CA2928148C - Process for the ruthenium catalyzed trans-selective hydrostannation of alkynes - Google Patents

Process for the ruthenium catalyzed trans-selective hydrostannation of alkynes Download PDF

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Publication number
CA2928148C
CA2928148C CA2928148A CA2928148A CA2928148C CA 2928148 C CA2928148 C CA 2928148C CA 2928148 A CA2928148 A CA 2928148A CA 2928148 A CA2928148 A CA 2928148A CA 2928148 C CA2928148 C CA 2928148C
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Canada
Prior art keywords
alkyl
optionally
substituents
chain
carbon atoms
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Active
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CA2928148A
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English (en)
French (fr)
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CA2928148A1 (en
Inventor
Alois Furstner
Stephan Rummelt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Studiengesellschaft Kohle gGmbH
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Studiengesellschaft Kohle gGmbH
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Publication of CA2928148A1 publication Critical patent/CA2928148A1/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22—Tin compounds
    • C07F7/2208—Compounds having tin linked only to carbon, hydrogen and/or halogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA2928148A 2013-10-22 2014-10-14 Process for the ruthenium catalyzed trans-selective hydrostannation of alkynes Active CA2928148C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP20130189792 EP2865684A1 (en) 2013-10-22 2013-10-22 Process for the ruthenium catalyzed trans-selective hydrostannation of alkynes
EP13189792.8 2013-10-22
PCT/EP2014/072068 WO2015059006A1 (en) 2013-10-22 2014-10-14 Process for the ruthenium catalyzed trans-selective hydrostannation of alkynes

Publications (2)

Publication Number Publication Date
CA2928148A1 CA2928148A1 (en) 2015-04-30
CA2928148C true CA2928148C (en) 2020-10-13

Family

ID=49484142

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2928148A Active CA2928148C (en) 2013-10-22 2014-10-14 Process for the ruthenium catalyzed trans-selective hydrostannation of alkynes

Country Status (8)

Country Link
US (1) US9556209B2 (https=)
EP (2) EP2865684A1 (https=)
JP (1) JP6499646B2 (https=)
CN (1) CN105940007B (https=)
CA (1) CA2928148C (https=)
DK (1) DK3060571T3 (https=)
ES (1) ES2659775T3 (https=)
WO (1) WO2015059006A1 (https=)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3438077A1 (en) * 2017-07-31 2019-02-06 Studiengesellschaft Kohle mbH Process for deoxyfluorination of phenols
CN116947915A (zh) * 2022-04-14 2023-10-27 北京理工大学 一种铝氢催化的乙烯基锡烷化合物的制备方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0826047B2 (ja) * 1994-03-22 1996-03-13 工業技術院長 ビニルスタナン類の製造方法
US20080300288A1 (en) * 2005-06-30 2008-12-04 Purdue Research Foundation Alkenyldiarylmethanes, Fused Analogs And Syntheses Thereof

Also Published As

Publication number Publication date
US20160251382A1 (en) 2016-09-01
CN105940007A (zh) 2016-09-14
EP2865684A1 (en) 2015-04-29
EP3060571A1 (en) 2016-08-31
CA2928148A1 (en) 2015-04-30
JP6499646B2 (ja) 2019-04-10
US9556209B2 (en) 2017-01-31
CN105940007B (zh) 2019-08-09
WO2015059006A1 (en) 2015-04-30
EP3060571B1 (en) 2017-12-06
DK3060571T3 (en) 2018-03-12
ES2659775T3 (es) 2018-03-19
JP2016536301A (ja) 2016-11-24

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