CA2759413C - Coating compositions and coatings produced from them and featuring high scratch resistance in association with good results in the erichsen cupping test and good antistonechip properties - Google Patents
Coating compositions and coatings produced from them and featuring high scratch resistance in association with good results in the erichsen cupping test and good antistonechip properties Download PDFInfo
- Publication number
- CA2759413C CA2759413C CA2759413A CA2759413A CA2759413C CA 2759413 C CA2759413 C CA 2759413C CA 2759413 A CA2759413 A CA 2759413A CA 2759413 A CA2759413 A CA 2759413A CA 2759413 C CA2759413 C CA 2759413C
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- coating composition
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/622—Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
- C08G18/6225—Polymers of esters of acrylic or methacrylic acid
- C08G18/6229—Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/62—Polymers of compounds having carbon-to-carbon double bonds
- C08G18/6216—Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
- C08G18/625—Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
- C08G18/6254—Polymers of alpha-beta ethylenically unsaturated carboxylic acids and of esters of these acids containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/778—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
- C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8083—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen
- C08G18/809—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102009030481.9 | 2009-06-24 | ||
| DE102009030481A DE102009030481A1 (de) | 2009-06-24 | 2009-06-24 | Beschichtungsmittel und daraus hergestellte Beschichtungen mit hoher Kratzfestigkeit bei gleichzeitig guten Ergebnissen in der Prüfung der Erichsentiefung und guten Steinschlagschutzeigenschaften |
| PCT/EP2010/001422 WO2010149236A1 (de) | 2009-06-24 | 2010-03-08 | Beschichtungsmittel und daraus hergestellte beschichtungen mit hoher kratzfestigkeit bei gleichzeitig guten ergebnissen in der prüfung der erichsentiefung und guten steinschlagschutzeigenschaften |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2759413A1 CA2759413A1 (en) | 2010-12-29 |
| CA2759413C true CA2759413C (en) | 2016-09-20 |
Family
ID=42269716
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2759413A Active CA2759413C (en) | 2009-06-24 | 2010-03-08 | Coating compositions and coatings produced from them and featuring high scratch resistance in association with good results in the erichsen cupping test and good antistonechip properties |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US9017818B2 (https=) |
| EP (1) | EP2445948B1 (https=) |
| JP (2) | JP5939979B2 (https=) |
| KR (1) | KR101736513B1 (https=) |
| CN (1) | CN102803330B (https=) |
| BR (1) | BRPI1014324B1 (https=) |
| CA (1) | CA2759413C (https=) |
| DE (1) | DE102009030481A1 (https=) |
| ES (1) | ES2444518T3 (https=) |
| MX (1) | MX2011012166A (https=) |
| PL (1) | PL2445948T3 (https=) |
