CA2850214C - Process for producing hydrogen peroxide - Google Patents
Process for producing hydrogen peroxide Download PDFInfo
- Publication number
- CA2850214C CA2850214C CA2850214A CA2850214A CA2850214C CA 2850214 C CA2850214 C CA 2850214C CA 2850214 A CA2850214 A CA 2850214A CA 2850214 A CA2850214 A CA 2850214A CA 2850214 C CA2850214 C CA 2850214C
- Authority
- CA
- Canada
- Prior art keywords
- hydrogen peroxide
- working solution
- reactor system
- ktpa
- hydrogenation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 464
- 238000000034 method Methods 0.000 title claims abstract description 233
- 230000008569 process Effects 0.000 title claims abstract description 157
- 239000012224 working solution Substances 0.000 claims abstract description 186
- 238000004519 manufacturing process Methods 0.000 claims abstract description 142
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 102
- 239000003054 catalyst Substances 0.000 claims abstract description 93
- 230000008929 regeneration Effects 0.000 claims abstract description 54
- 238000011069 regeneration method Methods 0.000 claims abstract description 54
- 239000003960 organic solvent Substances 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims description 34
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 32
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 11
- 230000001172 regenerating effect Effects 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 7
- 229910052763 palladium Inorganic materials 0.000 claims description 7
- 238000004064 recycling Methods 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 5
- AKIIJALHGMKJEJ-UHFFFAOYSA-N (2-methylcyclohexyl) acetate Chemical compound CC1CCCCC1OC(C)=O AKIIJALHGMKJEJ-UHFFFAOYSA-N 0.000 claims description 4
- UMWZLYTVXQBTTE-UHFFFAOYSA-N 2-pentylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(CCCCC)=CC=C3C(=O)C2=C1 UMWZLYTVXQBTTE-UHFFFAOYSA-N 0.000 claims description 4
- HXQPUEQDBSPXTE-UHFFFAOYSA-N Diisobutylcarbinol Chemical compound CC(C)CC(O)CC(C)C HXQPUEQDBSPXTE-UHFFFAOYSA-N 0.000 claims description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- WUKWGUZTPMOXOW-UHFFFAOYSA-N 2-(2-methylbutan-2-yl)anthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)(C)CC)=CC=C3C(=O)C2=C1 WUKWGUZTPMOXOW-UHFFFAOYSA-N 0.000 claims description 2
- IFHQWLHVCATXGU-UHFFFAOYSA-N 2-pentan-2-ylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)CCC)=CC=C3C(=O)C2=C1 IFHQWLHVCATXGU-UHFFFAOYSA-N 0.000 claims description 2
- 239000000758 substrate Substances 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 abstract description 50
- 230000003647 oxidation Effects 0.000 abstract description 49
- 238000000605 extraction Methods 0.000 abstract description 38
- 150000001875 compounds Chemical class 0.000 abstract description 26
- 230000007420 reactivation Effects 0.000 abstract description 17
- 229960002163 hydrogen peroxide Drugs 0.000 description 206
- 239000007789 gas Substances 0.000 description 32
- 239000001257 hydrogen Substances 0.000 description 28
- 229910052739 hydrogen Inorganic materials 0.000 description 28
- 150000004056 anthraquinones Chemical class 0.000 description 26
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 24
- 239000000243 solution Substances 0.000 description 19
- 230000008901 benefit Effects 0.000 description 14
- 238000005187 foaming Methods 0.000 description 14
- 239000002245 particle Substances 0.000 description 13
- 230000003197 catalytic effect Effects 0.000 description 11
- 239000007788 liquid Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 239000011261 inert gas Substances 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 238000005516 engineering process Methods 0.000 description 8
