CA3136247C - Systems and methods for recovering lithium from brines - Google Patents
Systems and methods for recovering lithium from brines Download PDFInfo
- Publication number
- CA3136247C CA3136247C CA3136247A CA3136247A CA3136247C CA 3136247 C CA3136247 C CA 3136247C CA 3136247 A CA3136247 A CA 3136247A CA 3136247 A CA3136247 A CA 3136247A CA 3136247 C CA3136247 C CA 3136247C
- Authority
- CA
- Canada
- Prior art keywords
- lithium
- brine
- pond
- precipitation
- stream
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 198
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 193
- 238000000034 method Methods 0.000 title claims abstract description 89
- 239000012535 impurity Substances 0.000 claims abstract description 113
- 238000001704 evaporation Methods 0.000 claims abstract description 90
- 230000008020 evaporation Effects 0.000 claims abstract description 89
- 238000000926 separation method Methods 0.000 claims abstract description 46
- 238000000975 co-precipitation Methods 0.000 claims abstract description 45
- 238000001556 precipitation Methods 0.000 claims abstract description 45
- 230000002349 favourable effect Effects 0.000 claims abstract description 17
- 239000012267 brine Substances 0.000 claims description 138
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 138
- 150000002500 ions Chemical class 0.000 claims description 45
- 150000003839 salts Chemical class 0.000 claims description 33
- 239000002244 precipitate Substances 0.000 claims description 29
- 239000012528 membrane Substances 0.000 claims description 25
- PALNZFJYSCMLBK-UHFFFAOYSA-K magnesium;potassium;trichloride;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-].[Cl-].[K+] PALNZFJYSCMLBK-UHFFFAOYSA-K 0.000 claims description 19
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 claims description 16
- 230000001376 precipitating effect Effects 0.000 claims description 16
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 13
- 239000004327 boric acid Substances 0.000 claims description 13
- 238000000909 electrodialysis Methods 0.000 claims description 12
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 claims description 10
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical group O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 claims description 10
- 229910052796 boron Inorganic materials 0.000 claims description 9
- 238000011084 recovery Methods 0.000 claims description 9
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 8
- 150000001768 cations Chemical class 0.000 claims description 8
- 238000000502 dialysis Methods 0.000 claims description 8
- RKGLUDFWIKNKMX-UHFFFAOYSA-L dilithium;sulfate;hydrate Chemical compound [Li+].[Li+].O.[O-]S([O-])(=O)=O RKGLUDFWIKNKMX-UHFFFAOYSA-L 0.000 claims description 8
- 238000005342 ion exchange Methods 0.000 claims description 8
- GMLLYEDWRJDBIT-UHFFFAOYSA-J magnesium;dipotassium;disulfate Chemical compound [Mg+2].[K+].[K+].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GMLLYEDWRJDBIT-UHFFFAOYSA-J 0.000 claims description 8
- 238000001179 sorption measurement Methods 0.000 claims description 8
- 229910003002 lithium salt Inorganic materials 0.000 claims description 7
- 159000000002 lithium salts Chemical class 0.000 claims description 7
- 238000001728 nano-filtration Methods 0.000 claims description 7
- 238000012545 processing Methods 0.000 claims description 7
- 229910052925 anhydrite Inorganic materials 0.000 claims description 6
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 6
- BMQVDVJKPMGHDO-UHFFFAOYSA-K magnesium;potassium;chloride;sulfate;trihydrate Chemical compound O.O.O.[Mg+2].[Cl-].[K+].[O-]S([O-])(=O)=O BMQVDVJKPMGHDO-UHFFFAOYSA-K 0.000 claims description 6
- 150000001450 anions Chemical class 0.000 claims description 5
