CA2870387C - Matrices and sealants which are based on sulfur-containing polymers and which comprise a photoinitiator, curing and coating methods, and use of said matrices and sealants - Google Patents
Matrices and sealants which are based on sulfur-containing polymers and which comprise a photoinitiator, curing and coating methods, and use of said matrices and sealants Download PDFInfo
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- CA2870387C CA2870387C CA2870387A CA2870387A CA2870387C CA 2870387 C CA2870387 C CA 2870387C CA 2870387 A CA2870387 A CA 2870387A CA 2870387 A CA2870387 A CA 2870387A CA 2870387 C CA2870387 C CA 2870387C
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- Prior art keywords
- sealant
- curing
- isocyanate
- mixture
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000565 sealant Substances 0.000 title claims abstract description 312
- 229920000642 polymer Polymers 0.000 title claims abstract description 90
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 229910052717 sulfur Inorganic materials 0.000 title claims abstract description 33
- 239000011593 sulfur Substances 0.000 title claims abstract description 33
- 238000000576 coating method Methods 0.000 title claims abstract description 25
- 238000001723 curing Methods 0.000 title description 266
- 239000000203 mixture Substances 0.000 claims abstract description 211
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 153
- 239000012948 isocyanate Substances 0.000 claims abstract description 146
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 138
- 239000011159 matrix material Substances 0.000 claims abstract description 130
- 230000005855 radiation Effects 0.000 claims abstract description 122
- 238000000034 method Methods 0.000 claims abstract description 83
- 229920001021 polysulfide Polymers 0.000 claims abstract description 63
- 229920005601 base polymer Polymers 0.000 claims abstract description 61
- 239000005077 polysulfide Substances 0.000 claims abstract description 54
- 150000008117 polysulfides Polymers 0.000 claims abstract description 54
- 239000003054 catalyst Substances 0.000 claims abstract description 46
- 229920006295 polythiol Polymers 0.000 claims abstract description 43
- 150000003512 tertiary amines Chemical class 0.000 claims abstract description 40
- 229920001577 copolymer Polymers 0.000 claims abstract description 37
- 230000008569 process Effects 0.000 claims abstract description 26
- 239000000758 substrate Substances 0.000 claims abstract description 22
- 239000011248 coating agent Substances 0.000 claims abstract description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 239000001257 hydrogen Substances 0.000 claims abstract description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 5
- -1 aliphatic isocyanate Chemical class 0.000 claims description 98
- 238000003860 storage Methods 0.000 claims description 62
- 238000012545 processing Methods 0.000 claims description 53
- 239000000945 filler Substances 0.000 claims description 49
- 229910001868 water Inorganic materials 0.000 claims description 46
- 238000006243 chemical reaction Methods 0.000 claims description 43
- 150000001875 compounds Chemical class 0.000 claims description 40
- 239000000446 fuel Substances 0.000 claims description 40
- 150000003254 radicals Chemical class 0.000 claims description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 25
- 239000003504 photosensitizing agent Substances 0.000 claims description 24
- 239000005056 polyisocyanate Substances 0.000 claims description 24
- 229920001228 polyisocyanate Polymers 0.000 claims description 24
- 150000001412 amines Chemical class 0.000 claims description 23
- 239000000178 monomer Substances 0.000 claims description 22
- 239000002318 adhesion promoter Substances 0.000 claims description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 17
- 238000010276 construction Methods 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 17
- 239000000654 additive Substances 0.000 claims description 16
- 230000015572 biosynthetic process Effects 0.000 claims description 16
- 239000004014 plasticizer Substances 0.000 claims description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 15
- 230000003712 anti-aging effect Effects 0.000 claims description 15
- 239000003981 vehicle Substances 0.000 claims description 15
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims description 14
- 239000003063 flame retardant Substances 0.000 claims description 13