| RU (1) | RU2541531C2 (https=) |
| WO (1) | WO2010149236A1 (https=) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PL2091988T3 (pl) * | 2006-12-19 | 2013-07-31 | Basf Coatings Gmbh | Środek po włokowy o wysokiej odporności na zadrapania i odporności na działanie czynników atmosferycznych |
| DE102007061856A1 (de) * | 2007-12-19 | 2009-06-25 | Basf Coatings Ag | Beschichtungsmittel mit hoher Kratzbeständigkeit und Witterungsstabilität |
| DE102007061855A1 (de) * | 2007-12-19 | 2009-06-25 | Basf Coatings Ag | Beschichtungsmittel mit hoher Kratzbeständigkeit und Witterungsstabilität |
| DE102007061854A1 (de) * | 2007-12-19 | 2009-06-25 | Basf Coatings Ag | Beschichtungsmittel mit hoher Kratzbeständigkeit und Witterungsstabilität |
| DE102008030304A1 (de) | 2008-06-25 | 2009-12-31 | Basf Coatings Ag | Verwendung teilsilanisierter Verbindungen auf Polyisocyanatbasis als Vernetzungsmittel in Beschichtungszusammensetzungen und Beschichtungszusammensetzung enthaltend die Verbindungen |
| DE102010015675A1 (de) * | 2010-04-21 | 2011-10-27 | Basf Coatings Gmbh | Beschichtungsmittel mit verbesserter Ablaufneigung |
| EP2665758B1 (de) * | 2011-01-20 | 2017-12-06 | BASF Coatings GmbH | Wässriges polyurethanbeschichtungsmittel und daraus hergestellte beschichtungen mit hoher kratzbeständigkeit und guter chemikalienbeständigkeit |
| JP6033289B2 (ja) * | 2011-06-09 | 2016-11-30 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | 被覆剤組成物および該組成物から製造された高い耐引掻性と同時に良好な研磨性を有する被覆ならびにその使用 |
| CN103547607B (zh) | 2011-06-09 | 2015-07-15 | 巴斯夫涂料有限公司 | 涂布剂组合物和由其制备的具有高耐划伤性且同时具有良好的可抛光性的涂层及其用途 |
| US9371469B2 (en) | 2011-06-09 | 2016-06-21 | Basf Coatings Gmbh | Coating agent compositions, coatings made therefrom and exhibiting high scratch resistance and good polishability, and use thereof |
| DE102011105676B4 (de) * | 2011-06-22 | 2018-05-09 | Schoeller Technocell Gmbh & Co. Kg | Vorimprägnat und Dekorpapier oder dekorativer Beschichtungswerkstoff daraus |
| CN104487472B (zh) | 2012-07-25 | 2017-07-14 | 巴斯夫涂料有限公司 | 聚氨酯涂料组合物及其用途、多阶段涂覆方法 |
| CN104487473B (zh) | 2012-07-25 | 2017-05-17 | 巴斯夫涂料有限公司 | 聚氨酯涂料组合物、多阶段涂覆方法 |
| CN104903374B (zh) | 2012-12-03 | 2017-08-29 | 巴斯夫涂料有限公司 | 涂料组合物和由其制备的具有高耐刮擦性与良好抛光性和良好光学性能的涂层、及其用途 |
| MX374622B (es) | 2012-12-03 | 2025-03-06 | Basf Coatings Gmbh | Pintura de varias capas que induce efecto y/o color y método para su producción, y su uso. |
| EP2896639A1 (de) | 2014-01-15 | 2015-07-22 | BASF Coatings GmbH | Beschichtete metallisierte Oberflächen |
| EP2993202A1 (de) * | 2014-09-08 | 2016-03-09 | Evonik Degussa GmbH | Composite-Halbzeuge und daraus hergestellte Formteile sowie direkt hergestellte Formteile auf Basis von hydroxyfunktionalisierten (Meth)Acrylaten und Uretdionen, die duroplastisch vernetzt werden |
| JP6011895B2 (ja) * | 2014-09-30 | 2016-10-25 | 荒川化学工業株式会社 | 銅薄膜付基材用アンダーコート剤、銅薄膜付基材及び銅薄膜付基材の製造方法、並びに導電性フィルム |
| JP6619008B2 (ja) | 2014-12-08 | 2019-12-11 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | コーティング材料組成物、およびそれらから生成されるコーティング、ならびにその使用方法 |
