CN100361337C - Fuel cell capable of rapid response under output power abrupt intensification state - Google Patents

Fuel cell capable of rapid response under output power abrupt intensification state Download PDF

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Publication number
CN100361337C
CN100361337C CNB2004100673718A CN200410067371A CN100361337C CN 100361337 C CN100361337 C CN 100361337C CN B2004100673718 A CNB2004100673718 A CN B2004100673718A CN 200410067371 A CN200410067371 A CN 200410067371A CN 100361337 C CN100361337 C CN 100361337C
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air
fuel cell
hydrogen
supply device
power output
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CN1764002A (en
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葛栩栩
胡里清
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State Grid Corp of China SGCC
Shanghai Municipal Electric Power Co
Shanghai Shenli Technology Co Ltd
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Shanghai Shen Li High Tech Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The present invention relates to a fuel cell capable of quickly responding under the condition of sudden increase of output power, which comprises a fuel cell stack, a hydrogen storage device, a hydrogen pressure reducing valve, a hydrogen humidifying device, an air filter device, an air compression supplying device, an air supply device, an air humidifying device, a hydrogen water-steam separator, a hydrogen circulating pump, an air water-steam separator, a water tank, a cooling fluid circulating pump and a radiator, wherein the air replenishment device comprises a normally closed electromagnetic valve and a compressed air container. One end of the normally closed electromagnetic valve is communicated with an outlet end of the air compression supplying device, and the other end is communicated with the compressed air container. Compared with the prior art, the present invention has the characteristic of quickly responding and stably running under the condition of sudden increase of output power, and in addition, the air supply device of the present invention can also be used as an air source for a pneumatically operated brake, a pneumatic gate switching device and other pneumatic elements in vehicle.

Description

A kind of fuel cell that under the situation that power output increases suddenly, can respond fast
Technical field
The present invention relates to fuel cell, relate in particular to a kind of fuel cell that under the situation that power output increases suddenly, can respond fast.
Background technology
Electrochemical fuel cell is a kind of device that hydrogen and oxidant can be changed into electric energy and product.The internal core parts of this device are membrane electrode (Membrane Electrode Assembly are called for short MEA), and membrane electrode (MEA) is made up of as carbon paper a proton exchange membrane, two porous conductive materials of film two sides folder.The catalyst that contains the initiation electrochemical reaction of even tiny dispersion on two boundary faces of film and carbon paper is as the metal platinum catalyst.The membrane electrode both sides can electrochemistry will take place with conductive body to be sent out and answers the electronics that generates in the process, draws by external circuit, constitutes current circuit.
At the anode tap of membrane electrode, fuel can pass porousness diffusion material (carbon paper) by infiltration, and electrochemical reaction takes place on catalyst surface, lose electronics, form cation, cation can pass proton exchange membrane by migration, arrives the other end cathode terminal of membrane electrode.At the cathode terminal of membrane electrode, contain the gas of oxidant (as oxygen), as air, pass porousness diffusion material (carbon paper), and the generation electrochemical reaction obtains electronics on catalyst surface, forms anion by infiltration.The cation of coming in the anion and the anode tap migration of cathode terminal formation reacts, and forms product.
Adopting hydrogen is fuel, and the air that contains oxygen is in the Proton Exchange Membrane Fuel Cells of oxidant (or pure oxygen is an oxidant), and fuel hydrogen has just produced hydrogen cation (or being proton) in the catalytic electrochemical reaction of anode region.Proton exchange membrane helps the hydrogen cation to move to the cathodic region from the anode region.In addition, proton exchange membrane is separated the air-flow and the oxygen containing air-flow of hydrogen fuel, they can not mixed mutually and produces explosion type reaction.
In the cathodic region, oxygen obtains electronics on catalyst surface, forms anion, and moves the hydrogen cation reaction of coming, reaction of formation product water with the anode region.In the Proton Exchange Membrane Fuel Cells that adopts hydrogen, air (oxygen), anode reaction and cathode reaction can be expressed in order to following equation:
Anode reaction: H 2→ 2H ++ 2e
Cathode reaction: 1/2O 2+ 2H ++ 2e → H 2O
In typical Proton Exchange Membrane Fuel Cells, membrane electrode (MEA) generally all is placed in the middle of the pole plate of two conductions, and quarter is milled by die casting, punching press or machinery in the surface that every guide plate contacts with membrane electrode, and formation is the guiding gutter of one or more at least.These guide plates can above metal material pole plate, also can be the pole plate of graphite material.Fluid duct on these guide plates and guiding gutter import fuel and oxidant the anode region and the cathodic region on membrane electrode both sides respectively.In the structure of a Proton Exchange Membrane Fuel Cells monocell, only there is a membrane electrode, the membrane electrode both sides are respectively the baffler of anode fuel and the baffler of cathode oxidant.These bafflers are both as current collector plate, and also as the mechanical support on membrane electrode both sides, the guiding gutter on the baffler acts as a fuel again and enters the passage of anode, cathode surface with oxidant, and as the passage of taking away the water that generates in the fuel cell operation process.
