CA3095924A1 - Emulsifiable concentrate formulations of sdhi fungicides - Google Patents
Emulsifiable concentrate formulations of sdhi fungicides Download PDFInfo
- Publication number
- CA3095924A1 CA3095924A1 CA3095924A CA3095924A CA3095924A1 CA 3095924 A1 CA3095924 A1 CA 3095924A1 CA 3095924 A CA3095924 A CA 3095924A CA 3095924 A CA3095924 A CA 3095924A CA 3095924 A1 CA3095924 A1 CA 3095924A1
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- CA
- Canada
- Prior art keywords
- spp
- composition
- butyl
- phenyl
- sdhi
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 262
- 238000009472 formulation Methods 0.000 title claims abstract description 108
- 239000000417 fungicide Substances 0.000 title claims abstract description 46
- 239000004495 emulsifiable concentrate Substances 0.000 title abstract description 22
- 150000002148 esters Chemical class 0.000 claims abstract description 49
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 44
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 43
- 239000002904 solvent Substances 0.000 claims abstract description 43
- 150000001408 amides Chemical class 0.000 claims abstract description 35
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 31
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 24
- 102000019259 Succinate Dehydrogenase Human genes 0.000 claims abstract description 17
- 108010012901 Succinate Dehydrogenase Proteins 0.000 claims abstract description 17
- 229940124186 Dehydrogenase inhibitor Drugs 0.000 claims abstract description 9
- -1 2-ethyl-hexyl Chemical group 0.000 claims description 67
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 claims description 51
- 150000001875 compounds Chemical class 0.000 claims description 50
- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 claims description 30
- XCGBHLLWJZOLEM-UHFFFAOYSA-N 3-(difluoromethyl)-N-(7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1-methyl-1H-pyrazole-4-carboxamide Chemical compound CC1CC(C)(C)C(C(=CC=2)F)=C1C=2NC(=O)C1=CN(C)N=C1C(F)F XCGBHLLWJZOLEM-UHFFFAOYSA-N 0.000 claims description 30
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- 238000000034 method Methods 0.000 claims description 19
- HRKAMJBPFPHCSD-UHFFFAOYSA-N Tri-isobutylphosphate Chemical compound CC(C)COP(=O)(OCC(C)C)OCC(C)C HRKAMJBPFPHCSD-UHFFFAOYSA-N 0.000 claims description 17
- 239000003112 inhibitor Substances 0.000 claims description 15
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- BQYJATMQXGBDHF-UHFFFAOYSA-N difenoconazole Chemical compound O1C(C)COC1(C=1C(=CC(OC=2C=CC(Cl)=CC=2)=CC=1)Cl)CN1N=CN=C1 BQYJATMQXGBDHF-UHFFFAOYSA-N 0.000 claims description 14
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 claims description 13
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- LDLMOOXUCMHBMZ-UHFFFAOYSA-N bixafen Chemical compound FC(F)C1=NN(C)C=C1C(=O)NC1=CC=C(F)C=C1C1=CC=C(Cl)C(Cl)=C1 LDLMOOXUCMHBMZ-UHFFFAOYSA-N 0.000 claims description 7
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- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 6
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- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 6
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims description 6
