CA978204A - Hydrocyanation of olefins - Google Patents

Hydrocyanation of olefins

Info

Publication number
CA978204A
CA978204A CA147,820A CA147820A CA978204A CA 978204 A CA978204 A CA 978204A CA 147820 A CA147820 A CA 147820A CA 978204 A CA978204 A CA 978204A
Authority
CA
Canada
Prior art keywords
hydrocyanation
olefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA147,820A
Other languages
English (en)
Other versions
CA147820S (en
Inventor
Charles M. King
Chadwick A. Tolman
William C. Seidel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of CA978204A publication Critical patent/CA978204A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Toxicology (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CA147,820A 1971-08-02 1972-07-24 Hydrocyanation of olefins Expired CA978204A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US16835271A 1971-08-02 1971-08-02

Publications (1)

Publication Number Publication Date
CA978204A true CA978204A (en) 1975-11-18

Family

ID=22611173

Family Applications (1)

Application Number Title Priority Date Filing Date
CA147,820A Expired CA978204A (en) 1971-08-02 1972-07-24 Hydrocyanation of olefins

Country Status (9)

Country Link
US (1) US3798256A (xx)
JP (1) JPS5110202B1 (xx)
BE (1) BE787043A (xx)
CA (1) CA978204A (xx)
DE (1) DE2237703C3 (xx)
FR (1) FR2149848A5 (xx)
GB (1) GB1377228A (xx)
IT (1) IT963635B (xx)
NL (1) NL170531C (xx)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3925445A (en) * 1971-08-02 1975-12-09 Du Pont Hydrocyanation of olefins
US3966595A (en) * 1972-07-20 1976-06-29 E. I. Du Pont De Nemours And Company Method of making group VIII metal complex compounds
US3850973A (en) * 1973-09-26 1974-11-26 Du Pont Hydrocyanation of conjugated diolefins
US3864380A (en) * 1974-01-17 1975-02-04 Du Pont Hydrocyanation of Olefins
DE2811702A1 (de) * 1978-03-17 1979-09-20 Degussa Verfahren zur herstellung von cyancarbonsaeuren
US4330483A (en) * 1981-02-24 1982-05-18 E. I. Du Pont De Nemours And Company Hydrocyanation of olefins
US4328172A (en) * 1981-02-24 1982-05-04 E. I. Du Pont De Nemours And Company Hydrocyanation of olefins
US4434316A (en) 1983-03-25 1984-02-28 E. I. Du Pont De Nemours & Co. Separation of alkenes from alkadienes
US5143873A (en) * 1990-12-17 1992-09-01 E. I. Du Pont De Nemours And Company Process for activation or regeneration of nickel catalyst
US5175335A (en) * 1991-11-12 1992-12-29 E. I. Du Pont De Nemours And Company Enantioselective hydrocyanation of aromatic vinyl compounds
EP0730574B1 (en) * 1993-11-23 1998-08-19 E.I. Du Pont De Nemours And Company Processes and catalyst compositions for hydrocyanation of monoolefins
DE69519020T2 (de) 1994-04-14 2001-05-17 Du Pont Nickel und phosphinebidentat enthaltende katalysatorzusammen- setzungen zur hydrocyanierung von monoolefinen
US5382697A (en) * 1994-06-23 1995-01-17 E. I. Du Pont De Nemours And Company Preparation of triarylborane
TW315370B (xx) * 1994-10-07 1997-09-11 Du Pont
US5512696A (en) * 1995-07-21 1996-04-30 E. I. Du Pont De Nemours And Company Hydrocyanation process and multidentate phosphite and nickel catalyst composition therefor
US5449807A (en) * 1994-11-18 1995-09-12 E. I. Du Pont De Nemours And Company Catalyzed vapor phase hydrocyanation of diolefinic compounds
