铵盐。
抗菌剂和杀真菌剂也可包括在有益的皮肤试剂中。该类代表性的化合物有三氯生，tricloban，hexetidene，chlorhexadene，葡萄糖酸酯，锌盐(例如柠檬酸锌和苯酚磺酸锌)及其组合。
皮肤白亮剂也可包括在有益的皮肤试剂中。这类代表性的是烟酰胺，曲酸，熊果苷，香草醛，阿魏酸及其酯，间苯二酚，对苯二酚，胎盘提取物及其组合。
遮光剂也可包括在有益的皮肤试剂中，特别优选的这类物质如乙基己基对-甲氧基肉桂酸酯，商品名
，avobenzene商品名为
1789和二苯甲酮-3，也被称作羟苯甲酮。无机遮光剂活性剂可采用如微细的二氧化钛，聚乙烯和各种其它的聚合物。遮光剂的量一般为0.1-30wt％，优选2-20wt％，最优选4-10wt％重量。
功能助剂也可包括在本发明的组合物中。这些包括电解质，增稠剂及其混合物。这些物质的量约为0.1-20wt％，优选约为0.3-10wt％，最优选约为0.5-5wt％，基于组合物的总重量。
电解质可选自磷酸、硅酸、卤素、硫酸的碱金属、碱土金属或铵盐以及其混合物。代表性的磷酸盐是聚偏磷酸钾，三聚磷酸钠和四焦磷酸钠，焦磷酸钠或钾和六偏磷酸钠。最优选的是从Lipo ChemicalsInc.，Paterson New Jersey获得的聚偏磷酸钾Lipothix
，其是一种聚偏磷酸钾和碳酸氢钠比为70∶30的混合物。优选的硫酸盐是硫酸镁。
增稠剂包括无机或有机物质，其能提高皮肤的用后特性。特别优选的无机增稠剂是硅酸钠镁，即商品Optigel
。有机增稠剂包括藻酸以及藻酸的钠和钙盐，羧甲基纤维素钠，羟丙基甲基纤维素，羟丙基纤维素，羟乙基纤维素及其组合．最优选的是由Sud-ChemieRheologicals，Louisville，Kentucky市售的
藻酸。藻酸能够高效的除去如同碱性物质没有完全清洗而沉积在皮肤上的粘糊感。增稠剂的量约为0.1-20％。
本发明中有益的多糖是干燥固体无水物质如山梨糖醇，糖(如海藻糖)，淀粉，改性淀粉(例如辛烯基琥珀酸铝)及其混合物。最优选的是山梨糖醇。
沉积助剂也可包括在本发明的组合物中。这些沉积有益的皮肤试剂中的助剂沉积在皮肤表面。以此目的，特别有效的是阳离子单体和聚合物。例如：氯化十一二烷基三甲基铵；氯化十八烷基三(2-羟乙基)铵；氯化十二烷基二甲基苄基铵；氯化十六烷基二甲基苄基铵；氯化十六烷基吡啶锚；氯化聚二烯丙基二甲基铵；二烯丙基二甲基铵盐与丙烯酰胺的共聚物；氯化瓜尔羟丙基三铵；阳离子羟基乙基纤维素；氯化十六烷基三甲基铵；氯化癸基二甲基辛基铵；和氯化十四烷基三甲基铵。
为本发明的目的，最优选的是阳离子瓜尔胶如Jaguar
，其是一种氯化瓜尔羟丙基铵和市售的商品Merquat 220O聚季铵7。所述沉积助剂的量约为0.01-1wt％，优选约为0.05-0.5wt％，最优选0.1-0.3wt％。
有利的是所迷的发泡清洗组合物中可包含一种动情剂如芳香物和/或植物提取物。芳香物和植物通常是液体的。因此，有必要均匀分别并且允许液体组分吸收到固体粉末中。一个最优达到此目的的方法是将这些液体喷洒在固体上。芳香物和/或植物组合用量约为0.1-3wt％，优选0.5-2wt％，最优选0.8-1.5wt％，基于组合物的总重量。
术语“芳香物”定义为有气味组分的混合物，可任选与适宜的溶剂稀释剂/或载体混合，采用它的目的是提供所需的气味。特别优选的有气味组分是环状或非环状的萜烯和类萜化合物。这些物质基于异戊二烯重复单元。例如包括α-和β-蒎烯，月桂烯，香叶基醇和醋酸酯，莰烯，d1-苎烯，α-和β-水芹烯，三环烯，萜品油烯，allocimmane，香叶醇，橙花醇，里那醇，二氢里那醇，柠檬醛，紫罗兰酮，甲基紫罗兰酮，香茅醇，香茅醛，α-松油醇，β-松油醇，α-小茴香醇，龙脑，异龙脑，樟脑，1-松油醇，4-双缩松油醇，二氢松油醇，甲基萎叶酚，茴香脑，1，4和2，8桉树脑，香叶基腈，异龙脑醋酸酯，沉香基醋酸酯，丁子香烯，α-雪松烯，愈创醇，广藿香醇，α-和β-檀香醇及其混合物。
特别适用与本发明的植物包括西洋蓍草，春黄菊，茉莉花，熏衣草，七叶树，鼠尾草，百里香，丝兰，款东及其混合物。
防腐剂可根据需要加入本发明的化妆品组合物中以防止潜在的有害微生物生长。适宜本发明组合物的传统防腐剂是对羟基安息香酸的烷基酯。近来适用的其它防腐剂包括乙内酰脲衍生物，丙酸盐，和各种季铵盐化合物。化妆品领域的化学家熟知适当的防腐剂，并且常规选择防腐剂以满足防腐测试和保证产品的稳定性。特别优选的防腐剂是苯氧基乙醇，对羟基苯甲酸甲酯，对羟基苯甲酸丙酯，咪唑烷基脲，脱氢醋酸钠和苄基醇。防腐剂的优选量约为0.01-2wt％，基于组合物的总重量。
着色剂也可包括在本发明的组合物中。这些物质的含量范围约为0.05-5wt％，优选为0.1-3wt％重量。