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 6
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 6
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 6
- JWUCHKBSVLQQCO-UHFFFAOYSA-N 1-(2-fluorophenyl)-1-(4-fluorophenyl)-2-(1H-1,2,4-triazol-1-yl)ethanol Chemical compound C=1C=C(F)C=CC=1C(C=1C(=CC=CC=1)F)(O)CN1C=NC=N1 JWUCHKBSVLQQCO-UHFFFAOYSA-N 0.000 claims description 5
- RXTJLDXSGNEJIT-UHFFFAOYSA-N 2,3-dihydro-1h-inden-4-amine Chemical compound NC1=CC=CC2=C1CCC2 RXTJLDXSGNEJIT-UHFFFAOYSA-N 0.000 claims description 5
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- WVPGXJOLGGFBCR-UHFFFAOYSA-N trioctyl phosphate Chemical compound CCCCCCCCOP(=O)(OCCCCCCCC)OCCCCCCCC WVPGXJOLGGFBCR-UHFFFAOYSA-N 0.000 claims description 4
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 claims description 3
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- XQMIGRUKENWSIJ-UHFFFAOYSA-N aniline;pyrimidine Chemical class C1=CN=CN=C1.NC1=CC=CC=C1 XQMIGRUKENWSIJ-UHFFFAOYSA-N 0.000 claims description 3
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- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical compound C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 3
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 claims description 3
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- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 claims description 3
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 3
- ONCZDRURRATYFI-TVJDWZFNSA-N trifloxystrobin Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)C1=CC=CC(C(F)(F)F)=C1 ONCZDRURRATYFI-TVJDWZFNSA-N 0.000 claims description 3
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- 229960004546 thiabendazole Drugs 0.000 description 1
- VJQYLJSMBWXGDV-UHFFFAOYSA-N tiadinil Chemical compound N1=NSC(C(=O)NC=2C=C(Cl)C(C)=CC=2)=C1C VJQYLJSMBWXGDV-UHFFFAOYSA-N 0.000 description 1
- HYVWIQDYBVKITD-UHFFFAOYSA-N tolylfluanid Chemical compound CN(C)S(=O)(=O)N(SC(F)(Cl)Cl)C1=CC=C(C)C=C1 HYVWIQDYBVKITD-UHFFFAOYSA-N 0.000 description 1
- 239000011031 topaz Substances 0.000 description 1
- 229910052853 topaz Inorganic materials 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- HSMVPDGQOIQYSR-KGENOOAVSA-N triflumizole Chemical compound C1=CN=CN1C(/COCCC)=N/C1=CC=C(Cl)C=C1C(F)(F)F HSMVPDGQOIQYSR-KGENOOAVSA-N 0.000 description 1
- GSURLQOINUQIIH-UHFFFAOYSA-N triheptyl phosphate Chemical compound CCCCCCCOP(=O)(OCCCCCCC)OCCCCCCC GSURLQOINUQIIH-UHFFFAOYSA-N 0.000 description 1
- SFENPMLASUEABX-UHFFFAOYSA-N trihexyl phosphate Chemical compound CCCCCCOP(=O)(OCCCCCC)OCCCCCC SFENPMLASUEABX-UHFFFAOYSA-N 0.000 description 1
- QJAVUVZBMMXBRO-UHFFFAOYSA-N tripentyl phosphate Chemical compound CCCCCOP(=O)(OCCCCC)OCCCCC QJAVUVZBMMXBRO-UHFFFAOYSA-N 0.000 description 1
- KOWVWXQNQNCRRS-UHFFFAOYSA-N tris(2,4-dimethylphenyl) phosphate Chemical compound CC1=CC(C)=CC=C1OP(=O)(OC=1C(=CC(C)=CC=1)C)OC1=CC=C(C)C=C1C KOWVWXQNQNCRRS-UHFFFAOYSA-N 0.000 description 1
- LIPMRGQQBZJCTM-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C LIPMRGQQBZJCTM-UHFFFAOYSA-N 0.000 description 1
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 1