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 13
- 230000003197 catalytic effect Effects 0.000 claims description 12
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 11
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 11
- 239000003431 cross linking reagent Substances 0.000 claims description 11
- 239000003960 organic solvent Substances 0.000 claims description 11
- 230000000996 additive effect Effects 0.000 claims description 10
- 238000007789 sealing Methods 0.000 claims description 10
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 10
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 9
- 229920005989 resin Polymers 0.000 claims description 7
- 239000011347 resin Substances 0.000 claims description 7
- 239000000378 calcium silicate Substances 0.000 claims description 6
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 6
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims description 6
- 238000005266 casting Methods 0.000 claims description 6
- DGVMNQYBHPSIJS-UHFFFAOYSA-N dimagnesium;2,2,6,6-tetraoxido-1,3,5,7-tetraoxa-2,4,6-trisilaspiro[3.3]heptane;hydrate Chemical compound O.[Mg+2].[Mg+2].O1[Si]([O-])([O-])O[Si]21O[Si]([O-])([O-])O2 DGVMNQYBHPSIJS-UHFFFAOYSA-N 0.000 claims description 6
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims description 6
- 125000001302 tertiary amino group Chemical group 0.000 claims description 5
- 230000007547 defect Effects 0.000 claims description 4
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 claims description 4
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims description 4
- 238000012423 maintenance Methods 0.000 claims description 4
- 238000005452 bending Methods 0.000 claims description 3
- 238000005304 joining Methods 0.000 claims description 3
- 238000004870 electrical engineering Methods 0.000 claims description 2
- 230000000977 initiatory effect Effects 0.000 claims 1
- 229920000570 polyether Polymers 0.000 abstract description 19
- 239000004721 Polyphenylene oxide Substances 0.000 abstract description 16
- 238000010521 absorption reaction Methods 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 10
- 239000010410 layer Substances 0.000 description 39
- 229920005862 polyol Polymers 0.000 description 27
- 150000003077 polyols Chemical class 0.000 description 27
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 21
- 230000000052 comparative effect Effects 0.000 description 20
- 239000000126 substance Substances 0.000 description 19
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 14
- 238000002156 mixing Methods 0.000 description 14
- 125000003396 thiol group Chemical group [H]S* 0.000 description 14
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 12
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 229920005906 polyester polyol Polymers 0.000 description 12
- 125000004432 carbon atom Chemical group C* 0.000 description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 238000003848 UV Light-Curing Methods 0.000 description 9
- 238000004132 cross linking Methods 0.000 description 9
- 239000004848 polyfunctional curative Substances 0.000 description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 8
- 229910021536 Zeolite Inorganic materials 0.000 description 8
- 239000003570 air Substances 0.000 description 8
- 230000008901 benefit Effects 0.000 description 8
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 8
- 239000012965 benzophenone Substances 0.000 description 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 8
- 230000006870 function Effects 0.000 description 8
- 239000004814 polyurethane Substances 0.000 description 8
- 229920002635 polyurethane Polymers 0.000 description 8
- 239000010457 zeolite Substances 0.000 description 8
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 7
- 239000004113 Sepiolite Substances 0.000 description 7
- 150000003973 alkyl amines Chemical group 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- 210000003298 dental enamel Anatomy 0.000 description 7
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- 229910021485 fumed silica Inorganic materials 0.000 description 7
- 229920001568 phenolic resin Polymers 0.000 description 7
- 239000005011 phenolic resin Substances 0.000 description 7
- 239000002516 radical scavenger Substances 0.000 description 7
- 229910052624 sepiolite Inorganic materials 0.000 description 7
- 235000019355 sepiolite Nutrition 0.000 description 7
