CA2875700C - Cha type zeolitic materials and methods for their preparation using cycloalkylammonium compounds - Google Patents
Cha type zeolitic materials and methods for their preparation using cycloalkylammonium compounds Download PDFInfo
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- CA2875700C CA2875700C CA2875700A CA2875700A CA2875700C CA 2875700 C CA2875700 C CA 2875700C CA 2875700 A CA2875700 A CA 2875700A CA 2875700 A CA2875700 A CA 2875700A CA 2875700 C CA2875700 C CA 2875700C
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- zeolitic material
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- 239000000463 material Substances 0.000 title claims abstract description 317
- 238000000034 method Methods 0.000 title claims abstract description 190
- 150000001875 compounds Chemical class 0.000 title claims abstract description 80
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 173
- 230000008569 process Effects 0.000 claims abstract description 152
- 238000010521 absorption reaction Methods 0.000 claims description 132
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 92
- 239000003054 catalyst Substances 0.000 claims description 66
- 238000002835 absorbance Methods 0.000 claims description 44
- 229910052676 chabazite Inorganic materials 0.000 claims description 44
- 238000002425 crystallisation Methods 0.000 claims description 37
- 230000008025 crystallization Effects 0.000 claims description 37
- 239000013078 crystal Substances 0.000 claims description 31
- 239000003795 chemical substances by application Substances 0.000 claims description 28
- 239000000377 silicon dioxide Substances 0.000 claims description 27
- 239000011734 sodium Substances 0.000 claims description 27
- 238000010438 heat treatment Methods 0.000 claims description 26
- UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 claims description 25
- 238000002329 infrared spectrum Methods 0.000 claims description 24
- 239000010457 zeolite Substances 0.000 claims description 22
- 235000012239 silicon dioxide Nutrition 0.000 claims description 21
- 230000010354 integration Effects 0.000 claims description 20
- 229910052681 coesite Inorganic materials 0.000 claims description 19
- 229910052906 cristobalite Inorganic materials 0.000 claims description 19
- 229910052708 sodium Inorganic materials 0.000 claims description 19
- 229910052682 stishovite Inorganic materials 0.000 claims description 19
- 229910052905 tridymite Inorganic materials 0.000 claims description 19
- 238000005342 ion exchange Methods 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 16
- 238000001035 drying Methods 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 15
- 238000005004 MAS NMR spectroscopy Methods 0.000 claims description 14
- 238000005406 washing Methods 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
- 239000008119 colloidal silica Substances 0.000 claims description 13
- 238000006467 substitution reaction Methods 0.000 claims description 13
- 238000002441 X-ray diffraction Methods 0.000 claims description 12
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 12
- 229910021536 Zeolite Inorganic materials 0.000 claims description 11
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 11
- 229910021485 fumed silica Inorganic materials 0.000 claims description 10
- 239000002808 molecular sieve Substances 0.000 claims description 10
- 229910052700 potassium Inorganic materials 0.000 claims description 10
- 101100008649 Caenorhabditis elegans daf-5 gene Proteins 0.000 claims description 9
- 150000002739 metals Chemical class 0.000 claims description 9
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 7
- 239000003463 adsorbent Substances 0.000 claims description 7
- 239000008131 herbal destillate Substances 0.000 claims description 7
- 239000000741 silica gel Substances 0.000 claims description 7
- 229910002027 silica gel Inorganic materials 0.000 claims description 7
- HCKMSHYCAFVSGW-UHFFFAOYSA-N cyclohexyl(trimethyl)azanium Chemical class C[N+](C)(C)C1CCCCC1 HCKMSHYCAFVSGW-UHFFFAOYSA-N 0.000 claims description 6
- 150000003839 salts Chemical class 0.000 claims description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 6
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 4
- 150000004645 aluminates Chemical class 0.000 claims description 4
- YOUGRGFIHBUKRS-UHFFFAOYSA-N benzyl(trimethyl)azanium Chemical compound C[N+](C)(C)CC1=CC=CC=C1 YOUGRGFIHBUKRS-UHFFFAOYSA-N 0.000 claims description 4
