CN100351205C - Heat-insulating energy-saving temperature-constant ceramic brick and manufacturing process thereof - Google Patents
Heat-insulating energy-saving temperature-constant ceramic brick and manufacturing process thereof Download PDFInfo
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- CN100351205C CN100351205C CNB2006100602815A CN200610060281A CN100351205C CN 100351205 C CN100351205 C CN 100351205C CN B2006100602815 A CNB2006100602815 A CN B2006100602815A CN 200610060281 A CN200610060281 A CN 200610060281A CN 100351205 C CN100351205 C CN 100351205C
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Abstract
The present invention relates to an energy-saving ceramic brick with thermal insulation and constant temperature and a production technology thereof, which solves the problems that the existing heat insulation material has the poor effects of thermal insulation and constant temperature. The ceramic brick is composed of a semi-finished ceramic brick with thermal insulation and thermal-insulating and temperature-constant paint coated on the surface of the semi-finished ceramic brick, wherein the semi-finished ceramic brick with thermal insulation is prepared from the following raw materials according to the proportion by weight: 30% to 40% of kaoline, 20% to 30% of calcite powder, 5% to 10% of talcum powder, 10% to 15% of hollow microsphere and 20% to 25% of water. The thermal-insulating and temperature-constant paint is prepared from the following raw materials according to the proportion by weight: 25% to 35% of supreme white powder, 8% to 13% of hollow microsphere, 3% to 5% of talcum powder, 35% to 42% of silicone resin, 15% to 25% of solvent, 0.3% to 1% of pigment and 1 to 3% of auxiliary agent. The production technology comprises the following steps: the semi-finished ceramic brick with thermal insulation and the thermal-insulating and temperature-constant paint are respectively produced, and the thermal-insulating and temperature-constant paint is sprayed on the brick surface of the semi-finished ceramic brick with thermal insulation for two to three times; finally, the ceramic brick can be obtained after the thermal-insulating and temperature-constant paint is dried and shaped on the semi-finished ceramic brick with thermal insulation. The ceramic brick has the good effects of thermal insulation and constant temperature, and has the advantages of energy saving and long service life.
Description
Technical field
The present invention relates to a kind of ceramic tile and production technique thereof.
Background technology
In history and flooring lagging material in recent years free edema with the heart involved adobe and thermal insulating coating are arranged, its existing problems are as follows: 1. hollow cement brick effect of heat insulation is humble, easily piles up rubbish, and is not attractive in appearance; The thermal insulating coating life-span in recent years extremely short, easily efflorescence, easily delamination.
Because hollow cement brick effect of heat insulation is very humble, easily piles up rubbish again, very not attractive in appearance, people early have recognized that.Thermal insulating coating in recent years, being about to thermal insulating coating directly is painted on cement flooring (thickness is about 1mm) and carries out heat insulation, its ten days eight days effect of heat insulation that begin are more obvious, but because performance extreme differences such as its anti-efflorescence, resistant, cohesive force, generally at 1 month to 2 months, long then half a year, one-year age quite serious efflorescence, delamination, pickup etc. just occur and lose its heat insulating function, bring a joyful bad result who is all in vain to the human consumer.Therefore, thermal insulating coating is in recent years also failed the real flooring heat-insulating energy-saving temperature-constant problem that thoroughly solves.To thoroughly solve flooring heat-insulating energy-saving temperature-constant problem, must have a kind of stand throughout the year expose to the sun and rain, sometimes cold and sometimes hot test and do not change original performance itself, promptly sun-proof, anti-ly freeze, anti-pouring, wear-resistingly, anti-soak, the flooring heat-insulating energy-saving temperature-constant material of resistant.
Summary of the invention
First purpose of the present invention is to provide the heat-insulating energy-saving temperature-constant ceramic brick of a kind of heat insulation good constant-temperature effect, long service life at the shortcoming that existing lagging material exists heat insulation constant temperature weak effect, thermal insulating coating life-span lacks on it.
