CH175243A - Process for the production of a new metal-containing dye. - Google Patents
Process for the production of a new metal-containing dye.Info
- Publication number
- CH175243A CH175243A CH175243DA CH175243A CH 175243 A CH175243 A CH 175243A CH 175243D A CH175243D A CH 175243DA CH 175243 A CH175243 A CH 175243A
- Authority
- CH
- Switzerland
- Prior art keywords
- new metal
- containing dye
- production
- dye
- nitro
- Prior art date
Links
- 239000002184 metal Substances 0.000 title claims description 6
- 229910052751 metal Inorganic materials 0.000 title claims description 6
- 239000000975 dye Substances 0.000 claims description 11
- DOPJTDJKZNWLRB-UHFFFAOYSA-N 2-Amino-5-nitrophenol Chemical compound NC1=CC=C([N+]([O-])=O)C=C1O DOPJTDJKZNWLRB-UHFFFAOYSA-N 0.000 claims description 3
- 239000005749 Copper compound Substances 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000001880 copper compounds Chemical class 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 2
- 229920000297 Rayon Polymers 0.000 claims description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims description 2
- 239000003638 chemical reducing agent Substances 0.000 claims description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/24—Disazo or polyazo compounds
- C09B45/28—Disazo or polyazo compounds containing copper
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Zusatzpatent zum Hauptpatent Nr. 172368. Verfahren zur Herstellung eines neuen metallhaltigen Farbstoffes. Es wurde gefunden, .dass man einen neuen metallhaltigen Farbstoff erhält, wenn mau die Kupferverbindung des Farbstoffes aus diazotiertem 5-Nitro-2-aminophenol und 2- Oxynaphthalin-3. 6-disulfosäure mit solchen Reduktionsmitteln in alkalischem Medium be handelt, die die Nitrogruppe in die Azo- gruppe unter Verkettung zweier Moleküle überführen.
Der neue metallhaltige Farbstoff bildet ein dunkles Pulver, das sich in Wasser mit neinblauer Farbe löst und Baumwolle und Viskose in echten neinblauen Tönen anfärbt. <I>Beispiel:</I> Eine wässerige Lösung, die 10 Teile der Kupferverbindung des Farbstoffes .aus diazo- tiertem 5-Nitr o-2-aminophenol und 2-Oxy- naphthalin - 3. 6 - disulfosäure enthält, wird mit einer Lösung aus 8 Teilen Zinnchlonür in überschüssiger Natriumhydroxydlösung bei 60 bis<B>80'</B> versetzt. Die ursprünglich violette Farbe der Lösung schlägt nach Blau um.
Durch Zugabe von etwas Natriumchlorid wird der neue Farbstoff als blauer Nieder schlag abgeschieden. Dieser wird filtriert und getrocknet.
Additional patent to main patent No. 172368. Process for the production of a new metal-containing dye. It has been found that a new metal-containing dye is obtained if the copper compound of the dye is made from diazotized 5-nitro-2-aminophenol and 2-oxynaphthalene-3. 6-disulfonic acid is treated in an alkaline medium with reducing agents which convert the nitro group into the azo group by linking two molecules.
The new metal-containing dye forms a dark powder that dissolves in water with a no-blue color and dyes cotton and viscose in real no-blue tones. <I> Example: </I> An aqueous solution that contains 10 parts of the copper compound of the dye. From diazo-tated 5-nitr o-2-aminophenol and 2-oxynaphthalene - 3. 6 - disulfonic acid is mixed with a Solution of 8 parts of tin chloride in excess sodium hydroxide solution at 60 to <B> 80 '</B>. The original purple color of the solution changes to blue.
By adding a little sodium chloride, the new dye is deposited as a blue precipitate. This is filtered and dried.
Claims (1)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH172368T | 1933-05-25 | ||
| CH175243T | 1933-05-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH175243A true CH175243A (en) | 1935-02-15 |
Family
ID=25719203
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH175243D CH175243A (en) | 1933-05-25 | 1933-05-25 | Process for the production of a new metal-containing dye. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH175243A (en) |
-
1933
- 1933-05-25 CH CH175243D patent/CH175243A/en unknown
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