- 239000011591 potassium Substances 0.000 claims description 4
- 238000000634 powder X-ray diffraction Methods 0.000 claims description 4
- 239000004115 Sodium Silicate Substances 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 235000019795 sodium metasilicate Nutrition 0.000 claims description 3
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 3
- 229910052593 corundum Inorganic materials 0.000 claims 3
- 229910001845 yogo sapphire Inorganic materials 0.000 claims 3
- -1 tetraalkylammonium cation Chemical class 0.000 abstract description 64
- 125000000753 cycloalkyl group Chemical group 0.000 abstract description 22
- 125000000217 alkyl group Chemical group 0.000 abstract description 20
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 9
- 230000009102 absorption Effects 0.000 description 125
- 229910052757 nitrogen Inorganic materials 0.000 description 43
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 42
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 40
- 239000010949 copper Substances 0.000 description 37
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 36
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 35
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 31
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 29
- 229910052782 aluminium Inorganic materials 0.000 description 28
- 239000000047 product Substances 0.000 description 28
- 229910052802 copper Inorganic materials 0.000 description 24
- 229910052742 iron Inorganic materials 0.000 description 23
- 239000000758 substrate Substances 0.000 description 22
- 238000006243 chemical reaction Methods 0.000 description 21
- 235000019441 ethanol Nutrition 0.000 description 19
- 239000007789 gas Substances 0.000 description 19
- 229910052759 nickel Inorganic materials 0.000 description 19
- 229910052725 zinc Inorganic materials 0.000 description 19
- 229910052783 alkali metal Inorganic materials 0.000 description 18
- 239000000843 powder Substances 0.000 description 18
- 150000001340 alkali metals Chemical class 0.000 description 16
- 235000010210 aluminium Nutrition 0.000 description 16
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 16
- 239000011701 zinc Substances 0.000 description 16
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 125000004429 atom Chemical group 0.000 description 15
- 229910052804 chromium Inorganic materials 0.000 description 14
- 239000011651 chromium Substances 0.000 description 14
- 238000011282 treatment Methods 0.000 description 14
- 229910052726 zirconium Inorganic materials 0.000 description 14
- 238000012360 testing method Methods 0.000 description 13
- 239000010936 titanium Substances 0.000 description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 12
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 12
- 150000001768 cations Chemical class 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 12
- 229910052710 silicon Inorganic materials 0.000 description 12
- 229910052709 silver Inorganic materials 0.000 description 12
- 239000010944 silver (metal) Substances 0.000 description 12
- 229910052719 titanium Inorganic materials 0.000 description 12
- 229910052796 boron Inorganic materials 0.000 description 11
- 229960004756 ethanol Drugs 0.000 description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 11
- 230000032683 aging Effects 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 10
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 10
- 229910052718 tin Inorganic materials 0.000 description 10
- 239000002253 acid Substances 0.000 description 9
- 150000001336 alkenes Chemical class 0.000 description 9
- 230000003197 catalytic effect Effects 0.000 description 9
- 125000002091 cationic group Chemical group 0.000 description 9
- 239000012153 distilled water Substances 0.000 description 9
- 238000001914 filtration Methods 0.000 description 9
- 125000005842 heteroatom Chemical group 0.000 description 9
- 125000000623 heterocyclic group Chemical group 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 9
- 229910052744 lithium Inorganic materials 0.000 description 9
- 150000002894 organic compounds Chemical class 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 8
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 8
- 229910052785 arsenic Inorganic materials 0.000 description 8
- 238000004231 fluid catalytic cracking Methods 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 8
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 8