- 238000004061 bleaching Methods 0.000 description 7
- 239000006260 foam Substances 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 6
- -1 cyclic ester Chemical class 0.000 description 6
- 238000010790 dilution Methods 0.000 description 6
- 239000012895 dilution Substances 0.000 description 6
- 238000004821 distillation Methods 0.000 description 6
- 230000007613 environmental effect Effects 0.000 description 6
- 239000007800 oxidant agent Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 238000005065 mining Methods 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 239000004753 textile Substances 0.000 description 5
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 4
- 238000006701 autoxidation reaction Methods 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 238000012423 maintenance Methods 0.000 description 4
- 238000007726 management method Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- OTBHDFWQZHPNPU-UHFFFAOYSA-N 1,2,3,4-tetrahydroanthracene-9,10-dione Chemical class O=C1C2=CC=CC=C2C(=O)C2=C1CCCC2 OTBHDFWQZHPNPU-UHFFFAOYSA-N 0.000 description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003849 aromatic solvent Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 230000032258 transport Effects 0.000 description 3
- SJEBAWHUJDUKQK-UHFFFAOYSA-N 2-ethylanthraquinone Chemical compound C1=CC=C2C(=O)C3=CC(CC)=CC=C3C(=O)C2=C1 SJEBAWHUJDUKQK-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- 230000005465 channeling Effects 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 231100001261 hazardous Toxicity 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000009776 industrial production Methods 0.000 description 2
- 238000011031 large-scale manufacturing process Methods 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 238000004076 pulp bleaching Methods 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 150000004053 quinones Chemical class 0.000 description 2
- 125000004151 quinonyl group Chemical group 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229910052703 rhodium Inorganic materials 0.000 description 2
- 239000010948 rhodium Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000011877 solvent mixture Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- MCYPCBFOVKMNDW-UHFFFAOYSA-N 2-butan-2-ylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)CC)=CC=C3C(=O)C2=C1 MCYPCBFOVKMNDW-UHFFFAOYSA-N 0.000 description 1
- MAKLMMYWGTWPQM-UHFFFAOYSA-N 2-butylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(CCCC)=CC=C3C(=O)C2=C1 MAKLMMYWGTWPQM-UHFFFAOYSA-N 0.000 description 1
- BQUNPXRABCSKJZ-UHFFFAOYSA-N 2-propan-2-ylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)C)=CC=C3C(=O)C2=C1 BQUNPXRABCSKJZ-UHFFFAOYSA-N 0.000 description 1
- YTPSFXZMJKMUJE-UHFFFAOYSA-N 2-tert-butylanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=CC(C(C)(C)C)=CC=C3C(=O)C2=C1 YTPSFXZMJKMUJE-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- NPXOKRUENSOPAO-UHFFFAOYSA-N Raney nickel Chemical compound [Al].[Ni] NPXOKRUENSOPAO-UHFFFAOYSA-N 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000009455 aseptic packaging Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004517 catalytic hydrocracking Methods 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000002844 continuous effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000007792 gaseous phase Substances 0.000 description 1
- 239000011491 glass wool Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000004336 hydroxyquinones Chemical class 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000004434 industrial solvent Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000003908 quality control method Methods 0.000 description 1
