CN100392902C - Fuel cell capable of making hydrogen or air temperature and humidity entered into reaction stablizing - Google Patents

Fuel cell capable of making hydrogen or air temperature and humidity entered into reaction stablizing Download PDF

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Publication number
CN100392902C
CN100392902C CNB2004100680656A CN200410068065A CN100392902C CN 100392902 C CN100392902 C CN 100392902C CN B2004100680656 A CNB2004100680656 A CN B2004100680656A CN 200410068065 A CN200410068065 A CN 200410068065A CN 100392902 C CN100392902 C CN 100392902C
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hydrogen
air
fuel cell
cooling fluid
outlet
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CN1773760A (en
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夏建伟
胡里清
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State Grid Corp of China SGCC
Shanghai Municipal Electric Power Co
Shanghai Shenli Technology Co Ltd
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Shanghai Shen Li High Tech Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The present invention relates to fuel cell capable of making the temperature and humidity of hydrogen or air entering into reaction stable, which comprises a fuel cell stack, a hydrogen storage device, a hydrogen pressure reducing valve, a hydrogen humidifying device, an air filter device, an air compression supplying device, an air humidifying device, a hydrogen water-steam separator, a hydrogen circulation pump, an air water-steam separator, a water tank, a cooling fluid circulation pump, a radiator and an air or hydrogen temperature and humidity stabilizing device, wherein the air or hydrogen temperature and humidity stabilizing device is arranged between the air humidifying device or the hydrogen humidifying device and the air inlet or the hydrogen inlet of the fuel cell stack. Compared with the prior art, because the present invention is provided with a device capable of making the temperature and the humidity of the air or the hydrogen stable before the air or the hydrogen enters the fuel cell stack to react, the over-wet or the over-drying phenomenon in the fuel cell stack is avoided, and the operating stability of the fuel cell is increased.

