CA2991680C - Chemical absorbent composition - Google Patents
Chemical absorbent composition Download PDFInfo
- Publication number
- CA2991680C CA2991680C CA2991680A CA2991680A CA2991680C CA 2991680 C CA2991680 C CA 2991680C CA 2991680 A CA2991680 A CA 2991680A CA 2991680 A CA2991680 A CA 2991680A CA 2991680 C CA2991680 C CA 2991680C
- Authority
- CA
- Canada
- Prior art keywords
- metal
- bicarbonate
- carbonate
- metal carbonate
- particulate composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims abstract description 70
- 239000002250 absorbent Substances 0.000 title description 16
- 230000002745 absorbent Effects 0.000 title description 16
- 239000000126 substance Substances 0.000 title description 2
- 229910052751 metal Inorganic materials 0.000 claims abstract description 82
- 239000002184 metal Substances 0.000 claims abstract description 82
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 50
- 150000001875 compounds Chemical class 0.000 claims abstract description 31
- 238000000034 method Methods 0.000 claims abstract description 31
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims abstract description 27
- 239000004411 aluminium Substances 0.000 claims abstract description 21
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 21
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical class OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 14
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 13
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 23
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 22
- 239000002245 particle Substances 0.000 claims description 22
- 239000011230 binding agent Substances 0.000 claims description 16
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 11
- -1 alkaline earth metal carbonate Chemical class 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical group [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 5
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 238000005469 granulation Methods 0.000 claims description 4
- 230000003179 granulation Effects 0.000 claims description 4
- 229910000028 potassium bicarbonate Inorganic materials 0.000 claims description 4
- 235000015497 potassium bicarbonate Nutrition 0.000 claims description 4
- 239000011736 potassium bicarbonate Substances 0.000 claims description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 4
- 235000011181 potassium carbonates Nutrition 0.000 claims description 4
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical group [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 238000001125 extrusion Methods 0.000 claims description 2
- 239000008187 granular material Substances 0.000 description 20
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 11
- 150000004684 trihydrates Chemical class 0.000 description 10
- 229910001679 gibbsite Inorganic materials 0.000 description 8
- 235000017550 sodium carbonate Nutrition 0.000 description 8
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 6
- 229960000892 attapulgite Drugs 0.000 description 5
- 239000004927 clay Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910052625 palygorskite Inorganic materials 0.000 description 5
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- 150000001450 anions Chemical class 0.000 description 3
- 238000001354 calcination Methods 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 229910001948 sodium oxide Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 150000001399 aluminium compounds Chemical class 0.000 description 2
- 229910001593 boehmite Inorganic materials 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 2
- 229910001502 inorganic halide Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 150000002736 metal compounds Chemical class 0.000 description 2
- 150000004682 monohydrates Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000002594 sorbent Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001350 alkyl halides Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 229940077746 antacid containing aluminium compound Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910001680 bayerite Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- XFWJKVMFIVXPKK-UHFFFAOYSA-N calcium;oxido(oxo)alumane Chemical compound [Ca+2].[O-][Al]=O.[O-][Al]=O XFWJKVMFIVXPKK-UHFFFAOYSA-N 0.000 description 1
- NKCVNYJQLIWBHK-UHFFFAOYSA-N carbonodiperoxoic acid Chemical compound OOC(=O)OO NKCVNYJQLIWBHK-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000004691 decahydrates Chemical class 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004688 heptahydrates Chemical class 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 150000003388 sodium compounds Chemical class 0.000 description 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
Classifications
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- B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
- B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
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- B01J20/0248—Compounds of B, Al, Ga, In, Tl