消费者揉搓物该产品时，重要的是该网状物不易撕开。不像洗衣袋，本发明的袋不允许裂开而使其中的颗粒分散在洗涤水中。宁愿组合物的所有组分都通过溶解而通过可渗透的袋壁。
本发明的产品适用的皮肤表面包括脸，身体，头皮，腋窝和甚至腿/脚。当产品是一种脚清洁剂时，有利的是袋的一面是粗糙的而另一面基质是柔软、温和的。
除非在实施例和对比实施例中，或者其他地方明确表明，本说明书中所有表示物质的量的数值都应理解为有“约”修饰。
术语“包含”不是指限于其后所述的因素，而是含有没有具体说明的主要或次要功能的因素。换句活说，所列的步骤、因素或选择不需穷尽。
以下实施例将更全面的示出本发明的实施方案。除非另外说明，这里和权利要求书中所指的所有份数、百分数和比例都是以重量计的。
实施例1
根据表I的配方制备一种发泡清洁组合物。相A在高速剪切混合机中干混合。然后将芳香物喷洒在所得到的粉末上作为相B。此后将3克上述粉末放入一个5×8厘米袋中。袋壁由热密封的无纺纺边网周边的无纺SMMS复合网组成。所述的纺边网是一种纤维在垂直于袋的主轴取向的物质(也就是在横向)。
表I
实施例2
根据表II的配方制备另一种发泡清洁组合物。然后将所述组合物按照实施例1的方法密封在一个袋中。
表II
实施例3
根据表III的配方制备一种洁面发泡组合物。然后将所述组合物按照实施例1的方法密封在一个袋中。
表III
实施例4
按照本发明，根据表IV的配方制备本发明的另一种发泡清洁组合物。所述干混合物组分的重量为每份样品3.5克，放置于如图3所示的主轴和次轴(宽)为9厘米和5厘米的月形袋子中。粉末样品放置在密封高膨片一层纺边网和一SMS层之间。纺边网和SMS按使它们的纤维取向横穿主轴的方向来布置。袋的所有边通过超音速热焊接以保证粉末不逸出。
表IV
| 组分 | 重量％ |
| 柠檬酸(无水) | 24.00 |
| 碳酸氢钠 | 24.00 |
| 月桂烷磺基醋酸钠 | 3.75 |
| 椰油基羟乙磺酸钠 | 3.75 |
| 聚季铵7 | 0.50 |
| C14-C16烯烃磺酸钠 | 3.75 |
| 氯化瓜尔羟丙基三铵 | 0.40 |
| 维生素C棕榈酸酯 | 0.01 |
| 异十六烷基山萮酸酯 | 5.00 |
| 硬脂酰基乳酸钠 | 3.00 |
| 二甲基聚硅氧烷共聚多元醇磺基丁二酸二钠 | 1.00 |
| 维生素A棕榈酸酯 | 0.01 |
| 月桂酰乳酸钠 | 5.00 |
| PEG 8000 | 5.00 |
| 维生素E | 0.40 |
| 硅酸钙 | 9.00 |
| 麦芽糖糊精 | 11.13 |
| 芳香物 | 0.30 |
Claims (8)
1.一种表面清洁制品，所述制品包括：
-由多个壁组成的曲线袋，其中至少一个壁是透水的，并且至少一个壁由至少一种无纺缠结纤维网形成，所述纤维缠结方向与网的主长轴垂直；和
-一种通过水活化产生气体的起泡清洁剂组合物，其是一种无水干燥的固体，所述组合物容纳在袋中，和通过产生气体，所述袋壁向外膨胀。
2.根据权利要求1的制品，其中缠结的纤维是水缠结的。
3.根据权利要求1或2的制品，其中至少一个网具有横向和加工方向，并且通过取向，网的拉伸强度在横向和加工方向各自增加至少20％。
4.根据权利要求1的制品，其中至少一个网是选自熔喷、纺丝粘合和纺边结构的无纺片。
5.根据上述任一权利要求的制品，其中所述组合物包含0.5-80％重量的酸和1-80％重量的碱性物质。
6.根据上述任一权利要求的制品，其中袋的形状为椭圆形。
7.根据权利要求1-5中任一项的制品，其中袋的形状既不是方的，也不是矩形的。
8.一种清洁身体表面的方法，所述方法包括：
(i)制备一种制品，包括：
-由多个壁组成的曲线袋，其中至少一个壁是透水的，并且至少一个壁由至少一种无纺缠结纤维网形成，所述纤维缠结方向与网的主长轴垂直；和
-一种通过水活化产生气体的起泡清洁剂组合物，其是一种无水干燥的固体，所述组合物容纳在袋中，和通过产生气体，所述袋壁向外膨胀；
(2)浸湿所述制品产生起泡的清洁泡沫；和
(3)将浸湿的制品与产生的起泡清洁泡沫施用于使用者身体表面的一部分或多个部分，并清洗所述表面。
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| US20050042262A1 (en) | 2003-08-21 | 2005-02-24 | The Procter & Gamble Company | Effervescent cleansing article |
| MXPA06003372A (es) * | 2003-09-26 | 2006-06-08 | Procter & Gamble | Metodo para producir una estructura laminar efervescente. |
