CN113166426B - 含磷阻燃剂的制备方法及其在聚合物组合物中的用途 - Google Patents

含磷阻燃剂的制备方法及其在聚合物组合物中的用途 Download PDF

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CN113166426B
CN113166426B CN201980081081.3A CN201980081081A CN113166426B CN 113166426 B CN113166426 B CN 113166426B CN 201980081081 A CN201980081081 A CN 201980081081A CN 113166426 B CN113166426 B CN 113166426B
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metal
flame retardant
alkyl
zinc
aryl
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CN113166426A (zh
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西蒙·J·博尼哈迪
茱莉亚·约·李
何庆亮
拉梅什·夏尔马
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Arlanxeo Canada Inc
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C07F9/142—Esters of phosphorous acids with hydroxyalkyl compounds without further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
    • C08G83/008—Supramolecular polymers
    • C—CHEMISTRY; METALLURGY
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/40—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/14—Glass
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
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    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/06—Organic materials
    • C09K21/12—Organic materials containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Fireproofing Substances (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
CN201980081081.3A 2018-12-20 2019-12-18 含磷阻燃剂的制备方法及其在聚合物组合物中的用途 Active CN113166426B (zh)

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US201862782948P 2018-12-20 2018-12-20
US62/782,948 2018-12-20
US201962923446P 2019-10-18 2019-10-18
US62/923,446 2019-10-18
PCT/US2019/067184 WO2020132075A2 (en) 2018-12-20 2019-12-18 Method of preparing phosphorus-containing flame retardants and their use in polymer compositions

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EP (1) EP3898818B1 (https=)
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KR (2) KR20250052474A (https=)
CN (2) CN113166426B (https=)
AU (1) AU2019402918B2 (https=)
CA (1) CA3121912C (https=)
IL (1) IL284042B2 (https=)
MX (3) MX2021007136A (https=)
PH (1) PH12021551464A1 (https=)
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MX2022004412A (es) * 2019-10-18 2022-05-20 Lanxess Corp Metodo de preparacion de retardantes de llama que contienen fosforo y su uso en composiciones polimericas.
PL4168511T3 (pl) 2020-06-17 2025-12-08 Lanxess Corporation Środek obniżający palność i stabilizator w kombinacji do zastosowania z tworzywami termoplastycznymi
PH12022553503A1 (en) * 2020-06-17 2024-05-20 Lanxess Corp Antimony trioxide free flame retardant polymer composition
CA3186993A1 (en) * 2020-06-17 2021-12-23 Lanxess Corporation Flame retardant and stabilizer combined for use with thermoplastics
CN112280356B (zh) * 2020-09-30 2021-09-14 先登高科电气有限公司 一种阻燃漆包面涂层用复合阻燃剂及其制备方法和应用
CN113462020B (zh) * 2020-11-06 2022-04-26 江苏利思德新材料有限公司 具有双峰热失重分解特征的基于亚磷酸铝的复合体及其制备和应用
US12358217B2 (en) * 2021-01-08 2025-07-15 Peridot Print Llc Three-dimensional printing with flame retardant
CN117083331A (zh) * 2021-03-26 2023-11-17 朗盛德国有限责任公司 聚酰胺组合物
KR20230162644A (ko) 2021-03-26 2023-11-28 란세스 도이치란트 게엠베하 폴리아미드 조성물
CN117098802A (zh) 2021-03-26 2023-11-21 朗盛德国有限责任公司 聚酰胺组合物
JP2024541517A (ja) 2021-11-26 2024-11-08 ランクセス・コーポレーション 熱可塑性物質とともに使用するための組み合わされた難燃剤及び共力剤
EP4269495A4 (en) * 2022-01-26 2024-09-04 LG Chem, Ltd. THERMOPLASTIC RESIN COMPOSITION, METHOD FOR PRODUCING SAME AND MOLDED BODIES MADE THEREFROM
CN114479183B (zh) * 2022-02-25 2023-06-09 四川金核高分子材料有限公司 一种有机改性羟基锡酸锌-次磷酸盐阻燃剂及其制备方法
KR102501476B1 (ko) * 2022-03-22 2023-02-27 주식회사 유상 난연성 무연신 폴리프로필렌(cpp) 필름 및 이를 포함한 인테리어용 시트
CN114716472A (zh) * 2022-04-08 2022-07-08 青岛长荣化工科技有限公司 一种纺织涂层阻燃剂及其制备方法和应用
CN114524976B (zh) * 2022-04-13 2023-01-13 河南大学 一种m-SiO2@EDTMPA复合材料以及制备方法和应用
JP2025515201A (ja) 2022-05-12 2025-05-13 エンバリオ・ドイチュラント・ゲーエムベーハー 耐クリープ性ポリエステル組成物
CN115536909B (zh) * 2022-06-17 2023-11-17 上海力道新材料科技股份有限公司 一种无卤素阻燃剂组合物及其制备方法、用途
EP4655345A1 (en) 2023-01-27 2025-12-03 LANXESS Corporation Flame retardant and orange colorant combined for use with thermoplastics
WO2025028162A1 (ja) * 2023-08-02 2025-02-06 三菱瓦斯化学株式会社 ポリイミド樹脂組成物、成形体及びその製造方法、金属箔積層板
CN121889459A (zh) 2023-09-20 2026-04-17 朗盛公司 具有改善的粉末特性的含磷阻燃剂的制备方法
CN121712861A (zh) * 2024-03-11 2026-03-20 株式会社Lg化学 阻燃化合物和使用其的阻燃树脂组合物、阻燃产品
WO2026084241A1 (ko) * 2024-10-16 2026-04-23 삼성전자 주식회사 난연 플라스틱 소재 및 이를 포함하는 가전 기기
CN119505529B (zh) * 2024-12-09 2025-05-30 宁波市郎驰新材料科技有限公司 一种耐腐蚀阻燃复合材料管及其制备方法

