CA2861935C - Procede pour produire de l'hydroxyde d'aluminium au moyen d'une precipitation ensemencee d'une solution d'aluminate de sodium sursaturee - Google Patents
Procede pour produire de l'hydroxyde d'aluminium au moyen d'une precipitation ensemencee d'une solution d'aluminate de sodium sursaturee Download PDFInfo
- Publication number
- CA2861935C CA2861935C CA2861935A CA2861935A CA2861935C CA 2861935 C CA2861935 C CA 2861935C CA 2861935 A CA2861935 A CA 2861935A CA 2861935 A CA2861935 A CA 2861935A CA 2861935 C CA2861935 C CA 2861935C
- Authority
- CA
- Canada
- Prior art keywords
- precipitation tank
- agitation
- seeded precipitation
- seeded
- aluminum hydroxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000001556 precipitation Methods 0.000 title claims abstract description 177
- 238000000034 method Methods 0.000 title claims abstract description 54
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 title claims abstract description 44
- 230000008569 process Effects 0.000 title claims abstract description 40
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical class [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 238000013019 agitation Methods 0.000 claims abstract description 105
- 239000002245 particle Substances 0.000 claims abstract description 32
- 229910001388 sodium aluminate Inorganic materials 0.000 claims abstract description 22
- 230000008021 deposition Effects 0.000 claims abstract description 12
- 238000012546 transfer Methods 0.000 claims abstract description 9
- 238000009792 diffusion process Methods 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims description 33
- 239000013078 crystal Substances 0.000 claims description 24
- 238000007664 blowing Methods 0.000 claims description 4
- 238000005185 salting out Methods 0.000 claims description 2
- 239000007787 solid Substances 0.000 abstract description 17
- 238000002156 mixing Methods 0.000 description 37
- 238000004519 manufacturing process Methods 0.000 description 26
- 239000002002 slurry Substances 0.000 description 22
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 12
- 239000007788 liquid Substances 0.000 description 12
- 238000002425 crystallisation Methods 0.000 description 10
- 230000008025 crystallization Effects 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000004131 Bayer process Methods 0.000 description 4
- 230000004913 activation Effects 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000010523 cascade reaction Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 238000009434 installation Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000004931 aggregating effect Effects 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- -1 aluminate anions Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006557 surface reaction Methods 0.000 description 1
- 230000005514 two-phase flow Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
- C01F7/14—Aluminium oxide or hydroxide from alkali metal aluminates
- C01F7/144—Aluminium oxide or hydroxide from alkali metal aluminates from aqueous aluminate solutions by precipitation due to cooling, e.g. as part of the Bayer process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D9/00—Crystallisation
- B01D9/0036—Crystallisation on to a bed of product crystals; Seeding
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Abstract