Second purpose of the present invention is to provide a kind of production technique of heat-insulating energy-saving temperature-constant ceramic brick of the present invention.
First purpose of the present invention is achieved in that ceramic tile of the present invention is by the work in-process heat insulating ceramic tile be coated in the heat insulation constant temperature of its lip-deep one deck lacquer and constitute, the raw material of described work in-process heat insulating ceramic tile consists of, (1) kaolin 30%-40%, (2) calcite in powder 20%-30%, (3) talcum powder 5%-10%, (4) cenosphere 10%-15%, (5) water 20%-25%; The raw material of described heat insulation constant temperature lacquer consists of, (1) Cornstarch 25%-35%, (2) cenosphere 8%-13%, (3) talcum powder 3%-5%, (4) fluorine silicon resin 35%-42%, (5) solvent 15%-25%, (6) pigment 0-1%, (7) auxiliary agent 1-3%, described auxiliary agent is by the defoamer of 15%-30%, the dispersion agent of 15%-30%, the solidifying agent of 15%-30%, the sanitas of 15%-30% is formed; Above content is weight percentage.
Solvent selected for use butanone preferable during the raw material of the heat insulation constant temperature lacquer of ceramic tile of the present invention was formed.
Work in-process heat insulating ceramic tile employing thickness is 8-12mm in the ceramic tile of the present invention, and length and width is that the specification of 25mm-50mm is preferable.
The coat-thickness that coats with lacquer in the ceramic tile of the present invention adopts 0.3mm-0.6mm preferable.
Second purpose of the present invention is achieved in that production technique of the present invention comprises the steps,
(1) the various raw materials with the work in-process heat insulating ceramic tile mix the adobe that is pressed into specification, naturally put into kiln high temperature after parching and burn till the work in-process heat insulating ceramic tile, the temperature of kiln is at 1000 ℃-1200 ℃, the raw material of described work in-process heat insulating ceramic tile consists of, (1) kaolin 30%-40%, (2) calcite in powder 20%-30%, (3) talcum powder 5%-10%, (4) cenosphere 10%-15%, (5) water 20%-25% is in weight percentage;
(2) the raw material batch mixing of heat insulation constant temperature lacquer is reacted after-filtration, make heat insulation constant temperature lacquer, the raw material of described heat insulation constant temperature lacquer consists of, (1) Cornstarch 25%-35%, (2) cenosphere 8%-13%, (3) talcum powder 3%-5%, (4) fluorine silicon resin 35%-42%, (5) solvent 15%-25%, (6) pigment 0-1%, (7) auxiliary agent 1-3%, described auxiliary agent is by the defoamer of 15%-30%, the dispersion agent of 15%-30%, the solidifying agent of 15%-30%, the sanitas of 15%-30% is formed, and above content is weight percentage;
(3) the heat insulation constant temperature lacquer that (2) step was made divides on the brick face of the work in-process heat insulating ceramic tile that is sprayed on (1) step gained for two to three times, parch and promptly get ceramic tile of the present invention after qualitative, described spraying process is between 30 ℃-60 ℃ of room temps, and relative humidity is carried out under the condition below 50%.
In (2) step of production technique of the present invention, the preparation method of heat insulation constant temperature lacquer is preferably as follows: solvent is put into reactor, put into Cornstarch, cenosphere, talcum powder more respectively, stirred 8-10 minute; To go up step gained material then and put into the shredder grinding; Then previous step gained material and fluorine silicon resin, pigment are put into reactor and stirred 12-15 minute; Put into auxiliary agent then and stirred 12-15 minute, stopped to stir restir 5-6 minute 3-5 minute; Then previous step gained material is filtered, get filtrate and be heat insulation constant temperature lacquer.
The present invention adopts above spraying method, and mutually combining of work in-process heat insulating ceramic tile and heat insulation constant temperature lacquer is very stable, never delamination.
