CA2819895A1 - Polymers, method of producing the same, and articles made therefrom - Google Patents
Polymers, method of producing the same, and articles made therefrom Download PDFInfo
- Publication number
- CA2819895A1 CA2819895A1 CA2819895A CA2819895A CA2819895A1 CA 2819895 A1 CA2819895 A1 CA 2819895A1 CA 2819895 A CA2819895 A CA 2819895A CA 2819895 A CA2819895 A CA 2819895A CA 2819895 A1 CA2819895 A1 CA 2819895A1
- Authority
- CA
- Canada
- Prior art keywords
- granular polymer
- mean
- less
- ratio
- density
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 264
- 238000000034 method Methods 0.000 title description 18
- 239000002245 particle Substances 0.000 claims abstract description 130
- 239000012018 catalyst precursor Substances 0.000 claims description 42
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 32
- 239000010936 titanium Substances 0.000 claims description 30
- 239000007795 chemical reaction product Substances 0.000 claims description 26
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 19
- 239000007787 solid Substances 0.000 claims description 16
- 239000002002 slurry Substances 0.000 claims description 12
- 150000002681 magnesium compounds Chemical class 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 9
- 150000003609 titanium compounds Chemical class 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003426 co-catalyst Substances 0.000 claims description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 230000002140 halogenating effect Effects 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 6
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 6
- 150000002736 metal compounds Chemical class 0.000 claims description 6
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 6
- 230000000379 polymerizing effect Effects 0.000 claims description 6
- 150000001336 alkenes Chemical class 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 3
- 229910010062 TiCl3 Inorganic materials 0.000 claims 2
- 238000006116 polymerization reaction Methods 0.000 description 23
- 239000000203 mixture Substances 0.000 description 17
- 230000000052 comparative effect Effects 0.000 description 16
- 239000003054 catalyst Substances 0.000 description 14
- 238000009826 distribution Methods 0.000 description 14
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 14
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 239000011777 magnesium Substances 0.000 description 10
- -1 polyethylene Polymers 0.000 description 10
- 239000000499 gel Substances 0.000 description 9
- 239000002243 precursor Substances 0.000 description 9
- 239000007921 spray Substances 0.000 description 9
- 239000000843 powder Substances 0.000 description 8
- 238000001694 spray drying Methods 0.000 description 8
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 7
- 229910052749 magnesium Inorganic materials 0.000 description 7
- 229910010061 TiC13 Inorganic materials 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 6
- 238000005259 measurement Methods 0.000 description 6
- 239000008188 pellet Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 235000011147 magnesium chloride Nutrition 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 230000009977 dual effect Effects 0.000 description 4
- 229910052735 hafnium Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000001186 cumulative effect Effects 0.000 description 3
- 229910021485 fumed silica Inorganic materials 0.000 description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 3
- 230000026030 halogenation Effects 0.000 description 3
- 238000005658 halogenation reaction Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000007873 sieving Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- 150000003623 transition metal compounds Chemical class 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000004876 x-ray fluorescence Methods 0.000 description 3
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000071 blow moulding Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000001739 density measurement Methods 0.000 description 2
- 239000003085 diluting agent Substances 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 229920006158 high molecular weight polymer Polymers 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000002480 mineral oil Substances 0.000 description 2
- 235000010446 mineral oil Nutrition 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000034 Plastomer Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 229940075894 denatured ethanol Drugs 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000011549 displacement method Methods 0.000 description 1
- VJYFKVYYMZPMAB-UHFFFAOYSA-N ethoprophos Chemical compound CCCSP(=O)(OCC)SCCC VJYFKVYYMZPMAB-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007863 gel particle Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
- C08F4/652—Pretreating with metals or metal-containing compounds
- C08F4/654—Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/06—Catalyst characterized by its size
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201061428970P | 2010-12-31 | 2010-12-31 | |
