CA3150909C - Procede de synthese electrocatalytique efficace de solutions de produits liquides purs comprenant h2o2, des composes oxygenes, de l'ammoniac, etc. - Google Patents
Procede de synthese electrocatalytique efficace de solutions de produits liquides purs comprenant h2o2, des composes oxygenes, de l'ammoniac, etc. Download PDFInfo
- Publication number
- CA3150909C CA3150909C CA3150909A CA3150909A CA3150909C CA 3150909 C CA3150909 C CA 3150909C CA 3150909 A CA3150909 A CA 3150909A CA 3150909 A CA3150909 A CA 3150909A CA 3150909 C CA3150909 C CA 3150909C
- Authority
- CA
- Canada
- Prior art keywords
- solid electrolyte
- cathode
- cell
- exchange membrane
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 48
- 239000012263 liquid product Substances 0.000 title claims abstract description 42
- 230000015572 biosynthetic process Effects 0.000 title claims abstract description 30
- 238000003786 synthesis reaction Methods 0.000 title claims abstract description 30
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title description 6
- 229910021529 ammonia Inorganic materials 0.000 title description 3
- 239000003054 catalyst Substances 0.000 claims abstract description 144
- 239000007784 solid electrolyte Substances 0.000 claims abstract description 116
- 238000006722 reduction reaction Methods 0.000 claims abstract description 90
- 239000012528 membrane Substances 0.000 claims abstract description 49
- 238000009792 diffusion process Methods 0.000 claims abstract description 48
- 239000010411 electrocatalyst Substances 0.000 claims abstract description 36
- 230000008569 process Effects 0.000 claims abstract description 35
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 34
- 238000005341 cation exchange Methods 0.000 claims abstract description 32
- 239000003011 anion exchange membrane Substances 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 86
- 239000007789 gas Substances 0.000 claims description 72
- 229910001868 water Inorganic materials 0.000 claims description 61
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 53
- 239000006229 carbon black Substances 0.000 claims description 39
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 36
- 229910052760 oxygen Inorganic materials 0.000 claims description 35
- 239000001301 oxygen Substances 0.000 claims description 35
- 229910052799 carbon Inorganic materials 0.000 claims description 31
- 125000004429 atom Chemical group 0.000 claims description 30
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 29
- 239000002041 carbon nanotube Substances 0.000 claims description 28
- 239000008367 deionised water Substances 0.000 claims description 24
- 229910021641 deionized water Inorganic materials 0.000 claims description 24
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 23
- 150000003624 transition metals Chemical class 0.000 claims description 23
- 229910052723 transition metal Inorganic materials 0.000 claims description 22
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 16
- 229920000642 polymer Polymers 0.000 claims description 16
- 150000002500 ions Chemical class 0.000 claims description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- 229910052742 iron Inorganic materials 0.000 claims description 12
- 239000000919 ceramic Substances 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 10
- 229910052797 bismuth Inorganic materials 0.000 claims description 9
- 239000002322 conducting polymer Substances 0.000 claims description 9
- 229920001940 conductive polymer Polymers 0.000 claims description 9
- 229910052763 palladium Inorganic materials 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 8
- 229910002651 NO3 Inorganic materials 0.000 claims description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 7
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 7
- 239000007809 chemical reaction catalyst Substances 0.000 claims description 7
- 239000000376 reactant Substances 0.000 claims description 7
- 150000004770 chalcogenides Chemical class 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 5
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- 239000004793 Polystyrene Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011245 gel electrolyte Substances 0.000 claims description 4