Technique effect of the present invention is: ceramic tile of the present invention is really stood throughout the year and is exposed to the sun and rain, sometimes cold and sometimes hot, the complex environment that dust is billowing tests and not efflorescence, not delamination, nondiscoloration, ageing-resistant, wear-resisting wiping, water-fast bubble, anti-pollution, have superior heat insulation, constant temperature, energy-conservation, waterproof, antifouling, anti-wiping, performance such as weather-proof, ceramic tile of the present invention shop card is in the building flooring, heat insulation, constant temperature, water resistance is good, save the air-conditioning power consumption energy winter in summer, can reduce air-conditioning power consumption spending more than 35%, long service life, reach more than 30 years, cost is low, construction is simple, reduces and pollutes.In addition, it is selective that the allotment of the present invention by pigment can draw the product of each money of all kinds, spreads obedient flooring, and its finishing effect can allow each human consumer just in accordance with the wish.
It is because following reason that the present invention has above technique effect:
1, hollow core microballon of the present invention is to make the heat insulation last corbel material of micropore gas phase; Kaolin, calcite in powder, talcum powder are the quality matetrials of firing ceramic tile, and adhesion is strong, fire and do not ftracture, and it is strong to fire the product hardness that draws; Fluorine silicon resin is the fine macromolecular material, has superior cohesive force, weather-proof, anti-efflorescence, self-cleaning property; Cornstarch has superior weathering resistance, is silene; Talcum powder increases the levelling property of spraying; Defoamer can be eliminated the bubble in the paint; Dispersion agent is with the pigment homodisperse; Solidifying agent energy catalyst coatings is dry and hard rapidly; Sanitas never degenerates paint for a long time; Solvent can adjust paint rare denseness.
2, ceramic tile of the present invention in the brick body, utilize cenosphere carry out sufficient micropore gas phase heat insulation (and in recent years the thermal insulating coating coating of usefulness have only 1mm thick below), add the photothermal reflectance of lacquer painting, its heat-insulating energy-saving temperature-constant effect surmounts far away in other lagging material.The ceramic tile of high-temperature firing, macromolecular material lacquer and the ceramic tile of the present invention that draws by the special process making, in the cement structures flooring, performances such as it is heat insulation, constant temperature, flintiness, self-cleaning, wear resistance, sun-resistant, rain resistance, anti-efflorescence all are superior to other heat insulation waterproof material greatly with grout or water-proof putty shop card.
Embodiment
Embodiment one:
Embodiment one is the beige heat-insulating energy-saving temperature-constant ceramic brick, it is by the work in-process heat insulating ceramic tile and is coated in the heat insulation constant temperature of its lip-deep one deck lacquer and constitutes, the specification of ceramic tile is long 30mm * wide 30mm * thick 8.38mm, and the raw material of work in-process heat insulating ceramic tile and heat insulation constant temperature lacquer is formed as follows respectively:
1. the raw material of work in-process heat insulating ceramic tile is formed: units, gross weight 10000kg
(1) kaolin (south, Lianjiang City power kaolin TSC-1) 3300,
(2) calcite in powder (325 orders, whiteness 80%) 2900,
(3) talcum powder (triumphant return board industry second patent flour) 500,
(4) cenosphere (Shanghai positive U.S. company product) 1100,
(5) water 2200;
The specification of work in-process heat insulating ceramic tile is long 30mm * wide 30mm * thick 8mm;
2. the raw material of heat insulation constant temperature lacquer is formed: units, gross weight 288kg
(1) Cornstarch (RPO2) 72,
(2) cenosphere (Shanghai positive U.S. company product) 37,
(3) talcum powder (the superfine powder of triumphant return board industry) 11.5,
(4) fluorine silicon resin (good fortune is returned B603) 115,
(5) butanone (purity 〉=99.5%) 45,
(6) orange mill base (import: Dutch BS company produces) 1.5,
(7) auxiliary agent 6,
570 type defoamers, 0.9,168 type dispersion agent 1.8 in the auxiliary agent, E12 solidifying agent 1.5,315 type sanitass 1.8.570 type defoamers are available from Shenzhen on-year Science and Technology Ltd., and its composition is the polysiloxane solvent; 168 type dispersion agents are available from Shenzhen on-year Science and Technology Ltd., and its composition is a titanate coupling agent; The E12 solidifying agent is available from Shenzhen on-year Science and Technology Ltd., and its composition is the organic amine solvent, and solvent is ester class, arene mixed solvent; 315 type sanitass are available from Shenzhen on-year Science and Technology Ltd., and its composition is that isothiazole drenches ketone.All embodiment is identical therewith for the source of each component of auxiliary agent and composition in following examples.
