CA992093A - Process for producing n-phosphonomethyl glycine - Google Patents

Process for producing n-phosphonomethyl glycine

Info

Publication number
CA992093A
CA992093A CA172,933A CA172933A CA992093A CA 992093 A CA992093 A CA 992093A CA 172933 A CA172933 A CA 172933A CA 992093 A CA992093 A CA 992093A
Authority
CA
Canada
Prior art keywords
producing
phosphonomethyl glycine
phosphonomethyl
glycine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA172,933A
Other languages
English (en)
Other versions
CA172933S (en
Inventor
John E. Franz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/258,281 external-priority patent/US3954848A/en
Application filed by Monsanto Co filed Critical Monsanto Co
Application granted granted Critical
Publication of CA992093A publication Critical patent/CA992093A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Saccharide Compounds (AREA)
CA172,933A 1972-05-31 1973-05-30 Process for producing n-phosphonomethyl glycine Expired CA992093A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US05/258,281 US3954848A (en) 1972-05-31 1972-05-31 Process for producing N-phosphonomethyl glycine
US05/333,414 US3950402A (en) 1972-05-31 1973-02-16 Process for producing N-phosphonomethyl glycine

Publications (1)

Publication Number Publication Date
CA992093A true CA992093A (en) 1976-06-29

Family

ID=26946544

Family Applications (1)

Application Number Title Priority Date Filing Date
CA172,933A Expired CA992093A (en) 1972-05-31 1973-05-30 Process for producing n-phosphonomethyl glycine

Country Status (25)

Country Link
US (1) US3950402A (sl)
JP (1) JPS5111093B2 (sl)
BE (1) BE800238A (sl)
BG (1) BG21212A3 (sl)
CA (1) CA992093A (sl)
CH (1) CH574968A5 (sl)
CS (1) CS177133B2 (sl)
DD (1) DD104303A5 (sl)
DE (1) DE2327680C3 (sl)
DK (1) DK138951B (sl)
EG (1) EG11140A (sl)
ES (2) ES415335A1 (sl)
FR (2) FR2186477B1 (sl)
GB (1) GB1432043A (sl)
HU (1) HU167343B (sl)
IE (1) IE37730B1 (sl)
IL (1) IL42393A (sl)
IT (1) IT988869B (sl)
NL (1) NL162656C (sl)
NO (2) NO140556C (sl)
PL (1) PL107856B1 (sl)
RO (2) RO62901A (sl)
SE (2) SE404019B (sl)
SU (1) SU623523A3 (sl)
YU (2) YU36977B (sl)