- 150000004059 quinone derivatives Chemical class 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000012776 robust process Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/584—Recycling of catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11184576.4 | 2011-10-11 | ||
| EP11184576 | 2011-10-11 | ||
| PCT/EP2012/069414 WO2013053617A1 (en) | 2011-10-11 | 2012-10-02 | Process for producing hydrogen peroxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2850214A1 CA2850214A1 (en) | 2013-04-18 |
| CA2850214C true CA2850214C (en) | 2020-08-25 |
Family
ID=46963742
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2850214A Active CA2850214C (en) | 2011-10-11 | 2012-10-02 | Process for producing hydrogen peroxide |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US9617153B2 (forum.php) |
| EP (1) | EP2766300B1 (forum.php) |
| CN (1) | CN103974899B (forum.php) |
| AP (1) | AP3843A (forum.php) |
| AR (1) | AR088292A1 (forum.php) |
| BR (1) | BR112014008478B1 (forum.php) |
| CA (1) | CA2850214C (forum.php) |
| CL (1) | CL2014000810A1 (forum.php) |
| ES (1) | ES2808336T3 (forum.php) |
| IN (1) | IN2014CN03354A (forum.php) |
| MY (1) | MY169486A (forum.php) |
| PE (1) | PE20141490A1 (forum.php) |
| PT (1) | PT2766300T (forum.php) |
| RU (1) | RU2609474C2 (forum.php) |
| UY (1) | UY34377A (forum.php) |
| WO (1) | WO2013053617A1 (forum.php) |
| ZA (1) | ZA201402448B (forum.php) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IN2014CN03356A (forum.php) | 2011-10-11 | 2015-07-03 | Solvay | |
| CN105540551B (zh) * | 2014-11-03 | 2017-07-28 | 中国石油化工股份有限公司 | 一种双氧水生产中的高效氢化工艺 |
| US9890397B1 (en) | 2015-07-15 | 2018-02-13 | Gaurab Chakrabarti | Hydrogen peroxide production method, system, and apparatus |
| BR112018003016A2 (pt) * | 2015-08-19 | 2018-09-18 | Solvay | processo para fabricação de peróxido de hidrogênio |
| US11203769B1 (en) | 2017-02-13 | 2021-12-21 | Solugen, Inc. | Hydrogen peroxide and gluconic acid production |
| CN108862205B (zh) * | 2018-08-29 | 2023-09-12 | 江苏德邦工程有限公司 | 一种双氧水制备装置 |
| US20220274833A1 (en) * | 2019-09-11 | 2022-09-01 | Solvay Sa | Process for manufacturing an aqueous hydrogen peroxide solution |
| WO2021048365A1 (en) * | 2019-09-11 | 2021-03-18 | Solvay Sa | Process for manufacturing an alkyl substituted cyclohexanecarbonitrile |
| CN114702012B (zh) * | 2022-04-06 | 2024-05-03 | 山东华鲁恒升化工股份有限公司 | 一种工作液及其制备方法和在蒽醌法生产双氧水中的应用 |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2158525A (en) | 1935-10-10 | 1939-05-16 | Ig Farbenindustrie Ag | Production of hydrogen peroxide |
| IT360853A (forum.php) | 1937-04-07 | |||
| US2739875A (en) * | 1951-12-06 | 1956-03-27 | Du Pont | Regeneration of degraded alkylanthraquinone solutions for the production of hydrogen peroxide |
| GB798237A (en) | 1956-01-27 | 1958-07-16 | Du Pont | Improvements in or relating to the production of hydrogen peroxide |
| US3330625A (en) * | 1963-10-22 | 1967-07-11 | Pittsburgh Plate Glass Co | Hydrogen peroxide manufacture |
| US4061598A (en) | 1976-06-25 | 1977-12-06 | E. I. Du Pont De Nemours And Company | Catalyst for hydrogenating anthraquinones |
| US4428922A (en) | 1982-05-14 | 1984-01-31 | Fmc Corporation | Process for manufacturing hydrogen peroxide |
| JPS604121A (ja) | 1983-06-23 | 1985-01-10 | Taisho Pharmaceut Co Ltd | 坐剤 |
| US5488024A (en) * | 1994-07-01 | 1996-01-30 | Phillips Petroleum Company | Selective acetylene hydrogenation |
| FI97465C (fi) | 1995-02-10 | 1996-12-27 | Kemira Chemicals Oy | Menetelmä vetyperoksidin valmistamiseksi |
| FR2730985B1 (fr) | 1995-02-28 | 1997-08-01 | Chemoxal Sa | Procede et installation de production de peroxyde d'hydrogene |
| US5662878A (en) * | 1996-04-25 | 1997-09-02 | University Of Chicago | Process for the production of hydrogen peroxide |