| MX375884B (es) * | 2014-12-08 | 2025-03-06 | Basf Coatings Gmbh | Composiciones no acuosas de materiales de recubrimiento, recubrimientos producidos a partir de ellas y que tienen mejoradas adhesion y resistencia a los arañazos y tambien el uso de las mismas. |
| CN107406572B (zh) | 2015-03-17 | 2020-06-30 | 科思创德国股份有限公司 | 含有硅烷基团并且基于1,5-二异氰酸根合戊烷的多异氰酸酯 |
| EP3085720A1 (de) | 2015-04-21 | 2016-10-26 | Covestro Deutschland AG | Hydrophil modifizierter polyisocyanuratkunststoff und verfahren zu dessen herstellung |
| JP6629355B2 (ja) | 2015-06-15 | 2020-01-15 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | 車輪リムをコーティングする方法、並びに得られる防汚性及び耐ブレーキダスト性のコーティング |
| KR102071433B1 (ko) * | 2015-06-15 | 2020-01-30 | 바스프 코팅스 게엠베하 | 폴리우레탄 코팅제 조성물 및 다층 페인트 시스템의 제조를 위한 그의 용도 |
| CN107771200A (zh) | 2015-06-15 | 2018-03-06 | 巴斯夫涂料有限公司 | 涂覆轮辋的方法及以此得到的防污和防制动粉尘的涂层 |
| EP3347392B1 (en) | 2015-09-09 | 2021-03-10 | Covestro Intellectual Property GmbH & Co. KG | Scratch-resistant aqueous 2k pu coatings |
| KR102555281B1 (ko) | 2015-09-09 | 2023-07-14 | 코베스트로 도이칠란트 아게 | 스크래치-내성 2-성분 폴리우레탄 코팅 |
| JP2019519642A (ja) * | 2016-05-24 | 2019-07-11 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツングBASF Coatings GmbH | 汚染耐性および(自己)浄化特性が改善されたコーティング組成物ならびにそれから製造されるコーティング、ならびにそれを使用する方法 |
| EP3275918A1 (en) * | 2016-07-27 | 2018-01-31 | Clariant Plastics & Coatings Ltd | Compositions comprising polyacrylate-polysilane block copolymers |
| US11664491B2 (en) | 2016-09-06 | 2023-05-30 | Johnson Matthey Plc | Anode for an electrochemical cell |
| EP3760658A1 (de) | 2019-07-03 | 2021-01-06 | Covestro Deutschland AG | Beständige 2k-pur-beschichtungen |
| EP4175820A1 (de) * | 2020-07-02 | 2023-05-10 | Covestro Deutschland AG | Beschichtungen aus polyisocyanuratbeschichtungen (rim) und deren anwendung in spritzgiessprozessen |
| US12022583B2 (en) | 2020-07-10 | 2024-06-25 | Asiatelco Technologies, Inc. | Portable devices, systems and methods with automated heat control assembly |
| US11512818B2 (en) | 2020-07-10 | 2022-11-29 | Junming Ding | Multi-mode portable lighting device with novel battery charging unit |
| US20250236755A1 (en) * | 2022-02-18 | 2025-07-24 | Kansai Paint Co., Ltd. | Coating composition and method for forming coating film |
| JP2023183519A (ja) * | 2022-06-16 | 2023-12-28 | ビーエーエスエフ コーティングス ゲゼルシャフト ミット ベシュレンクテル ハフツング | トップコート層、これを含む積層フィルム、およびこの積層フィルムにより加飾された加飾物品 |
| WO2025223454A1 (en) | 2024-04-24 | 2025-10-30 | Basf Coatings Gmbh | A curable coating composition and its curing method |
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| JP2008535946A (ja) | 2005-03-11 | 2008-09-04 | ザ シャーウィン−ウィリアムズ カンパニー | 引掻き抵抗性硬化性コーティーング組成物 |
| US20070026154A1 (en) | 2005-07-29 | 2007-02-01 | Ayumu Yokoyama | Method for producing damage resistant multi-layer coating on an automotive body or part thereof |
| JP2009503122A (ja) * | 2005-07-29 | 2009-01-29 | 関西ペイント株式会社 | 水性クリヤ塗料組成物及び上塗り複層塗膜形成方法 |