- 239000011541 reaction mixture Substances 0.000 description 8
- 229910052712 strontium Inorganic materials 0.000 description 8
- 229910052720 vanadium Inorganic materials 0.000 description 8
- 229910008051 Si-OH Inorganic materials 0.000 description 7
- 229910006358 Si—OH Inorganic materials 0.000 description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 7
- 239000004202 carbamide Substances 0.000 description 7
- 238000010531 catalytic reduction reaction Methods 0.000 description 7
- GWEYVXCWRZZNTB-UHFFFAOYSA-M cyclohexyl(trimethyl)azanium;hydroxide Chemical compound [OH-].C[N+](C)(C)C1CCCCC1 GWEYVXCWRZZNTB-UHFFFAOYSA-M 0.000 description 7
- 238000000921 elemental analysis Methods 0.000 description 7
- 239000012467 final product Substances 0.000 description 7
- 229910052733 gallium Inorganic materials 0.000 description 7
- 229910052732 germanium Inorganic materials 0.000 description 7
- 238000000449 magic angle spinning nuclear magnetic resonance spectrum Methods 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 229910003202 NH4 Inorganic materials 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 6
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 6
- 235000011128 aluminium sulphate Nutrition 0.000 description 6
- 229940063656 aluminum chloride Drugs 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 229910001679 gibbsite Inorganic materials 0.000 description 6
- 150000004679 hydroxides Chemical class 0.000 description 6
- 238000002955 isolation Methods 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 229910052758 niobium Inorganic materials 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 229960001866 silicon dioxide Drugs 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 239000011135 tin Substances 0.000 description 6
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 5
- 238000013019 agitation Methods 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 5
- 239000000956 alloy Substances 0.000 description 5
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 238000005119 centrifugation Methods 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000002243 precursor Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 5
- 239000012258 stirred mixture Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 4
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 4
- 239000007848 Bronsted acid Substances 0.000 description 4
- 239000011149 active material Substances 0.000 description 4
- 150000004703 alkoxides Chemical group 0.000 description 4
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910052729 chemical element Inorganic materials 0.000 description 4
- 229910052737 gold Inorganic materials 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 229910052738 indium Inorganic materials 0.000 description 4
- 229910052741 iridium Inorganic materials 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 229910052703 rhodium Inorganic materials 0.000 description 4
- 229910052707 ruthenium Inorganic materials 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 3
- 229910018557 Si O Inorganic materials 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 150000003973 alkyl amines Chemical class 0.000 description 3
- 229910052787 antimony Inorganic materials 0.000 description 3
- WGQKYBSKWIADBV-UHFFFAOYSA-O benzylaminium Chemical compound [NH3+]CC1=CC=CC=C1 WGQKYBSKWIADBV-UHFFFAOYSA-O 0.000 description 3
- 229910052790 beryllium Inorganic materials 0.000 description 3
- 229910052792 caesium Inorganic materials 0.000 description 3
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
- 229910052878 cordierite Inorganic materials 0.000 description 3
- 239000002178 crystalline material Substances 0.000 description 3
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 150000004820 halides Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 3
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 3
- 150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 229910052845 zircon Inorganic materials 0.000 description 3
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229910002016 Aerosil® 200 Inorganic materials 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- AIJULSRZWUXGPQ-UHFFFAOYSA-N Methylglyoxal Chemical compound CC(=O)C=O AIJULSRZWUXGPQ-UHFFFAOYSA-N 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229940022663 acetate Drugs 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 125000003545 alkoxy group Chemical group 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 229940024545 aluminum hydroxide Drugs 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 229940000425 combination drug Drugs 0.000 description 2