- -1 borate ions Chemical class 0.000 claims description 5
- 229910052602 gypsum Inorganic materials 0.000 claims description 5
- 239000010440 gypsum Substances 0.000 claims description 5
- 238000000638 solvent extraction Methods 0.000 claims description 5
- VLCLHFYFMCKBRP-UHFFFAOYSA-N tricalcium;diborate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]B([O-])[O-].[O-]B([O-])[O-] VLCLHFYFMCKBRP-UHFFFAOYSA-N 0.000 claims description 5
- 238000011144 upstream manufacturing Methods 0.000 claims description 5
- 229910052928 kieserite Inorganic materials 0.000 claims description 4
- 238000004064 recycling Methods 0.000 claims description 4
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 claims description 4
- 238000011282 treatment Methods 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 3
- 229910052564 epsomite Inorganic materials 0.000 claims description 3
- 229910052930 hexahydrite Inorganic materials 0.000 claims description 3
- OBTSLRFPKIKXSZ-UHFFFAOYSA-N lithium potassium Chemical compound [Li].[K] OBTSLRFPKIKXSZ-UHFFFAOYSA-N 0.000 claims description 3
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 claims description 3
- 239000010446 mirabilite Substances 0.000 claims description 3
- 239000001103 potassium chloride Substances 0.000 claims description 3
- 235000011164 potassium chloride Nutrition 0.000 claims description 3
- 230000008030 elimination Effects 0.000 claims description 2
- 238000003379 elimination reaction Methods 0.000 claims description 2
- 230000009467 reduction Effects 0.000 claims description 2
- HZRMTWQRDMYLNW-UHFFFAOYSA-N lithium metaborate Chemical compound [Li+].[O-]B=O HZRMTWQRDMYLNW-UHFFFAOYSA-N 0.000 claims 3
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 claims 2
- 239000011777 magnesium Substances 0.000 description 39
- 230000008569 process Effects 0.000 description 36
- 235000002639 sodium chloride Nutrition 0.000 description 34
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 33
- 229910052749 magnesium Inorganic materials 0.000 description 29
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 26
- 239000000203 mixture Substances 0.000 description 24
- 238000004088 simulation Methods 0.000 description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 15
- 239000011734 sodium Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 8
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000013459 approach Methods 0.000 description 7
- 239000011575 calcium Substances 0.000 description 7
- 238000000605 extraction Methods 0.000 description 6
- 239000012621 metal-organic framework Substances 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 239000010442 halite Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 4
- 229910052939 potassium sulfate Inorganic materials 0.000 description 4
- 238000001223 reverse osmosis Methods 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 238000011143 downstream manufacturing Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000013505 freshwater Substances 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 230000003134 recirculating effect Effects 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000003306 harvesting Methods 0.000 description 2
- 238000011034 membrane dialysis Methods 0.000 description 2
- 230000003204 osmotic effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 101100309487 Mus musculus Samhd1 gene Proteins 0.000 description 1
- 101100369237 Mus musculus Tgtp1 gene Proteins 0.000 description 1
- 101100369238 Mus musculus Tgtp2 gene Proteins 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910021538 borax Inorganic materials 0.000 description 1