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2002
- 2002-06-10 US US10/166,099 patent/US6919089B2/en not_active Expired - Fee Related
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2003
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- 2003-01-27 JP JP2003569171A patent/JP2005525346A/ja active Pending
- 2003-01-27 CN CNB038041278A patent/CN100379400C/zh not_active Expired - Fee Related
- 2003-01-27 EP EP20030742505 patent/EP1476133B1/en not_active Expired - Lifetime
- 2003-01-27 KR KR10-2004-7012776A patent/KR20040083524A/ko not_active Application Discontinuation
- 2003-01-27 DE DE2003607433 patent/DE60307433T2/de not_active Expired - Lifetime
- 2003-01-27 AU AU2003226968A patent/AU2003226968B2/en not_active Ceased
- 2003-01-27 WO PCT/EP2003/000794 patent/WO2003070211A1/en active IP Right Grant
- 2003-01-27 ES ES03742505T patent/ES2270061T3/es not_active Expired - Lifetime
- 2003-01-27 MX MXPA04007891A patent/MXPA04007891A/es active IP Right Grant
- 2003-01-27 AT AT03742505T patent/ATE335460T1/de not_active IP Right Cessation
-
2004
- 2004-07-02 ZA ZA200405300A patent/ZA200405300B/xx unknown
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| CN1233993A (zh) * | 1996-10-16 | 1999-11-03 | 普罗克特和甘保尔公司 | 一次性无纺清洁用品 |
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Also Published As
| Publication number | Publication date |
|---|---|
| US6919089B2 (en) | 2005-07-19 |
| WO2003070211A1 (en) | 2003-08-28 |
| ATE335460T1 (de) | 2006-09-15 |
| EP1476133B1 (en) | 2006-08-09 |
| ES2270061T3 (es) | 2007-04-01 |
| ZA200405300B (en) | 2005-07-04 |
| AU2003226968A1 (en) | 2003-09-09 |
| DE60307433D1 (de) | 2006-09-21 |
| US20030003136A1 (en) | 2003-01-02 |
| KR20040083524A (ko) | 2004-10-02 |
| CN1633278A (zh) | 2005-06-29 |
| DE60307433T2 (de) | 2006-12-07 |
| EP1476133A1 (en) | 2004-11-17 |
| CA2473044A1 (en) | 2003-08-28 |
| AU2003226968B2 (en) | 2005-11-17 |
| MXPA04007891A (es) | 2004-10-15 |
| JP2005525346A (ja) | 2005-08-25 |
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