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/003—Specific sorbent material, not covered by C10G25/02 or C10G25/03
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- B01D2257/20—Halogens or halogen compounds
- B01D2257/206—Organic halogen compounds
- B01D2257/2064—Chlorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2220/00—Aspects relating to sorbent materials
- B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
- B01J2220/42—Materials comprising a mixture of inorganic materials
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Gas Separation By Absorption (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1513836.5 | 2015-08-05 | ||
| GBGB1513836.5A GB201513836D0 (en) | 2015-08-05 | 2015-08-05 | Chemical absorbent composition |
| PCT/GB2016/052099 WO2017021684A1 (en) | 2015-08-05 | 2016-07-12 | Chemical absorbent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2991680A1 CA2991680A1 (en) | 2017-02-09 |
| CA2991680C true CA2991680C (en) | 2023-09-26 |
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| Application Number | Title | Priority Date | Filing Date |
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| CA2991680A Active CA2991680C (en) | 2015-08-05 | 2016-07-12 | Chemical absorbent composition |
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|---|---|
| US (1) | US11045784B2 (enExample) |
| EP (1) | EP3331645B1 (enExample) |
| JP (2) | JP6917358B2 (enExample) |
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| CN (1) | CN107921408A (enExample) |
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| GB (2) | GB201513836D0 (enExample) |
| MY (1) | MY184767A (enExample) |
| PT (1) | PT3331645T (enExample) |
| WO (1) | WO2017021684A1 (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020044474A (ja) | 2018-09-18 | 2020-03-26 | クラリアント触媒株式会社 | 有機ハロゲン化合物の吸収剤、それを用いた炭化水素ガスからの有機ハロゲン化合物の除去方法、その方法を用いたハロゲン化合物の吸収装置、及び炭化水素ガスの製造方法 |
| CN111408336A (zh) * | 2020-03-18 | 2020-07-14 | 鲁西催化剂有限公司 | 一种氧化铝脱氯剂及其制备方法 |
| EP4284547A1 (en) | 2021-01-29 | 2023-12-06 | Sud Chemie India Pvt. Ltd. | Low-cost novel adsorbent with high chloride removal capacity |
| WO2024135611A1 (ja) * | 2022-12-21 | 2024-06-27 | 日揮触媒化成株式会社 | 炭化水素プロセス流処理用のハロゲン吸着剤 |
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| GB9403260D0 (en) | 1994-02-21 | 1994-04-13 | Ici Plc | Absorbents |
| GB9802439D0 (en) | 1998-02-06 | 1998-04-01 | Ici Plc | Absorbents |
| JPH11262662A (ja) * | 1998-03-18 | 1999-09-28 | Nittetsu Mining Co Ltd | 有害物質除去剤およびその製造方法 |
| JP2002336646A (ja) | 2001-05-16 | 2002-11-26 | Taiheiyo Cement Corp | 排煙処理剤および使用済み排煙処理剤の処理方法 |
| JP4111137B2 (ja) * | 2001-10-12 | 2008-07-02 | 旭硝子株式会社 | ハロゲン系ガスの除去方法 |
| KR20070087600A (ko) * | 2004-12-13 | 2007-08-28 | 아사히 가라스 가부시키가이샤 | 할로겐계 가스의 제거 방법 및 할로겐계 가스의 제거제 |
| US7758837B2 (en) * | 2005-05-06 | 2010-07-20 | Uop Llc | Scavengers for removal of acid gases from fluid streams |
| US20070116620A1 (en) * | 2005-11-21 | 2007-05-24 | Kanazirev Vladislav I | Halide scavengers for high temperature applications |
| CN101448561A (zh) * | 2006-05-19 | 2009-06-03 | 旭硝子株式会社 | 卤素类气体的除去方法及卤素类气体的除去剂 |
| US7790130B2 (en) | 2007-08-31 | 2010-09-07 | Uop Llc | Wide mesoporous alumina composites having trimodal pore structure |
| CN101773768A (zh) * | 2010-03-16 | 2010-07-14 | 长春惠工净化工业有限公司 | 从气体中脱除HCl的干法脱氯剂及其制备方法 |
| DE102013005497B4 (de) | 2013-03-28 | 2017-05-04 | Fels-Werke Gmbh | Granulat zur Absorption von Schadgasen und Verfahren zu dessen Herstellung |
| CN103830996B (zh) * | 2014-02-18 | 2015-08-26 | 东南大学 | 脱除HCl气体的中高温脱氯剂及其制备方法 |
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2016
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- 2016-07-12 ES ES16741117T patent/ES2765985T3/es active Active
- 2016-07-12 CN CN201680045846.4A patent/CN107921408A/zh active Pending
- 2016-07-12 MY MYPI2018700408A patent/MY184767A/en unknown
- 2016-07-12 JP JP2018505585A patent/JP6917358B2/ja active Active
- 2016-07-12 GB GB1612053.7A patent/GB2542659B/en active Active
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- 2016-07-12 PT PT167411172T patent/PT3331645T/pt unknown
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- 2016-07-12 CA CA2991680A patent/CA2991680C/en active Active
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2021
- 2021-03-19 JP JP2021046206A patent/JP2021107077A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| EP3331645A1 (en) | 2018-06-13 |
| CA2991680A1 (en) | 2017-02-09 |
| JP2018523572A (ja) | 2018-08-23 |
| GB201513836D0 (en) | 2015-09-16 |
| WO2017021684A1 (en) | 2017-02-09 |
| GB2542659B (en) | 2020-03-25 |
| JP6917358B2 (ja) | 2021-08-11 |
| JP2021107077A (ja) | 2021-07-29 |
| GB2542659A (en) | 2017-03-29 |
| PT3331645T (pt) | 2020-02-04 |
| US20180214844A1 (en) | 2018-08-02 |
| CN107921408A (zh) | 2018-04-17 |
| KR20180037195A (ko) | 2018-04-11 |
| MY184767A (en) | 2021-04-21 |
| EP3331645B1 (en) | 2019-10-30 |
| KR102532959B1 (ko) | 2023-05-16 |
| US11045784B2 (en) | 2021-06-29 |
| ES2765985T3 (es) | 2020-06-11 |
| GB201612053D0 (en) | 2016-08-24 |
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