Description

Can make the hydrogen that enters reaction or the fuel cell of air themperature and moisture stable
Technical field
The present invention relates to fuel cell, relate in particular to and to make the hydrogen that enters reaction or the fuel cell of air themperature and moisture stable.
Background technology
Electrochemical fuel cell is a kind of device that hydrogen and oxidant can be changed into electric energy and product.The internal core parts of this device are membrane electrode (Membrane Electrode Assembly are called for short MEA), and membrane electrode (MEA) is made up of as carbon paper a proton exchange membrane, two porous conductive materials of film two sides folder.The catalyst that contains the initiation electrochemical reaction of even tiny dispersion on two boundary faces of film and carbon paper is as the metal platinum catalyst.The membrane electrode both sides can electrochemistry will take place with conductive body to be sent out and answers the electronics that generates in the process, draws by external circuit, constitutes current circuit.
At the anode tap of membrane electrode, fuel can pass porousness diffusion material (carbon paper) by infiltration, and electrochemical reaction takes place on catalyst surface, lose electronics, form cation, cation can pass proton exchange membrane by migration, arrives the other end cathode terminal of membrane electrode.At the cathode terminal of membrane electrode, contain the gas of oxidant (as oxygen), as air, pass porousness diffusion material (carbon paper), and the generation electrochemical reaction obtains electronics on catalyst surface, forms anion by infiltration.The cation of coming in the anion and the anode tap migration of cathode terminal formation reacts, and forms product.
Adopting hydrogen is fuel, and the air that contains oxygen is in the Proton Exchange Membrane Fuel Cells of oxidant (or pure oxygen is an oxidant), and fuel hydrogen has just produced hydrogen cation (or being proton) in the catalytic electrochemical reaction of anode region.Proton exchange membrane helps the hydrogen cation to move to the cathodic region from the anode region.In addition, proton exchange membrane is separated the air-flow and the oxygen containing air-flow of hydrogen fuel, they can not mixed mutually and produces explosion type reaction.
In the cathodic region, oxygen obtains electronics on catalyst surface, forms anion, and moves the hydrogen cation reaction of coming, reaction of formation product water with the anode region.In the Proton Exchange Membrane Fuel Cells that adopts hydrogen, air (oxygen), anode reaction and cathode reaction can be expressed in order to following equation:
Anode reaction: H 2→ 2H ++ 2e
Cathode reaction: 1/2O 2+ 2H ++ 2e → H 2O
In typical Proton Exchange Membrane Fuel Cells, membrane electrode (MEA) generally all is placed in the middle of the pole plate of two conductions, and quarter is milled by die casting, punching press or machinery in the surface that every guide plate contacts with membrane electrode, and formation is the guiding gutter of one or more at least.These guide plates can above metal material pole plate, also can be the pole plate of graphite material.Fluid duct on these guide plates and guiding gutter import fuel and oxidant the anode region and the cathodic region on membrane electrode both sides respectively.In the structure of a Proton Exchange Membrane Fuel Cells monocell, only there is a membrane electrode, the membrane electrode both sides are respectively the baffler of anode fuel and the baffler of cathode oxidant.These bafflers are both as current collector plate, and also as the mechanical support on membrane electrode both sides, the guiding gutter on the baffler acts as a fuel again and enters the passage of anode, cathode surface with oxidant, and as the passage of taking away the water that generates in the fuel cell operation process.
In order to increase the gross power of whole Proton Exchange Membrane Fuel Cells, two or more monocells can be connected into battery pack or be unified into battery pack by the mode that tiles usually by straight folded mode.In straight folded, in-line battery pack, can there be guiding gutter on the two sides of a pole plate, and wherein one side can be used as the anode guide face of a membrane electrode, and another side can be used as the cathode diversion face of another adjacent membranes electrode, and this pole plate is called bipolar plates.A series of monocell connects together by certain way and forms a battery pack.Battery pack tightens together by front end-plate, end plate and pull bar usually and becomes one.
A typical battery stack generally includes: the water conservancy diversion import and the flow-guiding channel of (1) fuel and oxidant gas are distributed to fuel (hydrogen-rich gas that obtains as hydrogen, methyl alcohol or methyl alcohol, natural gas, gasoline) and oxidant (mainly being oxygen or air) in the guiding gutter of each anode, cathode plane equably after reforming; (2) import and export and the flow-guiding channel of cooling fluid (as water) are evenly distributed to cooling fluid in each battery pack inner cooling channel, and the heat absorption that hydrogen in the fuel cell, the exothermic reaction of oxygen electrochemistry are generated is also taken battery pack out of and dispelled the heat; (3) outlet of fuel and oxidant gas and corresponding flow-guiding channel, fuel gas and oxidant gas are when discharging, and portability goes out the liquid that generates in the fuel cell, the water of steam state.Usually, the import and export of all fuel, oxidant, cooling fluid are all opened on the end plate of fuel battery or on two end plates.