- VVJRSSJSRXEOQL-UHFFFAOYSA-N calcium;potassium;sulfuric acid;hydrate Chemical compound O.[K].[K].[Ca].OS(O)(=O)=O.OS(O)(=O)=O VVJRSSJSRXEOQL-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- URSLCTBXQMKCFE-UHFFFAOYSA-N dihydrogenborate Chemical compound OB(O)[O-] URSLCTBXQMKCFE-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 150000002641 lithium Chemical class 0.000 description 1
- 150000002680 magnesium Chemical class 0.000 description 1
- 239000004941 mixed matrix membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005325 percolation Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000000063 preceeding effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
- C22B26/10—Obtaining alkali metals
- C22B26/12—Obtaining lithium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/04—Halides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D15/00—Lithium compounds
- C01D15/06—Sulfates; Sulfites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/04—Chlorides
- C01D3/06—Preparation by working up brines; seawater or spent lyes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/26—Magnesium halides
- C01F5/30—Chlorides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/38—Magnesium nitrates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/40—Magnesium sulfates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
- C22B3/24—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition by adsorption on solid substances, e.g. by extraction with solid resins
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/42—Treatment or purification of solutions, e.g. obtained by leaching by ion-exchange extraction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Manufacturing & Machinery (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202063023528P | 2020-05-12 | 2020-05-12 | |
| US63/023,528 | 2020-05-12 | ||
| PCT/US2021/032027 WO2021231597A1 (en) | 2020-05-12 | 2021-05-12 | Systems and methods for recovering lithium from brines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3136247A1 CA3136247A1 (en) | 2021-11-12 |
| CA3136247C true CA3136247C (en) | 2022-12-20 |
Family
ID=78511805
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3136247A Active CA3136247C (en) | 2020-05-12 | 2021-05-12 | Systems and methods for recovering lithium from brines |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP3947756A4 (es) |
| CN (1) | CN113924375B (es) |
| AU (1) | AU2021254665B2 (es) |
| CA (1) | CA3136247C (es) |
| IL (1) | IL287465B2 (es) |
| JO (1) | JOP20210311A1 (es) |
| MX (1) | MX2021013733A (es) |
| PE (1) | PE20220205A1 (es) |
| WO (1) | WO2021231597A1 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022177999A1 (en) * | 2021-02-16 | 2022-08-25 | Energy Exploration Technologies, Inc. | Polymeric materials and methods for selective ion separation or transport |
| WO2023215353A1 (en) * | 2022-05-03 | 2023-11-09 | Schlumberger Technology Corporation | Impurity control in lithium recovery |
| WO2023225245A1 (en) * | 2022-05-20 | 2023-11-23 | Schlumberger Technology Corporation | Lithium recovery from precipitated solids |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL118655A0 (en) * | 1995-07-18 | 1996-10-16 | Tarim Associates For Scient Mi | Process for recovery of lithium and other metals and salts from brines |
| US6921522B2 (en) * | 1998-07-16 | 2005-07-26 | Chemetall Foote Corporation | Production of lithium compounds directly from lithium containing brines |
| WO2010006366A1 (en) * | 2008-07-18 | 2010-01-21 | Rincon Lithium Limited | A process for recovering lithium from a brine |
| JP5556450B2 (ja) * | 2010-07-02 | 2014-07-23 | パナソニック株式会社 | 回転式圧縮機 |
| AU2011236094B2 (en) * | 2011-01-20 | 2012-11-29 | Rockwood Lithium Inc. | Production of high purity lithium compounds directly from lithium containing brines |
| JP5791917B2 (ja) * | 2011-02-23 | 2015-10-07 | Jx日鉱日石金属株式会社 | リチウム回収方法 |
