CA2721780C - Rhenium recovery from superalloys and associated methods - Google Patents
Rhenium recovery from superalloys and associated methods Download PDFInfo
- Publication number
- CA2721780C CA2721780C CA2721780A CA2721780A CA2721780C CA 2721780 C CA2721780 C CA 2721780C CA 2721780 A CA2721780 A CA 2721780A CA 2721780 A CA2721780 A CA 2721780A CA 2721780 C CA2721780 C CA 2721780C
- Authority
- CA
- Canada
- Prior art keywords
- rhenium
- superalloy
- scrap
- milling
- grinding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229910000601 superalloy Inorganic materials 0.000 title claims abstract description 105
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 title claims abstract description 94
- 229910052702 rhenium Inorganic materials 0.000 title claims abstract description 90
- 238000000034 method Methods 0.000 title claims abstract description 52
- 238000011084 recovery Methods 0.000 title description 16
- 230000003647 oxidation Effects 0.000 claims abstract description 39
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 39
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 28
- 230000001965 increasing effect Effects 0.000 claims abstract description 21
- DYIZHKNUQPHNJY-UHFFFAOYSA-N oxorhenium Chemical compound [Re]=O DYIZHKNUQPHNJY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910003449 rhenium oxide Inorganic materials 0.000 claims abstract description 16
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 11
- 230000001590 oxidative effect Effects 0.000 claims abstract description 10
- 239000002245 particle Substances 0.000 claims description 33
- 238000000227 grinding Methods 0.000 claims description 26
- 238000003801 milling Methods 0.000 claims description 15
- 238000010316 high energy milling Methods 0.000 claims description 9
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 238000000498 ball milling Methods 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 238000009792 diffusion process Methods 0.000 description 16
- 229910045601 alloy Inorganic materials 0.000 description 8
- 239000000956 alloy Substances 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 8
- 238000004886 process control Methods 0.000 description 8
- 238000010304 firing Methods 0.000 description 7
- 239000002699 waste material Substances 0.000 description 7
- 230000006870 function Effects 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- 239000013078 crystal Substances 0.000 description 5
- 229910052750 molybdenum Inorganic materials 0.000 description 5
- 239000011733 molybdenum Substances 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 238000001878 scanning electron micrograph Methods 0.000 description 5
- 239000008117 stearic acid Substances 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 229910052804 chromium Inorganic materials 0.000 description 4
- 239000011651 chromium Substances 0.000 description 4
- 230000001788 irregular Effects 0.000 description 4
- 238000003754 machining Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000013459 approach Methods 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229910001173 rene N5 Inorganic materials 0.000 description 3
- 229910052715 tantalum Inorganic materials 0.000 description 3
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052758 niobium Inorganic materials 0.000 description 2
- 239000010955 niobium Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910052727 yttrium Inorganic materials 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- QSHYGLAZPRJAEZ-UHFFFAOYSA-N 4-(chloromethyl)-2-(2-methylphenyl)-1,3-thiazole Chemical compound CC1=CC=CC=C1C1=NC(CCl)=CS1 QSHYGLAZPRJAEZ-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910000995 CMSX-10 Inorganic materials 0.000 description 1
- 229910001011 CMSX-4 Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000691 Re alloy Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- YUSUJSHEOICGOO-UHFFFAOYSA-N molybdenum rhenium Chemical compound [Mo].[Mo].[Re].[Re].[Re] YUSUJSHEOICGOO-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011946 reduction process Methods 0.000 description 1
