CH297246A - Process for the preparation of a polyazo dye. - Google Patents

Process for the preparation of a polyazo dye.

Info

Publication number
CH297246A
CH297246A CH297246DA CH297246A CH 297246 A CH297246 A CH 297246A CH 297246D A CH297246D A CH 297246DA CH 297246 A CH297246 A CH 297246A
Authority
CH
Switzerland
Prior art keywords
dye
copper
polyazo
polyazo dye
mol
Prior art date
Application number
Other languages
German (de)
Inventor
Ag Sandoz
Original Assignee
Ag Sandoz
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ag Sandoz filed Critical Ag Sandoz
Publication of CH297246A publication Critical patent/CH297246A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B35/00Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
    • C09B35/38Trisazo dyes ot the type
    • C09B35/40Trisazo dyes ot the type the component K being a dihydroxy or polyhydroxy compound
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B45/00Complex metal compounds of azo dyes
    • C09B45/48Preparation from other complex metal compounds of azo dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Description

  

  <B>Zusatzpatent</B> zum Hauptpatent Nr. 29241.2.    Verfahren     zur        Herstellung        eines        Polyazofarbstoffes.            G=egenstand    des vorliegenden Patentes ist  ein Verfahren zur Herstellung eines     Polyazo-          farbstoffes,    welches darin besteht,     da.ss    man  1     11o1    der     Tetrazoverbindung    aus 3,3'-Di-         methoxy-4,4'-diamino-1,

  1'-diphenyl    mit 1     Mol          1-Oxynapht.halin-4-sulfonsäure    und mit 1     Mol     der     Kupferkomplexverbindung    aus dem     Mono-          azofarbstoff    der     Zusammensetzung     
EMI0001.0019     
    kuppelt und den erhaltenen     Polyazofarbstoff     unter Aufspaltung der     Methoxygruppen    mit  einem kupferabgebenden Mittel behandelt.  



  <I>Beispiel:</I>  Die     Tetrazoverbindung    aus 24,4 Teilen       3,3'-Dimethoxy-4,4'-diamino-1,1'-diphenyl    wird    in üblicher Weise     sodaalkalisch    mit 22,4 Tei  len     1-Oxynaphthalin-4-sulfonsäure    zur Zwi  schenverbindung gekuppelt.

   Die isolierte Zwi  schenverbindung trägt man ein in eine Lösung  von 63,2 Teilen der     Kupferkomplexverbin-          dung    des     Monoazofarbstoffes    der Zusammen  setzung  
EMI0001.0029     
    250 Teilen     Pyridin    und 50 Teilen Ammoniak       25        %        ig        in        500        Teilen        Wasser.        Nach        Beendi-          gung    der Kupplung wird der     Trisazofarbstoff     isoliert und nach den üblichen Methoden  <RTI  

   ID="0001.0042">   ent-          methylierend        gekupfert.     



  Die     Kupferkomplexverbindung    des neuen  Farbstoffes stellt getrocknet ein dunkles Pul  ver dar, das sich sowohl in Wasser als auch    in     konzentrierter    Schwefelsäure mit blauer  Farbe löst und Baumwolle in echten blau  grauen Tönen färbt.



  <B> Additional patent </B> to main patent no. 29241.2. Process for the preparation of a polyazo dye. The subject of the present patent is a process for the preparation of a polyazo dye, which consists in that 1 11o1 of the tetrazo compound are obtained from 3,3'-dimethoxy-4,4'-diamino-1,

  1'-diphenyl with 1 mole of 1-oxynaphth.halin-4-sulfonic acid and with 1 mole of the copper complex compound from the monoazo dye of the composition
EMI0001.0019
    couples and treated the polyazo dye obtained with splitting of the methoxy groups with a copper donor.



  <I> Example: </I> The tetrazo compound from 24.4 parts of 3,3'-dimethoxy-4,4'-diamino-1,1'-diphenyl becomes soda-alkaline in the usual way with 22.4 parts of 1-oxynaphthalene -4-sulfonic acid coupled to the inter mediate connection.

   The isolated intermediate compound is incorporated into a solution of 63.2 parts of the copper complex compound of the monoazo dye of the composition
EMI0001.0029
    250 parts of pyridine and 50 parts of 25% ammonia in 500 parts of water. After the coupling has ended, the trisazo dye is isolated and <RTI. By the customary methods

   ID = "0001.0042"> coppered demethylating.



  The copper complex compound of the new dye, when dried, is a dark powder that dissolves in water as well as in concentrated sulfuric acid with a blue color and dyes cotton in real blue-gray tones.

 

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines Polyazo- farbstoffes, dadurch gekennzeichnet, dass man 1 Mol der Tetrazoverbindung aus 3,3'-Di- methoxy-4,4'-diamino-1, PATENT CLAIM: Process for the production of a polyazo dye, characterized in that 1 mol of the tetrazo compound is obtained from 3,3'-dimethoxy-4,4'-diamino-1, 1'-diphenyl mit 1 Mol l.-Oxynaphthalin-4-sulfonsäure und mit 1 1M1 der Kupferkomplexv erbindung aus dem @Iono- azofarbstoff der Zusammensetzung EMI0002.0010 kuppelt und den erhaltenen Polyazofarbstoff unter Aufspaltung der Methoxy gruppen mit einem kupferabgebenden :Mittel behandelt. 1'-diphenyl with 1 mol of l.-oxynaphthalene-4-sulfonic acid and with 1 1M1 of the copper complex compound from the @iono azo dye of the composition EMI0002.0010 coupled and treated the polyazo dye obtained with splitting of the methoxy groups with a copper-releasing agent. Der neue kupferhaltige Farbstoff stellt. ein dunkles Pulver dar, das sieh sowohl in Was ser als aueh in konzentrierter Sehwefelsäure mit blauer Farbe löst und Baumwolle in eeh- ten blaugrauen Tönen färbt. <B>UNTERANSPRÜCHE:</B> 1. Verfahren naeh Patentansprueh, da- dureh gekennzeiehnet, da.ss die zweite Kupp lung in Gegenwart einer organisehen tertiären Base ausgeführt. wird. 2. The new copper-containing dye represents. a dark powder which dissolves in water as well as in concentrated sulfuric acid with a blue color and dyes cotton in deep blue-gray tones. <B> SUBClaims: </B> 1. Method according to patent claim, characterized in that the second coupling is carried out in the presence of an organic tertiary base. becomes. 2. Verfahren naeh Patentansprueh und Unteransprueh 1, dadureh gekennzeiehnet, dass man als organisehe tertiäre Base Py ridin wählt. Method according to patent claim and sub-claim 1, dadureh marked that pyridine is chosen as the organic tertiary base.
CH297246D 1951-01-19 1951-01-19 Process for the preparation of a polyazo dye. CH297246A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH297246T 1951-01-19
CH292412T 1951-01-19

Publications (1)

Publication Number Publication Date
CH297246A true CH297246A (en) 1954-03-15

Family

ID=25733230

Family Applications (1)

Application Number Title Priority Date Filing Date
CH297246D CH297246A (en) 1951-01-19 1951-01-19 Process for the preparation of a polyazo dye.

Country Status (1)

Country Link
CH (1) CH297246A (en)

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