| US61/428,970 | 2010-12-31 | ||
| PCT/US2011/067937 WO2012092507A1 (en) | 2010-12-31 | 2011-12-29 | Polymers, method of producing the same, and articles made therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2819895A1 true CA2819895A1 (en) | 2012-07-05 |
Family
ID=45541082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2819895A Abandoned CA2819895A1 (en) | 2010-12-31 | 2011-12-29 | Polymers, method of producing the same, and articles made therefrom |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US9644049B2 (OSRAM) |
| EP (1) | EP2658884A1 (OSRAM) |
| JP (2) | JP2014502659A (OSRAM) |
| KR (1) | KR20140001993A (OSRAM) |
| CN (2) | CN107266613A (OSRAM) |
| BR (1) | BR112013016970A2 (OSRAM) |
| CA (1) | CA2819895A1 (OSRAM) |
| SG (1) | SG191342A1 (OSRAM) |
| WO (1) | WO2012092507A1 (OSRAM) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2546516T3 (es) * | 2010-12-31 | 2015-09-24 | Union Carbide Chemicals & Plastics Technology Llc | Control de la distribución de peso molecular de resinas usando sistemas de catalizador mixtos |
| US11124586B1 (en) * | 2020-11-09 | 2021-09-21 | Chevron Phillips Chemical Company Lp | Particle size control of metallocene catalyst systems in loop slurry polymerization reactors |
| WO2022125581A2 (en) | 2020-12-08 | 2022-06-16 | Chevron Phillips Chemical Company Lp | Particle size control of supported chromium catalysts in loop slurry polymerization reactors |
| CN117980344A (zh) | 2021-09-13 | 2024-05-03 | 切弗朗菲利浦化学公司 | 水力旋流器对用于烯烃聚合的催化剂体系组分的修改 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5405901A (en) | 1994-07-06 | 1995-04-11 | Union Carbide Chemicals & Plastics Technology Corporation | Process of producing ethylene polymer blends in gas phase |
| US5589539A (en) | 1994-11-23 | 1996-12-31 | Union Carbide Chemicals & Plastics Technology Corporation | Process for preparing an in situ polyethylene blend |
| US6187866B1 (en) | 1999-06-04 | 2001-02-13 | Union Carbide Chemicals & Plastics Technology Corporation | Staged reactor process |
| US6617405B1 (en) | 1999-07-14 | 2003-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | Process for the preparation of polyethylene |
| US6248831B1 (en) | 1999-12-06 | 2001-06-19 | Union Carbide Chemicals & Plastics Technology Corporation | High strength polyethylene film |
| ATE283294T1 (de) | 2000-05-10 | 2004-12-15 | Repsol Quimica Sa | Verfahren zur herstellung von bimodalem polyethylen |
| TW200504093A (en) | 2003-05-12 | 2005-02-01 | Dow Global Technologies Inc | Polymer composition and process to manufacture high molecular weight-high density polyethylene and film therefrom |
| WO2005052010A1 (en) * | 2003-11-20 | 2005-06-09 | Union Carbide Chemicals & Plastics Technology Corporation | Spray-dried, mixed metal ziegler catalyst compositions |
| EP1732957B1 (en) * | 2004-04-07 | 2012-05-23 | Union Carbide Chemicals & Plastics Technology LLC | Method of controlling olefin polymerization |
| CA2574364C (en) * | 2004-08-09 | 2012-11-27 | Robert J. Jorgensen | Robust spray-dried ziegler-natta procatalyst and polymerization process employing same |
| WO2009015107A1 (en) * | 2007-07-20 | 2009-01-29 | Yeda Research And Development Co. Ltd. | Modulation of toll-like receptors for controlling neurogenesis |
| SG187414A1 (en) * | 2007-12-31 | 2013-02-28 | Dow Global Technologies Inc | Ethylene-based polymer compositions, methods of making the same, and articles prepared from the same |
| ES2402326T3 (es) * | 2007-12-31 | 2013-04-30 | Dow Global Technologies Llc | Proceso de polimerización de polímeros basados en olefinas |
| CA2793693A1 (en) * | 2010-04-05 | 2011-10-13 | Dow Global Technologies Llc | Process for polymerizing olefin-based polymers containing high molecular weight fractions in condensed and super-condensed mode |
-
2011
- 2011-12-29 BR BR112013016970-2A patent/BR112013016970A2/pt not_active Application Discontinuation
- 2011-12-29 CN CN201710571868.0A patent/CN107266613A/zh active Pending
- 2011-12-29 KR KR1020137020170A patent/KR20140001993A/ko not_active Ceased
- 2011-12-29 CA CA2819895A patent/CA2819895A1/en not_active Abandoned
- 2011-12-29 CN CN2011800688618A patent/CN103403039A/zh active Pending
- 2011-12-29 JP JP2013547678A patent/JP2014502659A/ja not_active Withdrawn
- 2011-12-29 EP EP11813750.4A patent/EP2658884A1/en not_active Withdrawn
- 2011-12-29 WO PCT/US2011/067937 patent/WO2012092507A1/en not_active Ceased
- 2011-12-29 US US13/991,541 patent/US9644049B2/en not_active Expired - Fee Related
- 2011-12-29 SG SG2013048897A patent/SG191342A1/en unknown
-
2018
- 2018-01-24 JP JP2018009278A patent/JP2018083955A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012092507A1 (en) | 2012-07-05 |
| US9644049B2 (en) | 2017-05-09 |
| JP2014502659A (ja) | 2014-02-03 |
| CN107266613A (zh) | 2017-10-20 |
| JP2018083955A (ja) | 2018-05-31 |
| US20130324681A1 (en) | 2013-12-05 |
| SG191342A1 (en) | 2013-08-30 |
| CN103403039A (zh) | 2013-11-20 |
| EP2658884A1 (en) | 2013-11-06 |
| BR112013016970A2 (pt) | 2020-08-04 |
| KR20140001993A (ko) | 2014-01-07 |
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