Proton Exchange Membrane Fuel Cells can be used as the dynamical system of delivery vehicles such as car, ship, can be used as movable type, fixed Blast Furnace Top Gas Recovery Turbine Unit (TRT) again.
When used in proton exchange membrane fuel cell is done car, ship power system or movable type and stationary power generation station, must comprise battery pile, fuel hydrogen supply system, air supply subsystem, cooling heat dissipation subsystem, control and electric energy output various piece automatically.
Fig. 1 is at present typical fuel cell generation, and 1 is fuel cell pack in Fig. 1, and 2 are storage hydrogen bottle or other hydrogen-storing devices, 3 is pressure-reducing valve, and 4 are air filtration worry device, and 5 is the air compression feeding mechanism, 6 is the hydrogen Water-vapor seperator, 6 ' is the air Water-vapor seperator, and 7 is water tank, and 8 is the cooling fluid circulating pump, 9 is radiator, 10 is the hydrogen circulating pump, and 11 is the hydrogen humidifying device, and 12 is the air humidification device.
According to the at present typical integrated and operation logic of fuel cell generation, must be to hydrogen and air that fuel cell pack is carried through voltage stabilizing and through humidifying device (11,12) after, become humid air, the hydrogen that reaches certain relative humidity and temperature and then enter electrochemical reaction takes place in the fuel cell pack.Otherwise the dry or inadequate air of humidification, when hydrogen is carried to fuel cell pack, excessive air, hydrogen can cause the proton exchange membrane dehydration in core component-membrane electrode in the fuel cell pack, the proton exchange membrane dehydration will cause internal resistance of fuel cell sharply to increase, and runnability sharply descends.
Being applied to the Proton Exchange Membrane Fuel Cells humidifying device at present mainly contains following several:
1. before dry air, fuel hydrogen enter fuel cell, make hydrone and air molecule be the gaseous state that mixes after in humidifying device, directly contacting, collide with pure water, air, when hydrone enters fuel cell, be the air that reaches certain relative humidity.
2. before dry air or fuel hydrogen and pure water enter fuel cell, not directly contact in humidifying device, but can allow hydrone freely see through but the film that do not allow gas molecule see through is separated by one deck, when film flows through dry air or hydrogen on one side, and the film another side is when flowing through pure water, hydrone will see through the film another side on one side from film automatically, makes air molecule mix the air of the relative humidity that reaches certain with hydrone.This film can be a proton exchange membrane, as Nafion film of E.I.Du Pont Company etc.
3. a kind of utilization of Shenli Science and Technology Co Ltd, Shanghai invention enters the humidifying device (number of patent application: 02217654.3) that dry air and the humid air that goes out fuel cell before the fuel cell carry out the water exchange, this humidifying device is made of a rotation inner bag, the interior absorbent material of filling, when dry air passes through, the hydrone on packing material surface in the inner bag is taken away, and humid air and water are by packing material surface in inner bag adsorbed water molecule again.
But present technical scheme becomes after the hydrogen that fuel cell pack is carried passes through humidification with air and directly enters fuel cell pack generation electrochemical reaction behind the humid air that reaches certain relative humidity and temperature, the hydrogen following technological deficiency is arranged:
1. in general, above-mentioned humidifying device all is to design for the condition of work of fuel cell when the nominal operation state.When hydrogen of carrying to fuel cell pack and the bigger variation of air mass flow generation, such as hour at flow, caused humidification easily, the hydrogen or the easy condensation of air of crossing humidification go out a small amount of aqueous water, and this aqueous water will be brought into respectively in fuel cell hydrogen flow guide groove, the air conducting groove by wet hydrogen, humid air.Cause the water blockoff of guiding gutter.In certain monocell in the hydrogen flow guide groove in water blockoff or the air conducting groove water blockoff can cause this monocell to be in the starvation of fuel hydrogen or air supply deficiency, this monocell performance will sharply descend, and can cause this electrode antipole when serious and burn.
2. the design of above-mentioned humidifying device generally all is under the nominal operation state by fuel cell, and under the nominal operation temperature, specified hydrogen, air mass flow can reach the hydrogen of design object, the control of relative air humidity after by humidifying device.But when ambient temperature changes and outside air relative humidity variations greatly the time, hydrogen, the relative air humidity that the passes through above-mentioned humidifying device controlling value that will depart from objectives, promptly wet excessively or overdrying causes the fuel cell operation unstable properties.
Summary of the invention
Purpose of the present invention is exactly that a kind of help improving the hydrogen that making of operation stability enter reaction or the fuel cell of air themperature and moisture stable are provided in order to overcome the defective that above-mentioned prior art exists.
