CH167391A - Process for the preparation of an azo dye. - Google Patents
Process for the preparation of an azo dye.Info
- Publication number
- CH167391A CH167391A CH167391DA CH167391A CH 167391 A CH167391 A CH 167391A CH 167391D A CH167391D A CH 167391DA CH 167391 A CH167391 A CH 167391A
- Authority
- CH
- Switzerland
- Prior art keywords
- preparation
- azo dye
- sulfonic acid
- dye
- oxynaphthyl
- Prior art date
Links
Landscapes
- Coloring (AREA)
Description
Verfahren zur Darstellung eines AzofarbstofFes. Gemäss dem im Hauptpatent beschriebenen Verfahren wird ein Leder in saurem Bade anfärbender Azofarbstoff erhalten, wenn man 4'- N itrophenyl - b - oxynaphthyl-1. 2-triazol-7- sulfosäure mit diazotierter 4-Aminoazobenzol- 4'-sulfosäure in alkalischem Bade kuppelt.
Wie nun weiter gefunden wurde, erhält man einen Farbstoff mit ganz ähnlichen Eigenschaften, wenn man als Azokomponente die 4'-Nitropherryl-8-oxynaphthyl-1.2-triazol- 6-sulfosäure wählt.
<I>Beispiel:</I> 27,7 Teile 4-Aminoazobenzol-4'-sulfosäure werden in bekannter Weise diazotiert und mit einer kalten sodaalkalisch gehaltenen Lösung von 40,8 Teilen 4'-nitrophenyl-8- oxynaphthyl-1.2-triazol-6-sulfosarrr,ern Na trium der Formel
EMI0001.0021
vereinigt. Nach beendeter Kupplung wird mit Kochsalz abgeschiedeu und der Farbstoff in üblicher Weise aufgearbeitet. Er färbt Chromleder und vegetabilisch gegerbtes Leder in schönen rot braunen Tönen von guter Lichtechtheit an.
Process for the preparation of an azo dye. According to the process described in the main patent, an azo dye which dyes leather in an acid bath is obtained if 4'-nitrophenyl-b-oxynaphthyl-1. 2-triazole-7-sulfonic acid couples with diazotized 4-aminoazobenzene-4'-sulfonic acid in an alkaline bath.
As has now been further found, a dye with very similar properties is obtained if 4'-nitropherryl-8-oxynaphthyl-1,2-triazole-6-sulfonic acid is chosen as the azo component.
<I> Example: </I> 27.7 parts of 4-aminoazobenzene-4'-sulfonic acid are diazotized in a known manner and treated with a cold solution of 40.8 parts of 4'-nitrophenyl-8-oxynaphthyl-1,2-triazole which is kept alkaline with soda -6-sulfosarrr, ern sodium of the formula
EMI0001.0021
united. When the coupling is complete, it is separated off with common salt and the dye is worked up in the usual way. It stains chrome leather and vegetable-tanned leather in beautiful red-brown shades of good lightfastness.
Claims (1)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE167391X | 1932-02-15 | ||
CH164547T | 1933-10-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH167391A true CH167391A (en) | 1934-02-15 |
Family
ID=25717973
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH167391D CH167391A (en) | 1932-02-15 | 1932-11-04 | Process for the preparation of an azo dye. |
Country Status (1)
Country | Link |
---|---|
CH (1) | CH167391A (en) |
-
1932
- 1932-11-04 CH CH167391D patent/CH167391A/en unknown
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