CH192050A - Process for the production of a new azo dye. - Google Patents
Process for the production of a new azo dye.Info
- Publication number
- CH192050A CH192050A CH192050DA CH192050A CH 192050 A CH192050 A CH 192050A CH 192050D A CH192050D A CH 192050DA CH 192050 A CH192050 A CH 192050A
- Authority
- CH
- Switzerland
- Prior art keywords
- azo dye
- new azo
- production
- aminobenzene
- dye
- Prior art date
Links
- 239000000987 azo dye Substances 0.000 title claims description 6
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 238000000034 method Methods 0.000 title claims description 3
- 239000002253 acid Substances 0.000 claims description 5
- 239000000975 dye Substances 0.000 claims description 5
- 150000008049 diazo compounds Chemical class 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000001045 blue dye Substances 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000005605 benzo group Chemical group 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000000664 diazo group Chemical class [N-]=[N+]=[*] 0.000 description 1
- 238000006193 diazotization reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B33/00—Disazo and polyazo dyes of the types A->K<-B, A->B->K<-C, or the like, prepared by diazotising and coupling
- C09B33/02—Disazo dyes
- C09B33/08—Disazo dyes in which the coupling component is a hydroxy-amino compound
- C09B33/10—Disazo dyes in which the coupling component is a hydroxy-amino compound in which the coupling component is an amino naphthol
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
Zusatzpatent zum Hauptpatent Nr. 190424. Verfahren zur Herstellung eines neuen Azofarbstoffes. Es wurde gefunden, dass man einen:
neuen Azofarbstoff erhält, wenn man die Diazover- bindung des 1-Aminobenzol-2,-methylsulfons in saurem Medium mit 1-Amino-8-ogynaph- thalin-3,6-,disulfonsäure vereinigt und diesen so erhältlichen Farbstoff in alkalischem Medium mit der Diazoverbindung von 1- Amino#benzo#l-3-methylsulfon umsetzt.
Der neue Azo,farbstoff bildet eindunkles Pulver, das sich in Wasser mit blauer Färbe löst und Wolle aus saurem Bade in blauschwarzen Tönen von guten Echtheitseigenschaften färbt.
<I>Beispiel:</I> 17,1 Teile 1-Aminobenzol-2-methylsulfon werden fein pulverisiert, mit 30 Teilen :Salz- säure und 30 Teilen Wasser gut ange schwemmt und bei<B>5,0'</B> in Lösung gebracht. Beim Abkühlen, fällt das Chlorhydrat der Base in feiner Form aus.
Man :gibt 100 Teile Eis zu und innerhalb etwa 10 Minuten lässt man die berechnete Menge Natriumnitrit zu- tropfen.
Nach ca. 20 Minuten ist die Diazo- tierung fertig. Diese Diazolösung .giesst man nun unter Rühren zu .3'1,9 Teilen fein gefäll ter 1-Amino-8-ogynaphthalin-3,6@-,
disulfon- säure und rührt ca. 3 Stunden bei gewöhn licher Temperatur. Dann trägt man 35 Teile Natriumcarbonat ein und vereinigt sodaalka- lisch mit einer Diazolösung aus 17.1 Teilen 1-Aminobenzol-3-methylsulfo#n, die auf be- kannte Weise hergestellt wird.
Der Farb stoff fällt aus und wird abfiltziert. Durch Umlösen und Ausealzen wird er gereinigt. Nach dem Trocknen erhält man ein dunkles Pulver, das sich in Wasser mit blauer Farbe löst und Wolle aus saurem Bade blauschwarz färbt.
Additional patent to main patent No. 190424. Process for the production of a new azo dye. It has been found that one can:
new azo dye is obtained when the diazo compound of 1-aminobenzene-2-methylsulfone is combined in an acidic medium with 1-amino-8-ogynaphthalene-3,6-, disulfonic acid and this dye thus obtainable in an alkaline medium with the Diazo compound of 1- Amino # benzo # l-3-methylsulfone converts.
The new azo dye forms a dark powder that dissolves in water with a blue dye and dyes wool from an acid bath in blue-black shades with good fastness properties.
<I> Example: </I> 17.1 parts of 1-aminobenzene-2-methylsulfone are finely powdered, with 30 parts of hydrochloric acid and 30 parts of water, and at <B> 5.0 '</ B > brought into solution. On cooling, the hydrochloride of the base precipitates in fine form.
Man: add 100 parts of ice and allow the calculated amount of sodium nitrite to drip in within about 10 minutes.
Diazotization is finished after approx. 20 minutes. This diazo solution is then poured into .3'1.9 parts of finely precipitated 1-amino-8-ogynaphthalene-3,6 @ -, with stirring
disulfonic acid and stir for about 3 hours at normal temperature. 35 parts of sodium carbonate are then introduced and combined with a soda-alkaline solution of 17.1 parts of 1-aminobenzene-3-methylsulphon, which is prepared in a known manner.
The dye precipitates and is filtered off. It is cleaned by dissolving and curing it. After drying, a dark powder is obtained which dissolves in water with a blue color and dyes wool from an acid bath blue-black.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH190424T | 1936-01-30 | ||
| CH192050T | 1936-01-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH192050A true CH192050A (en) | 1937-07-15 |
Family
ID=25721990
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH192050D CH192050A (en) | 1936-01-30 | 1936-01-30 | Process for the production of a new azo dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH192050A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997027248A3 (en) * | 1996-01-25 | 1997-08-28 | Basf Ag | Acid disazo dyes as well as sulphonamides as their intermediate product |
-
1936
- 1936-01-30 CH CH192050D patent/CH192050A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997027248A3 (en) * | 1996-01-25 | 1997-08-28 | Basf Ag | Acid disazo dyes as well as sulphonamides as their intermediate product |
| US6130320A (en) * | 1996-01-25 | 2000-10-10 | Basf Aktiengesellschaft | Acid disazo dyes as well as sulphonamides as their intermediate product |
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