CA2899313C - Foamable hot melt adhesive compositions and use thereof - Google Patents
Foamable hot melt adhesive compositions and use thereof Download PDFInfo
- Publication number
- CA2899313C CA2899313C CA2899313A CA2899313A CA2899313C CA 2899313 C CA2899313 C CA 2899313C CA 2899313 A CA2899313 A CA 2899313A CA 2899313 A CA2899313 A CA 2899313A CA 2899313 C CA2899313 C CA 2899313C
- Authority
- CA
- Canada
- Prior art keywords
- adhesive
- hot melt
- foamed
- melt adhesive
- foamed adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004831 Hot glue Substances 0.000 title claims abstract description 79
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 239000000853 adhesive Substances 0.000 claims abstract description 119
- 230000001070 adhesive effect Effects 0.000 claims abstract description 119
- 229920001400 block copolymer Polymers 0.000 claims description 33
- 229920000642 polymer Polymers 0.000 claims description 26
- 210000000497 foam cell Anatomy 0.000 claims description 23
- 238000002844 melting Methods 0.000 claims description 12
- 230000008018 melting Effects 0.000 claims description 11
- 229920000098 polyolefin Polymers 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 8
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 8
- 239000004014 plasticizer Substances 0.000 claims description 8
- 239000000155 melt Substances 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 239000004711 α-olefin Substances 0.000 claims description 6
- 239000004005 microsphere Substances 0.000 claims description 5
- 239000004604 Blowing Agent Substances 0.000 claims description 4
- 239000004156 Azodicarbonamide Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 claims description 3
- 235000019399 azodicarbonamide Nutrition 0.000 claims description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 3
- CZGWDPMDAIPURF-UHFFFAOYSA-N (4,6-dihydrazinyl-1,3,5-triazin-2-yl)hydrazine Chemical compound NNC1=NC(NN)=NC(NN)=N1 CZGWDPMDAIPURF-UHFFFAOYSA-N 0.000 claims description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 claims description 2
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 2
- VYFOAVADNIHPTR-UHFFFAOYSA-N isatoic anhydride Chemical compound NC1=CC=CC=C1CO VYFOAVADNIHPTR-UHFFFAOYSA-N 0.000 claims description 2
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide Chemical compound NNC(N)=O DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 claims description 2
- MARUHZGHZWCEQU-UHFFFAOYSA-N 5-phenyl-2h-tetrazole Chemical compound C1=CC=CC=C1C1=NNN=N1 MARUHZGHZWCEQU-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 18
- 238000005187 foaming Methods 0.000 abstract description 13
- 238000004806 packaging method and process Methods 0.000 abstract description 6
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- 239000006260 foam Substances 0.000 description 27
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- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 13
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 13
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- 229920000573 polyethylene Polymers 0.000 description 6
- 235000007586 terpenes Nutrition 0.000 description 6
- 239000011324 bead Substances 0.000 description 5
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- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 150000003505 terpenes Chemical class 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
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- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
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- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 2
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- 125000005498 phthalate group Chemical class 0.000 description 2
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- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- LOXRGHGHQYWXJK-UHFFFAOYSA-N 1-octylsulfanyloctane Chemical group CCCCCCCCSCCCCCCCC LOXRGHGHQYWXJK-UHFFFAOYSA-N 0.000 description 1
- KJUGUADJHNHALS-UHFFFAOYSA-N 1H-tetrazole Substances C=1N=NNN=1 KJUGUADJHNHALS-UHFFFAOYSA-N 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
- VYWRBUBXZALATG-UHFFFAOYSA-N 2-hydroxyoctadecanamide Chemical compound CCCCCCCCCCCCCCCCC(O)C(N)=O VYWRBUBXZALATG-UHFFFAOYSA-N 0.000 description 1
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- YFHKLSPMRRWLKI-UHFFFAOYSA-N 2-tert-butyl-4-(3-tert-butyl-4-hydroxy-5-methylphenyl)sulfanyl-6-methylphenol Chemical compound CC(C)(C)C1=C(O)C(C)=CC(SC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 YFHKLSPMRRWLKI-UHFFFAOYSA-N 0.000 description 1
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 description 1
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 1
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- 239000012790 adhesive layer Substances 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
