CH178548A - Process for the production of a new dye of the anthraquinone series. - Google Patents
Process for the production of a new dye of the anthraquinone series.Info
- Publication number
- CH178548A CH178548A CH178548DA CH178548A CH 178548 A CH178548 A CH 178548A CH 178548D A CH178548D A CH 178548DA CH 178548 A CH178548 A CH 178548A
- Authority
- CH
- Switzerland
- Prior art keywords
- new dye
- mole
- aniline
- production
- blue
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B1/00—Dyes with anthracene nucleus not condensed with any other ring
- C09B1/16—Amino-anthraquinones
- C09B1/20—Preparation from starting materials already containing the anthracene nucleus
- C09B1/36—Dyes with acylated amino groups
- C09B1/46—Dyes with acylated amino groups the acyl groups being residues of cyanuric acid or an analogous heterocyclic compound
- C09B1/467—Dyes with acylated amino groups the acyl groups being residues of cyanuric acid or an analogous heterocyclic compound attached to two or more anthraquinone rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
Verfahren zur Herstellung eines neuen Farbstoffes der Anthraehinonreihe. Es wurde gefunden, dass man einen neuen Farbstoff der Anthrachinonreihe erhält, wenn man auf 1 Mol Cyanurchlorid 2 Mol 1 . 4-Diaminoanthrachinon-2 .
6-disulf onsäure und 1 Mol Anilin derart einwirken lässt, dass je zwei Halogenatome des Cyanurchlorids durch je 1 Mol des Diaminoanthrachinon- derivates und das dritte Halogenatom durch 1 Mol Anilin ausgetauscht werden.
Der neue Farbstoff bildet ein dunkles Pulver, das sich in Wasser mit blauvioletter Farbe löst, und Viskosekunstseide, Wolle oder Seide in blaustichigvioletten Tönen von vorzüglicher Lichtechtheit färbt. <I>Beispiel:</I> 18,5 Teile Cyanurchlorid werden in 800 Teilen Wasser fein suspendiert. Zu dieser Suspension giesst man eine neutrale Lösung von 39,8 Teilen 1 .4-Diaminoanthrachinon- 2.6-disulfonsäure in 1200 Teilen Wasser.
Man rührt bei 20 3 bis 4 Stunden und giesst allmählich 50 Teile 10%ige Natrium karbonatlösung dazu, so dass die Reaktion immer neutral bleibt. Dann gibt man eine neutrale Lösung von weiteren 39,8 Teilen 1 . 4-Diaminoanthrachinon-2. 6-disulf onsäure und 14 Teilen kristallisiertem Natriumazetat in 1000 Teilen Wasser dazu. Man erhöht nun die Temperatur auf 40 bis 45 und rührt 24 Stunden. Dann wird mit Natrium karbonatlösung genau neutralisiert und 18,6 Teile Anilin zugegeben.
Man erhitzt das Ganze während 2 Stunden auf<B>90',</B> macht durch Zugabe von Natriumkarbonat alkalisch und salzt den gebildeten Farbstoff aus.
Process for the production of a new dye of the anthraehinone series. It has been found that a new dye of the anthraquinone series is obtained if 2 moles of 1 per mole of cyanuric chloride are used. 4-diaminoanthraquinone-2.
6-disulphonic acid and 1 mol of aniline can act in such a way that every two halogen atoms of the cyanuric chloride are replaced by 1 mol of the diaminoanthraquinone derivative and the third halogen atom is replaced by 1 mol of aniline.
The new dye forms a dark powder that dissolves in water with a blue-violet color and dyes viscose artificial silk, wool or silk in blue-tinged violet shades of excellent lightfastness. <I> Example: </I> 18.5 parts of cyanuric chloride are finely suspended in 800 parts of water. A neutral solution of 39.8 parts of 1,4-diaminoanthraquinone-2,6-disulfonic acid in 1200 parts of water is poured into this suspension.
The mixture is stirred at 20 for 3 to 4 hours and gradually poured in 50 parts of 10% sodium carbonate solution so that the reaction always remains neutral. Then a neutral solution of a further 39.8 parts of 1 is added. 4-diaminoanthraquinone-2. 6-disulfonic acid and 14 parts of crystallized sodium acetate in 1000 parts of water. The temperature is now increased to 40 to 45 and the mixture is stirred for 24 hours. Then it is exactly neutralized with sodium carbonate solution and 18.6 parts of aniline are added.
The whole is heated to <B> 90 'for 2 hours, </B> making it alkaline by adding sodium carbonate and salting out the dye formed.
Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH178548T | 1938-02-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH178548A true CH178548A (en) | 1935-07-31 |
Family
ID=4428588
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH178548D CH178548A (en) | 1938-02-19 | 1934-11-13 | Process for the production of a new dye of the anthraquinone series. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH178548A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1041912B (en) * | 1954-11-29 | 1958-10-30 | Ici Ltd | Process for dyeing or printing cellulosic textile fabrics |
-
1934
- 1934-11-13 CH CH178548D patent/CH178548A/en unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1041912B (en) * | 1954-11-29 | 1958-10-30 | Ici Ltd | Process for dyeing or printing cellulosic textile fabrics |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DE665430C (en) | Process for the preparation of dyes of the anthraquinone series | |
CH178548A (en) | Process for the production of a new dye of the anthraquinone series. | |
CH181719A (en) | Process for the production of a new dye of the anthraquinone series. | |
CH181718A (en) | Process for the production of a new dye of the anthraquinone series. | |
CH181721A (en) | Process for the production of a new dye of the anthraquinone series. | |
CH181720A (en) | Process for the production of a new dye of the anthraquinone series. | |
CH183118A (en) | Process for the production of a new dye of the anthraquinone series. | |
DE915128C (en) | Process for the production of unsymmetrical xanthenium compounds | |
DE695032C (en) | Process for the preparation of dyes of the anthraquinone series | |
CH183114A (en) | Process for the preparation of an azo dye. | |
CH209262A (en) | Process for the production of a new dye of the anthraquinone series. | |
AT149660B (en) | Process for the preparation of acidic triphenylmethane dyes. | |
CH183115A (en) | Process for the preparation of an azo dye. | |
CH209263A (en) | Process for the production of a new dye of the anthraquinone series. | |
CH203043A (en) | Process for the production of a new dye of the anthraquinone series. | |
CH183866A (en) | Process for the preparation of an azo dye. | |
CH183117A (en) | Process for the preparation of an azo dye. | |
CH193251A (en) | Process for the production of an acidic wool dye. | |
CH199369A (en) | Process for the preparation of an azo dye. | |
CH233845A (en) | Process for the preparation of a polyazo dye. | |
CH282631A (en) | Process for the preparation of an indolyl-diphenylmethane dye. | |
CH186171A (en) | Process for the production of a vat dye. | |
CH193252A (en) | Process for the production of an acidic wool dye. | |
CH199465A (en) | Process for the preparation of a dye of the anthraquinone series. | |
CH230423A (en) | Process for the production of an acidic wool dye. |