CA2992816A1 - Polyethylene terephtalate renforce de graphene - Google Patents

Polyethylene terephtalate renforce de graphene Download PDF

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Publication number
CA2992816A1
CA2992816A1 CA2992816A CA2992816A CA2992816A1 CA 2992816 A1 CA2992816 A1 CA 2992816A1 CA 2992816 A CA2992816 A CA 2992816A CA 2992816 A CA2992816 A CA 2992816A CA 2992816 A1 CA2992816 A1 CA 2992816A1
Authority
CA
Canada
Prior art keywords
pet
graphene
nanocomposites
ultrasound
polyethylene terephthalate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2992816A
Other languages
English (en)
Inventor
Jay Clarke Hanan
Sudheer BANDLA
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Niagara Bottling LLC
Original Assignee
Niagara Bottling LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US15/073,477 external-priority patent/US9957360B2/en
Priority claimed from US15/203,668 external-priority patent/US10737418B2/en
Application filed by Niagara Bottling LLC filed Critical Niagara Bottling LLC
Publication of CA2992816A1 publication Critical patent/CA2992816A1/fr
Abandoned legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/002Methods
    • B29B7/007Methods for continuous mixing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58Component parts, details or accessories; Auxiliary operations
    • B29B7/72Measuring, controlling or regulating
    • B29B7/726Measuring properties of mixture, e.g. temperature or density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/80Component parts, details or accessories; Auxiliary operations
    • B29B7/88Adding charges, i.e. additives
    • B29B7/90Fillers or reinforcements, e.g. fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/0001Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/20Compounding polymers with additives, e.g. colouring
    • C08J3/22Compounding polymers with additives, e.g. colouring using masterbatch techniques
    • C08J3/226Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • C08K3/042Graphene or derivatives, e.g. graphene oxides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/34Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices
    • B29B7/38Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary
    • B29B7/46Mixing; Kneading continuous, with mechanical mixing or kneading devices with movable mixing or kneading devices rotary with more than one shaft
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/003PET, i.e. poylethylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16Fillers
    • B29K2105/162Nanoparticles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2507/00Use of elements other than metals as filler
    • B29K2507/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2367/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2367/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

La présente invention concerne une composition et un procédé pour obtenir du polyéthylène téréphtalate renforcé de graphène (PET). Des nanodisquettes de graphène (GNP) comprenant du graphène multicouche sont utilisées pour renforcer le PET, permettant ainsi d'améliorer les propriétés du PET pour diverses nouvelles applications. Des mélanges maîtres comprenant du polyéthylène téréphtalate présentant des nanodisquettes de graphène dispersées sont obtenus par mélange. Les mélanges maîtres sont utilisés pour former des nanocomposites PET-GNP selon des fractions pondérales comprises entre 0,5 % et 15 %. Dans certains modes de réalisation, le PET et les GNP sont soumis à un mélange par fusion par extrusion double vis. Dans certains modes de réalisation, un dispositif à ultrasons est couplé à une extrudeuse double vis de manière à faciliter le mélange par fusion. Dans certains modes de réalisation, les nanocomposites PET-GNP sont préparés au moyen d'un moulage par injection à grande vitesse. Les nanocomposites PET-GNP sont comparés suivant leurs propriétés mécaniques, thermiques et rhéologiques de manière à distinguer différents procédés de mélange.
CA2992816A 2015-07-08 2016-07-07 Polyethylene terephtalate renforce de graphene Abandoned CA2992816A1 (fr)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US201562190193P 2015-07-08 2015-07-08
US62/190,193 2015-07-08
US15/073,477 2016-03-17
US15/073,477 US9957360B2 (en) 2015-03-17 2016-03-17 Graphene reinforced polyethylene terephthalate
US15/203,668 US10737418B2 (en) 2015-03-17 2016-07-06 Graphene reinforced polyethylene terephthalate
US15/203,668 2016-07-06
PCT/US2016/041368 WO2017007953A1 (fr) 2015-07-08 2016-07-07 Polyéthylène téréphtalate renforcé de graphène