| AU2011376865A1 (en) * | 2011-09-15 | 2013-05-02 | Orocobre Limited | Process for producing lithium carbonate from concentrated lithium brine |
| AR083538A1 (es) * | 2011-10-24 | 2013-03-06 | Minera Exar S A | Produccion de carbonato de litio de alta pureza grado de bateria a partir de salmueras naturales o industriales |
| WO2014098357A1 (ko) * | 2012-12-21 | 2014-06-26 | 재단법인 포항산업과학연구원 | 리튬 함유 용액으로부터 리튬을 추출하는 방법 |
| WO2017039724A1 (en) * | 2015-08-28 | 2017-03-09 | Albemarle Corporation | Processes for recovering lithium values from lithium-containing brines |
| US11920211B2 (en) * | 2017-06-26 | 2024-03-05 | Daniel Ernesto Galli | Method for obtaining concentrated brine of minimum impurity content from brine found in natural salt flats and salt marshes, said method having minimum environmental impact and maximum lithium recovery |
| CN110606499A (zh) * | 2018-06-15 | 2019-12-24 | 上海东硕环保科技股份有限公司 | 一种含锂盐湖卤水提锂组合装置 |
| CN109748298A (zh) * | 2019-02-23 | 2019-05-14 | 温州大学新材料与产业技术研究院 | 一种从含锂卤水中自发选择性分离镁富集锂的方法及其装置 |
-
2021
- 2021-05-12 WO PCT/US2021/032027 patent/WO2021231597A1/en unknown
- 2021-05-12 AU AU2021254665A patent/AU2021254665B2/en active Active
- 2021-05-12 EP EP21789600.0A patent/EP3947756A4/en active Pending
- 2021-05-12 MX MX2021013733A patent/MX2021013733A/es unknown
- 2021-05-12 CA CA3136247A patent/CA3136247C/en active Active
- 2021-05-12 JO JOP/2021/0311A patent/JOP20210311A1/ar unknown
- 2021-05-12 PE PE2021001898A patent/PE20220205A1/es unknown
- 2021-05-12 CN CN202180003093.1A patent/CN113924375B/zh active Active
- 2021-05-12 IL IL287465A patent/IL287465B2/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN113924375B (zh) | 2023-04-04 |
| EP3947756A1 (en) | 2022-02-09 |
| PE20220205A1 (es) | 2022-02-01 |
| IL287465B1 (en) | 2023-11-01 |
| AU2021254665B2 (en) | 2022-04-21 |
| CA3136247A1 (en) | 2021-11-12 |
| IL287465B2 (en) | 2024-03-01 |
| WO2021231597A9 (en) | 2022-01-20 |
| IL287465A (en) | 2021-12-01 |
| JOP20210311A1 (ar) | 2023-01-30 |
| AU2021254665A1 (en) | 2021-12-02 |
| WO2021231597A1 (en) | 2021-11-18 |
| EP3947756A4 (en) | 2022-07-06 |
| CN113924375A (zh) | 2022-01-11 |
| MX2021013733A (es) | 2021-12-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US12018347B2 (en) | Systems and methods for recovering lithium from brines | |
| CA3136247C (en) | Systems and methods for recovering lithium from brines | |
| US20220324717A1 (en) | Process for selective adsorption and recovery of lithium from natural and synthetic brines | |
| US20200189925A1 (en) | Process for recovery of lithium from a geothermal brine | |
| CN103074502B (zh) | 用于从高镁锂比的盐湖卤水分离锂的盐湖卤水处理方法 | |
| EP3793945A1 (en) | Process for selective adsorption and recovery of lithium from natural and synthetic brines | |
| US20220144655A1 (en) | Method for concentrating and purifying eluate brine for the production of a purified lithium compound | |
| AU2008222613B2 (en) | A method of treating potash | |
| CN106379919B (zh) | 一种含锂废弃液的综合利用方法 | |
| KR101257434B1 (ko) | 염수로부터 경제적으로 고순도의 인산리튬을 추출하는 방법 | |
| TWI619676B (zh) | 製造氯化鈉鹽水之方法及系統 | |
| CN208008625U (zh) | 一种反渗透浓水的分盐浓缩系统 | |
| CN115676856B (zh) | 一种盐湖提锂方法及系统 | |
| US20240067530A1 (en) | Systems and Methods for Recovering Lithium from Brines Field | |
| Suud et al. | Lithium Extraction Method from Geothermal Brine to Find Suitable Method for Geothermal Fields in Indonesia: A Review | |
| Zhang et al. | Pre-fractionation of potassium ions from brine/bittern by selective electrodialysis: Effect of crucial factors and its preliminary application | |
| KR20230142589A (ko) | 수산화리튬의 직접적인 제조를 위한 시스템 및 방법 | |
| CN106517255A (zh) | 一种降低老卤中镁锂比的装置及方法 | |
| WO2024155455A1 (en) | Solvent extraction for selective lithium recovery | |
| CN116199385A (zh) | 一种水中一价和多价离子的分离方法和盐湖提锂的方法 | |
| CN116024440A (zh) | 一种从硫酸钠亚型盐湖卤水中吸附-萃取提锂的方法 |