- 230000004913 activation Effects 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- LEVJVKGPFAQPOI-UHFFFAOYSA-N phenylmethanone Chemical compound O=[C]C1=CC=CC=C1 LEVJVKGPFAQPOI-UHFFFAOYSA-N 0.000 description 6
- SZXKSDXHODZTFS-UHFFFAOYSA-N 4-[4,5-bis[4-(dimethylamino)phenyl]-1H-imidazol-2-yl]-2,6-dimethoxyphenol Chemical compound COC1=C(O)C(OC)=CC(C=2NC(=C(N=2)C=2C=CC(=CC=2)N(C)C)C=2C=CC(=CC=2)N(C)C)=C1 SZXKSDXHODZTFS-UHFFFAOYSA-N 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 150000004756 silanes Chemical class 0.000 description 5
- DMYOHQBLOZMDLP-UHFFFAOYSA-N 1-[2-(2-hydroxy-3-piperidin-1-ylpropoxy)phenyl]-3-phenylpropan-1-one Chemical compound C1CCCCN1CC(O)COC1=CC=CC=C1C(=O)CCC1=CC=CC=C1 DMYOHQBLOZMDLP-UHFFFAOYSA-N 0.000 description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 4
- 229910000838 Al alloy Inorganic materials 0.000 description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000004593 Epoxy Substances 0.000 description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
- 239000004952 Polyamide Substances 0.000 description 4
- 229920001079 Thiokol (polymer) Polymers 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
- 235000012241 calcium silicate Nutrition 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229920002647 polyamide Polymers 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- YIKSHDNOAYSSPX-UHFFFAOYSA-N 1-propan-2-ylthioxanthen-9-one Chemical compound S1C2=CC=CC=C2C(=O)C2=C1C=CC=C2C(C)C YIKSHDNOAYSSPX-UHFFFAOYSA-N 0.000 description 3
- UUEWCQRISZBELL-UHFFFAOYSA-N 3-trimethoxysilylpropane-1-thiol Chemical compound CO[Si](OC)(OC)CCCS UUEWCQRISZBELL-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- 238000000862 absorption spectrum Methods 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
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- 239000002131 composite material Substances 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
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- HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 2
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 2
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- YBUIRAZOPRQNDE-UHFFFAOYSA-N [dimethoxy(methyl)silyl]methyl 2-methylprop-2-enoate Chemical compound CO[Si](C)(OC)COC(=O)C(C)=C YBUIRAZOPRQNDE-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
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- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical class O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 1
- CDMDQYCEEKCBGR-UHFFFAOYSA-N 1,4-diisocyanatocyclohexane Chemical compound O=C=NC1CCC(N=C=O)CC1 CDMDQYCEEKCBGR-UHFFFAOYSA-N 0.000 description 1
- ATOUXIOKEJWULN-UHFFFAOYSA-N 1,6-diisocyanato-2,2,4-trimethylhexane Chemical compound O=C=NCCC(C)CC(C)(C)CN=C=O ATOUXIOKEJWULN-UHFFFAOYSA-N 0.000 description 1
- YXRKNIZYMIXSAD-UHFFFAOYSA-N 1,6-diisocyanatohexane Chemical compound O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O.O=C=NCCCCCCN=C=O YXRKNIZYMIXSAD-UHFFFAOYSA-N 0.000 description 1
- RHNNQENFSNOGAM-UHFFFAOYSA-N 1,8-diisocyanato-4-(isocyanatomethyl)octane Chemical compound O=C=NCCCCC(CN=C=O)CCCN=C=O RHNNQENFSNOGAM-UHFFFAOYSA-N 0.000 description 1
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- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
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- 230000018109 developmental process Effects 0.000 description 1
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- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- WUDNUHPRLBTKOJ-UHFFFAOYSA-N ethyl isocyanate Chemical compound CCN=C=O WUDNUHPRLBTKOJ-UHFFFAOYSA-N 0.000 description 1
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- 150000002431 hydrogen Chemical class 0.000 description 1
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- 230000006872 improvement Effects 0.000 description 1
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- 238000007689 inspection Methods 0.000 description 1
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- 239000011229 interlayer Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
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- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
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- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
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- 150000004819 silanols Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