- 229910052738 indium Inorganic materials 0.000 claims description 4
- 229910052745 lead Inorganic materials 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229920002223 polystyrene Polymers 0.000 claims description 4
- 229910052741 iridium Inorganic materials 0.000 claims description 3
- 229910052718 tin Inorganic materials 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 239000012495 reaction gas Substances 0.000 claims 2
- PIVSXYQVNSKDFF-UHFFFAOYSA-N 1,2-dimethyl-1h-imidazol-1-ium;chloride Chemical compound [Cl-].C[NH+]1C=CN=C1C PIVSXYQVNSKDFF-UHFFFAOYSA-N 0.000 claims 1
- 229910052684 Cerium Inorganic materials 0.000 claims 1
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 72
- 239000000243 solution Substances 0.000 description 72
- 235000019253 formic acid Nutrition 0.000 description 67
- 239000010410 layer Substances 0.000 description 53
- 239000000047 product Substances 0.000 description 38
- 238000004519 manufacturing process Methods 0.000 description 35
- 230000009467 reduction Effects 0.000 description 32
- 150000001450 anions Chemical class 0.000 description 21
- 239000004020 conductor Substances 0.000 description 21
- 230000000694 effects Effects 0.000 description 21
- 238000013461 design Methods 0.000 description 20
- 230000003647 oxidation Effects 0.000 description 18
- 239000000446 fuel Substances 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 15
- 150000001768 cations Chemical class 0.000 description 15
- 239000007788 liquid Substances 0.000 description 15
- 239000007787 solid Substances 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 239000003792 electrolyte Substances 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 230000007935 neutral effect Effects 0.000 description 11
- 230000002829 reductive effect Effects 0.000 description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000003575 carbonaceous material Substances 0.000 description 10
- 238000006555 catalytic reaction Methods 0.000 description 10
- 230000036961 partial effect Effects 0.000 description 10
- 238000000746 purification Methods 0.000 description 10
- 238000004458 analytical method Methods 0.000 description 9
- 239000002019 doping agent Substances 0.000 description 9
- 125000000524 functional group Chemical group 0.000 description 9
- 239000002135 nanosheet Substances 0.000 description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 8
- -1 Ir) respectively Chemical class 0.000 description 8
- 239000007832 Na2SO4 Substances 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 8
- 238000005868 electrolysis reaction Methods 0.000 description 8
- 239000012535 impurity Substances 0.000 description 8
- 229910052755 nonmetal Inorganic materials 0.000 description 8
- 230000037361 pathway Effects 0.000 description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 description 8
- 235000011152 sodium sulphate Nutrition 0.000 description 8
- 238000004659 sterilization and disinfection Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000012512 characterization method Methods 0.000 description 7
- 238000011068 loading method Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 238000011065 in-situ storage Methods 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 6
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 5
- 241000894006 Bacteria Species 0.000 description 5
- 238000005349 anion exchange Methods 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 5
- 239000003014 ion exchange membrane Substances 0.000 description 5
- 238000004626 scanning electron microscopy Methods 0.000 description 5
- 238000001228 spectrum Methods 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 238000011282 treatment Methods 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- 229920000557 Nafion® Polymers 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000003929 acidic solution Substances 0.000 description 4
- 239000012670 alkaline solution Substances 0.000 description 4
- 238000013459 approach Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 4
- 230000006872 improvement Effects 0.000 description 4
- 230000007774 longterm Effects 0.000 description 4
- 229910052748 manganese Inorganic materials 0.000 description 4
