CH178548A - Process for the production of a new dye of the anthraquinone series. - Google Patents

Process for the production of a new dye of the anthraquinone series.

Info

Publication number
CH178548A
CH178548A CH178548DA CH178548A CH 178548 A CH178548 A CH 178548A CH 178548D A CH178548D A CH 178548DA CH 178548 A CH178548 A CH 178548A
Authority
CH
Switzerland
Prior art keywords
new dye
mole
aniline
production
blue
Prior art date
Application number
Other languages
German (de)
Inventor
Gesellschaft Fuer Chemis Basel
Original Assignee
Chem Ind Basel
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chem Ind Basel filed Critical Chem Ind Basel
Publication of CH178548A publication Critical patent/CH178548A/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B1/00Dyes with anthracene nucleus not condensed with any other ring
    • C09B1/16Amino-anthraquinones
    • C09B1/20Preparation from starting materials already containing the anthracene nucleus
    • C09B1/36Dyes with acylated amino groups
    • C09B1/46Dyes with acylated amino groups the acyl groups being residues of cyanuric acid or an analogous heterocyclic compound
    • C09B1/467Dyes with acylated amino groups the acyl groups being residues of cyanuric acid or an analogous heterocyclic compound attached to two or more anthraquinone rings

Description

  

  Verfahren zur Herstellung eines neuen Farbstoffes der     Anthraehinonreihe.       Es wurde gefunden, dass man einen neuen  Farbstoff der     Anthrachinonreihe    erhält,  wenn man auf 1     Mol        Cyanurchlorid    2     Mol     1 .     4-Diaminoanthrachinon-2    .

       6-disulf        onsäure     und 1     Mol    Anilin derart einwirken lässt, dass  je zwei Halogenatome des     Cyanurchlorids     durch je 1     Mol    des     Diaminoanthrachinon-          derivates    und das dritte Halogenatom durch  1     Mol    Anilin ausgetauscht werden.  



  Der neue Farbstoff bildet ein dunkles  Pulver, das sich in Wasser mit blauvioletter  Farbe löst, und     Viskosekunstseide,    Wolle  oder Seide in     blaustichigvioletten    Tönen von  vorzüglicher Lichtechtheit färbt.    <I>Beispiel:</I>    18,5 Teile     Cyanurchlorid    werden in 800  Teilen Wasser fein suspendiert. Zu dieser  Suspension giesst man     eine    neutrale Lösung  von 39,8 Teilen 1     .4-Diaminoanthrachinon-          2.6-disulfonsäure    in 1200 Teilen Wasser.

    Man rührt bei 20   3 bis 4 Stunden und    giesst allmählich 50 Teile 10%ige Natrium  karbonatlösung dazu, so dass die     Reaktion     immer neutral bleibt.     Dann    gibt man eine  neutrale Lösung von weiteren 39,8 Teilen  1 .     4-Diaminoanthrachinon-2.        6-disulf        onsäure     und 14 Teilen kristallisiertem     Natriumazetat     in 1000 Teilen Wasser dazu. Man erhöht  nun die Temperatur auf 40 bis 45       und     rührt 24 Stunden. Dann wird mit Natrium  karbonatlösung genau neutralisiert und 18,6  Teile Anilin zugegeben.

   Man erhitzt das  Ganze während 2 Stunden auf<B>90',</B> macht  durch Zugabe von Natriumkarbonat alkalisch  und salzt den gebildeten Farbstoff aus.



  Process for the production of a new dye of the anthraehinone series. It has been found that a new dye of the anthraquinone series is obtained if 2 moles of 1 per mole of cyanuric chloride are used. 4-diaminoanthraquinone-2.

       6-disulphonic acid and 1 mol of aniline can act in such a way that every two halogen atoms of the cyanuric chloride are replaced by 1 mol of the diaminoanthraquinone derivative and the third halogen atom is replaced by 1 mol of aniline.



  The new dye forms a dark powder that dissolves in water with a blue-violet color and dyes viscose artificial silk, wool or silk in blue-tinged violet shades of excellent lightfastness. <I> Example: </I> 18.5 parts of cyanuric chloride are finely suspended in 800 parts of water. A neutral solution of 39.8 parts of 1,4-diaminoanthraquinone-2,6-disulfonic acid in 1200 parts of water is poured into this suspension.

    The mixture is stirred at 20 for 3 to 4 hours and gradually poured in 50 parts of 10% sodium carbonate solution so that the reaction always remains neutral. Then a neutral solution of a further 39.8 parts of 1 is added. 4-diaminoanthraquinone-2. 6-disulfonic acid and 14 parts of crystallized sodium acetate in 1000 parts of water. The temperature is now increased to 40 to 45 and the mixture is stirred for 24 hours. Then it is exactly neutralized with sodium carbonate solution and 18.6 parts of aniline are added.

   The whole is heated to <B> 90 'for 2 hours, </B> making it alkaline by adding sodium carbonate and salting out the dye formed.

 

Claims (1)

PATENTAN SPRÜCII Verfahren zur Herstellung eines neuen Farbstoffes der Anthrachinonreihe, dadurch gekennzeichnet, dass man auf 1 Mol Cyanur- chlorid 2 Mol 1. PATENTAN SPRÜCII Process for the preparation of a new dye of the anthraquinone series, characterized in that 1 mole of cyanuric chloride is used for 2 moles of 1. 4-Diaminoanthrachinon-2. 6- disulfonsäure und 1 Mol Anilin derart ein wirken lässt, dass je zwei Halogenatome des Cyanurchlorids durch je 1 Mol des Diamino- anthrachinonderivates und das dritte Halo genatom durch 1 112o1 Anilin ausgetauscht werden. Der neue Farbstoff bildet ein dunkles Pulver, das sich in Wasser mit blauviolet- ter Farbe löst, und Viskosekunstseide, Wolle oder Seide in blaustichigvioletten Tönen von vorzüglicher Lichtechtheit färbt. 4-diaminoanthraquinone-2. 6-disulfonic acid and 1 mole of aniline act in such a way that every two halogen atoms of the cyanuric chloride are replaced by 1 mole each of the diamino anthraquinone derivative and the third halogen atom is replaced by 1,121 o1 aniline. The new dye forms a dark powder which dissolves in water with a blue-violet color and dyes viscose artificial silk, wool or silk in blue-tinged violet shades of excellent lightfastness.
CH178548D 1938-02-19 1934-11-13 Process for the production of a new dye of the anthraquinone series. CH178548A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH178548T 1938-02-19

Publications (1)

Publication Number Publication Date
CH178548A true CH178548A (en) 1935-07-31

Family

ID=4428588

Family Applications (1)

Application Number Title Priority Date Filing Date
CH178548D CH178548A (en) 1938-02-19 1934-11-13 Process for the production of a new dye of the anthraquinone series.

Country Status (1)

Country Link
CH (1) CH178548A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1041912B (en) * 1954-11-29 1958-10-30 Ici Ltd Process for dyeing or printing cellulosic textile fabrics

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1041912B (en) * 1954-11-29 1958-10-30 Ici Ltd Process for dyeing or printing cellulosic textile fabrics

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