| DE102005045228A1 (de) * | 2005-09-22 | 2007-04-05 | Basf Coatings Ag | Verwendung von Phosphonsäurediestern und Diphosphonsäurediestern sowie silangruppenhaltige, härtbare Gemische, enthaltend Phosphonsäurediester und Diphosphonsäurediester |
| PL2091988T3 (pl) | 2006-12-19 | 2013-07-31 | Basf Coatings Gmbh | Środek po włokowy o wysokiej odporności na zadrapania i odporności na działanie czynników atmosferycznych |
| JP2008208205A (ja) * | 2007-02-26 | 2008-09-11 | Mitsubishi Rayon Co Ltd | 塗料組成物、被覆物品、および自動車用外板 |
| DE102007013262A1 (de) * | 2007-03-15 | 2008-09-18 | Basf Coatings Ag | Beschichtungsmittel enthaltend Addukte mit Silanfunktionalität und daraus hergestellte hochkratzfeste Beschichtungen mit verbesserter Rissbeständigkeit |
| JP4368395B2 (ja) * | 2007-08-22 | 2009-11-18 | Basfコーティングスジャパン株式会社 | 塗料組成物、塗装仕上げ方法及び塗装物品 |
| DE102007061855A1 (de) | 2007-12-19 | 2009-06-25 | Basf Coatings Ag | Beschichtungsmittel mit hoher Kratzbeständigkeit und Witterungsstabilität |
| DE102008060454A1 (de) | 2008-12-05 | 2010-06-10 | Basf Coatings Ag | Beschichtungsmittel und daraus hergestellte Beschichtungen mit hoher Kratzbeständigkeit und Witterungsstabilität sowie guten optischen Eigenschaften |
| DE102009006543A1 (de) * | 2009-01-29 | 2010-08-05 | Epcos Ag | Überspannungsableiter |
-
2009
- 2009-06-24 DE DE102009030481A patent/DE102009030481A1/de not_active Withdrawn
-
2010
- 2010-03-08 CA CA2759413A patent/CA2759413C/en active Active
- 2010-03-08 EP EP10708926.0A patent/EP2445948B1/de active Active
- 2010-03-08 WO PCT/EP2010/001422 patent/WO2010149236A1/de not_active Ceased
- 2010-03-08 KR KR1020117031639A patent/KR101736513B1/ko active Active
- 2010-03-08 US US13/378,817 patent/US9017818B2/en active Active
- 2010-03-08 ES ES10708926T patent/ES2444518T3/es active Active
- 2010-03-08 BR BRPI1014324 patent/BRPI1014324B1/pt not_active IP Right Cessation
- 2010-03-08 MX MX2011012166A patent/MX2011012166A/es active IP Right Grant
- 2010-03-08 PL PL10708926T patent/PL2445948T3/pl unknown
- 2010-03-08 JP JP2012516529A patent/JP5939979B2/ja active Active
- 2010-03-08 RU RU2012102103/04A patent/RU2541531C2/ru active
- 2010-03-08 CN CN201080025319.XA patent/CN102803330B/zh active Active
-
2015
- 2015-04-03 JP JP2015076888A patent/JP2015155544A/ja not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JP5939979B2 (ja) | 2016-06-29 |
| EP2445948B1 (de) | 2013-12-11 |
| KR101736513B1 (ko) | 2017-05-16 |
| CN102803330A (zh) | 2012-11-28 |
| BRPI1014324B1 (pt) | 2019-12-10 |
| RU2012102103A (ru) | 2013-07-27 |
| KR20120102498A (ko) | 2012-09-18 |
| CA2759413A1 (en) | 2010-12-29 |
| PL2445948T3 (pl) | 2014-04-30 |
| WO2010149236A1 (de) | 2010-12-29 |
| US20120100380A1 (en) | 2012-04-26 |
| CN102803330B (zh) | 2016-01-13 |
| JP2012530816A (ja) | 2012-12-06 |
| DE102009030481A1 (de) | 2011-01-05 |
| US9017818B2 (en) | 2015-04-28 |
| BRPI1014324A2 (pt) | 2016-04-05 |
| JP2015155544A (ja) | 2015-08-27 |
| RU2541531C2 (ru) | 2015-02-20 |
| EP2445948A1 (de) | 2012-05-02 |
| ES2444518T3 (es) | 2014-02-25 |
| MX2011012166A (es) | 2011-12-16 |
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