Families Citing this family (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4072706A (en) * 1976-01-02 1978-02-07 Monsanto Company Oxidation of phosphonomethylamines
MX4703E (es) * 1976-12-20 1982-08-04 Monsanto Co Procedimiento mejorado para la preparacion de mono y disales de n-fosfonometilglicina
US4454043A (en) * 1980-11-17 1984-06-12 Monsanto Company Column switching procedure
IL66824A0 (en) * 1982-06-25 1982-12-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby
IL68716A (en) * 1983-05-17 1987-03-31 Geshuri Lab Ltd Process for producing n-phosphonomethylglycine
US4579689A (en) * 1985-02-11 1986-04-01 Monsanto Company Oxidation with coated catalyst
US4582650A (en) * 1985-02-11 1986-04-15 Monsanto Company Oxidation with encapsulated co-catalyst
US4696772A (en) * 1985-02-28 1987-09-29 Monsanto Company Amine oxidation using carbon catalyst having oxides removed from surface
US4657705A (en) * 1985-09-23 1987-04-14 Monsanto Company Process for the preparation of N-substituted aminomethylphosphonic acids
GB8726714D0 (en) * 1987-11-14 1987-12-16 Beecham Group Plc Compounds
FR2635522B1 (fr) * 1988-08-18 1990-11-16 Rhone Poulenc Agrochimie N-sulfonomethylglycinate procede de preparation, utilisation dans la preparation d'herbicides de type glyphosate
US5187292A (en) * 1988-08-18 1993-02-16 Rhone-Poulenc Agrochimie N-sulfomethylglycinate, use in the preparation of herbicides of the glyphosate type
US4898972A (en) * 1988-09-26 1990-02-06 Monsanto Company Process for producing N-phosphonomethylglycine
HU204533B (en) * 1988-11-02 1992-01-28 Nitrokemia Ipartelepek Process for producing n-phosphono-methyl-glycine
US4937376A (en) * 1989-05-25 1990-06-26 Monsanto Company Process for producing N-phosphonomethylglycine
US4952723A (en) * 1989-07-31 1990-08-28 Monsanto Company Process for producing N-phosphonomethylglycine
US5047579A (en) * 1990-01-26 1991-09-10 Monsanto Company Process for producing n-phosphonomethylglycine
ES2021229A6 (es) * 1990-03-12 1991-10-16 Ercros Sa Perfeccionamientos introducidos en un procedimiento de obtencion de n-fosfonometilglicina por oxidacion de n-fosfonometiliminodiacetico.
US5077430A (en) * 1990-06-25 1991-12-31 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5077431A (en) * 1990-06-25 1991-12-31 Monsanto Company Peroxide process for producing n-phosphonomethylglycine
US5023369A (en) * 1990-06-25 1991-06-11 Monsanto Company Process for producing N-phosphonomethylglycine
US5043475A (en) * 1990-06-25 1991-08-27 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5095140A (en) * 1990-06-25 1992-03-10 Monsanto Company Peroxide process for producing N-phosphonomethylglycine
US5061820A (en) * 1990-10-22 1991-10-29 Monsanto Company Process for producing N-phosphonomethylgylcine
US5072033A (en) * 1990-12-11 1991-12-10 Monsanto Company Process for producing N-phosphonomethylglycine
GB9300641D0 (en) * 1993-01-14 1993-03-03 Zeneca Ltd Process
SI9400449A (en) * 1994-12-20 1996-06-30 Pinus D D Process for preparing N-phosphonomethyl glycin
US6365772B1 (en) * 1995-05-30 2002-04-02 Hampshire Chemical Corp. Facile synthesis of phosphonomethylglycine from phosphonomethyliminodiacetic acid
EP0833831B1 (en) * 1995-06-07 2002-02-13 Monsanto Technology LLC Process for preparing n-phosphonomethyliminodiacetic acid
US5986128A (en) * 1996-11-01 1999-11-16 Monsanto Company Use of monosodium iminodiacetic acid solutions in the preparation of N-phosphonomethyliminodiacetic acid
WO1999041260A1 (en) * 1998-02-12 1999-08-19 Monsanto Company Process for making glyphosate by oxidizing n-substituted glyphosates
US6232494B1 (en) * 1998-02-12 2001-05-15 Monsanto Company Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine
US6417133B1 (en) 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
US5962729A (en) * 1998-05-14 1999-10-05 Calgon Carbon Corporation Method for the manufacture of N-phosphonomethylglycine from N-phosphonomethyliminodiacetic acid using a catalytic carbon
IL140488A0 (en) * 1998-07-06 2002-02-10 Syngenta Participations Ag Preparation of n-phosphonomethylglycine salts
IES980552A2 (en) * 1998-07-09 1999-08-11 Agritech Chemical Ltd Improved process for preparing N-phosphonomethyl iminodiacetic acid
WO2000014093A1 (en) * 1998-09-08 2000-03-16 Hampshire Chemical Corp. Synthesis of phosphonomethyliminodiacetic acid with reduced effluent
WO2001007447A1 (de) 1999-07-23 2001-02-01 Basf Aktiengesellschaft Verfahren zur herstellung von glyphosate oder eines salzes davon
CA2381413A1 (en) 1999-08-11 2001-02-22 Basf Aktiengesellschaft Method for the production of phosphonomethylglycine
MX240933B (es) 1999-12-21 2006-10-09 Monsanto Technology Llc Uso de un promotor suplementario en conjunto con un catalizador que contiene metal noble, soportado en carbon, en reacciones de oxidacion en fase liquida. .
PT102419A (pt) * 2000-02-09 2001-08-30 Pedro Manuel Brito Da Silva Co N-fosfonoalquil)glicina n-(fosfonobenzil)glicina e n-(fosfonofenetil)glicina e seu processo de fabrico e a sua aplicacao como herbicida
AU2001264605C1 (en) 2000-05-15 2005-10-06 Monsanto Technology Llc Preparation of iminodiacetic acid compounds from monoethanolamine substrates
EP1283841B1 (en) 2000-05-22 2005-11-16 Monsanto Technology LLC Reaction systems for making n-(phosphonomethyl)glycine compounds
US6927304B2 (en) 2000-05-22 2005-08-09 Monsanto Technology Llc De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions
WO2002095373A1 (en) * 2001-05-22 2002-11-28 Monsanto Technology Llc Use of infrared spectroscopy for on-line process control and endpoint detection
DE10130136A1 (de) * 2001-06-22 2003-01-02 Basf Ag Verfahren zur Gewinnung von N-Phosphonomethylglycin
CA2463776A1 (en) 2001-10-18 2003-04-24 Monsanto Technology Llc Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts
MX261990B (es) * 2002-02-14 2008-11-07 Monsanto Technology Llc Catalizador de oxidacion y procedimiento para su preparacion y procedimiento para oxidacion mediante el uso del mismo.
US7390920B2 (en) * 2002-02-14 2008-06-24 Monsanto Technology Llc Oxidation catalyst and process
US6921834B2 (en) 2002-05-22 2005-07-26 Dow Agrosciences Llc Continuous process for preparing N-phosphonomethyl glycine
JP4202047B2 (ja) * 2002-05-24 2008-12-24 富士通株式会社 ヘッド位置制御方法及びデイスク記憶装置
AR040319A1 (es) * 2002-06-28 2005-03-23 Monsanto Technology Llc Uso de telurio en catalizadores con contenido de metales nobles y con soporte de carbon para reacciones de oxidacion en fase liquida
EP1684900B1 (en) * 2003-08-14 2013-02-27 Monsanto Technology LLC Process for oxidation of N-(phosphonomethyl)iminodiacetic acid or salt thereof
WO2005028487A1 (en) * 2003-09-17 2005-03-31 Monsanto Technology Llc Process for recovering a crystalline product from solution
TW200624171A (en) * 2004-09-15 2006-07-16 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
AR054096A1 (es) * 2004-11-12 2007-06-06 Monsanto Technology Llc Recuperacion de metales nobles de corrientes de proceso acuosas y proceso de preparacion de n-(fosfonometil)-glicina
MX2007010066A (es) * 2005-02-17 2007-11-07 Monsanto Technology Llc Catalizadores que contienen metales de transicion y combinaciones de catalizadores que incluyen catalizadores que contienen metales de transicion y procedimientos para su preparacion y uso como catalizadores de oxidacion.
TW200718706A (en) * 2005-04-25 2007-05-16 Monsanto Technology Llc Altering the crystal size distribution of N-(phosphonomethyl)iminodiacetic acid for improved filtration and product quality
BRPI0708081A2 (pt) * 2006-02-17 2011-05-17 Monsanto Technology Llc catalisadores contendo metal de transição e processos para a sua preparação e uso como catalisadores de pilha termoelétrica
US7771494B2 (en) * 2007-01-31 2010-08-10 Monsanto Technology Llc Process for selective removal of water and impurities from N-(phosphonomethyl)glycine
US8252953B2 (en) 2008-05-01 2012-08-28 Monsanto Technology Llc Metal utilization in supported, metal-containing catalysts
CN101353358B (zh) * 2008-09-05 2011-01-19 江苏好收成韦恩农化股份有限公司 用改进反应系统制备n-(膦酰基甲基)甘氨酸的方法
CN103044486A (zh) * 2013-01-02 2013-04-17 北京化工大学 一种直接氧化双甘膦制备草甘膦的方法
BR112019027682A2 (pt) 2017-06-26 2020-09-15 Monsanto Technology Llc controle de fósforo para fluxos de resíduos provenientes de processos de produção de glifosato
CN109796491A (zh) * 2018-12-24 2019-05-24 荆州鸿翔化工有限公司 一种制备草甘膦的方法