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- 125000003011 styrenyl group Chemical class [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 150000001911 terphenyls Chemical class 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 125000005425 toluyl group Chemical group 0.000 description 1
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical class CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- UOKUUKOEIMCYAI-UHFFFAOYSA-N trimethoxysilylmethyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)COC(=O)C(C)=C UOKUUKOEIMCYAI-UHFFFAOYSA-N 0.000 description 1
- VEDJZFSRVVQBIL-UHFFFAOYSA-N trisilane Chemical compound [SiH3][SiH2][SiH3] VEDJZFSRVVQBIL-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
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- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D181/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Coating compositions based on polysulfones; Coating compositions based on derivatives of such polymers
- C09D181/04—Polysulfides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/04—Polysulfides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D181/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur, with or without nitrogen, oxygen, or carbon only; Coating compositions based on polysulfones; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Sealing Material Composition (AREA)
- Polyurethanes Or Polyureas (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102012205951.2 | 2012-04-12 | ||
| DE102012205951.2A DE102012205951B4 (de) | 2012-04-12 | 2012-04-12 | Dichtmassen-System, ungehärtete Grundmasse und Mischung, Härter, Verfahren zum Beschichten eines Substrates und Verwendung eines Dichtmassen-Systems |
| PCT/EP2013/057353 WO2013153047A1 (de) | 2012-04-12 | 2013-04-09 | Grund- und dichtmassen auf basis schwefel-haltiger polymere mit einem photo-initiator, verfahren zum aushärten und zum beschichten sowie ihre verwendung |
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| CA2870387A1 CA2870387A1 (en) | 2013-10-17 |
| CA2870387C true CA2870387C (en) | 2020-12-22 |
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| CA2870387A Expired - Fee Related CA2870387C (en) | 2012-04-12 | 2013-04-09 | Matrices and sealants which are based on sulfur-containing polymers and which comprise a photoinitiator, curing and coating methods, and use of said matrices and sealants |
Country Status (11)
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| US9382448B2 (en) * | 2014-08-29 | 2016-07-05 | Prc-Desoto International, Inc. | Polythioether sealants with enhanced thermal resistance |
| EP3256542B1 (de) | 2015-02-13 | 2022-07-06 | Chemetall GmbH | Dichtmasse auf basis von mercaptoterminiertem basispolymer/epoxidverbindung und verfahren zum härten mittels eines photolatenten katalysators |
| US9856359B2 (en) | 2015-04-08 | 2018-01-02 | The Boeing Company | Core-shell particles, compositions incorporating the core-shell particles and methods of making the same |
| ITUB20156094A1 (it) * | 2015-12-02 | 2017-06-02 | Bridgestone Corp | Metodo di trattamento di uno strato sigillante di uno pneumatico |
| GB2565666B (en) | 2016-03-30 | 2022-02-09 | The Patent Well LLC | A clear sprayable sealant for aircraft parts and assemblies |
| US11198757B2 (en) | 2016-11-03 | 2021-12-14 | 3M Innovative Properties Company | Compositions including a photolatent amine, camphorquinone, and coumarin and related methods |
| WO2018085546A1 (en) * | 2016-11-03 | 2018-05-11 | 3M Innovative Properties Company | Composition including a polythiol, a polyepoxide, a photolatent base, and an amine and methods relating to the composition |
| US11059991B2 (en) | 2017-06-28 | 2021-07-13 | The Patent Well LLC | Aircraft fluid resistant sealant for use on aircraft parts |
| JP7273724B2 (ja) | 2017-11-29 | 2023-05-15 | 日東電工株式会社 | シーラントシート |
| DE102018113977A1 (de) * | 2018-06-12 | 2019-12-12 | ECO Holding 1 GmbH | Nockenwelleneinheit und Verfahren zur Herstellung einer Nockenwelleneinheit |
| CN112368354B (zh) * | 2018-06-26 | 2024-04-09 | 日东电工株式会社 | 密封剂片 |
| CN110180524A (zh) * | 2019-06-04 | 2019-08-30 | 大连理工大学 | 一种基于硅酸钙基复合催化剂制备碳酸甘油酯的方法 |
| EP4076772A1 (en) | 2019-12-19 | 2022-10-26 | Chemetall GmbH | Polyurea coating systems as sealants for the exterior of fuel tanks |
| WO2021132486A1 (ja) * | 2019-12-25 | 2021-07-01 | 日東電工株式会社 | 積層体 |
| CN111303365A (zh) * | 2020-02-28 | 2020-06-19 | 江苏广信感光新材料股份有限公司 | 一种聚硫代氨基甲酸酯高分子树脂的制备方法 |
