CA2878305C - Film with low ocs gel index - Google Patents

Film with low ocs gel index Download PDF

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Publication number
CA2878305C
CA2878305C CA2878305A CA2878305A CA2878305C CA 2878305 C CA2878305 C CA 2878305C CA 2878305 A CA2878305 A CA 2878305A CA 2878305 A CA2878305 A CA 2878305A CA 2878305 C CA2878305 C CA 2878305C
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Canada
Prior art keywords
polypropylene
melt
melt strength
range
linear
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Active
Application number
CA2878305A
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English (en)
French (fr)
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CA2878305A1 (en
Inventor
Katja Klimke
Hermann Braun
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Borealis GmbH
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Borealis GmbH
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Publication of CA2878305A1 publication Critical patent/CA2878305A1/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/52—Polymerisation initiated by wave energy or particle radiation by electric discharge, e.g. voltolisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/54—Polymerisation initiated by wave energy or particle radiation by X-rays or electrons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2351/00—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2351/06—Characterised by the use of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L2023/40—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with compounds changing molecular weight
    • C08L2023/42—Depolymerisation, vis-breaking or degradation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/16—Applications used for films
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/07—Long chain branching

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CA2878305A 2012-07-25 2013-07-19 Film with low ocs gel index Active CA2878305C (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP12177878.1 2012-07-25
EP12177878 2012-07-25
PCT/EP2013/065263 WO2014016206A1 (en) 2012-07-25 2013-07-19 Film with low ocs gel index

Publications (2)

Publication Number Publication Date
CA2878305A1 CA2878305A1 (en) 2014-01-30
CA2878305C true CA2878305C (en) 2017-07-04

Family

ID=48803558

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2878305A Active CA2878305C (en) 2012-07-25 2013-07-19 Film with low ocs gel index

Country Status (11)

Country Link
US (1) US9376549B2 (Direct)
EP (1) EP2877535B1 (Direct)
JP (1) JP5986314B2 (Direct)
KR (1) KR101531814B1 (Direct)
CN (1) CN104718249B (Direct)
BR (1) BR112015000853A2 (Direct)
CA (1) CA2878305C (Direct)
ES (1) ES2626363T3 (Direct)
IN (1) IN2014DN10848A (Direct)
MX (1) MX366376B (Direct)
WO (1) WO2014016206A1 (Direct)

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CN104508036B (zh) 2012-07-25 2018-02-16 博里利斯股份公司 由具有低凝胶含量的聚丙烯制造的泡沫
ES2574437T3 (es) * 2013-06-05 2016-06-17 Borealis Ag Producción en una etapa de una composición de polipropileno
EP3018153B1 (en) 2014-11-05 2019-02-27 Borealis AG Long-chain branched polypropylene for foam application
EP3018156B1 (en) * 2014-11-05 2023-03-22 Borealis AG Branched polypropylene for foam applications
EP3018154B1 (en) * 2014-11-05 2019-01-09 Borealis AG Long-chain branched polypropylene for film application
CN107848222B (zh) * 2015-02-04 2019-08-27 博里利斯股份公司 在挤出机中制备改性烯烃聚合物的方法
EP3280748B1 (en) * 2015-04-10 2021-07-14 Borealis AG Process for mixing olefin polymer with reactants
BR112017027434A2 (pt) 2015-08-13 2018-09-04 Exxonmobil Chemical Patents Inc folhas com múltiplas camadas compreendendo um polipropileno com alta resistência do fundido
US10676604B2 (en) * 2015-10-21 2020-06-09 Borealis Ag Long-branched polypropylene composition with increased melt strength stability
CN109312092B (zh) * 2016-08-18 2021-06-01 日本聚丙烯株式会社 微多孔性薄膜用聚丙烯树脂组合物和其用途
EP3333221B1 (en) 2016-12-09 2021-03-17 Borealis AG Polypropylene composition for foaming applications
JP6851477B2 (ja) * 2016-12-30 2021-03-31 ボレアリス エージー 低排出量のポリプロピレン発泡シート
KR102257918B1 (ko) * 2017-02-07 2021-05-27 엑손모빌 케미칼 패턴츠 인코포레이티드 개선된 가공성을 갖는 고 용융 강도 폴리프로필렌
WO2018147944A1 (en) * 2017-02-07 2018-08-16 Exxonmobil Chemical Patents Inc. High melt strength polypropylenes with improved processability
EP3652221B1 (en) 2017-07-13 2021-08-11 ExxonMobil Chemical Patents Inc. Process to produce strain hardened polypropylene
PH12020550043B1 (en) * 2017-09-21 2022-06-10 Tbm Co Ltd Thermoplastic resin composition and formed article formed by using thermoplastic resin composition
ES2974283T3 (es) * 2017-10-25 2024-06-26 Borealis Ag Composición de polipropileno cargado con propiedades termo-mecánicas mejoradas
WO2020231526A1 (en) 2019-05-15 2020-11-19 Exxonmobil Chemical Patents Inc. Polypropylene-based compositions
US12415875B2 (en) 2019-07-04 2025-09-16 Borealis Ag Long-chain branched propylene polymer composition
JP7697979B2 (ja) * 2020-06-26 2025-06-24 ボレアリス・アクチェンゲゼルシャフト バランスのとれた耐屈曲性を有するｈｍｓ ｐｐ発泡シート用のポリプロピレン組成物
ES2969463T3 (es) 2021-04-01 2024-05-20 Borealis Ag Composición polimérica adecuada para elaborar películas
CN114058115B (zh) * 2021-08-31 2023-06-06 成都金发科技新材料有限公司 一种抗菌抗病毒高冲击聚丙烯组合物及其制备方法和应用
EP4573133A1 (en) * 2022-08-19 2025-06-25 Borealis AG Process for preparing a long chain branched polypropylene composition

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Also Published As

Publication number Publication date
US9376549B2 (en) 2016-06-28
CN104718249A (zh) 2015-06-17
MX2015000615A (es) 2015-04-14
US20150133590A1 (en) 2015-05-14
EP2877535B1 (en) 2017-03-15
CA2878305A1 (en) 2014-01-30
JP5986314B2 (ja) 2016-09-06
IN2014DN10848A (Direct) 2015-09-04
EP2877535A1 (en) 2015-06-03
BR112015000853A2 (pt) 2017-06-27
WO2014016206A1 (en) 2014-01-30
ES2626363T3 (es) 2017-07-24
CN104718249B (zh) 2017-03-29
KR101531814B1 (ko) 2015-06-25
MX366376B (es) 2019-07-05
JP2015522701A (ja) 2015-08-06
KR20150030767A (ko) 2015-03-20

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