- 208000012839 conversion disease Diseases 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- 238000010908 decantation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 2
- HHLFWLYXYJOTON-UHFFFAOYSA-N glyoxylic acid Chemical compound OC(=O)C=O HHLFWLYXYJOTON-UHFFFAOYSA-N 0.000 description 2
- 239000002638 heterogeneous catalyst Substances 0.000 description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 238000002429 nitrogen sorption measurement Methods 0.000 description 2
- 238000010899 nucleation Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- 239000003826 tablet Substances 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
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- 101100114416 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) con-10 gene Proteins 0.000 description 1
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- YSVZGWAJIHWNQK-UHFFFAOYSA-N [3-(hydroxymethyl)-2-bicyclo[2.2.1]heptanyl]methanol Chemical compound C1CC2C(CO)C(CO)C1C2 YSVZGWAJIHWNQK-UHFFFAOYSA-N 0.000 description 1
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- 150000003842 bromide salts Chemical class 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
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- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 238000007385 chemical modification Methods 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
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- 239000011248 coating agent Substances 0.000 description 1
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- 238000007906 compression Methods 0.000 description 1
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- XURMURYJWMFWER-UHFFFAOYSA-N cyclohexyl-ethyl-dimethylazanium Chemical compound CC[N+](C)(C)C1CCCCC1 XURMURYJWMFWER-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000011026 diafiltration Methods 0.000 description 1
- 125000005265 dialkylamine group Chemical group 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
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- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
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- 238000010348 incorporation Methods 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
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- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- 239000007769 metal material Substances 0.000 description 1
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- CSJDCSCTVDEHRN-UHFFFAOYSA-N methane;molecular oxygen Chemical compound C.O=O CSJDCSCTVDEHRN-UHFFFAOYSA-N 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229910052670 petalite Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 238000004375 physisorption Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 1
- 229960005335 propanol Drugs 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011214 refractory ceramic Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 238000000371 solid-state nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000005346 substituted cycloalkyl group Chemical group 0.000 description 1
- 238000000967 suction filtration Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
Classifications
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
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- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9427—Processes characterised by a specific catalyst for removing nitrous oxide
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
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- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
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- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
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- B01J29/50—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the erionite or offretite type, e.g. zeolite T, as exemplified by patent document US2950952
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
- B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
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- C—CHEMISTRY; METALLURGY
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- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
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- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
