CA2770008A1 - Processes for removing hydrogen sulfide from refined hydrocarbon streams - Google Patents

Processes for removing hydrogen sulfide from refined hydrocarbon streams Download PDF

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Publication number
CA2770008A1
CA2770008A1 CA2770008A CA2770008A CA2770008A1 CA 2770008 A1 CA2770008 A1 CA 2770008A1 CA 2770008 A CA2770008 A CA 2770008A CA 2770008 A CA2770008 A CA 2770008A CA 2770008 A1 CA2770008 A1 CA 2770008A1
Authority
CA
Canada
Prior art keywords
hydrocarbon stream
refined hydrocarbon
corrosion inhibitor
processing equipment
volume
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA2770008A
Other languages
English (en)
French (fr)
Inventor
Malcolm Craig Winslow
Larry John Karas
Sherif Eldin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
General Electric Co
Original Assignee
General Electric Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Electric Co filed Critical General Electric Co
Publication of CA2770008A1 publication Critical patent/CA2770008A1/en
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G75/00—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
    • C10G75/02—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general by addition of corrosion inhibitors
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G75/00—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general
    • C10G75/04—Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general by addition of antifouling agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/20—Organic compounds not containing metal atoms
    • C10G29/22—Organic compounds not containing metal atoms containing oxygen as the only hetero atom
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/104—Light gasoline having a boiling range of about 20 - 100 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1044—Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1051—Kerosene having a boiling range of about 180 - 230 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1055—Diesel having a boiling range of about 230 - 330 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1037—Hydrocarbon fractions
    • C10G2300/1048—Middle distillates
    • C10G2300/1059—Gasoil having a boiling range of about 330 - 427 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1077—Vacuum residues
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4075—Limiting deterioration of equipment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
CA2770008A 2009-08-04 2010-07-02 Processes for removing hydrogen sulfide from refined hydrocarbon streams Abandoned CA2770008A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/535,252 2009-08-04
US12/535,252 US20110031165A1 (en) 2009-08-04 2009-08-04 Processes for removing hydrogen sulfide from refined hydrocarbon streams
PCT/US2010/040871 WO2011016935A2 (en) 2009-08-04 2010-07-02 Processes for removing hydrogen sulfide from refined hydrocarbo streams

Publications (1)

Publication Number Publication Date
CA2770008A1 true CA2770008A1 (en) 2011-02-10

Family

ID=43478134

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2770008A Abandoned CA2770008A1 (en) 2009-08-04 2010-07-02 Processes for removing hydrogen sulfide from refined hydrocarbon streams

Country Status (12)

Country Link
US (1) US20110031165A1 (es)
EP (1) EP2462207A2 (es)
JP (1) JP2013501126A (es)
KR (1) KR20120055582A (es)
CN (1) CN102549114A (es)
AU (1) AU2010281621A1 (es)
BR (1) BR112012002528A2 (es)
CA (1) CA2770008A1 (es)
MX (1) MX2012001530A (es)
RU (1) RU2012103702A (es)
SG (1) SG178245A1 (es)
WO (1) WO2011016935A2 (es)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101293268B1 (ko) 2011-04-14 2013-08-16 한국화학연구원 식물유 유래 이미다졸린 화합물을 포함하는 방청제
WO2013049027A1 (en) * 2011-09-27 2013-04-04 General Electric Company Hydrogen sulfide scavenger compositions, methods for making and processes for removing hydrogen sulfide from liquid hydrocarbon media
EP3470390B1 (en) 2013-01-30 2023-06-07 Ecolab USA Inc. Hydrogen sulfide scavengers
EP3253850B1 (en) * 2015-02-04 2019-09-18 Ecolab USA Inc. Diphenyliodonium salts as sulfidogenesis inhibitors and antimicrobials
EP3286175B1 (en) 2015-04-22 2020-12-02 Ecolab USA Inc. Development of a high temperature stable scavenger for removal of hydrogen sulfide
WO2017044248A1 (en) * 2015-09-08 2017-03-16 Ecolab Usa Inc. Hydrogen sulfide scavengers
US10407626B2 (en) * 2015-09-08 2019-09-10 Ecolab Usa Inc. Hydrocarbon soluble/dispersible hemiformals as hydrogen sulfide scavengers
EP3400087B1 (en) * 2016-01-05 2020-02-19 Dorf Ketal Chemicals (India) Private Limited Hydrogen sulfide scavenging additive composition and method of use thereof
MX2019001208A (es) 2016-07-29 2019-05-02 Ecolab Usa Inc Composiciones antiincrustantes y barredoras de sulfuro de hidrogeno.
US10301553B2 (en) 2017-02-28 2019-05-28 Ecolab Usa Inc. Use of sulfonium salts as hydrogen sulfide inhibitors
EP3652274A1 (en) 2017-07-13 2020-05-20 Ecolab USA, Inc. Method of removing a sulfur containing compound by adding a composition
US10900128B2 (en) 2018-08-29 2021-01-26 Championx Usa Inc. Use of sulfonium salts as corrosion inhibitors
CA3127439A1 (en) 2019-01-23 2020-07-30 Championx Usa Inc. Complete removal of solids during hydrogen sulfide scavenging operations using a scavenger and a michael acceptor