In order to increase the gross power of whole Proton Exchange Membrane Fuel Cells, two or more monocells can be connected into battery pack or be unified into battery pack by the mode that tiles usually by straight folded mode.In straight folded, in-line battery pack, can there be guiding gutter on the two sides of a pole plate, and wherein one side can be used as the anode guide face of a membrane electrode, and another side can be used as the cathode diversion face of another adjacent membranes electrode, and this pole plate is called bipolar plates.A series of monocell connects together by certain way and forms a battery pack.Battery pack tightens together by front end-plate, end plate and pull bar usually and becomes one.
A typical battery stack generally includes: the water conservancy diversion import and the flow-guiding channel of (1) fuel and oxidant gas are distributed to fuel (hydrogen-rich gas that obtains as hydrogen, methyl alcohol or methyl alcohol, natural gas, gasoline) and oxidant (mainly being oxygen or air) in the guiding gutter of each anode, cathode plane equably after reforming; (2) import and export and the flow-guiding channel of cooling fluid (as water) are evenly distributed to cooling fluid in each battery pack inner cooling channel, and the heat absorption that hydrogen in the fuel cell, the exothermic reaction of oxygen electrochemistry are generated is also taken battery pack out of and dispelled the heat; (3) outlet of fuel and oxidant gas and corresponding flow-guiding channel, fuel gas and oxidant gas are when discharging, and portability goes out the liquid that generates in the fuel cell, the water of steam state.Usually, the import and export of all fuel, oxidant, cooling fluid are all opened on the end plate of fuel battery or on two end plates.
Proton Exchange Membrane Fuel Cells can be used as the dynamical system of delivery vehicles such as car, ship, can be used as movable type, fixed Blast Furnace Top Gas Recovery Turbine Unit (TRT) again.
When Proton Exchange Membrane Fuel Cells can be used as car, ship power system or movable type and stationary power generation station, must comprise battery pile, fuel hydrogen supply system, air supply subsystem, cooling heat dissipation subsystem, control and electric energy output various piece automatically.
Fig. 1 is a fuel cell generation, and 1 is fuel cell pack in Fig. 1, and 2 are storage hydrogen bottle or other hydrogen-storing devices, and 3 is pressure-reducing valve, and 4 is air filter, and 5 is the air compression feeding mechanism; 6 ', 6 is Water-vapor seperator, and 7 is water tank, and 8 is the cooling fluid circulating pump, and 9 is radiator, and 10 is the hydrogen circulating pump, and 11,12 is humidifying device.
According to the principle or the principle of typical above-mentioned fuel cell generation operation at present, the patent of invention of Shenli Science and Technology Co Ltd, Shanghai " a kind of fuel cell that has device for controlling dynamically " for example, Chinese patent application number is 200410016609.4; 200420020471.0.Controller in the fuel cell generation, by temperature of fuel cell, power output demand are monitored and are calculated, determine control, fuel cell pack is realized under the power condition that any power output requires: 1. the related control of power output and working temperature hydrogen flowing quantity, air mass flow; 2. the related control of power output and hydrogen flowing quantity, air mass flow, wherein hydrogen flowing quantity with air mass flow by the demanded power output metering than being 1.2,2.0 controls respectively; 3. hydrogen flowing quantity and air mass flow link with the humidifying device that can realize dynamic humidification adjusting control accordingly respectively and dynamically control, and make hydrogen, air under any flow that enters in the fuel cell pack all keep best relative humidity (a certain numerical value in the middle of 70%~95%); 4. according to the situation of extraneous weather temperature and humidity, regulate and control method (3) point together, and reach and the identical purpose of (3) point.Final purpose is to make fuel cell pack realize high-effect operation and move that fuel cell pack can have best fuel efficiency under best operating condition under the power condition that any power output requires.