- 239000002105 nanoparticle Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910000510 noble metal Inorganic materials 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000006798 recombination Effects 0.000 description 4
- 238000005215 recombination Methods 0.000 description 4
- 230000027756 respiratory electron transport chain Effects 0.000 description 4
- 239000000523 sample Substances 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- 238000013112 stability test Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 125000000542 sulfonic acid group Chemical group 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 238000001308 synthesis method Methods 0.000 description 4
- 238000004627 transmission electron microscopy Methods 0.000 description 4
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 3
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- XOJVVFBFDXDTEG-UHFFFAOYSA-N Norphytane Natural products CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 3
- 241000872198 Serjania polyphylla Species 0.000 description 3
- 238000010306 acid treatment Methods 0.000 description 3
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 3
- 150000004056 anthraquinones Chemical class 0.000 description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 3
- 238000006758 bulk electrolysis reaction Methods 0.000 description 3
- 239000003010 cation ion exchange membrane Substances 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- 239000003651 drinking water Substances 0.000 description 3
- 235000020188 drinking water Nutrition 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 238000007306 functionalization reaction Methods 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 229910021389 graphene Inorganic materials 0.000 description 3
- 238000002173 high-resolution transmission electron microscopy Methods 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 239000010416 ion conductor Substances 0.000 description 3
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 3
- 239000011244 liquid electrolyte Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 150000002843 nonmetals Chemical class 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 238000011002 quantification Methods 0.000 description 3
- 230000002441 reversible effect Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- WTXXSZUATXIAJO-OWBHPGMISA-N (Z)-14-methylpentadec-2-enoic acid Chemical compound CC(CCCCCCCCCC\C=C/C(=O)O)C WTXXSZUATXIAJO-OWBHPGMISA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 2
- 229910014033 C-OH Inorganic materials 0.000 description 2
- 229910014570 C—OH Inorganic materials 0.000 description 2
- 238000003775 Density Functional Theory Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000004693 Polybenzimidazole Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000003917 TEM image Methods 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000004998 X ray absorption near edge structure spectroscopy Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000004630 atomic force microscopy Methods 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- PPNKDDZCLDMRHS-UHFFFAOYSA-N dinitrooxybismuthanyl nitrate Chemical class [Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PPNKDDZCLDMRHS-UHFFFAOYSA-N 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000002384 drinking water standard Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 238000000192 extended X-ray absorption fine structure spectroscopy Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 229910003480 inorganic solid Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(III) nitrate Inorganic materials [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
- 238000013507 mapping Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000013580 millipore water Substances 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229920002480 polybenzimidazole Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000036647 reaction Effects 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000001350 scanning transmission electron microscopy Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- CHRJZRDFSQHIFI-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;styrene Chemical compound C=CC1=CC=CC=C1.C=CC1=CC=CC=C1C=C CHRJZRDFSQHIFI-UHFFFAOYSA-N 0.000 description 1