- KPGXUAIFQMJJFB-UHFFFAOYSA-H tungsten hexachloride Chemical compound Cl[W](Cl)(Cl)(Cl)(Cl)Cl KPGXUAIFQMJJFB-UHFFFAOYSA-H 0.000 description 1
- YNWVFADWVLCOPU-MAUPQMMJSA-N uniconazole P Chemical compound C1=NC=NN1/C([C@@H](O)C(C)(C)C)=C/C1=CC=C(Cl)C=C1 YNWVFADWVLCOPU-MAUPQMMJSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- BCEHBSKCWLPMDN-MGPLVRAMSA-N voriconazole Chemical compound C1([C@H](C)[C@](O)(CN2N=CN=C2)C=2C(=CC(F)=CC=2)F)=NC=NC=C1F BCEHBSKCWLPMDN-MGPLVRAMSA-N 0.000 description 1
- 229960004740 voriconazole Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003799 water insoluble solvent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201862652426P | 2018-04-04 | 2018-04-04 | |
US62/652,426 | 2018-04-04 | ||
PCT/US2019/025854 WO2019195591A1 (en) | 2018-04-04 | 2019-04-04 | Emulsifiable concentrate formulations of sdhi fungicides |
Publications (1)
Publication Number | Publication Date |
---|---|
CA3095924A1 true CA3095924A1 (en) | 2019-10-10 |
Family
ID=66248697
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA3095924A Pending CA3095924A1 (en) | 2018-04-04 | 2019-04-04 | Emulsifiable concentrate formulations of sdhi fungicides |
Country Status (11)
Country | Link |
---|---|
US (1) | US20210195899A1 (de) |
EP (1) | EP3772940A1 (de) |
CN (1) | CN112118737B (de) |
AR (1) | AR114466A1 (de) |
AU (1) | AU2019247835A1 (de) |
BR (1) | BR112020020338A2 (de) |
CA (1) | CA3095924A1 (de) |
CL (1) | CL2020002551A1 (de) |
MX (1) | MX2020010403A (de) |
RU (1) | RU2020136040A (de) |
WO (1) | WO2019195591A1 (de) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AR120687A1 (es) * | 2019-12-05 | 2022-03-09 | Upl Corporation Ltd | Combinaciones fungicidas |
TW202128016A (zh) * | 2019-12-19 | 2021-08-01 | 美商富曼西公司 | 二醯胺懸浮濃縮組合物 |
AU2021221827A1 (en) * | 2021-08-25 | 2023-03-16 | Adama Australia Pty Limited | Highly Loaded Solo Cyclanilide Formulations |
WO2024013735A1 (en) * | 2022-07-13 | 2024-01-18 | Adama Makhteshim Ltd. | Agrochemical composition of sdhi fungicides |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2205590A1 (de) | 1972-02-07 | 1973-08-16 | Hoechst Ag | Verdunstungshemmendes zusatzmittel fuer konzentrierte pflanzenschutzmitteldispersionen |
JPS60224606A (ja) * | 1984-04-23 | 1985-11-09 | Kao Corp | 農薬組成物 |
DE4319263A1 (de) * | 1992-07-03 | 1994-01-05 | Schoenherr Joerg | Pflanzenbehandlungsmittel |
EP0655197B1 (de) * | 1993-11-16 | 1998-07-01 | Bayer Ag | Verwendung von Phosphorsäureestern als Kristallisationsinhibitoren |
DE19823252A1 (de) | 1998-05-26 | 1999-12-02 | Henkel Kgaa | Wäßrige, agrochemische Wirkstoffe enthaltende Mittel |
DE19963381A1 (de) * | 1999-12-28 | 2001-07-12 | Aventis Cropscience Gmbh | Tensid/Lösungsmittel-Systeme |
DE10343872A1 (de) | 2003-09-23 | 2005-04-21 | Bayer Cropscience Ag | Suspensionskonzentrate |
EP1938687A1 (de) * | 2006-12-18 | 2008-07-02 | Bayer CropScience AG | Penetrationsförderer für Fungizide |
NZ603839A (en) | 2010-04-27 | 2014-12-24 | Sumitomo Chemical Co | Pesticidal composition and its use |
JP5782678B2 (ja) | 2010-04-27 | 2015-09-24 | 住友化学株式会社 | 有害生物防除組成物およびその用途 |
UA107591C2 (xx) | 2010-04-27 | 2015-01-26 | Пестицидна композиція і її застосування | |
JP5712504B2 (ja) | 2010-04-27 | 2015-05-07 | 住友化学株式会社 | 有害生物防除組成物およびその用途 |
