CH106933A - Process for the preparation of an azo acid dye. - Google Patents

Process for the preparation of an azo acid dye.

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Publication number
CH106933A
CH106933A CH106933DA CH106933A CH 106933 A CH106933 A CH 106933A CH 106933D A CH106933D A CH 106933DA CH 106933 A CH106933 A CH 106933A
Authority
CH
Switzerland
Prior art keywords
preparation
acid dye
azo acid
dye
azo
Prior art date
Application number
Other languages
German (de)
Inventor
Farbwerke Vorm Meiste Bruening
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst Ag filed Critical Hoechst Ag
Publication of CH106933A publication Critical patent/CH106933A/en

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Description

  

  Verfahren zur Herstellung eines     Azosäurefarbstoffes.       In einer     deutschen    Patentschrift wurden       Fasen    beschrieben, welche durch Einwirkung  von     aliphatischen        Ketonen    auf die Salze der       Anilinbasen    entstehen, und als deren An  fangsglied das aus Aceton und salzsaurem  Anilin erhältliche     Di.aminodiphenyldimethyl-          methan    anzusprechen ist.  



  Es wurde nunmehr gefunden,     da.ss    sich die       Tetrazoverbindung    des     p-p'=diamino-;diphenyl-          dimethylmethäns    in alkalischer Lösung mit  dem     1-(2'-Chlor-5'-siilfo)-phenyl-3-methyl-5-          pyrazolon    zu einem Farbstoff verbindet,     wel-          eher    Wolle im sauren Bade vorzüglich  wasch- und     walkecht    und sehr gut lichtecht       grünstichig    gelb färbt.

           Beispiel:     22,6 kg     p-p'-Diamino-diphenyl-dimethyl-          methan        (Fp        132')    werden     in        bekannter     Weise     tetrazatiert    und in     sodo-    oder bicar-         bonat-alkalischer    Lösung     gekuppelt.mit    64 kg  des     Natriumsalzes    des     1-(2'-Chlor-5'-sulfo)-          phenyl-3-:

  methyl-5-pyra.zolons.    Der Farbstoff  wird in bekannter Weise     isoliert    und     liefert     auf Wolle     grünstichig    gelbe Färbungen von  vorzüglicher Wasch-, Walk- und Licht  echtheit.



  Process for the preparation of an azo acid dye. In a German patent, phases were described which are formed by the action of aliphatic ketones on the salts of the aniline bases, and the di.aminodiphenyldimethyl methane obtainable from acetone and hydrochloric aniline is to be addressed as the starting element.



  It has now been found that the tetrazo compound of p-p '= diamino-; diphenyl-dimethylmethane in alkaline solution with 1- (2'-chloro-5'-silfo) -phenyl-3-methyl-5- Pyrazolone combines to form a dye which dyes wool in an acidic bath with an excellent wash and squelch fastness and very good lightfast greenish yellow.

           Example: 22.6 kg of p-p'-diamino-diphenyl-dimethyl-methane (mp 132 ') are tetrazated in a known manner and coupled in a soda or bicarbonate-alkaline solution. With 64 kg of the sodium salt of 1- ( 2'-chloro-5'-sulfo) - phenyl-3-:

  methyl-5-pyra.zolons. The dye is isolated in a known manner and provides greenish-tinged yellow dyeings with excellent wash, milled and light fastness on wool.

 

Claims (1)

PATENTANSPRUCH'. Verfahren zur Herstellung eines Azo- säurefarbstaffes, dadurch gekennzeichnet, da.ss man die Tetrazoverbindung des p-p'-Di.amino- diphenyl-dimethylmethans mit dem 1-(2' Chlor-5'-sulfo)-phenyl-3-methyl-5-pyrazolon kuppelt. Der Farbstoff liefert :auf Wolle grünstichiggelbe Färbungen von vorzüglicher Nasch-, Walk- und Lichtechtheit. PATENT CLAIM '. Process for the preparation of an azo acid dye, characterized in that the tetrazo compound of p-p'-di.amino-diphenyl-dimethylmethane is used with 1- (2 'chloro-5'-sulfo) -phenyl-3-methyl -5-pyrazolone couples. The dye provides: greenish-yellow dyeings on wool with excellent fastness to snacking, milled and lightfast.
CH106933D 1922-11-10 1923-10-20 Process for the preparation of an azo acid dye. CH106933A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE106933X 1922-11-10
CH105236T 1923-10-20

Publications (1)

Publication Number Publication Date
CH106933A true CH106933A (en) 1924-09-16

Family

ID=25706831

Family Applications (1)

Application Number Title Priority Date Filing Date
CH106933D CH106933A (en) 1922-11-10 1923-10-20 Process for the preparation of an azo acid dye.

Country Status (1)

Country Link
CH (1) CH106933A (en)

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