CH192046A - Process for the production of a new azo dye. - Google Patents
Process for the production of a new azo dye.Info
- Publication number
- CH192046A CH192046A CH192046DA CH192046A CH 192046 A CH192046 A CH 192046A CH 192046D A CH192046D A CH 192046DA CH 192046 A CH192046 A CH 192046A
- Authority
- CH
- Switzerland
- Prior art keywords
- azo dye
- new azo
- production
- dye
- blue
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B33/00—Disazo and polyazo dyes of the types A->K<-B, A->B->K<-C, or the like, prepared by diazotising and coupling
- C09B33/02—Disazo dyes
- C09B33/08—Disazo dyes in which the coupling component is a hydroxy-amino compound
- C09B33/10—Disazo dyes in which the coupling component is a hydroxy-amino compound in which the coupling component is an amino naphthol
Description
Zusatzpatent zum Hauptpatent Nr. 190424. Verfahren zur Herstellung eines neuen Azofarbstoffes. Es wurde gefunden, dass man einen neuen Azofarbstoff erhält, wenn man die Diazover- bindung des 1-Aminobenzol-4-riitro-2-benzyl- sulfons in saurem Medium mit 1-Amino-8- oxynaphthalin-3,6-disulfonsäure vereinigt und diesen so erhältlichen Farbstoff in alkalischem Medium mit Diazobenzol umsetzt.
Der neue Azofarbstoff bildet ein dunkles Pulver, das sich in Wasser mit blauer Farbe löst und Wolle aus saurem Bade in blauschwarzen Tönen von guten Echtheitseigenschaften färbt. <I>Beispiel:</I> 29,2 Teile 1-Aminobenzol-4-nitro-2-benzyl- sulfon werden fein pulverisiert und nach bekannten Methoden in konz. Schwefelsäure mit 7 Teilen Natriumnitrit diazotiert. Diese Diazolösung trägt man in Eiswasser ein und' gibt unter Rühren 31,9 Teile fein gefällte 1-Amino-8-oxynaphthalin-3,6-disulfonsäure zu und rührt ca. 3 Stunden bei gewöhnlicher Temperatur.
Dann trägt man das notwendige Natriumcarbonat ein und vereinigt in alkali schem Medium mit einer Diazolösung aus 9,3 Teilen Anilin, die auf bekannte Weise hergestellt wird. Der Farbstoff fällt aus und wird abfiltriert. Durch Umlösen und Aus salzen wird er gereinigt. Nach dem Trocknen erhält man ein dunkles Pulver, das sich in Wasser mit blauer Farbe löst und Wolle aus saurem Bade blauschwarz färbt.
Additional patent to main patent No. 190424. Process for the production of a new azo dye. It has been found that a new azo dye is obtained if the diazo compound of 1-aminobenzene-4-nitro-2-benzylsulfone is combined with 1-amino-8-oxynaphthalene-3,6-disulfonic acid in an acidic medium and this thus obtainable dye reacts in an alkaline medium with diazobenzene.
The new azo dye forms a dark powder that dissolves in water with a blue color and dyes wool from an acid bath in blue-black shades with good fastness properties. <I> Example: </I> 29.2 parts of 1-aminobenzene-4-nitro-2-benzyl sulfone are finely pulverized and concentrated in conc. Sulfuric acid diazotized with 7 parts of sodium nitrite. This diazo solution is poured into ice water and 31.9 parts of finely precipitated 1-amino-8-oxynaphthalene-3,6-disulfonic acid are added with stirring and the mixture is stirred for about 3 hours at ordinary temperature.
Then you enter the necessary sodium carbonate and combined in an alkaline Shem medium with a diazo solution of 9.3 parts of aniline, which is prepared in a known manner. The dye precipitates and is filtered off. It is cleaned by dissolving and salting out. After drying, a dark powder is obtained which dissolves in water with a blue color and dyes wool from an acid bath blue-black.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH190424T | 1936-01-30 | ||
CH192046T | 1936-01-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH192046A true CH192046A (en) | 1937-07-15 |
Family
ID=25721986
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH192046D CH192046A (en) | 1936-01-30 | 1936-01-30 | Process for the production of a new azo dye. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH192046A (en) |
-
1936
- 1936-01-30 CH CH192046D patent/CH192046A/en unknown
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