Procédé de production d'hydroxyde d'aluminium par décomposition à germes d'une solution d'aluminate de sodium sursaturée, dans lequel l'agitation est uniquement effectuée localement au fond d'un réservoir de décomposition à germes avec une intensité suffisante pour maintenir les particules d'hydroxyde d'aluminium au fond du réservoir de décomposition à germes dans un état de suspension, afin de favoriser un transfert de masse par diffusion de la solution d'aluminate de sodium avec une teneur élevée en matières solides et un rapport moléculaire élevé au fond du réservoir de décomposition à germes, et empêcher les particules d'hydroxyde d'aluminium au fond du réservoir de décomposition à germes de produire des précipités.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210019003.0 | 2012-01-20 | ||
CN201210019003.0A CN102583474B (zh) | 2012-01-20 | 2012-01-20 | 过饱和铝酸钠溶液晶种分解生产氢氧化铝的工艺方法 |
PCT/CN2012/074190 WO2013107120A1 (fr) | 2012-01-20 | 2012-04-17 | Procédé de production d'hydroxyde d'aluminium par décomposition à germes de solution d'aluminate de sodium sursaturée |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2861935A1 CA2861935A1 (fr) | 2013-07-25 |
CA2861935C true CA2861935C (fr) | 2016-12-06 |
Family
ID=46472837
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2861935A Active CA2861935C (fr) | 2012-01-20 | 2012-04-17 | Procede pour produire de l'hydroxyde d'aluminium au moyen d'une precipitation ensemencee d'une solution d'aluminate de sodium sursaturee |
Country Status (4)
Country | Link |
---|---|
CN (1) | CN102583474B (fr) |
AU (1) | AU2012365963B2 (fr) |
CA (1) | CA2861935C (fr) |
WO (1) | WO2013107120A1 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102992366A (zh) * | 2012-11-19 | 2013-03-27 | 贵州省新材料研究开发基地 | 氢氧化铝微粉制备工艺方法 |
CN103736317A (zh) * | 2013-12-14 | 2014-04-23 | 中国铝业股份有限公司 | 一种种分过滤机供料方法 |
CN110127737B (zh) * | 2019-07-01 | 2023-09-19 | 济源职业技术学院 | 拜耳法氧化铝生产中防止种分周期性细化的装置 |
CN112960682B (zh) * | 2021-03-03 | 2022-10-11 | 杭州智华杰科技有限公司 | 一种提高层析氧化铝再生次数的方法 |
CN114184152B (zh) * | 2021-12-03 | 2024-05-14 | 中国铝业股份有限公司 | 晶种分解槽的积料厚度测量方法、存储介质及电子设备 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2653858A (en) * | 1951-09-22 | 1953-09-29 | Aluminum Co Of America | Precipitation of aluminum hydroxide |
NO135059C (fr) * | 1975-04-16 | 1977-02-02 | Norsk Hydro As | |
US6217622B1 (en) * | 1998-10-22 | 2001-04-17 | Alcan International Limited | Method and apparatus for precipitating and classifying solids in high concentrations |
AU2002301811B2 (en) * | 2001-11-07 | 2007-08-23 | Sumitomo Chemical Company, Limited | Aluminum hydroxide aggregated particles, process for producing the same, vessel used therefor, and process for producing aluminum hydroxide powder |
CN201458765U (zh) * | 2009-08-18 | 2010-05-12 | 胡大乔 | 铝酸钠溶液柱状流平底分解槽 |
CN101628726A (zh) * | 2009-08-18 | 2010-01-20 | 胡大乔 | 铝酸钠溶液柱状流平底分解槽 |
CN101955212B (zh) * | 2010-09-26 | 2013-03-27 | 苏向东 | 铝酸钠溶液平推流分解反应装置 |
CN101955213B (zh) * | 2010-09-26 | 2013-01-02 | 胡大乔 | 铝酸钠溶液平推流晶种分解槽 |
CN201825743U (zh) * | 2010-09-26 | 2011-05-11 | 胡大乔 | 铝酸钠溶液平推流晶种分解槽 |
CN201825742U (zh) * | 2010-09-26 | 2011-05-11 | 苏向东 | 铝酸钠溶液平推流分解反应装置 |
CN202011755U (zh) * | 2011-01-18 | 2011-10-19 | 贵州科学院 | 微搅动多锥底组合平推流氢氧化铝种分槽 |
CN202175569U (zh) * | 2011-05-10 | 2012-03-28 | 贵州科学院 | 氢氧化铝大型平底晶种分解槽 |
-
2012
- 2012-01-20 CN CN201210019003.0A patent/CN102583474B/zh active Active
- 2012-04-17 CA CA2861935A patent/CA2861935C/fr active Active
- 2012-04-17 WO PCT/CN2012/074190 patent/WO2013107120A1/fr active Application Filing
- 2012-04-17 AU AU2012365963A patent/AU2012365963B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN102583474A (zh) | 2012-07-18 |
WO2013107120A1 (fr) | 2013-07-25 |
CN102583474B (zh) | 2014-08-27 |
AU2012365963B2 (en) | 2015-11-26 |
CA2861935A1 (fr) | 2013-07-25 |
AU2012365963A1 (en) | 2014-09-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request |
Effective date: 20140718 |