The principle of the dynamic control of above-mentioned fuel cell generation and principle, realize operational factor exactly according to fuel cell, require etc. to monitor automatically and to calculate in different working temperatures, environment, power output, and control by the target setting value and to reach fuel cell in best operating condition and high efficiency operation.
The wherein related control of power output and hydrogen flowing quantity, air mass flow, hydrogen flowing quantity are pressed the demanded power output metering than 1.2; It is more extremely important than 2.0~2.5 controls that air mass flow is pressed the demanded power output metering, otherwise long-play under the hydrogen of excessive flow, air regime, whole fuel cell generation overall efficiency is reduced, also can make the fuel cell operation condition be in abnormal state, serious situation can make fuel battery performance reduce, or even irreversibly performance loss.
Though the control of the dynamic object of above-mentioned fuel cell generation can be guaranteed whole fuel cell long-play, and can reach and be in the high efficiency state but when fuel cell generation uses as the dynamical system on the various delivery vehicles, or as movable type, when use in the distributing power station, the situation that all can require fuel cell output power to increase suddenly.For example, when fuel cell electric vehicle starting, quicken, or climbing, or during the power supply of fuel cell power generation station, the user increases situations such as some powerful loads suddenly, all can cause the situation that requires fuel cell output power to increase suddenly.
The fuel cell power generation principle is actually in the fuel cell hydrogen fuel and generates water with supply airborne oxygen chemical combination to fuel cell, and this chemical reaction process is the process that most of chemical energy changes into electric energy.So the speed of fuel cell power generation is subjected to the influence of many factors:
(1) to the speed and the adequacy of fuel cell supply hydrogen fuel, air;
(2) speed of hydrogen, the electrode diffusion of airborne oxygen in fuel cell;
(3) hydrogen, the airborne oxygen catalytic reaction speed in electrode;
Wherein (2), (3) point designs relevant with the generating capacity of fuel cell itself.
In general, when situations such as fuel cell electric vehicle sudden startup, acceleration occurring, or during the situations such as user's loading suddenly of fuel cell power generation station supply, the response speed that requires fuel cell output power is very fast.
The fuel cell generation of design has following serious technological deficiency now:
Though the promptly generating capacity of the design of fuel cell rated output power own generally all can satisfy as vehicle-mounted power source, or the requirement of power station maximum power requirement, but fuel cell is as vehicle-mounted power source, or during the power station, from idling mode or low power demand, be increased to high-power suddenly even maximum power requirement is recurrent.The principle and the principle of the dynamic control of present fuel cell generation, realize operational factor exactly according to fuel cell, require etc. to monitor automatically and to calculate in different working temperatures, environment, power output, and control by the target setting value and to reach fuel cell high efficiency operation under best operating condition.The wherein related control of power output and hydrogen flowing quantity, air mass flow, hydrogen flowing quantity are pressed the demanded power output metering than 1.2; Air mass flow is pressed the demanded power output metering than 2.0~2.5 controls.The related control of power output and air mass flow generally is the power demand size according to external circuit, and the motor speed that calculates and regulate air transport device reaches the adjusting air mass flow, and makes air mass flow reach 2.0~2.5 target control requirement.
That is to say when external circuit requirement fuel cell output power increases suddenly, air transport device in the necessary first fuel metering battery generating system of fuel cell generation, as the motor speed in air compressor machine, the air blast, motor speed is accelerated greatly, with the flow of increase air, and reach the air mass flow requirement that increases power output to the fuel cell pack conveying.
In general, electric machine speed regulation needs the time, and particularly motor often needs the 0.5-1 second even the longer time interval when low speed is adjusted to high speed.But when fuel cell electric vehicle is in situations such as sudden startup, acceleration, or situation such as the user of fuel cell power generation station supply loading suddenly is when occurring, just require the response speed of fuel cell output power very fast, the time interval is less than 0.5 second often greatly.
Air transports not as good as response so fuel cell generation can appear in above-mentioned situation, and causes whole fuel cell generation can't respond the power demand that output increases suddenly fast, and when serious, whole fuel cell generation can cause collapse.
Summary of the invention
Purpose of the present invention is exactly to provide a kind of fuel cell that can respond fast for the defective that overcomes above-mentioned prior art existence under the situation that power output increases suddenly.