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- C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
- C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
- C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
- C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
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- B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
- B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/405—Limiting CO, NOx or SOx emissions
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/10—Capture or disposal of greenhouse gases of nitrous oxide (N2O)
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP12170709 | 2012-06-04 | ||
| EP12170709.5 | 2012-06-04 | ||
| PCT/IB2013/054569 WO2013182974A1 (en) | 2012-06-04 | 2013-06-03 | Cha type zeolitic materials and methods for their preparation using cycloalkylammonium compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2875700A1 CA2875700A1 (en) | 2013-12-12 |
| CA2875700C true CA2875700C (en) | 2020-09-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2875700A Active CA2875700C (en) | 2012-06-04 | 2013-06-03 | Cha type zeolitic materials and methods for their preparation using cycloalkylammonium compounds |
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| EP (1) | EP2855354B1 (enExample) |
| JP (1) | JP6227634B2 (enExample) |
| KR (1) | KR102108057B1 (enExample) |
| CN (2) | CN107673366A (enExample) |
| BR (1) | BR112014030263B1 (enExample) |
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| MX (1) | MX363327B (enExample) |
| PL (1) | PL2855354T3 (enExample) |
| RU (1) | RU2627399C2 (enExample) |
| WO (1) | WO2013182974A1 (enExample) |
| ZA (1) | ZA201409466B (enExample) |
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| US10315924B2 (en) * | 2014-06-05 | 2019-06-11 | Basf Se | CHA type zeolitic materials and methods for their preparation using combinations of cycloalkyl-and tetraalkylammonium compounds |
| CN107073155B (zh) * | 2014-10-31 | 2020-07-28 | 东亚合成株式会社 | 消臭剂及使用其的消臭性加工品、以及消臭剂及消臭性加工品的制造方法 |
| ES2574500B1 (es) | 2014-12-17 | 2017-03-31 | Consejo Superior De Investigaciones Científicas (Csic) | Síntesis de la zeolita con la estructura cristalina CHA, procedimiento de síntesis y su uso en aplicaciones catalíticas |
| JP6949842B2 (ja) * | 2015-12-09 | 2021-10-13 | ビーエーエスエフ コーポレーション | Ｃｈａ型ゼオライト材料、並びにシクロアルキル−、及びエチルトリメチルアンモニウム化合物の組み合わせを用いるそれらの製造方法 |
| MY197118A (en) * | 2016-05-23 | 2023-05-26 | Tosoh Corp | Cha-type zeolite and production method therefor |
| WO2018064273A1 (en) * | 2016-09-30 | 2018-04-05 | Johnson Matthey Public Limited Company | A novel zeolite synthesis with a fluoride source |
| WO2018113566A1 (en) * | 2016-12-21 | 2018-06-28 | Basf Se | Process for the production of a zeolitic material via solvent-free interzeolitic conversion |
| US11224867B2 (en) | 2017-05-15 | 2022-01-18 | Basf Corporation | Process for preparing a zeolitic material having framework type AEI |
| US11148954B2 (en) | 2017-05-15 | 2021-10-19 | Basf Corporation | Process for preparing a zeolitic material comprising a metal M and having framework type AEI |
| MY190284A (en) * | 2017-10-11 | 2022-04-12 | Tosoh Corp | Metal-containing cha-type zeolite and method for producing the same |
| WO2019101854A1 (en) | 2017-11-22 | 2019-05-31 | Basf Se | Zeolite synthesis in a reactor with controlled velocity profile |
| CN110240179B (zh) * | 2018-03-09 | 2021-05-07 | 国家能源投资集团有限责任公司 | Sapo-34分子筛及其制备方法和应用 |
| US20210138441A1 (en) * | 2018-05-14 | 2021-05-13 | Umicore Ag & Co. Kg | Stable CHA Zeolites |
| CN112236230B (zh) * | 2018-05-14 | 2024-03-19 | 优美科股份公司及两合公司 | 稳定的小孔沸石 |
| CN112469666B (zh) * | 2018-08-02 | 2023-12-01 | 巴斯夫欧洲公司 | 使用负载有机模板的晶种连续合成沸石材料的方法 |
| WO2020039074A1 (en) | 2018-08-24 | 2020-02-27 | Umicore Ag & Co. Kg | Method for the preparation of a molecular sieve of the cha-type |
| US11219885B2 (en) * | 2018-11-30 | 2022-01-11 | Johnson Matthey Public Limited Company | JMZ-1, a CHA-containing zeolite and methods of preparation |
| KR102835708B1 (ko) * | 2018-12-19 | 2025-07-21 | 바스프 에스이 | Cha형 제올라이트 물질 및 이의 제조 방법 |
| WO2020156506A1 (en) * | 2019-01-31 | 2020-08-06 | Basf Se | A zeolitic material having framework type cha |
| JP2022523138A (ja) * | 2019-03-14 | 2022-04-21 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニー | Ｃｈａ含有モレキュラーシーブであるｊｍｚ－１ｓ及びその調製方法 |
| GB2595760B (en) | 2019-03-28 | 2023-03-22 | Johnson Matthey Plc | Molecular sieve intergrowths of cha and aft having an "sfw-GME tail", methods of preparation and use |