| BR9712193A (pt) | 1996-10-04 | 1999-08-31 | . | Catalisadores de hidrogenação à base de paládio, platina ou ródio, sobre um suporte de óxidos de zircónio e de silício, processo de fabricação e utilização dos mesmos, e, processo de fabricação de peróxido de hidrogênio. |
| GB2334028A (en) | 1998-02-04 | 1999-08-11 | Solvay | Making hydrogen peroxide by the anthraquinone process |
| FR2803783B1 (fr) | 2000-01-13 | 2002-04-26 | Valfond Argentan S A | Piece bimetallique en alliage d'aluminium comportant un insert massif en titane ou alliage de titane |
| DE10336852A1 (de) * | 2003-08-11 | 2005-03-10 | Degussa | Verfahren zur Herstellung von Wasserstoffperoxid nach dem Anthrachinon-Kreisprozess |
| US8366796B2 (en) | 2007-07-09 | 2013-02-05 | Range Fuels, Inc. | Modular and distributed methods and systems to convert biomass to syngas |
| FR2930772B1 (fr) * | 2008-04-30 | 2010-04-30 | Arkema France | Synthese directe d'eau oxygenee sur le site d'une papeterie |
| KR100998082B1 (ko) | 2008-07-22 | 2010-12-03 | 오씨아이 주식회사 | 생산성을 향상시킨 과산화수소 제조 방법 및 이를 위한조성물 |
| ES2677004T3 (es) | 2008-12-17 | 2018-07-27 | Thyssenkrupp Uhde Chlorine Engineers (Italia) S.R.L. | Proceso para producir cloro, sosa caustica, e hidrógeno |
| US8558043B2 (en) | 2009-03-04 | 2013-10-15 | Kior, Inc. | Modular biomass treatment unit |
| US20120027667A1 (en) | 2009-03-27 | 2012-02-02 | Solvay Sa | Method for the production of hydrogen peroxide |
| IN2014CN03356A (forum.php) | 2011-10-11 | 2015-07-03 | Solvay | |
| EP2639200A1 (en) | 2012-03-13 | 2013-09-18 | Solvay Sa | Plant for hydrogen peroxide production and a process using it |
-
2012
- 2012-10-02 IN IN3354CHN2014 patent/IN2014CN03354A/en unknown
- 2012-10-02 WO PCT/EP2012/069414 patent/WO2013053617A1/en active Application Filing
- 2012-10-02 PE PE2014000526A patent/PE20141490A1/es active IP Right Grant
- 2012-10-02 BR BR112014008478-5A patent/BR112014008478B1/pt not_active IP Right Cessation
- 2012-10-02 CN CN201280056747.8A patent/CN103974899B/zh active Active
- 2012-10-02 ES ES12766674T patent/ES2808336T3/es active Active
- 2012-10-02 MY MYPI2014000987A patent/MY169486A/en unknown
- 2012-10-02 US US14/350,825 patent/US9617153B2/en not_active Expired - Fee Related
- 2012-10-02 CA CA2850214A patent/CA2850214C/en active Active
- 2012-10-02 EP EP12766674.1A patent/EP2766300B1/en not_active Revoked
- 2012-10-02 RU RU2014118565A patent/RU2609474C2/ru active
- 2012-10-02 PT PT127666741T patent/PT2766300T/pt unknown
- 2012-10-02 AP AP2014007562A patent/AP3843A/en active
- 2012-10-09 UY UY0001034377A patent/UY34377A/es active IP Right Grant
- 2012-10-10 AR ARP120103775A patent/AR088292A1/es active IP Right Grant
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2014
- 2014-04-02 ZA ZA2014/02448A patent/ZA201402448B/en unknown
- 2014-04-02 CL CL2014000810A patent/CL2014000810A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AR088292A1 (es) | 2014-05-21 |
| CN103974899B (zh) | 2017-03-29 |
| RU2014118565A (ru) | 2015-11-20 |
| PT2766300T (pt) | 2020-07-29 |
| RU2609474C2 (ru) | 2017-02-02 |
| MY169486A (en) | 2019-04-15 |
| BR112014008478A2 (pt) | 2017-04-11 |
| AP2014007562A0 (en) | 2014-04-30 |
| ZA201402448B (en) | 2016-03-30 |
| CN103974899A (zh) | 2014-08-06 |
| UY34377A (es) | 2013-04-30 |
| WO2013053617A1 (en) | 2013-04-18 |
| CL2014000810A1 (es) | 2014-06-20 |
| EP2766300A1 (en) | 2014-08-20 |
| ES2808336T3 (es) | 2021-02-26 |
| CA2850214A1 (en) | 2013-04-18 |
| BR112014008478A8 (pt) | 2020-05-19 |
| IN2014CN03354A (forum.php) | 2015-07-03 |
| AP3843A (en) | 2016-09-30 |
| EP2766300B1 (en) | 2020-05-20 |
| US20140234202A1 (en) | 2014-08-21 |
| PE20141490A1 (es) | 2014-10-23 |
| US9617153B2 (en) | 2017-04-11 |
| BR112014008478B1 (pt) | 2021-04-13 |
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