| CN117363017B (zh) * | 2022-06-30 | 2025-03-11 | 比亚迪股份有限公司 | Pps树脂组合物、pps树脂复合材料及其制备方法和应用 |
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| US3645816A (en) | 1969-07-14 | 1972-02-29 | Lockheed Aircraft Corp | Method for sealing leaks in fluid tanks |
| TW436491B (en) * | 1997-08-22 | 2001-05-28 | Ciba Sc Holding Ag | Compositions for use in base-catalysed reactions, a process for curing said compostions and a process for photochemically generating bases in base catalysed polymeriaztion reactions |
| JP2001220423A (ja) * | 2000-02-10 | 2001-08-14 | Toray Thiokol Co Ltd | 硬化型組成物 |
| BR0109262A (pt) * | 2000-03-09 | 2003-06-17 | Pbt Brands Inc | Politioéteres quimicamente resistentes e formação dos mesmos |
| AU2001260325B2 (en) * | 2000-05-26 | 2005-03-10 | Akzo Nobel N.V. | Photoactivatable coating composition |
| JP2002012765A (ja) * | 2000-06-27 | 2002-01-15 | Yokohama Rubber Co Ltd:The | 硬化性組成物 |
| DE10108136B4 (de) | 2001-02-20 | 2014-05-22 | Chemetall Gmbh | Verfahren zum Beschichten eines Substrates mit einer Dichtmasse, Dichtmasse vor und nach der Aushärtung sowie Verwendung der nicht-ausgehärteten Dichtmasse |
| JP2002338947A (ja) * | 2001-05-15 | 2002-11-27 | Hitachi Kasei Polymer Co Ltd | １成分形シーリング材 |
| JP2003012754A (ja) * | 2001-07-04 | 2003-01-15 | Toray Fine Chemicals Co Ltd | 硬化型組成物 |
| US7067612B2 (en) | 2003-01-30 | 2006-06-27 | Prc-Desoto International, Inc. | Preformed compositions in shaped form |
| DE602004001336T2 (de) * | 2003-02-06 | 2007-02-01 | Akzo Nobel Coatings International B.V. | Spritzpistole und verfahren zum aufbringen einer durchaktinische strahlung härtbaren beschichtung |
| US7189781B2 (en) * | 2003-03-13 | 2007-03-13 | H.B. Fuller Licensing & Finance Inc. | Moisture curable, radiation curable sealant composition |
| RU2336288C2 (ru) | 2003-04-30 | 2008-10-20 | Прк-Десото Интернэшнл, Инк. | Предварительно сформованные эмп/рчп-экранирующие композиции в профилированной форме и способ герметизации отверстия |
| US9096014B2 (en) * | 2003-07-01 | 2015-08-04 | Transitions Optical, Inc. | Oriented polymeric sheets exhibiting dichroism and articles containing the same |
| US8089678B2 (en) | 2003-07-01 | 2012-01-03 | Transitions Optical, Inc | Clear to circular polarizing photochromic devices and methods of making the same |
| JP2007505977A (ja) * | 2003-09-19 | 2007-03-15 | ダウ グローバル テクノロジーズ インコーポレイティド | 接着剤接合されたエンジンおよびトランスミッションの部品 |
| DE102004020429A1 (de) * | 2004-04-27 | 2005-11-24 | Degussa Ag | Uretdiongruppenhaltige Polyurethanzusammensetzungen, welche bei niedriger Temperatur härtbar sind und (teil-)kristalline Harze enthalten |
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-
2012
- 2012-04-12 DE DE102012205951.2A patent/DE102012205951B4/de not_active Expired - Fee Related
-
2013
- 2013-04-09 ES ES13714666.8T patent/ES2614031T3/es active Active
- 2013-04-09 WO PCT/EP2013/057353 patent/WO2013153047A1/de active Application Filing
- 2013-04-09 BR BR112014025333A patent/BR112014025333A8/pt active Search and Examination
- 2013-04-09 PT PT137146668T patent/PT2836562T/pt unknown
- 2013-04-09 US US14/391,590 patent/US10370562B2/en not_active Expired - Fee Related
- 2013-04-09 CA CA2870387A patent/CA2870387C/en not_active Expired - Fee Related
- 2013-04-09 RU RU2014145253A patent/RU2637004C2/ru active
- 2013-04-09 JP JP2015504925A patent/JP6293116B2/ja not_active Expired - Fee Related
- 2013-04-09 CN CN201380030637.9A patent/CN104471001B/zh not_active Expired - Fee Related
- 2013-04-09 EP EP13714666.8A patent/EP2836562B1/de active Active
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2019
- 2019-06-19 US US16/445,942 patent/US11124674B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| RU2637004C2 (ru) | 2017-11-29 |
| EP2836562B1 (de) | 2016-11-02 |
| BR112014025333A8 (pt) | 2021-04-06 |
| US20190300747A1 (en) | 2019-10-03 |
| EP2836562A1 (de) | 2015-02-18 |
| PT2836562T (pt) | 2017-02-13 |
| CN104471001A (zh) | 2015-03-25 |
| CA2870387A1 (en) | 2013-10-17 |
| CN104471001B (zh) | 2018-03-02 |
| JP2015520251A (ja) | 2015-07-16 |
| BR112014025333A2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 2017-06-20 |
| US11124674B2 (en) | 2021-09-21 |
| DE102012205951A1 (de) | 2013-10-17 |
| WO2013153047A1 (de) | 2013-10-17 |
| US10370562B2 (en) | 2019-08-06 |
| RU2014145253A (ru) | 2016-05-27 |
| ES2614031T3 (es) | 2017-05-29 |
| JP6293116B2 (ja) | 2018-03-14 |
| US20150065599A1 (en) | 2015-03-05 |
| DE102012205951B4 (de) | 2016-09-01 |
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