NZ603845A (en) | 2010-04-27 | 2014-09-26 | Sumitomo Chemical Co | Pesticidal composition and its use |
JP5724210B2 (ja) | 2010-04-28 | 2015-05-27 | 住友化学株式会社 | 植物病害防除組成物およびその用途 |
JP5724212B2 (ja) | 2010-04-28 | 2015-05-27 | 住友化学株式会社 | 植物病害防除組成物およびその用途 |
WO2011135835A1 (en) | 2010-04-28 | 2011-11-03 | Sumitomo Chemical Company, Limited | Plant disease control composition and its use |
JP5789918B2 (ja) | 2010-04-28 | 2015-10-07 | 住友化学株式会社 | 植物病害防除組成物およびその用途 |
NZ603844A (en) | 2010-04-28 | 2014-08-29 | Sumitomo Chemical Co | Pesticidal composition and its use |
CA2797376C (en) | 2010-04-28 | 2018-11-20 | Sumitomo Chemical Company, Limited | Plant disease controlling compositions comprising a carboxamide compound and an azole fungicide |
JP5724211B2 (ja) | 2010-04-28 | 2015-05-27 | 住友化学株式会社 | 植物病害防除組成物およびその用途 |
KR101812361B1 (ko) | 2010-04-28 | 2017-12-26 | 스미또모 가가꾸 가부시키가이샤 | 유해 생물 방제 조성물 및 그의 용도 |
AR083653A1 (es) | 2010-10-25 | 2013-03-13 | Stepan Co | Amidas grasas y derivados de la metatesis de aceites naturales |
IT1403275B1 (it) | 2010-12-20 | 2013-10-17 | Isagro Ricerca Srl | Indanilanilidi ad elevata attività fungicida e loro composizioni fitosanitarie |
WO2012150163A1 (en) * | 2011-05-03 | 2012-11-08 | Basf Se | Adjuvant comprising dimethylsulfoxide and a phosphate ester |
EP2612554A1 (de) | 2012-01-09 | 2013-07-10 | Bayer CropScience AG | Fungizide Zusammensetzungen umfassend Fluopyram, mindestens einer Succinat-Dehydrogenase-Inhibitor und optional mindestens ein Triazol-Fungizid |
ITMI20121045A1 (it) | 2012-06-15 | 2013-12-16 | Isagro Ricerca Srl | Composizioni sinergiche per la protezione di colture agrarie e relativo uso |
CA2898921C (en) * | 2013-03-27 | 2021-01-19 | Basf Se | Emulsifiable concentrate comprising pesticide, alkyl lactate, fatty acid dialkylamide and diester |
JP2016522822A (ja) * | 2013-05-10 | 2016-08-04 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 殺有害生物剤、ラクトン、およびリン酸トリ−c1−c6−アルキルを含む乳化性濃縮物 |
-
2019
- 2019-04-03 AR ARP190100876A patent/AR114466A1/es unknown
- 2019-04-04 CA CA3095924A patent/CA3095924A1/en active Pending
- 2019-04-04 WO PCT/US2019/025854 patent/WO2019195591A1/en unknown
- 2019-04-04 EP EP19718965.7A patent/EP3772940A1/de active Pending
- 2019-04-04 CN CN201980032415.8A patent/CN112118737B/zh active Active
- 2019-04-04 MX MX2020010403A patent/MX2020010403A/es unknown
- 2019-04-04 AU AU2019247835A patent/AU2019247835A1/en active Pending
- 2019-04-04 BR BR112020020338-6A patent/BR112020020338A2/pt active Search and Examination
- 2019-04-04 US US17/045,178 patent/US20210195899A1/en not_active Abandoned
- 2019-04-04 RU RU2020136040A patent/RU2020136040A/ru unknown
-
2020
- 2020-10-01 CL CL2020002551A patent/CL2020002551A1/es unknown
Also Published As
Publication number | Publication date |
---|---|
CN112118737A (zh) | 2020-12-22 |
RU2020136040A (ru) | 2022-05-05 |
WO2019195591A1 (en) | 2019-10-10 |
CN112118737B (zh) | 2022-10-28 |
EP3772940A1 (de) | 2021-02-17 |
MX2020010403A (es) | 2021-01-08 |
US20210195899A1 (en) | 2021-07-01 |
AU2019247835A1 (en) | 2020-10-22 |
BR112020020338A2 (pt) | 2021-03-30 |
CL2020002551A1 (es) | 2021-02-05 |
AR114466A1 (es) | 2020-09-09 |
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