Purpose of the present invention can be achieved through the following technical solutions: can make the hydrogen that enters reaction or the fuel cell of air themperature and moisture stable, comprise fuel cell pack, hydrogen-storing device, the hydrogen pressure-reducing valve, the hydrogen humidifying device, air filter, the air compression feeding mechanism, the air humidification device, the hydrogen Water-vapor seperator, the hydrogen circulating pump, the air Water-vapor seperator, water tank, the cooling fluid circulating pump, radiator, it is characterized in that, also comprise air or hydrogen temperature and humidity stabilization device, this air or hydrogen temperature and humidity stabilization device are arranged on air or hydrogen humidifying device and air or hydrogen and enter between the inlet of fuel cell pack.
Described air or hydrogen temperature and humidity stabilization device comprise a cavity, are provided with at least two layers of comb in this cavity.
Be provided with upper and lower two layers of comb in the described cavity.
Described cavity bottom is provided with damp-heat air or hydrogen inlet, the top is provided with damp-heat air or hydrogen outlet, comb top, described upper strata is provided with the first cooling fluid import, the bottom is provided with the outlet of first cooling fluid, described lower floor comb top is provided with the second cooling fluid import, the bottom is provided with the outlet of second cooling fluid, and described cavity bottom links to each other with a deionizater by pipeline, and this deionizater links to each other with a water tank again.
Described first cooling fluid outlet links to each other with the inlet of radiator, and the outlet of this radiator links to each other with the second cooling fluid import.
The described first cooling fluid import links to each other with the outlet of fuel cell pack cooling fluid, and described second cooling fluid outlet links to each other with the cooling fluid pump inlet.
Described cavity bottom is bell mouth shape and collects condensed water.
Described water tank upper is provided with an overflow pipe.
Compared with prior art, the present invention is provided with a device that can make air or hydrogen temperature and moisture stable owing to enter fuel cell pack at air or hydrogen before participating in reaction, therefore avoided crossing wet or overdrying phenomenon in the fuel cell pack, improved the operation stability of fuel cell.
Description of drawings
Fig. 1 is the structural representation of existing fuel cell;
Fig. 2 can make the structural representation of air or hydrogen temperature and humidity stabilization device for the present invention.
Embodiment
Below in conjunction with drawings and the specific embodiments, the invention will be further described.
Embodiment
As Fig. 1, shown in Figure 2, a kind of hydrogen that enters reaction or fuel cell of air themperature and moisture stable of making, comprise fuel cell pack 1, hydrogen-storing device 2, hydrogen pressure-reducing valve 3, hydrogen humidifying device 11, air filter 4, air compression feeding mechanism 5, air humidification device 12, hydrogen Water-vapor seperator 6, hydrogen circulating pump 10, air Water-vapor seperator 6 ', water tank 7, cooling fluid circulating pump 8, radiator 9, air or hydrogen temperature and humidity stabilization device 13, this air or hydrogen temperature and humidity stabilization device 13 be arranged on air or hydrogen humidifying device 11 or 12 and air or hydrogen enter between the inlet of fuel cell pack.
Described air or hydrogen temperature and humidity stabilization device 13 comprise a cavity 14, be provided with in this cavity 14, following two layers of comb 15,16, described cavity bottom is provided with damp-heat air or hydrogen inlet 17, the top is provided with damp-heat air or hydrogen outlet 18, comb 15 tops, described upper strata are provided with the first cooling fluid import 19, the bottom is provided with first cooling fluid outlet 20, described lower floor comb 16 tops are provided with the second cooling fluid import 21, the bottom is provided with second cooling fluid outlet 22, described cavity 14 bottoms link to each other with a deionizater 23 by pipeline, and this deionizater 23 links to each other with a water tank 24 again.Described first cooling fluid outlet 20 links to each other with the inlet of radiator 9, and the outlet of this radiator 9 links to each other with the second cooling fluid import 21.The cooling fluid outlet of the described first cooling fluid import 19 and fuel cell pack 1 links to each other, and described second cooling fluid exports 22 and links to each other with 8 imports of cooling fluid circulating pump.Described cavity 14 bottoms are bell mouth shape and collect condensed water.Described water tank 24 tops are provided with an overflow pipe 25.
Present embodiment is the fuel cell of a 10KW, 65 ℃ of cooling water outlet temperatures, and behind radiator, cooling water is reduced to 60 ℃, and promptly upper and lower two layers of comb temperature difference are 5 ℃.
Outside air temperature can change bigger, be generally 0 ℃ or 40 ℃, become 100% through humidity behind the humidifying device, temperature may be between 70 ℃~78 ℃, if directly enter the fuel cell pack reaction, be subjected to the outside air temperature variable effect big, but after the present invention new humidity and adjustment stabilizing arrangement, air themperature is no matter between 70 ℃~78 ℃, and all elder generation is after lower floor's comb cooling, and big appointment is stabilized in about 61 ℃, again through after the heating of upper strata comb, getting back to about 64 ℃, is 64 ℃ so enter the air of fuel cell pack all the time, and relative humidity approximately is about 80%.
Equally, after hydrogen temperature and humidity were regulated stabilizing arrangement through the present invention, the hydrogen that enters fuel cell pack was 64 ℃ all the time, and relative humidity approximately also is about 80%.