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| US9657200B2 (en) | 2012-09-27 | 2017-05-23 | Henkel IP & Holding GmbH | Waterborne adhesives for reduced basis weight multilayer substrates and use thereof |
| US9738817B2 (en) | 2012-10-09 | 2017-08-22 | Avery Dennison Corporation | Adhesives and related methods |
| CN109705391B (zh) * | 2014-08-17 | 2021-08-24 | 弗麦提克有限责任公司 | 自发泡热熔粘合剂组合物以及制成并且使用它们的方法 |
| US10279361B2 (en) | 2014-08-17 | 2019-05-07 | Foammatick, Llc | Self-foaming hot melt adhesive compositions and methods of making and using same |
| CN107109170B (zh) | 2014-08-21 | 2020-01-17 | 陶氏环球技术有限责任公司 | 包括嵌段复合物相容剂的热熔性粘合剂组合物 |
| CN107207913A (zh) * | 2014-12-18 | 2017-09-26 | 汉高知识产权控股有限责任公司 | 可发泡热熔性垫片密封剂及其用途 |
| WO2016127056A1 (en) | 2015-02-05 | 2016-08-11 | Avery Dennison Corporation | Label assemblies for adverse environments |
| KR102092951B1 (ko) * | 2016-03-21 | 2020-03-25 | 주식회사 엘지화학 | 양면 점착 테이프용 기재 필름 및 이의 제조방법 |
| EP3238931A1 (en) * | 2016-04-29 | 2017-11-01 | Segezha Packaging A/S | Adhesive application process |
| CN106167686B (zh) * | 2016-09-05 | 2018-10-26 | 东莞市魔丽身段服装有限公司 | 一种发泡热熔粘胶及一种隐形文胸 |
| WO2018118767A1 (en) | 2016-12-22 | 2018-06-28 | Avery Dennison Corporation | Convertible pressure sensitive adhesives comprising urethane (meth) acrylate oligomers |
| TWI714815B (zh) * | 2016-12-26 | 2021-01-01 | 日商迪愛生股份有限公司 | 物品、物品之製造方法及空隙之填充方法 |
| CN110691834B (zh) | 2017-05-22 | 2021-11-05 | H.B.富乐公司 | 热熔融粘合剂组合物 |
| WO2019018523A1 (en) | 2017-07-18 | 2019-01-24 | Henkel IP & Holding GmbH | DIELECTRIC HEATING OF EXPANDABLE COMPOSITIONS |
| US11926134B2 (en) | 2017-08-25 | 2024-03-12 | Henkel Ag & Co. Kgaa | Process for forming improved protective eco-friendly pouch and packaging and products made therefrom |
| US12157619B2 (en) | 2017-08-25 | 2024-12-03 | Henkel Ag & Co. Kgaa | Process for forming improved protective eco-friendly pouch and packaging and products made therefrom |
| CN108300388A (zh) * | 2018-01-24 | 2018-07-20 | 广东荣嘉新材料科技有限公司 | 一种针对封装物流快递纸箱的环保型热熔胶及其制备方法与应用 |
| CN108395872A (zh) * | 2018-01-24 | 2018-08-14 | 广东荣嘉新材料科技有限公司 | 一种可贴合生物降解快递袋的环保型热熔胶及其制备方法与应用 |
| EP3527361A1 (de) | 2018-02-16 | 2019-08-21 | Henkel AG & Co. KGaA | Verfahren zur herstellung eines mehrschichtigen substrats |
| CN110951417A (zh) * | 2018-09-26 | 2020-04-03 | 东莞市台煜塑胶科技有限公司 | 一种发泡热熔胶及制作工艺 |
| CN109468106A (zh) * | 2018-11-12 | 2019-03-15 | 重庆迅昌汽车零部件有限公司 | 一种发泡热熔胶的制备方法 |
| CN109943079A (zh) * | 2019-03-18 | 2019-06-28 | 军事科学院系统工程研究院军需工程技术研究所 | 一种聚酰胺弹性体发泡材料及其制备方法 |
| CN110804408B (zh) * | 2019-11-21 | 2021-10-29 | 佛山南宝高盛高新材料有限公司 | 一种填充密封热熔胶及制备方法与应用 |
| US20230002651A1 (en) * | 2019-12-06 | 2023-01-05 | Bostik, Inc. | Hot melt pressure sensitive adhesives based on ethylene-acrylate block copolymers |
| WO2021130619A1 (en) * | 2019-12-23 | 2021-07-01 | 3M Innovative Properties Company | Core-sheath filaments including blowing agent |
| US20240416634A1 (en) * | 2023-06-16 | 2024-12-19 | H.B. Fuller Company | Impact absorbing material and method of forming |
| WO2025052688A1 (ja) * | 2023-09-07 | 2025-03-13 | 株式会社ユポ・コーポレーション | ラベル付き成形体 |
| DE102023132977A1 (de) * | 2023-11-27 | 2025-05-28 | Tesa Se | Schäumbare Haftklebeformulierung enthaltend hydrierte Vinylaromatenblockcopolymere |
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-
2013
- 2013-12-31 WO PCT/US2013/078446 patent/WO2014116395A1/en not_active Ceased
- 2013-12-31 EP EP13872511.4A patent/EP2948512B1/en active Active
- 2013-12-31 BR BR112015017383A patent/BR112015017383A2/pt not_active Application Discontinuation
- 2013-12-31 CN CN201380071320.XA patent/CN105308140B/zh active Active
- 2013-12-31 JP JP2015555170A patent/JP6443634B2/ja not_active Expired - Fee Related
- 2013-12-31 CA CA2899313A patent/CA2899313C/en active Active
- 2013-12-31 KR KR1020157020341A patent/KR102181725B1/ko not_active Expired - Fee Related
- 2013-12-31 RU RU2015135327A patent/RU2015135327A/ru not_active Application Discontinuation
-
2015
- 2015-07-23 US US14/806,785 patent/US10336920B2/en active Active
-
2019
- 2019-05-20 US US16/416,620 patent/US20190270917A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP2948512B1 (en) | 2023-07-05 |
| CA2899313A1 (en) | 2014-07-31 |
| WO2014116395A1 (en) | 2014-07-31 |
| CN105308140B (zh) | 2019-11-05 |
| RU2015135327A (ru) | 2017-03-03 |
| US20190270917A1 (en) | 2019-09-05 |
| BR112015017383A2 (pt) | 2017-07-11 |
| CN105308140A (zh) | 2016-02-03 |
| US20150322301A1 (en) | 2015-11-12 |
| JP6443634B2 (ja) | 2018-12-26 |
| JP2016505700A (ja) | 2016-02-25 |
| KR102181725B1 (ko) | 2020-11-24 |
| EP2948512A4 (en) | 2016-11-16 |
| EP2948512A1 (en) | 2015-12-02 |
| KR20160006660A (ko) | 2016-01-19 |
| US10336920B2 (en) | 2019-07-02 |
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