CH141308A - Process for the preparation of a sulfur-containing compound. - Google Patents
Process for the preparation of a sulfur-containing compound.Info
- Publication number
- CH141308A CH141308A CH141308DA CH141308A CH 141308 A CH141308 A CH 141308A CH 141308D A CH141308D A CH 141308DA CH 141308 A CH141308 A CH 141308A
- Authority
- CH
- Switzerland
- Prior art keywords
- sulfur
- preparation
- containing compound
- acid
- ethylhexahydrophenyldithiocarbamic
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 3
- 150000001875 compounds Chemical class 0.000 title claims description 3
- 229910052717 sulfur Inorganic materials 0.000 title claims description 3
- 239000011593 sulfur Substances 0.000 title claims description 3
- 159000000009 barium salts Chemical class 0.000 claims description 4
- LAYHGEVCXKHWPT-UHFFFAOYSA-N cyclohexyl(ethyl)carbamodithioic acid Chemical compound CCN(C(S)=S)C1CCCCC1 LAYHGEVCXKHWPT-UHFFFAOYSA-N 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 3
- 238000004073 vulcanization Methods 0.000 claims 1
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZUYFLSARRQBQPE-UHFFFAOYSA-M [Cl-].[Ba+] Chemical compound [Cl-].[Ba+] ZUYFLSARRQBQPE-UHFFFAOYSA-M 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- AGVKXDPPPSLISR-UHFFFAOYSA-N n-ethylcyclohexanamine Chemical compound CCNC1CCCCC1 AGVKXDPPPSLISR-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Verfahren zur Darstellung einer schwefelhaltigen Verbindung. Durch das Hauptpatent Nr. 132304 in Verbindung mit seinem Zusatzpatent ist ein Verfahren bekannt geworden, nach dem man das Natriumsalz der Äthylhexahydrophenyl- dithiokarbaminsäure erhalten kann.
Es wurde nun gefunden, dass man das Bariumsalz der Äthylhexahydrophenyldithio- karbaminsäure erhaltet) kann, wenn man das Natriumsalz der Äthylhexahydrophettyldithio- karbaminsäure mit Bariumsalzen umsetzt.
<I>Beispiel:</I> Zu der aus 127 Teilen Hexahydroäthyl- anilin, 500 Teilen Wasser und 85 Teilen 48 % iger Natronlange durch Einlaufenlassen von 76 Teilen Schwefelkohlenstoff bei Tem peraturen unter<B>100</B> C erhältlichen Lösung von äthylhexahydrophenyldithiokarbatninsau- rern Natrium gibt man eine Lösung von 123 Teilen Chlorbarium in 400 Teilen Wasser.
Das Bariumsalz der Äthylhexahydrophenyl- dithiokarbaminsäure scheidet sich in Form von weissen Blättchen aus. Die Löslichkeit in Wasser von<B>50-600</B> beträgt etwa 50/0.
Process for the preparation of a sulfur-containing compound. Through the main patent no. 132304 in connection with its additional patent, a process has become known by which the sodium salt of ethylhexahydrophenyldithiocarbamic acid can be obtained.
It has now been found that the barium salt of ethylhexahydrophenyldithiocarbamic acid can be obtained if the sodium salt of ethylhexahydrophettyldithiocarbamic acid is reacted with barium salts.
<I> Example: </I> To the solution of 127 parts of hexahydroethyl aniline, 500 parts of water and 85 parts of 48% strength sodium bicarbonate by running in 76 parts of carbon disulfide at temperatures below <B> 100 </B> C A solution of 123 parts of chlorobarium in 400 parts of water is added to sodium ethylhexahydrophenyldithiokarbatninsaur-.
The barium salt of ethylhexahydrophenyldithiocarbamic acid separates out in the form of white flakes. The solubility in water of <B> 50-600 </B> is about 50/0.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CH141308T | 1928-06-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH141308A true CH141308A (en) | 1930-07-31 |
Family
ID=4398252
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH141308D CH141308A (en) | 1928-06-29 | 1928-06-29 | Process for the preparation of a sulfur-containing compound. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH141308A (en) |
-
1928
- 1928-06-29 CH CH141308D patent/CH141308A/en unknown
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