CA2856493A1 - Improved metal passivator/trap for fcc processes - Google Patents

Improved metal passivator/trap for fcc processes Download PDF

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Publication number
CA2856493A1
CA2856493A1 CA2856493A CA2856493A CA2856493A1 CA 2856493 A1 CA2856493 A1 CA 2856493A1 CA 2856493 A CA2856493 A CA 2856493A CA 2856493 A CA2856493 A CA 2856493A CA 2856493 A1 CA2856493 A1 CA 2856493A1
Authority
CA
Canada
Prior art keywords
catalyst
trap
fcc
metal
calcined
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2856493A
Other languages
English (en)
French (fr)
Inventor
Bram W. Hoffer
David M. Stockwell
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Corp
Original Assignee
BASF Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF Corp filed Critical BASF Corp
Publication of CA2856493A1 publication Critical patent/CA2856493A1/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/843—Arsenic, antimony or bismuth
    • B01J23/8435—Antimony
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0211—Impregnation using a colloidal suspension
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/12—Oxidising
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/205—Metal content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/28—Propane and butane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
CA2856493A 2011-11-21 2011-11-21 Improved metal passivator/trap for fcc processes Abandoned CA2856493A1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US2011/061648 WO2013077836A1 (en) 2011-11-21 2011-11-21 Improved metal passivator/trap for fcc processes

Publications (1)

Publication Number Publication Date
CA2856493A1 true CA2856493A1 (en) 2013-05-30

Family

ID=48470149

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2856493A Abandoned CA2856493A1 (en) 2011-11-21 2011-11-21 Improved metal passivator/trap for fcc processes

Country Status (9)

Country Link
EP (1) EP2782980A4 (zh)
JP (1) JP5982496B2 (zh)
KR (1) KR20140096134A (zh)
CN (1) CN104066819B (zh)
BR (1) BR112014012163A2 (zh)
CA (1) CA2856493A1 (zh)
RU (1) RU2603964C2 (zh)
WO (1) WO2013077836A1 (zh)
ZA (1) ZA201404460B (zh)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9895680B2 (en) 2013-12-19 2018-02-20 Basf Corporation FCC catalyst compositions containing boron oxide
US9441167B2 (en) * 2013-12-19 2016-09-13 Basf Corporation Boron oxide in FCC processes
CN106475155B (zh) * 2015-08-28 2019-09-20 江苏科创石化有限公司 一种金属钝化剂及其制备方法
CN109126898A (zh) * 2018-09-26 2019-01-04 宜兴汉光高新石化有限公司 一种可同时钝化多种金属、提高轻油及总液收率的钝化剂及其制备方法
CN110339865B (zh) * 2019-07-29 2020-06-02 华东理工大学 一种催化裂化抗金属增液剂及其制备方法
CN114602484B (zh) * 2020-12-03 2023-10-10 中国石油化工股份有限公司 一种加氢脱残炭催化剂的制备方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4178267A (en) * 1976-03-29 1979-12-11 Phillips Petroleum Company Passivating metals on cracking catalysts
US4111845A (en) * 1977-02-11 1978-09-05 Mckay Dwight L Cracking catalyst modified by antimony thiophosphate
DK160995C (da) * 1977-10-25 1991-11-04 Phillips Petroleum Co Forureningsdeaktiveret krakningskatalysator, dens anvendelse og middel til dens fremstilling
US4321129A (en) * 1978-09-12 1982-03-23 Phillips Petroleum Company Cracking process employing catalyst having combination of antimony and tin
US4370220A (en) * 1979-12-31 1983-01-25 Exxon Research And Engineering Co. Process for reducing coke formation in heavy feed catalytic cracking
US4372841A (en) * 1979-12-31 1983-02-08 Exxon Research And Engineering Co. Process for reducing coke formation in heavy feed catalytic cracking
US4335021A (en) * 1980-02-04 1982-06-15 Phillips Petroleum Company Catalyst regeneration
JPS57202381A (en) * 1981-06-05 1982-12-11 Exxon Research Engineering Co Method of reducing coke production on catalysis of heavy supply
US4576709A (en) * 1982-09-02 1986-03-18 Ashland Oil, Inc. Catalytic upgrading of reduced crudes and residual oils with a coke selective catalyst
JPS60258288A (ja) * 1984-06-01 1985-12-20 ガルフ・リサ−チ・エンド・デベロツプメント・コンパニ− 接触分解方法
US4889617A (en) * 1986-03-24 1989-12-26 Chevron Research Company Method of suppressing sodium poisoning of cracking catalysts during fluid catalytic cracking
US4784752A (en) * 1987-05-05 1988-11-15 Chevron Research Company Method for suppressing the poisoning effects of contaminant metals on cracking catalysts in fluid catalytic cracking
US4935121A (en) * 1989-06-22 1990-06-19 Phillips Petroleum Company Reactivation of metal-contaminated cracking catalysts
US5037786A (en) * 1990-04-04 1991-08-06 Phillips Petroleum Company Metals passivation-zeolite containing cracking catalysts
GB2245001A (en) * 1990-06-11 1991-12-18 Unilever Plc Catalyst compositions containing metal ion-exchanged zeolites
US5401384A (en) * 1993-12-17 1995-03-28 Inteven, S.A. Antimony and tin containing compound, use of such a compound as a passivating agent, and process for preparing such a compound
US6110357A (en) * 1994-09-28 2000-08-29 Phillips Petroleum Company Passivated catalysts for cracking process
JP2695121B2 (ja) * 1994-12-16 1997-12-24 インテヴェップ，エス．エイ． アンチモン及び錫を含有する化合物及びその製造方法
CN1122703C (zh) * 1998-12-29 2003-10-01 中国石油化工集团公司 用于烃类催化裂化的一种助剂及其使用方法
RU2283177C2 (ru) * 2001-08-14 2006-09-10 Петролеум Энерджи Сентер Катализатор для каталитического крекинга тяжелых нефтепродуктов в псевдоожиженном слое и способ каталитического крекинга в псевдоожиженном слое
CN100540141C (zh) * 2005-09-28 2009-09-16 华东理工大学 催化裂化金属钝化剂及其制备方法
US7678735B2 (en) * 2005-11-28 2010-03-16 Engelhard Corporation FCC additive for partial and full burn NOx control

Also Published As

Publication number Publication date
RU2603964C2 (ru) 2016-12-10
EP2782980A4 (en) 2015-11-11
JP2015504473A (ja) 2015-02-12
WO2013077836A1 (en) 2013-05-30
CN104066819B (zh) 2016-12-07
EP2782980A1 (en) 2014-10-01
ZA201404460B (en) 2015-12-23
JP5982496B2 (ja) 2016-08-31
KR20140096134A (ko) 2014-08-04
CN104066819A (zh) 2014-09-24
RU2014125128A (ru) 2015-12-27
BR112014012163A2 (pt) 2017-05-30

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Legal Events

Date Code Title Description
EEER Examination request

Effective date: 20141121

FZDE Dead

Effective date: 20180228