Purpose of the present invention can be achieved through the following technical solutions: a kind of fuel cell that can respond fast under the situation that power output increases suddenly, comprise fuel cell pack, hydrogen-storing device, the hydrogen pressure-reducing valve, the hydrogen humidifying device, air filter, the air compression feeding mechanism, the air humidification device, the hydrogen Water-vapor seperator, the hydrogen circulating pump, the air Water-vapor seperator, water tank, the cooling fluid circulating pump, radiator, it is characterized in that, also comprise the air supply device, this air supply device comprises normally closed solenoid valve, compressed air reservoir, one end of described normally closed solenoid valve is communicated with the port of export of air compression feeding mechanism, and the other end of described normally closed solenoid valve is communicated with compressed air reservoir.
Described air supply device also comprises the first auxiliary air filter, and this first auxiliary air filter is located between normally closed solenoid valve and the compressed air reservoir.
Described air supply device also comprises the auxiliary air compression pump, and the port of export of this auxiliary air compression pump is communicated with compressed air reservoir.
Described air supply device also comprises the second auxiliary air filter, and this second auxiliary air filter is communicated with the entrance point of auxiliary air compression pump.
Described air supply device also comprises air pressure probe, and this air pressure probe is communicated with compressed air reservoir.
Described air supply device also can be used as the source of the gas of pneumatically operated brake, jettron door gear and other pneumatic element on fuel-cell vehicle.
Compared with prior art, technical solution of the present invention has increased a string rapid-action additional air device for supplying on the air supply pipeline.As long as this air supply device is when fuel cell requires to increase power output suddenly, will open normally closed solenoid valve automatically, a large amount of like this compressed air that originally were stored in the compressed air reservoir will replenish to fuel cell pack fast, timely, this time that can remedy the electric machine speed regulation of air compression plant effect that lags, fuel cell can guarantee the quick response of high-power unexpected increase.On the other hand, when the electric machine speed regulation of air compression plant reaches normal supply air mass flow and pressure, normally closed solenoid valve can be closed automatically, and the auxiliary air compression pump can be according to the pressure size in the compressed air reservoir, start gas storage again, till reaching setting pressure and quit work automatically.In addition, compressed air in this compressed air reservoir simultaneously can the double as vehicle launch, as the source of the gas of aerodynamic brake, pneumatic open and close car door.
Description of drawings
Fig. 1 is the structural representation of existing fuel cell;
Fig. 2 is the structural representation of fuel cell of the present invention.
Among Fig. 2 51: normally closed solenoid valve, 52: the first auxiliary air filters, 53: compressed air reservoir, 54: pressure sensor, 55: auxiliary air compression pump, 56: the second auxiliary air filters.
Embodiment
The invention will be further described below in conjunction with specific embodiment.
Embodiment 1
As shown in Figure 2, a kind of fuel cell that can respond fast under the situation that power output increases suddenly comprises fuel cell pack 1, hydrogen-storing device 2, hydrogen pressure-reducing valve 3, hydrogen humidifying device 11, air filter 4, air compression feeding mechanism 5, air supply device, air humidification device 12, hydrogen Water-vapor seperator 6, hydrogen circulating pump 10, air Water-vapor seperator 6 ', water tank 7, cooling fluid circulating pump 8, radiator 9; Described air supply device comprises normally closed solenoid valve 51, compressed air reservoir 53, the first auxiliary air filter 52, auxiliary air compression pump 55, the second auxiliary air filter 56, air pressure probe 54; One end of described normally closed solenoid valve 51 is communicated with the port of export of air compression feeding mechanism 5, the other end of described normally closed solenoid valve 51 is communicated with compressed air reservoir 53, the described first auxiliary air filter 52 is located between normally closed solenoid valve 51 and the compressed air reservoir 53, the port of export of described auxiliary air compression pump 55 is communicated with compressed air reservoir 53, the described second auxiliary air filter 56 is communicated with the entrance point of auxiliary air compression pump 55, and described air pressure probe 54 is communicated with compressed air reservoir 53.
The dynamical system that the fuel cell generation of present embodiment 50KW is used as car.
Be mounted with the air supply device by Fig. 2.Auxiliary air compression pump 55 is piston pumps of a kind of small-sized 500W, and compressed air reservoir 53 is that stainless a, volume is 6 liters a little storage tank.When car was in idling mode, the fuel cell pack power output was 5KW, and only as system's support operation, this moment, scroll type air compressor 5 rotating speeds were 500 rev/mins, and air demand is 300 liters/minute.Fuel cell stack operation pressure is 0.1~2 atmospheric pressure.In the air supply device in the compressed air reservoir 53 air pressure be 5 atmospheric pressure.