US5821378A (en) * 1995-01-27 1998-10-13 E. I. Du Pont De Nemours And Company Hydrocyanation of diolefins and isomerization of nonconjugated 2-alkyl-3-monoalkenenitriles
IN187044B (xx) * 1995-01-27 2002-01-05 Du Pont
DE19953058A1 (de) 1999-11-03 2001-05-10 Basf Ag Phosphite
DE10136488A1 (de) 2001-07-27 2003-02-06 Basf Ag Ni(O) enthaltendes Katalysatorsystem
AR036636A1 (es) 2001-10-12 2004-09-22 Basf Ag Fosfonita i, su uso como ligando en complejos de metal de transicion, dichos complejos, procedimiento para la obtencion de estos ultimos, uso de complejos de metal transitorio como catalizador y procedimientos para la adicion de acido cianhidrico a un doble enlace olefinico y para la isomerizacion d
DE10150285A1 (de) 2001-10-12 2003-04-17 Basf Ag Phosphonite
FR2849027B1 (fr) * 2002-12-23 2005-01-21 Rhodia Polyamide Intermediates Procede de synthese de composes comprenant des fonctions nitriles a partir de composes a insaturations ethyleniques
FR2850966B1 (fr) * 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
FR2854892B1 (fr) * 2003-05-12 2005-06-24 Rhodia Polyamide Intermediates Procede de fabrication de dinitriles
US7385071B2 (en) * 2003-10-28 2008-06-10 Invista North America S.A.R.L. Hydrocyanation of pentenenitriles and/or 2-methyl-3-butenenitrile using promoters obtained from the chlorination of titanium-rich ores
DE10350999A1 (de) 2003-10-30 2005-06-02 Basf Ag Katalysator, umfassend wenigstens einen Nickel(O)Komplex stabilisiert durch einen sterisch anspruchsvollen Chelatphosphinitphosphitliganden, sowie ein Verfahren zur Herstellung von Nitrilen
EP2322503B1 (en) * 2005-10-18 2014-12-31 Invista Technologies S.à.r.l. Process of making 3-aminopentanenitrile
WO2007109005A2 (en) * 2006-03-17 2007-09-27 Invista Technologies S.A R.L. Method for the purification of triorganophosphites by treatment with a basic additive
US7880028B2 (en) * 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
US7709674B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US7919646B2 (en) * 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US8906334B2 (en) 2007-05-14 2014-12-09 Invista North America S.A R.L. High efficiency reactor and process
US8101790B2 (en) * 2007-06-13 2012-01-24 Invista North America S.A.R.L. Process for improving adiponitrile quality
WO2009091771A2 (en) * 2008-01-15 2009-07-23 Invista Technologies S.A R.L Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
CN101918356B (zh) * 2008-01-15 2013-09-25 因温斯特技术公司 戊烯腈的氢氰化
JP2011515411A (ja) * 2008-03-19 2011-05-19 インビスタ テクノロジーズ エス エイ アール エル シクロドデカトリエンの製造方法およびラウロラクトンの製造方法
KR101610423B1 (ko) * 2008-10-14 2016-04-08 인비스타 테크놀러지스 에스.에이 알.엘. 2-ｓｅｃ-알킬-4,5-디-(ｎ-알킬)페놀의 제조 방법
WO2011017543A1 (en) * 2009-08-07 2011-02-10 Invista Technologies S.A. R.L. Hydrogenation and esterification to form diesters

Also Published As

Publication number Publication date
NL170531B (nl) 1982-06-16
DE2237703B2 (de) 1975-03-27
IT963635B (it) 1974-01-21
US3798256A (en) 1974-03-19
DE2237703A1 (de) 1973-02-15
FR2149848A5 (xx) 1973-03-30
NL7210606A (xx) 1973-02-06
NL170531C (nl) 1982-11-16
DE2237703C3 (de) 1975-11-13
GB1377228A (en) 1974-12-11
JPS5110202B1 (xx) 1976-04-02
BE787043A (fr) 1972-12-01

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