The thickness of heat insulation constant temperature lacquering is 0.38mm.
Embodiment two:
Embodiment two is white heat-insulating energy-saving temperature-constant ceramic brick, it is by the work in-process heat insulating ceramic tile and is coated in the heat insulation constant temperature of its lip-deep one deck lacquer and constitutes, the specification of ceramic tile is long 35mm * wide cv * thick 8.92mm, and the raw material of work in-process heat insulating ceramic tile and heat insulation constant temperature lacquer is formed as follows respectively:
1. the raw material of work in-process heat insulating ceramic tile is formed: units, gross weight 10000kg
(1) kaolin (south, Lianjiang City power kaolin TSC-1) 3500,
(2) calcite in powder (325 orders, whiteness 80%) 3000,
(3) talcum powder (triumphant return board industry second patent flour) 500,
(4) cenosphere (Shanghai positive U.S. company product) 1000,
(5) water 2000;
The specification of work in-process heat insulating ceramic tile is long 30mm * wide 30mm * thick 8.5mm;
2. the raw material of heat insulation constant temperature lacquer is formed: units, gross weight 288kg
(1) Cornstarch (RPO2) 76,
(2) cenosphere (Shanghai positive U.S. company product) 25,
(3) talcum powder (the superfine powder of triumphant return board industry) 8.8,
(4) fluorine silicon resin (good fortune is returned B603) 101,
(5) butanone (purity 〉=99.5%) 72,
(6) auxiliary agent 5.2,570 type defoamers, 1.3,168 type dispersion agents 0.78 wherein, E12 solidifying agent 1.56,315 type sanitass 1.56.
The thickness of heat insulation constant temperature lacquering is 0.42mm.
Embodiment three:
Embodiment three is a basket look heat-insulating energy-saving temperature-constant ceramic brick, it is by the work in-process heat insulating ceramic tile and is coated in the heat insulation constant temperature of its lip-deep one deck lacquer and constitutes, the specification of ceramic tile is long 40mm * wide 40mm * thick 9.5mm, and the raw material of work in-process heat insulating ceramic tile and heat insulation constant temperature lacquer is formed as follows respectively:
1. the raw material of work in-process heat insulating ceramic tile is formed: units, gross weight 10000kg
(1) kaolin (south, Lianjiang City power kaolin TSC-1) 4000,
(2) calcite in powder (325 orders, whiteness 80%) 2000,
(3) talcum powder (triumphant return board industry second patent flour) 1000,
(4) cenosphere (Shanghai positive U.S. company product) 1000,
(5) water 2000;
The specification of work in-process heat insulating ceramic tile is that specification is long 40mm * wide 40mm * thick 9mm;
2. the raw material of heat insulation constant temperature lacquer is formed: units, gross weight 288kg
(1) Cornstarch (RPO2) 100,
(2) cenosphere (Shanghai positive U.S. company product) 23.5,
(3) talcum powder (the superfine powder of triumphant return board industry) 10,
(4) fluorine silicon resin (good fortune is returned B603) 101,
(5) butanone (purity 〉=99.5%) 49.6,
(6) blue mill base (import: Dutch BS company produces) 1,
(7) auxiliary agent 2.9,
570 type defoamers, 0.87,168 type dispersion agent 0.725 in the auxiliary agent, E12 solidifying agent 0.435,315 type sanitas 0.87.
The thickness of heat insulation constant temperature lacquering is 0.5mm.
