CA3121912C - Method of preparing phosphorus-containing flame retardants and their use in polymer compositions - Google Patents

Method of preparing phosphorus-containing flame retardants and their use in polymer compositions Download PDF

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Publication number
CA3121912C
CA3121912C CA3121912A CA3121912A CA3121912C CA 3121912 C CA3121912 C CA 3121912C CA 3121912 A CA3121912 A CA 3121912A CA 3121912 A CA3121912 A CA 3121912A CA 3121912 C CA3121912 C CA 3121912C
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Prior art keywords
flame retardant
metal
zinc
alkyl
oxide
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CA3121912A
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English (en)
French (fr)
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CA3121912A1 (en
Inventor
Simon J. BONYHADY
Julia Yue LEE
Qingliang HE
Ramesh Sharma
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Lanxess Corp
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Lanxess Corp
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/06Phosphorus compounds without P—C bonds
    • C07F9/08Esters of oxyacids of phosphorus
    • C07F9/141Esters of phosphorous acids
    • C07F9/142Esters of phosphorous acids with hydroxyalkyl compounds without further substituents on alkyl
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181Acids containing aromatic rings
    • C08G63/183Terephthalic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G83/00Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • C08G83/008Supramolecular polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/40Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/49Phosphorus-containing compounds
    • C08K5/51Phosphorus bound to oxygen
    • C08K5/53Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317Phosphonic compounds, e.g. R—P(:O)(OR')2
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06Polyamides derived from polyamines and polycarboxylic acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00Fireproofing materials
    • C09K21/06Organic materials
    • C09K21/12Organic materials containing phosphorus
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Fireproofing Substances (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
CA3121912A 2018-12-20 2019-12-18 Method of preparing phosphorus-containing flame retardants and their use in polymer compositions Active CA3121912C (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201862782948P 2018-12-20 2018-12-20
US62/782,948 2018-12-20
US201962923446P 2019-10-18 2019-10-18
US62/923,446 2019-10-18
PCT/US2019/067184 WO2020132075A2 (en) 2018-12-20 2019-12-18 Method of preparing phosphorus-containing flame retardants and their use in polymer compositions

Publications (2)

Publication Number Publication Date
CA3121912A1 CA3121912A1 (en) 2020-06-25
CA3121912C true CA3121912C (en) 2024-06-18

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CA3121912A Active CA3121912C (en) 2018-12-20 2019-12-18 Method of preparing phosphorus-containing flame retardants and their use in polymer compositions

Country Status (13)

Country Link
US (3) US11993622B2 (https=)
EP (1) EP3898818B1 (https=)
JP (1) JP7518077B2 (https=)
KR (2) KR20250052474A (https=)
CN (2) CN113166426B (https=)
AU (1) AU2019402918B2 (https=)
CA (1) CA3121912C (https=)
IL (1) IL284042B2 (https=)
MX (3) MX2021007136A (https=)
PH (1) PH12021551464A1 (https=)
SG (1) SG11202105074RA (https=)
WO (1) WO2020132075A2 (https=)
ZA (1) ZA202103394B (https=)