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US3247094A (en) * 1962-11-23 1966-04-19 Nalco Chemical Co Inhibiting corrosion of metal conductors
DE2037789A1 (en) * 1970-07-30 1972-02-03 Texaco Development Corp., New York, N.Y. (V.St.A.) Anti corrosion cpds for oil wells
US3766053A (en) * 1972-06-29 1973-10-16 Nalco Chemical Co Corrosion inhibitors for refining & petrochemical processing equipment
JPS604273B2 (ja) * 1979-05-25 1985-02-02 日東紡績株式会社 金属の腐食抑制方法
US4388213A (en) * 1982-02-26 1983-06-14 Basf Aktiengesellschaft Cyclic amidine based corrosion inhibitors which inhibit corrosion caused by CO2 and H2 S
US4680127A (en) * 1985-12-13 1987-07-14 Betz Laboratories, Inc. Method of scavenging hydrogen sulfide
US5225103A (en) * 1989-08-23 1993-07-06 Hoechst Aktiengesellschaft Aqueous aldehyde solutions for trapping hydrogen sulfide in natural gas and crude oil producing plants
DE3927763A1 (de) * 1989-08-23 1991-02-28 Hoechst Ag Waessrige aldehydloesugen zum abfangen von schwefelwasserstoff
FR2651500A1 (fr) * 1989-09-05 1991-03-08 Hoechst France Nouvelles emulsions eau dans huile et leur application a l'elimination du sulfure d'hydrogene.
US5284635A (en) * 1989-09-05 1994-02-08 Societe Francaise Hoechst Process for the elimination of hydrogen sulfide by using water-in-oil emulsions
DE4002132A1 (de) * 1990-01-25 1991-08-01 Hoechst Ag Verfahren zum abfangen von schwefelwasserstoff mit glyoxal
US5530137A (en) * 1994-09-16 1996-06-25 Betz Paperchem, Inc. Methods and compositions for stabilizing fatty acid imidazoline solutions
US5744024A (en) * 1995-10-12 1998-04-28 Nalco/Exxon Energy Chemicals, L.P. Method of treating sour gas and liquid hydrocarbon
JP3053763B2 (ja) * 1996-03-08 2000-06-19 伯東株式会社 油溶性皮膜性腐食防止剤およびそれを用いた金属表面の腐食防止方法
DE60025035D1 (de) * 1999-11-30 2006-01-26 Ici Plc Verfahren zur Behandlung von Rohöl oder Öl in einem Raffinerieverfahren
US7517447B2 (en) * 2004-01-09 2009-04-14 Clearwater International, Llc Sterically hindered N-methylsecondary and tertiary amine sulfur scavengers and methods for making and using same
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Also Published As

Publication number Publication date
EP2462207A2 (en) 2012-06-13
BR112012002528A2 (pt) 2019-09-24
AU2010281621A1 (en) 2012-02-23
US20110031165A1 (en) 2011-02-10
WO2011016935A3 (en) 2012-04-12
MX2012001530A (es) 2012-05-08
CN102549114A (zh) 2012-07-04
SG178245A1 (en) 2012-03-29
KR20120055582A (ko) 2012-05-31
RU2012103702A (ru) 2013-09-10
WO2011016935A2 (en) 2011-02-10
JP2013501126A (ja) 2013-01-10

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Effective date: 20140702