Embodiment four:
Embodiment four is green heat-insulating energy-saving temperature-constant ceramic brick, it is by the work in-process heat insulating ceramic tile and is coated in the heat insulation constant temperature of its lip-deep one deck lacquer and constitutes, the specification of ceramic tile is long 50mm * wide 50mm * thick 11.6mm, and the raw material of work in-process heat insulating ceramic tile and heat insulation constant temperature lacquer is formed as follows respectively:
1. the raw material of work in-process heat insulating ceramic tile is formed: units, gross weight 10000kg
(1) kaolin (south, Lianjiang City power kaolin TSC-1) 3000,
(2) calcite in powder (325 orders, whiteness 80%) 2300,
(3) talcum powder (triumphant return board industry second patent flour) 700,
(4) cenosphere (Shanghai positive U.S. company product) 1500,
(5) water 2500;
The specification of work in-process heat insulating ceramic tile is long 50mm * wide 50mm * thick 11mm.
2. the raw material of heat insulation constant temperature lacquer is formed: units, gross weight 288kg
(1) Cornstarch (RPO2) 72,
(2) cenosphere (Shanghai positive U.S. company product) 25.2,
(3) talcum powder (the superfine powder of triumphant return board industry) 14.4,
(4) fluorine silicon resin (good fortune is returned B603) 120,
(5) butanone (purity 〉=99.5%) 45,
(6) green mill base (import: Dutch BS company produces) 2.8,
(7) auxiliary agent 8.6,
570 type defoamers, 2.58,168 type dispersion agents 2.15 in the auxiliary agent, E12 solidifying agent 2.58,315 type sanitass 1.29.
The thickness of heat insulation constant temperature lacquering is 0.6mm.
Embodiment five:
The production technique of the described heat insulation constant temperature ceramic tile of above embodiment is as follows:
One. the production method of work in-process heat insulating ceramic tile:
1. various feed kaolin, calcite in powder, talcum powder, the cenosphere of work in-process heat insulating ceramic tile being put into dry powder blender stirred 5 minutes;
2. the kaolin, calcite in powder, talcum powder, the cenosphere that stir are put into stirrer, add entry again and stirred 15 minutes;
3. with the material of previous step gained, after gradation is put into and carried out compacting on the adobe mould of required specification and flatten according to quantity, pour out and set level airing on frame plate;
4. the adobe behind the airing is put into stove and fired 10-15 hour, the temperature of stove gets the work in-process heat insulating ceramic tile at 1000 ℃-1200 ℃.
Two. the production method of heat insulation constant temperature lacquer:
1. the solvent butanone is put into reactor, put into Cornstarch, cenosphere, talcum powder respectively, stirred 10 minutes;
2. previous step gained material being put into shredder grinds;
3. the 2nd step gained material and fluorine silicon resin, pigment are put into reactor and stirred 15 minutes;
4. put into auxiliary agent then and stirred 15 minutes, stopped restir 5 minutes 5 minutes.
5. the 4th step gained material is put into screen(ing) machine and filter, get filtrate and be heat insulation constant temperature lacquer;
6. the barrel cage of the heat insulation constant temperature lacquer of the 5th step gained being packed into holds.
Three. spraying:
Below 50%, temperature indoor at 38 ℃ divides a secondary to be sprayed on the work in-process heat insulating ceramic tile in the above-mentioned heat insulation constant temperature lacquer that makes in relative humidity, and coat-thickness is 0.38mm, parches promptly getting the high-quality heat-insulating energy-saving temperature-constant ceramic brick after qualitative.In spraying process, room temp is controlled between 30 ℃-60 ℃, and spraying also can divide to be carried out for three times, and coat-thickness is 0.38mm-0.6mm.
Below only enumerated several embodiment, the composition that other is similar, be equal to, technology, content etc. all should belong to the protection domain of this patent, do not repeat them here.