- SLBOQBILGNEPEB-UHFFFAOYSA-N 1-chloroprop-2-enylbenzene Chemical compound C=CC(Cl)C1=CC=CC=C1 SLBOQBILGNEPEB-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- 238000005160 1H NMR spectroscopy Methods 0.000 description 1
- SLPKYEWAKMNCPT-UHFFFAOYSA-N 2,6-dimethyl-1-(3-[3-methyl-5-isoxazolyl]-propanyl)-4-[2-methyl-4-isoxazolyl]-phenol Chemical compound O1N=C(C)C=C1CCCOC1=C(C)C=C(C=2N=C(C)OC=2)C=C1C SLPKYEWAKMNCPT-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910002710 Au-Pd Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 241000588722 Escherichia Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 229910016874 Fe(NO3) Inorganic materials 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 102100031180 Hereditary hemochromatosis protein Human genes 0.000 description 1
- 101000993059 Homo sapiens Hereditary hemochromatosis protein Proteins 0.000 description 1
- 239000013032 Hydrocarbon resin Substances 0.000 description 1
- 239000006142 Luria-Bertani Agar Substances 0.000 description 1
- 238000005481 NMR spectroscopy Methods 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000000026 X-ray photoelectron spectrum Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- YOUGRGFIHBUKRS-UHFFFAOYSA-N benzyl(trimethyl)azanium Chemical compound C[N+](C)(C)CC1=CC=CC=C1 YOUGRGFIHBUKRS-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 230000001332 colony forming effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000002484 cyclic voltammetry Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 235000012209 glucono delta-lactone Nutrition 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002272 high-resolution X-ray photoelectron spectroscopy Methods 0.000 description 1
- 239000007970 homogeneous dispersion Substances 0.000 description 1
- 229920006270 hydrocarbon resin Polymers 0.000 description 1
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- 230000002147 killing effect Effects 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(II) nitrate Inorganic materials [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229910052752 metalloid Inorganic materials 0.000 description 1
- 150000002738 metalloids Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 239000002048 multi walled nanotube Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- ZMLDXWLZKKZVSS-UHFFFAOYSA-N palladium tin Chemical compound [Pd].[Sn] ZMLDXWLZKKZVSS-UHFFFAOYSA-N 0.000 description 1
- GPNDARIEYHPYAY-UHFFFAOYSA-N palladium(II) nitrate Inorganic materials [Pd+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O GPNDARIEYHPYAY-UHFFFAOYSA-N 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 239000005518 polymer electrolyte Substances 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000012974 tin catalyst Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten(VI) oxide Inorganic materials O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/28—Per-compounds
- C25B1/30—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/27—Ammonia
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/043—Carbon, e.g. diamond or graphene
- C25B11/044—Impregnation of carbon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B13/00—Diaphragms; Spacing elements
- C25B13/04—Diaphragms; Spacing elements characterised by the material
- C25B13/05—Diaphragms; Spacing elements characterised by the material based on inorganic materials
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
L'invention porte sur une cellule d'électrosynthèse à électrolyte solide poreux et sur un procédé associé correspondant pour la synthèse directe de produits liquides de haute pureté, la cellule d'électrosynthèse comprenant un compartiment de cathode contenant une électrode de cathode comportant une couche de diffusion de gaz chargée avec un électrocatalyseur de réaction de réduction sélective pour des réactions de réduction spécifiques. La cellule d'électrosynthèse comprend en outre un compartiment d'anode contenant une électrode d'anode contenant une couche de diffusion de gaz chargée avec un catalyseur pour des réactions d'oxydation; et un compartiment d'électrolyte solide comprenant un électrolyte solide poreux; une membrane conductrice de cations; et une membrane conductrice d'anions; (ou deux membranes conductrices de cations) le compartiment d'électrolyte solide étant séparé de la cathode et de l'anode par la membrane conductrice d'anions et la membrane conductrice de cations (ou par les deux membranes conductrices de cations).