When car quickens suddenly, require fuel cell pack fullcharging power output 50KW, motor should be controlled from 500 rev/mins and raise speed 5000 rev/mins this moment, and air mass flow must be supplied 3000 liters/minute to fuel cell pack, promptly 50 liters/second.Because about 0.5 second of the time lag of motor speed-raising, this moment, normally closed solenoid valve 51 was opened in 0.01 second automatically, can supply 25 liters/second air mass flow in 0.5 second to fuel cell pack.0.5 after second, motor speed has risen to 5000 rev/mins, this moment, normally closed solenoid valve 51 was closed automatically, small-sized piston pump 55 gas storage again of working automatically when pressure sensor 54 is less than 5 atmospheric pressure.Compressed air in this compressed air reservoir 53 also double as car aerodynamic brake is used.

Claims (6)

1. fuel cell that under the situation that power output increases suddenly, can respond fast, comprise fuel cell pack, hydrogen-storing device, the hydrogen pressure-reducing valve, the hydrogen humidifying device, air filter, the air compression feeding mechanism, the air humidification device, the hydrogen Water-vapor seperator, the hydrogen circulating pump, the air Water-vapor seperator, water tank, the cooling fluid circulating pump, radiator, it is characterized in that, also comprise the air supply device, this air supply device comprises normally closed solenoid valve, compressed air reservoir, one end of described normally closed solenoid valve is communicated with the port of export of air compression feeding mechanism, and the other end of described normally closed solenoid valve is communicated with compressed air reservoir.
2. a kind of fuel cell that under the situation that power output increases suddenly, can respond fast according to claim 1, it is characterized in that, described air supply device also comprises the first auxiliary air filter, and this first auxiliary air filter is located between normally closed solenoid valve and the compressed air reservoir.
3. a kind of fuel cell that under the situation that power output increases suddenly, can respond fast according to claim 1, it is characterized in that, described air supply device also comprises the auxiliary air compression pump, and the port of export of this auxiliary air compression pump is communicated with compressed air reservoir.
4. a kind of fuel cell that under the situation that power output increases suddenly, can respond fast according to claim 3, it is characterized in that, described air supply device also comprises the second auxiliary air filter, and this second auxiliary air filter is communicated with the entrance point of auxiliary air compression pump.
5. according to claim 1 or 2 or 4 described a kind of fuel cells that under the situation that power output increases suddenly, can respond fast, it is characterized in that, described air supply device also comprises air pressure probe, and this air pressure probe is communicated with compressed air reservoir.
6. a kind of fuel cell that under the situation that power output increases suddenly, can respond fast according to claim 1, it is characterized in that described air supply device also is used as the source of the gas of pneumatically operated brake, jettron door gear and pneumatic element on fuel-cell vehicle.
CNB2004100673718A 2004-10-22 2004-10-22 Fuel cell capable of rapid response under output power abrupt intensification state Active CN100361337C (en)

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CN105070928B (en) * 2015-07-08 2017-10-20 广东合即得能源科技有限公司 A kind of fuel cell oxygen system and method for supplying oxygen
CN105810978B (en) * 2016-05-26 2018-10-12 博源燃料电池(上海)有限公司 The dynamic response control method of methanol recapitalization fuel cell output power
CN108232241B (en) * 2017-12-28 2020-11-03 潍柴动力股份有限公司 Air compression system of fuel cell electric automobile and control method
CN110061263A (en) * 2018-01-19 2019-07-26 郑州宇通客车股份有限公司 A kind of hybrid fuel cell air subsystem, vehicle and control method
CN109216734B (en) * 2018-09-30 2023-10-31 河南豫氢动力有限公司 Auxiliary system for facilitating humidification and low-temperature start of fuel cell
CN110176609A (en) * 2019-06-30 2019-08-27 潍柴动力股份有限公司 A kind of air supply system of fuel battery engines and a kind of fuel-cell vehicle
JP7097098B2 (en) * 2020-12-07 2022-07-07 株式会社フクハラ Compressed pneumatic circuit structure connected to the fuel cell
DE102021210251A1 (en) 2021-09-16 2023-03-16 Robert Bosch Gesellschaft mit beschränkter Haftung Fuel cell system with emergency operation using compressed air supply

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