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CN106632468A (zh) * 2016-11-22 2017-05-10 同济大学 氨基三亚甲基膦酸金属盐阻燃剂的制备方法
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US6184405B1 (en) * 1996-11-04 2001-02-06 Ticona Gmbh Process for preparing aluminum salts of organic phosphoric acids
CN103003289A (zh) * 2010-06-24 2013-03-27 Icl-Ip美国公司 金属膦酸酯盐阻燃剂及其制造方法
CN105452264A (zh) * 2014-07-22 2016-03-30 科聚亚公司 含磷的阻燃剂
CN106573776A (zh) * 2014-07-29 2017-04-19 科聚亚公司 焦膦酸的盐作为阻燃剂
CN106632468A (zh) * 2016-11-22 2017-05-10 同济大学 氨基三亚甲基膦酸金属盐阻燃剂的制备方法
CN107189427A (zh) * 2017-06-24 2017-09-22 镇江严彦气体有限公司 一种阻燃聚合物组合物

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KR102803666B1 (ko) 2025-05-08
KR20210107664A (ko) 2021-09-01
EP3898818A2 (en) 2021-10-27
KR20250052474A (ko) 2025-04-18
US12365703B2 (en) 2025-07-22
EP3898818B1 (en) 2026-02-25
JP7518077B2 (ja) 2024-07-17
IL284042A (en) 2021-08-31
ZA202103394B (en) 2022-04-28
MX2021007136A (es) 2021-08-11
AU2019402918B2 (en) 2025-07-10
US12516076B2 (en) 2026-01-06
CN116023410B (zh) 2025-10-17
US20240262852A1 (en) 2024-08-08
IL284042B1 (en) 2025-04-01
WO2020132075A3 (en) 2020-10-15
PH12021551464A1 (en) 2022-04-11
WO2020132075A2 (en) 2020-06-25
JP2022514658A (ja) 2022-02-14
CA3121912A1 (en) 2020-06-25
BR112021011694A2 (pt) 2021-09-08
CN116023410A (zh) 2023-04-28
IL284042B2 (en) 2025-08-01
MX2025013740A (es) 2025-12-01
SG11202105074RA (en) 2021-07-29
CA3121912C (en) 2024-06-18
AU2019402918A1 (en) 2021-06-10
CN113166426A (zh) 2021-07-23
US20240343745A1 (en) 2024-10-17
US11993622B2 (en) 2024-05-28
MX2025013741A (es) 2025-12-01
US20220073547A1 (en) 2022-03-10

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