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201962874176P | 2019-07-15 | 2019-07-15 | |
| US62/874,176 | 2019-07-15 | ||
| PCT/US2020/042163 WO2021011675A1 (fr) | 2019-07-15 | 2020-07-15 | Procédé de synthèse électrocatalytique efficace de solutions de produits liquides purs comprenant h2o2, des composés oxygénés, de l'ammoniac, etc. |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3150909A1 CA3150909A1 (fr) | 2021-01-21 |
| CA3150909C true CA3150909C (fr) | 2024-02-06 |
Family
ID=72234915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3150909A Active CA3150909C (fr) | 2019-07-15 | 2020-07-15 | Procede de synthese electrocatalytique efficace de solutions de produits liquides purs comprenant h2o2, des composes oxygenes, de l'ammoniac, etc. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20220259746A1 (fr) |
| EP (1) | EP3999673A1 (fr) |
| CN (1) | CN114423887A (fr) |
| AU (1) | AU2020313943A1 (fr) |
| CA (1) | CA3150909C (fr) |
| WO (1) | WO2021011675A1 (fr) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2955054T3 (es) | 2017-09-10 | 2023-11-28 | Orbit Fab Inc | Sistemas y métodos para suministrar, almacenar, y procesar materiales en el espacio |
| WO2019051432A1 (fr) | 2017-09-10 | 2019-03-14 | Space Arena, Inc. | Enceintes pour faciliter des activités dans l'espace, ainsi que systèmes et procédés associés |
| US11814738B2 (en) * | 2020-01-30 | 2023-11-14 | Avantium Knowledge Centre B.V. | Electrochemical production of formate |
| KR102702526B1 (ko) * | 2020-05-22 | 2024-09-03 | 에이에스엠 아이피 홀딩 비.브이. | 과산화수소를 사용하여 박막을 증착하기 위한 장치 |
| CN112858427B (zh) * | 2021-01-26 | 2022-03-08 | 暨南大学 | 一种镍单原子锚定碳氮材料修饰电极及其制备方法与应用 |
| CN113020614B (zh) * | 2021-02-26 | 2022-09-02 | 中国科学技术大学 | 铜基单原子合金催化剂及其制备方法、应用、二氧化碳电还原制备甲酸的膜电极电解质电池 |
| CN113122869A (zh) * | 2021-03-10 | 2021-07-16 | 西南科技大学 | 一种连续流电催化合成氨装置及电催化合成氨的方法 |
| KR102544235B1 (ko) * | 2021-03-12 | 2023-06-16 | 포항공과대학교 산학협력단 | 고체전해질 기반 광전기화학적 순수 과산화수소 추출을 위한 광전기화학 셀, 그의 제조방법 및 그를 이용한 과산화수소의 제조방법 |
| CN113668001A (zh) * | 2021-07-27 | 2021-11-19 | 北京化工大学 | 析氢反应催化剂用于电催化硝酸根还原合成氨的方法 |
| CN113416966B (zh) * | 2021-07-30 | 2023-09-22 | 联科华技术有限公司 | 一种电催化制备过氧化氢的单原子催化剂、制备方法及其应用 |
| CN113526646B (zh) * | 2021-08-20 | 2022-04-05 | 中南大学 | 一种阴/阳极原位产双氧水的电芬顿体系及其在强化有机污染物降解中的应用 |
| CN113943947B (zh) * | 2021-09-28 | 2022-11-15 | 浙江工业大学 | 一种用于电化学还原二氧化碳复合薄膜电极及其制备方法 |
| CN114249388A (zh) * | 2021-12-06 | 2022-03-29 | 电子科技大学长三角研究院(湖州) | 一种用于高级氧化降解有机物的电解池装置及其应用 |
| DE102021214631A1 (de) * | 2021-12-17 | 2023-06-22 | Siemens Energy Global GmbH & Co. KG | Zellkonzept zur Nutzung nicht-ionisch leitfähiger Extraktionsmedien |
| CN114561655B (zh) * | 2022-03-28 | 2024-07-02 | 河北工业大学 | 一种稀土铈掺杂硫化镍/硫化铁异质结材料的制备方法和应用 |
| WO2023201039A1 (fr) * | 2022-04-14 | 2023-10-19 | William Marsh Rice University | Capture et récupération électrochimiques de dioxyde de carbone dans un système de réacteur à électrolyte solide |
| CN114717580A (zh) * | 2022-05-06 | 2022-07-08 | 哈尔滨工业大学 | 一种原位制备过氧化氢干雾的消毒装置及其运行方法 |
| CN114774978B (zh) * | 2022-05-10 | 2024-04-09 | 浙江工业大学 | 一种Ni-Fe MMO薄膜修饰的泡沫镍催化剂及其制备方法和应用 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2634290A1 (fr) * | 2012-02-28 | 2013-09-04 | Fritz Haber Institute of the Max Planck Society Department of Inorganic Chemistry | Hydrolyse électrolytique utilisant un composé MnOx sur support de carbone |
| CN204039512U (zh) * | 2014-07-29 | 2014-12-24 | 北京廷润膜技术开发有限公司 | 一种制备银氰化钾的电解装置 |
| US11091846B2 (en) * | 2016-06-24 | 2021-08-17 | Stichting Wageningen Research | Electrochemical process and reactor |
| EP3462526A1 (fr) * | 2017-09-27 | 2019-04-03 | Fritz-Haber-Institut Der Max-Planck-Gesellschaft | Espèce métallique dispersée atomiquement dans un liquide ionique à la surface d'un matériau carboné ayant une hybridation sp2 et son procédé de préparation |
-
2020
- 2020-07-15 EP EP20761367.0A patent/EP3999673A1/fr active Pending
- 2020-07-15 CN CN202080064803.7A patent/CN114423887A/zh active Pending
- 2020-07-15 CA CA3150909A patent/CA3150909C/fr active Active
- 2020-07-15 US US17/597,633 patent/US20220259746A1/en active Pending
- 2020-07-15 WO PCT/US2020/042163 patent/WO2021011675A1/fr unknown