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MX2022004412A (es) * 2019-10-18 2022-05-20 Lanxess Corp Metodo de preparacion de retardantes de llama que contienen fosforo y su uso en composiciones polimericas.
PL4168511T3 (pl) 2020-06-17 2025-12-08 Lanxess Corporation Środek obniżający palność i stabilizator w kombinacji do zastosowania z tworzywami termoplastycznymi
PH12022553503A1 (en) * 2020-06-17 2024-05-20 Lanxess Corp Antimony trioxide free flame retardant polymer composition
CA3186993A1 (en) * 2020-06-17 2021-12-23 Lanxess Corporation Flame retardant and stabilizer combined for use with thermoplastics
CN112280356B (zh) * 2020-09-30 2021-09-14 先登高科电气有限公司 一种阻燃漆包面涂层用复合阻燃剂及其制备方法和应用
CN113462020B (zh) * 2020-11-06 2022-04-26 江苏利思德新材料有限公司 具有双峰热失重分解特征的基于亚磷酸铝的复合体及其制备和应用
US12358217B2 (en) * 2021-01-08 2025-07-15 Peridot Print Llc Three-dimensional printing with flame retardant
CN117083331A (zh) * 2021-03-26 2023-11-17 朗盛德国有限责任公司 聚酰胺组合物
KR20230162644A (ko) 2021-03-26 2023-11-28 란세스 도이치란트 게엠베하 폴리아미드 조성물
CN117098802A (zh) 2021-03-26 2023-11-21 朗盛德国有限责任公司 聚酰胺组合物
JP2024541517A (ja) 2021-11-26 2024-11-08 ランクセス・コーポレーション 熱可塑性物質とともに使用するための組み合わされた難燃剤及び共力剤
EP4269495A4 (en) * 2022-01-26 2024-09-04 LG Chem, Ltd. THERMOPLASTIC RESIN COMPOSITION, METHOD FOR PRODUCING SAME AND MOLDED BODIES MADE THEREFROM
CN114479183B (zh) * 2022-02-25 2023-06-09 四川金核高分子材料有限公司 一种有机改性羟基锡酸锌-次磷酸盐阻燃剂及其制备方法
KR102501476B1 (ko) * 2022-03-22 2023-02-27 주식회사 유상 난연성 무연신 폴리프로필렌(cpp) 필름 및 이를 포함한 인테리어용 시트
CN114716472A (zh) * 2022-04-08 2022-07-08 青岛长荣化工科技有限公司 一种纺织涂层阻燃剂及其制备方法和应用
CN114524976B (zh) * 2022-04-13 2023-01-13 河南大学 一种m-SiO2@EDTMPA复合材料以及制备方法和应用
JP2025515201A (ja) 2022-05-12 2025-05-13 エンバリオ・ドイチュラント・ゲーエムベーハー 耐クリープ性ポリエステル組成物
CN115536909B (zh) * 2022-06-17 2023-11-17 上海力道新材料科技股份有限公司 一种无卤素阻燃剂组合物及其制备方法、用途
EP4655345A1 (en) 2023-01-27 2025-12-03 LANXESS Corporation Flame retardant and orange colorant combined for use with thermoplastics
WO2025028162A1 (ja) * 2023-08-02 2025-02-06 三菱瓦斯化学株式会社 ポリイミド樹脂組成物、成形体及びその製造方法、金属箔積層板
CN121889459A (zh) 2023-09-20 2026-04-17 朗盛公司 具有改善的粉末特性的含磷阻燃剂的制备方法
CN121712861A (zh) * 2024-03-11 2026-03-20 株式会社Lg化学 阻燃化合物和使用其的阻燃树脂组合物、阻燃产品
WO2026084241A1 (ko) * 2024-10-16 2026-04-23 삼성전자 주식회사 난연 플라스틱 소재 및 이를 포함하는 가전 기기
CN119505529B (zh) * 2024-12-09 2025-05-30 宁波市郎驰新材料科技有限公司 一种耐腐蚀阻燃复合材料管及其制备方法

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Also Published As

Publication number Publication date
KR102803666B1 (ko) 2025-05-08
KR20210107664A (ko) 2021-09-01
EP3898818A2 (en) 2021-10-27
KR20250052474A (ko) 2025-04-18
US12365703B2 (en) 2025-07-22
EP3898818B1 (en) 2026-02-25
JP7518077B2 (ja) 2024-07-17
CN113166426B (zh) 2023-03-10
IL284042A (en) 2021-08-31
ZA202103394B (en) 2022-04-28
MX2021007136A (es) 2021-08-11
AU2019402918B2 (en) 2025-07-10
US12516076B2 (en) 2026-01-06
CN116023410B (zh) 2025-10-17
US20240262852A1 (en) 2024-08-08
IL284042B1 (en) 2025-04-01
WO2020132075A3 (en) 2020-10-15
PH12021551464A1 (en) 2022-04-11
WO2020132075A2 (en) 2020-06-25
JP2022514658A (ja) 2022-02-14
CA3121912A1 (en) 2020-06-25
BR112021011694A2 (pt) 2021-09-08
CN116023410A (zh) 2023-04-28
IL284042B2 (en) 2025-08-01
MX2025013740A (es) 2025-12-01
SG11202105074RA (en) 2021-07-29
AU2019402918A1 (en) 2021-06-10
CN113166426A (zh) 2021-07-23
US20240343745A1 (en) 2024-10-17
US11993622B2 (en) 2024-05-28
MX2025013741A (es) 2025-12-01
US20220073547A1 (en) 2022-03-10

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