| WO2020225409A1 (en) | 2019-05-09 | 2020-11-12 | Basf Se | Process for a continuous synthesis of a cha zeolitic material from an emulsion |
| CN110975924B (zh) * | 2019-11-19 | 2021-12-07 | 上海应用技术大学 | 环己烯催化氧化制环己酮反应催化剂及制备方法和应用 |
| CN111871450A (zh) * | 2020-08-10 | 2020-11-03 | 中触媒新材料股份有限公司 | 一种cha结构分子筛及其尾气脱硝催化剂的制备方法与应用 |
| CN111871452A (zh) * | 2020-08-10 | 2020-11-03 | 中触媒新材料股份有限公司 | 一种用于柴油车尾气净化cha型分子筛、催化剂及制备方法与应用 |
| US20230211327A1 (en) | 2020-08-28 | 2023-07-06 | Tosoh Corporation | Cha-type zeolite and method for producing the same |
| EP4015454A1 (en) | 2020-12-21 | 2022-06-22 | Tosoh Corporation | Cha-type zeolite and manufacturing method thereof |
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| US6709644B2 (en) | 2001-08-30 | 2004-03-23 | Chevron U.S.A. Inc. | Small crystallite zeolite CHA |
| EP1485323B1 (en) * | 2002-03-15 | 2007-01-03 | ExxonMobil Chemical Patents Inc. | High silica chabazite, its synthesis and its use in the conversion of oxygenates to olefins |
| US6793901B2 (en) * | 2002-06-12 | 2004-09-21 | Exxonmobil Chemical Patents, Inc. | Synthesis of molecular sieves having the CHA framework type |
| US7247287B2 (en) * | 2003-06-11 | 2007-07-24 | Exxonmobil Chemical Patents Inc. | Synthesis of aluminophosphates and silicoaluminophosphates |
| EA010203B1 (ru) * | 2003-12-23 | 2008-06-30 | Эксонмобил Кемикэл Пейтентс Инк. | Содержащее шабазит молекулярное сито, его синтез и его применение при конверсии оксигенатов в олефины |
| US7090814B2 (en) * | 2004-11-10 | 2006-08-15 | Exxonmobil Chemical Patents Inc. | Method of synthesizing silicoaluminophosphate molecular sieves |
| US8048402B2 (en) * | 2005-08-18 | 2011-11-01 | Exxonmobil Chemical Patents Inc. | Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins |
| WO2007053239A1 (en) * | 2005-10-31 | 2007-05-10 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
| US7754187B2 (en) * | 2005-10-31 | 2010-07-13 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
| WO2007145724A1 (en) * | 2006-06-09 | 2007-12-21 | Exxonmobil Chemical Patents Inc. | Treatment of cha-type molecular sieves and their use in the conversion of oxygenates to olefins |
| KR101398291B1 (ko) * | 2006-09-25 | 2014-05-22 | 셰브런 유.에스.에이.인크. | 구조지향제 및 ｎ,ｎ,ｎ-트리알킬 벤질 4차 암모늄 양이온을 이용한 분자체 제조 방법 |
| US20080159950A1 (en) * | 2006-12-27 | 2008-07-03 | Miller Stephen J | Preparation of molecular sieve ssz-13 |
| CN102099293B (zh) * | 2008-05-21 | 2014-03-26 | 巴斯夫欧洲公司 | 直接合成具有CHA结构的含Cu沸石的方法 |
| US8268277B2 (en) * | 2008-07-25 | 2012-09-18 | Exxonmobil Chemical Patents Inc. | Synthesis of chabazite-containing molecular sieves and their use in the conversion of oxygenates to olefins |
| US8242041B2 (en) * | 2009-01-12 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Oxygenate conversion catalyst system and processes for making and using same |
| US8409546B2 (en) * | 2009-11-24 | 2013-04-02 | Basf Se | Process for the preparation of zeolites having B-CHA structure |
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- 2013-06-03 PL PL13800386T patent/PL2855354T3/pl unknown
- 2013-06-03 RU RU2014153662A patent/RU2627399C2/ru active
- 2013-06-03 CA CA2875700A patent/CA2875700C/en active Active
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- 2013-06-03 BR BR112014030263-4A patent/BR112014030263B1/pt active IP Right Grant
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- 2013-06-03 WO PCT/IB2013/054569 patent/WO2013182974A1/en not_active Ceased
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- 2013-06-03 JP JP2015515625A patent/JP6227634B2/ja active Active
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Also Published As
| Publication number | Publication date |
|---|---|
| RU2627399C2 (ru) | 2017-08-08 |
| KR102108057B1 (ko) | 2020-05-07 |
| MX363327B (es) | 2019-03-20 |
| PL2855354T3 (pl) | 2022-02-07 |
| MX2014014893A (es) | 2015-08-06 |
| WO2013182974A1 (en) | 2013-12-12 |
| EP2855354A4 (en) | 2016-03-23 |
| BR112014030263B1 (pt) | 2021-11-03 |
| CN107673366A (zh) | 2018-02-09 |
| CA2875700A1 (en) | 2013-12-12 |
| RU2014153662A (ru) | 2016-08-10 |
| BR112014030263A2 (pt) | 2017-06-27 |
| ZA201409466B (en) | 2016-08-31 |
| JP2015529608A (ja) | 2015-10-08 |
| EP2855354A1 (en) | 2015-04-08 |
| KR20150027171A (ko) | 2015-03-11 |
| JP6227634B2 (ja) | 2017-11-08 |
| CN104520235A (zh) | 2015-04-15 |
| EP2855354B1 (en) | 2021-09-22 |
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