- 2020-07-15 AU AU2020313943A patent/AU2020313943A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| CA3150909A1 (fr) | 2021-01-21 |
| AU2020313943A1 (en) | 2022-03-03 |
| CN114423887A (zh) | 2022-04-29 |
| US20220259746A1 (en) | 2022-08-18 |
| WO2021011675A1 (fr) | 2021-01-21 |
| EP3999673A1 (fr) | 2022-05-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA3150909C (fr) | Procede de synthese electrocatalytique efficace de solutions de produits liquides purs comprenant h2o2, des composes oxygenes, de l'ammoniac, etc. | |
| You et al. | Monolayer NiIr-layered double hydroxide as a long-lived efficient oxygen evolution catalyst for seawater splitting | |
| Zhang et al. | Recent advances in electrocatalytic oxygen reduction for on-site hydrogen peroxide synthesis in acidic media | |
| Hu et al. | Recent progress made in the mechanism comprehension and design of electrocatalysts for alkaline water splitting | |
| Zhou et al. | Layered metal–organic framework-derived metal oxide/carbon nanosheet arrays for catalyzing the oxygen evolution reaction | |
| Chen et al. | Active site engineering in porous electrocatalysts | |
| Liu et al. | Activation strategies of water-splitting electrocatalysts | |
| Hasani et al. | Graphene‐based catalysts for electrochemical carbon dioxide reduction | |
| Wu et al. | La-RuO2 nanocrystals with efficient electrocatalytic activity for overall water splitting in acidic media: synergistic effect of La doping and oxygen vacancy | |
| Miao et al. | Reduced graphene oxide supported nickel–manganese–cobalt spinel ternary oxide nanocomposites and their chemically converted sulfide nanocomposites as efficient electrocatalysts for alkaline water splitting | |
| Li et al. | Hydrothermal synthesis of monolithic Co3Se4 nanowire electrodes for oxygen evolution and overall water splitting with high efficiency and extraordinary catalytic stability | |
| Kim et al. | Recent advances in non-precious group metal-based catalysts for water electrolysis and beyond | |
| Pang et al. | CoO promoted the catalytic activity of nitrogen-doped MoS2 supported on carbon fibers for overall water splitting | |
| Luo et al. | Trimetallic molybdate nanobelts as active and stable electrocatalysts for the oxygen evolution reaction | |
| Wang et al. | Efficient oxygen evolution reaction from iron-molybdenum nitride/molybdenum oxide heterostructured composites | |
| Yang et al. | Atomic-scale Pt clusters decorated on porous α-Ni (OH) 2 nanowires as highly efficient electrocatalyst for hydrogen evolution reaction | |
| Tong et al. | Electrocatalytic oxygen reduction to produce hydrogen peroxide: rational design from single-atom catalysts to devices | |
| Lee et al. | Oxygen vacancies induced NiFe-hydroxide as a scalable, efficient, and stable electrode for alkaline overall water splitting | |
| Liang et al. | Engineering oxygen vacancies in mesocrystalline CuO nanosheets for water oxidation | |
| Wang et al. | Ni–Co–S–Se alloy nanocrystals: influence of the composition on their in situ transformation and electrocatalytic activity for the oxygen evolution reaction | |
| Tamilarasi et al. | Non-noble metal-based electro-catalyst for the oxygen evolution reaction (OER): Towards an active & stable electro-catalyst for PEM water electrolysis | |
| Chen et al. | Gas penetrating hollow fiber Bi with contractive bond enables industry-level CO2 electroreduction | |
| Wu et al. | Screening of transition metal oxides for electrocatalytic nitrate reduction to ammonia at large currents | |
| Zhang et al. | Robust and hydrophilic Mo-NiS@ NiTe core-shell heterostructure nanorod arrays for efficient hydrogen evolution reaction in alkaline freshwater and seawater | |
| Li et al. | Cobalt doping boosted electrocatalytic activity of CaMn 3 O 6 for hydrogen evolution reaction |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20220310 |
|
| EEER | Examination request |
Effective date: 20220310 |
|
| EEER | Examination request |
Effective date: 20220310 |
|
| EEER | Examination request |
Effective date: 20220310 |
|
| EEER | Examination request |
Effective date: 20220310 |
|
| EEER | Examination request |
Effective date: 20220310 |
|
| EEER | Examination request |
Effective date: 20220310 |
|
| EEER | Examination request |
Effective date: 20220310 |
|
| EEER | Examination request |
Effective date: 20220310 |