Publications (1)

Publication Number Publication Date
CA2992816A1 true CA2992816A1 (fr) 2017-01-12

Family

ID=57685938

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2992816A Abandoned CA2992816A1 (fr) 2015-07-08 2016-07-07 Polyethylene terephtalate renforce de graphene

Country Status (9)

Country Link
EP (1) EP3320036A4 (fr)
JP (1) JP6742580B2 (fr)
KR (1) KR20180040579A (fr)
CN (1) CN108350210A (fr)
AU (1) AU2016290096A1 (fr)
CA (1) CA2992816A1 (fr)
CO (1) CO2018001016A2 (fr)
MX (1) MX2018000002A (fr)
WO (1) WO2017007953A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3946878A4 (fr) * 2019-04-01 2022-12-21 Niagara Bottling, LLC Composite de polyéthylène téréphtalate et de graphène pour améliorer la consommation d'énergie de réchauffage

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* Cited by examiner, † Cited by third party
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CN107383395A (zh) * 2017-04-24 2017-11-24 劳富文 Pet材料的石墨烯色母料制作方法
JP7319198B2 (ja) * 2017-05-31 2023-08-01 ナノエクスプローラ インコーポレイテッド 超臨界流体を使用してポリマー母材中に黒鉛材料を剥離し分散させる方法
GB201715387D0 (en) 2017-09-22 2017-11-08 Cambridge Entpr Ltd Treatment of polymer particles
EP3790734A4 (fr) * 2018-05-09 2022-02-23 Niagara Bottling, LLC Nanocomposites de poly(téréphtalate d'éthylène)-graphène à dispersion améliorée
US20200002470A1 (en) * 2018-05-09 2020-01-02 Niagara Bottling, Llc Poly(ethylene terephthalate)-graphene nanocomposites from improved dispersion
CN110963486A (zh) * 2018-09-28 2020-04-07 浙江大学 一种基于方华层增强石墨烯与柔性基底界面的方法
CN110000947B (zh) * 2019-03-13 2023-12-22 华南理工大学 一种用于在线检测偏心转子挤出机共混效果的装置及方法
EP3980375A1 (fr) * 2019-06-05 2022-04-13 Cabot Corporation Oxyde de graphène réduit densifié et procédés de production
KR20220139905A (ko) * 2020-02-06 2022-10-17 라이텐, 인코포레이티드 복합 물질 시스템
JP2021187928A (ja) * 2020-05-28 2021-12-13 慧隆科技股▲ふん▼有限公司 グラフェンポリエステルチップ及びグラフェンダイヤフラムの製造方法

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EP2029265B1 (fr) * 2006-06-05 2013-08-14 The University of Akron Procédé et appareil en continu assisté par ultrasons pour la dispersion de nanofibres et de nanotubes dans des polymères
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3946878A4 (fr) * 2019-04-01 2022-12-21 Niagara Bottling, LLC Composite de polyéthylène téréphtalate et de graphène pour améliorer la consommation d'énergie de réchauffage

Also Published As

Publication number Publication date
CO2018001016A2 (es) 2018-04-30
WO2017007953A9 (fr) 2017-02-09
JP6742580B2 (ja) 2020-08-19
CN108350210A (zh) 2018-07-31
JP2018520917A (ja) 2018-08-02
AU2016290096A1 (en) 2018-01-25
WO2017007953A1 (fr) 2017-01-12
KR20180040579A (ko) 2018-04-20
MX2018000002A (es) 2019-01-31
EP3320036A4 (fr) 2018-12-26
EP3320036A1 (fr) 2018-05-16

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Legal Events

Date Code Title Description
FZDE Discontinued

Effective date: 20220928

FZDE Discontinued

Effective date: 20220928