CH181718A - Process for the production of a new dye of the anthraquinone series. - Google Patents

Process for the production of a new dye of the anthraquinone series.

Info

Publication number
CH181718A
CH181718A CH181718DA CH181718A CH 181718 A CH181718 A CH 181718A CH 181718D A CH181718D A CH 181718DA CH 181718 A CH181718 A CH 181718A
Authority
CH
Switzerland
Prior art keywords
mol
new dye
anthraquinone series
production
cyanuric chloride
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH181718A publication Critical patent/CH181718A/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16—Amino-anthraquinones
    • C09B1/20—Preparation from starting materials already containing the anthracene nucleus
    • C09B1/36—Dyes with acylated amino groups
    • C09B1/46—Dyes with acylated amino groups the acyl groups being residues of cyanuric acid or an analogous heterocyclic compound
    • C09B1/467—Dyes with acylated amino groups the acyl groups being residues of cyanuric acid or an analogous heterocyclic compound attached to two or more anthraquinone rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Description

  

  <B>Zusatzpatent</B> zum Hauptpatent Nr. 178548.         Verfahren    zur Herstellung eines neuen Farbstoffes der     Anthrachinonreihe.       Es wurde gefunden, dass man einen neuen  Farbstoff der     Anthrachinonreihe    erhält,  wenn man auf 1     Mol        Cvanurchlorid    1     Mol     1 .     4-Diaminoanthrachinon-2    .

       6-disulf        onsäure,     1     Mol        2-Amino-5-oxynaphthalin-7-sulfon-          säure    und 1     Mol    Anilin derart einwirken       lässt,    dass je ein Halogenatom des     Cyanur-          chlorides    durch je 1     Mol    der drei weiteren  Ausgangsstoffe ausgetauscht wird.  



  Der neue Farbstoff bildet ein dunkles  Pulver, das sich in Wasser mit     violetter     Farbe löst, und     Viskosekunstseide,    Wolle  oder Seide in reinen violetten Tönen von vor  züglicher Lichtechtheit färbt.  



  <I>Beispiel:</I>  18,5     'feile        Cyanurchlorid    werden in 800  Teilen Wasser fein suspendiert. Zu dieser  Suspension giesst man eine neutrale Lösung  von 39,8 Teilen 1     .4-Diaminoanthrachinon-          2.6-disulfonsäure    in 1200 Teilen Wasser.

    Man rührt bei 20   3 bis 4 Stunden und giesst    allmählich 50 Teile     10%ige        Natriumkar-          bonatlösung    dazu, so dass die Reaktion immer  neutral bleibt.     Dann    gibt man eine neutrale  Lösung von 23,9 Teilen     2-Amino-5-oxynaph-          thalin-7-sulfonsäure    und 14 Teilen kristalli  siertem     Natriumacetat    in 1000 Teilen Was  ser dazu. Man erhöht nun die Temperatur  auf 40 bis 45   und rührt 24 Stunden. Dann  wird mit     Natriumkarbonatlösung    genau neu  tralisiert und<B>18,6</B> Teile Anilin zugegeben.

    Man erhitzt das Ganze während 2 Stunden  auf 90  , macht durch Zugabe von Natrium  karbonat alkalisch und salzt den     gebildeten     Farbstoff aus.



  <B> Additional patent </B> to main patent no. 178548. Process for the production of a new dye from the anthraquinone series. It has been found that a new dye of the anthraquinone series is obtained if 1 mol of 1 mol of vanuric chloride is added to 1 mol of cvanuric chloride. 4-diaminoanthraquinone-2.

       6-disulphonic acid, 1 mol of 2-amino-5-oxynaphthalene-7-sulphonic acid and 1 mol of aniline can act in such a way that each halogen atom of the cyanuric chloride is replaced by 1 mol of each of the three other starting materials.



  The new dye forms a dark powder that dissolves in water with a violet color and dyes viscose rayon, wool or silk in pure violet tones that are extremely lightfast.



  <I> Example: </I> 18.5 'file cyanuric chloride are finely suspended in 800 parts of water. A neutral solution of 39.8 parts of 1,4-diaminoanthraquinone-2,6-disulfonic acid in 1200 parts of water is poured into this suspension.

    The mixture is stirred at 20 for 3 to 4 hours and 50 parts of 10% sodium carbonate solution are gradually poured in so that the reaction always remains neutral. Then you add a neutral solution of 23.9 parts of 2-amino-5-oxynaphthalene-7-sulfonic acid and 14 parts of crystallized sodium acetate in 1000 parts of water. The temperature is now increased to 40 to 45 and the mixture is stirred for 24 hours. Then it is exactly neutralized with sodium carbonate solution and <B> 18.6 </B> parts of aniline are added.

    The whole is heated to 90 for 2 hours, made alkaline by adding sodium carbonate and salted out the dye formed.

Claims (1)

PATENTANSPRUCH: Verfahren zur Herstellung eines neuen Farbstoffes der Anthrachinonreihe, dadurch gekennzeichnet, dass man auf 1 iNIol Cyanur- chlorid 1 Mol 1.4-Diaminoanthrachinon- 2.6-disulfonsäure, 1 Hol 2-Amino-5-oxy- naphthalin-7-sulfonsäure und 1 Mol Anilin derart einwirken lässt, PATENT CLAIM: Process for the preparation of a new dye of the anthraquinone series, characterized in that 1 mol of 1,4-diaminoanthraquinone-2,6-disulfonic acid, 1 mol of 2-amino-5-oxynaphthalene-7-sulfonic acid and 1 mol of cyanuric chloride are used for 1 mol Lets aniline take effect dass je ein Halogen- atom des Cy anurchlorides durch je 1 Mol der drei weiteren Ausgangsstoffe ausgetauscht wird. Der neue Farbstoff bildet ein dunkles Pulver, das sich in Wasser mit violetter Farbe löst, und Viskosekunstseide, Wolle oder Seide in reinen violetten Tönen von vor züglicher Lichtechtheit färbt. that one halogen atom of the cyanuric chloride is exchanged for one mole of each of the three other starting materials. The new dye forms a dark powder that dissolves in water with a violet color and dyes viscose rayon, wool or silk in pure violet tones that are extremely lightfast.
CH181718D 1934-11-13 1934-11-13 Process for the production of a new dye of the anthraquinone series. CH181718A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CH181718T 1934-11-13
CH178548T 1938-02-19

Publications (1)

Publication Number Publication Date
CH181718A true CH181718A (en) 1935-12-31

Family

ID=25720172

Family Applications (1)

Application Number Title Priority Date Filing Date
CH181718D CH181718A (en) 1934-11-13 1934-11-13 Process for the production of a new dye of the anthraquinone series.

Country Status (1)

Country Link
CH (1) CH181718A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1041912B (en) * 1954-11-29 1958-10-30 Ici Ltd Process for dyeing or printing cellulosic textile fabrics
DE1183187B (en) * 1960-11-14 1964-12-10 Ciba Geigy Process for the preparation of dyes of the anthraquinone series

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1041912B (en) * 1954-11-29 1958-10-30 Ici Ltd Process for dyeing or printing cellulosic textile fabrics
DE1183187B (en) * 1960-11-14 1964-12-10 Ciba Geigy Process for the preparation of dyes of the anthraquinone series

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