Claims (6)
1. heat-insulating energy-saving temperature-constant ceramic brick, it is characterized in that: by the work in-process heat insulating ceramic tile be coated in the heat insulation constant temperature of its lip-deep one deck lacquer and constitute, the raw material of described work in-process heat insulating ceramic tile consists of, (1) kaolin 30%-40%, (2) calcite in powder 20%-30%, (3) talcum powder 5%-10%, (4) cenosphere 10%-15%, (5) water 20%-25%;
The raw material of described heat insulation constant temperature lacquer consists of, (1) Cornstarch 25%-35%, (2) cenosphere 8%-13%, (3) talcum powder 3%-5%, (4) fluorine silicon resin 35%-42%, (5) solvent 15%-25%, (6) pigment 0-1%, (7) auxiliary agent 1-3%, described auxiliary agent is by the defoamer of 15%-30%, the dispersion agent of 15%-30%, the solidifying agent of 15%-30%, the sanitas of 15%-30% is formed; Above content is weight percentage.
2. heat-insulating energy-saving temperature-constant ceramic brick according to claim 1 is characterized in that: described solvent is a butanone.
3. heat-insulating energy-saving temperature-constant ceramic brick according to claim 1 and 2 is characterized in that: the specification of described work in-process heat insulating ceramic tile is thickness 8-12mm, and length and width is 25mm-50mm.
4. heat-insulating energy-saving temperature-constant ceramic brick according to claim 1 and 2 is characterized in that: the coat-thickness of described lacquer is 0.3mm-0.6mm.
5. the production technique of a heat-insulating energy-saving temperature-constant ceramic brick according to claim 1 is characterized in that comprising the steps:
(1) the various raw materials with the described work in-process heat insulating ceramic tile of claim 1 mix the adobe that is pressed into specification, put into kiln high temperature after parching naturally and burn till the work in-process heat insulating ceramic tile, and the temperature of kiln is at 1000 ℃-1200 ℃;
(2) with the raw material batch mixing reaction after-filtration of the described heat insulation constant temperature lacquer of claim 1, make heat insulation constant temperature lacquer;
(3) the heat insulation constant temperature lacquer that (2) step was made divides on the brick face of the work in-process heat insulating ceramic tile that is sprayed on (1) step gained for two to three times, parch qualitative after promptly, described spraying process is between 30 ℃-60 ℃ of room temps, and relative humidity is carried out under the condition below 50%.
6. the production technique of heat-insulating energy-saving temperature-constant ceramic brick according to claim 5 is characterized in that: in described (2) step, solvent is put into reactor, put into Cornstarch, cenosphere, talcum powder more respectively, stirred 8-10 minute; To go up step gained material then and put into the shredder grinding; Then previous step gained material and fluorine silicon resin, pigment are put into reactor and stirred 12-15 minute; Put into auxiliary agent then and stirred 12-15 minute, stopped to stir restir 5-6 minute 3-5 minute; Then previous step gained material is filtered, get filtrate and be heat insulation constant temperature lacquer.
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| CN101412614B (en) * | 2007-10-19 | 2011-12-28 | 周凤华 | Honeycomb vacuum hole heat insulating ceramic tile and technique for producing the same |
| CN102381852B (en) * | 2011-07-19 | 2016-04-13 | 谷艮之 | Composition board heat insulating nano material and preparation method thereof |
| CN108727961A (en) * | 2018-06-14 | 2018-11-02 | 苏州佳凯元新材料科技有限公司 | Heat insulating and corrosion coating and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1473888A (en) * | 2003-08-06 | 2004-02-11 | 李美珠 | Heat insulation leak-proof antifouling outer wall mastic |
| CN1559979A (en) * | 2004-03-09 | 2005-01-05 | 张尚坤 | Far infrared health-care ceramics and preparation technology thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1473888A (en) * | 2003-08-06 | 2004-02-11 | 李美珠 | Heat insulation leak-proof antifouling outer wall mastic |
| CN1559979A (en) * | 2004-03-09 | 2005-01-05 | 张尚坤 | Far infrared health-care ceramics and preparation technology thereof |
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