Claims (5)

1. can make the hydrogen that enters reaction or the fuel cell of air themperature and moisture stable, comprise fuel cell pack, hydrogen-storing device, the hydrogen pressure-reducing valve, the hydrogen humidifying device, air filter, the air compression feeding mechanism, the air humidification device, the hydrogen Water-vapor seperator, the hydrogen circulating pump, the air Water-vapor seperator, water tank, the cooling fluid circulating pump, radiator, it is characterized in that, also comprise air or hydrogen temperature and humidity stabilization device, this air or hydrogen temperature and humidity stabilization device are arranged on air or hydrogen humidifying device and air or hydrogen and enter between the inlet of fuel cell pack; Described air or hydrogen temperature and humidity stabilization device comprise a cavity, are provided with upper and lower two layers of comb in the described cavity; Described cavity bottom is provided with damp-heat air or hydrogen inlet, the top is provided with damp-heat air or hydrogen outlet, comb top, described upper strata is provided with the first cooling fluid import, the bottom is provided with the outlet of first cooling fluid, described lower floor comb top is provided with the second cooling fluid import, the bottom is provided with the outlet of second cooling fluid, and described cavity bottom links to each other with a deionizater by pipeline, and this deionizater links to each other with a water tank again.
2. the hydrogen that enters reaction or the fuel cell of air themperature and moisture stable of making according to claim 1, it is characterized in that, described first cooling fluid outlet links to each other with the inlet of radiator, and the outlet of this radiator links to each other with the second cooling fluid import.
3. the hydrogen that enters reaction or the fuel cell of air themperature and moisture stable of making according to claim 1, it is characterized in that, the described first cooling fluid import links to each other with the outlet of fuel cell pack cooling fluid, and described second cooling fluid outlet links to each other with the cooling fluid pump inlet.
4. the hydrogen that enters reaction or the fuel cell of air themperature and moisture stable of making according to claim 1 is characterized in that described cavity bottom is bell mouth shape and collects condensed water.
5. the hydrogen that enters reaction or the fuel cell of air themperature and moisture stable of making according to claim 1 is characterized in that described water tank upper is provided with an overflow pipe.
CNB2004100680656A 2004-11-11 2004-11-11 Fuel cell capable of making hydrogen or air temperature and humidity entered into reaction stablizing Active CN100392902C (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101345318B (en) * 2007-07-10 2010-06-16 比亚迪股份有限公司 Humidification system of fuel cell
KR20130056932A (en) * 2011-11-23 2013-05-31 에스케이이노베이션 주식회사 Battery pack
DE102015215201A1 (en) * 2015-08-10 2017-02-16 Volkswagen Ag Fuel cell stack with internal particle retention function as well as vehicle with such a fuel cell stack
CN109273742B (en) * 2018-09-27 2020-06-09 德州新动能铁塔发电有限公司 Air supply system of methanol-water reforming hydrogen production fuel cell

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002373686A (en) * 2001-06-14 2002-12-26 Mitsubishi Electric Corp Temperature and humidity regulating device and temperature and humidity regulating method for fuel cell reactant gas
JP2003178778A (en) * 2001-12-12 2003-06-27 Nissan Motor Co Ltd Fuel cell system
CN2739805Y (en) * 2004-11-11 2005-11-09 上海神力科技有限公司 Fuel cell capable of making incoming hydrogne or air temperature and humidity stable

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002373686A (en) * 2001-06-14 2002-12-26 Mitsubishi Electric Corp Temperature and humidity regulating device and temperature and humidity regulating method for fuel cell reactant gas
JP2003178778A (en) * 2001-12-12 2003-06-27 Nissan Motor Co Ltd Fuel cell system
CN2739805Y (en) * 2004-11-11 2005-11-09 上海神力科技有限公司 Fuel cell capable of making incoming hydrogne or air temperature and humidity stable

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