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA775575A (en) * 1961-11-13 1968-01-09 R. Irani Riyad Organic phosphorus compounds
US3429914A (en) * 1964-09-03 1969-02-25 Monsanto Co Organo-phosphono-amine oxides
DE2132511C3 (de) * 1971-06-30 1974-06-27 Joh. A. Benckiser Gmbh, 6700 Ludwigshafen Verfahren zur Herstellung von Aminomethylenphosphonsäuren

Also Published As

Publication number Publication date
FR2186477A1 (sl) 1974-01-11
SU623523A3 (ru) 1978-09-05
YU36977B (en) 1984-08-31
JPS4948620A (sl) 1974-05-11
IE37730L (en) 1973-11-30
CS177133B2 (sl) 1977-07-29
IE37730B1 (en) 1977-09-28
NO140556C (no) 1979-09-26
SE7600415L (sv) 1976-01-16
AU5627773A (en) 1974-12-05
NL162656C (nl) 1980-06-16
ES440610A1 (es) 1977-03-01
FR2186477B1 (sl) 1977-12-30
DK138951B (da) 1978-11-20
NO140556B (no) 1979-06-18
FR2193831A1 (sl) 1974-02-22
DK138951C (sl) 1979-06-05
IL42393A (en) 1975-12-31
NO783636L (no) 1973-12-03
DE2327680A1 (de) 1973-12-13
CH574968A5 (sl) 1976-04-30
RO66031A (ro) 1980-07-15
NO149176C (no) 1984-02-29
NO149176B (no) 1983-11-21
ES415335A1 (es) 1976-05-01
YU142773A (en) 1982-06-18
US3950402A (en) 1976-04-13
YU262880A (en) 1983-06-30
DE2327680B2 (de) 1978-05-11
SE407579B (sv) 1979-04-02
DE2327680C3 (de) 1979-01-04
BE800238A (fr) 1973-11-30
HU167343B (sl) 1975-09-27
IT988869B (it) 1975-04-30
SE404019B (sv) 1978-09-18
DD104303A5 (sl) 1974-03-05
RO62901A (sl) 1977-08-15
GB1432043A (en) 1976-04-14
EG11140A (en) 1977-08-15
JPS5111093B2 (sl) 1976-04-08
NL162656B (nl) 1980-01-15
NL7307449A (sl) 1973-12-04
BG21212A3 (sl) 1976-03-20
PL107856B1 (pl) 1980-03-31
YU42985B (en) 1989-02-28
FR2193831B1 (sl) 1978-01-06
IL42393A0 (en) 1973-07-30

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