- 239000003870 refractory metal Substances 0.000 description 1
- DECCZIUVGMLHKQ-UHFFFAOYSA-N rhenium tungsten Chemical compound [W].[Re] DECCZIUVGMLHKQ-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B61/00—Obtaining metals not elsewhere provided for in this subclass
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G47/00—Compounds of rhenium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/626,973 US8038764B2 (en) | 2009-11-30 | 2009-11-30 | Rhenium recovery from superalloys and associated methods |
| US12/626,973 | 2009-11-30 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2721780A1 CA2721780A1 (en) | 2011-05-30 |
| CA2721780C true CA2721780C (en) | 2017-12-12 |
Family
ID=43466466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2721780A Expired - Fee Related CA2721780C (en) | 2009-11-30 | 2010-11-18 | Rhenium recovery from superalloys and associated methods |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US8038764B2 (enExample) |
| EP (1) | EP2339036B1 (enExample) |
| JP (1) | JP5802382B2 (enExample) |
| CA (1) | CA2721780C (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102409164A (zh) * | 2011-12-02 | 2012-04-11 | 中国科学院过程工程研究所 | 一种混合稀土矿防结块焙烧方法 |
| JP5854985B2 (ja) | 2012-12-28 | 2016-02-09 | パンパシフィック・カッパー株式会社 | 硫化レニウムからの過レニウム酸水溶液の製造方法 |
| JP5902610B2 (ja) * | 2012-12-28 | 2016-04-13 | パンパシフィック・カッパー株式会社 | 硫化レニウムからの過レニウム酸水溶液の製造方法 |
| CN106757156B (zh) * | 2016-12-08 | 2018-08-10 | 江苏鼎杰合金科技有限公司 | 一种从含Re高温合金废料中回收Re的方法 |
| CN112646964B (zh) * | 2020-12-17 | 2022-02-22 | 中国科学院金属研究所 | 一种具有梯度纳米结构表层的高温合金及其制备方法 |
| CN114892012A (zh) * | 2022-04-25 | 2022-08-12 | 中国航发成都发动机有限公司 | 一种镍基高温合金返回料的重熔净化方法 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2848313A (en) * | 1955-05-04 | 1958-08-19 | Takahashi Rintaro | Method of chemically disintegrating and pulverizing solid material |
| US3348942A (en) * | 1965-03-08 | 1967-10-24 | Chase Brass & Copper Co | Recovery of rhenium values |
| JPS5021998B1 (enExample) * | 1968-08-20 | 1975-07-26 | ||
| JPS5426914A (en) * | 1977-08-03 | 1979-02-28 | Toshiba Corp | Recovering method for rhenium in rhenium-tungsten alloy |
| US4604265A (en) * | 1985-08-22 | 1986-08-05 | Gte Products Corporation | Recovery of tungsten and rhenium |
| US4787561A (en) * | 1986-08-13 | 1988-11-29 | Gte Products Corporation | Fine granular metallic powder particles and process for producing same |
| US4880170A (en) * | 1989-01-03 | 1989-11-14 | Gte Products Corporation | Process for producing fine copper powder with enhanced sinterability |
| JPH03193607A (ja) * | 1989-12-20 | 1991-08-23 | Hitachi Ltd | 金属の分離精製方法及び装置 |
| US5455120A (en) | 1992-03-05 | 1995-10-03 | General Electric Company | Nickel-base superalloy and article with high temperature strength and improved stability |
| RU2061079C1 (ru) * | 1993-05-14 | 1996-05-27 | Рэм Павлович Гель | Способ извлечения оксида рения из отходов |
| US5482789A (en) * | 1994-01-03 | 1996-01-09 | General Electric Company | Nickel base superalloy and article |
| DE4439041C2 (de) | 1994-11-02 | 1998-08-13 | Starck H C Gmbh Co Kg | Verfahren zum Aufschluß und Rückgewinnung der metallischen Bestandteile aus rheniumhaltigen Superlegierungen |
| US6131835A (en) | 1997-08-29 | 2000-10-17 | Mg Technologies, Inc. | Methods for treating ores |
| US6835365B1 (en) * | 1997-12-11 | 2004-12-28 | Moosa Mahomed Adia | Crystal growth |
| PE20020492A1 (es) | 2000-07-25 | 2002-06-03 | Phelps Dodge Corp | Metodo para la recuperacion de metales de materiales con contenido de metales usando lixiviacion a presion a temperatura media |
| DE10155791C1 (de) | 2001-11-14 | 2003-07-17 | Starck H C Gmbh | Verfahren zum elektrochemischen Aufschluss von Superlegierungen |
| US20030119658A1 (en) * | 2001-12-21 | 2003-06-26 | Conocophillips Company | Recovery of rhenium from a spent catalyst via sublimation |
| US7645315B2 (en) * | 2003-01-13 | 2010-01-12 | Worldwide Strategy Holdings Limited | High-performance hardmetal materials |
| JP5299899B2 (ja) * | 2006-03-31 | 2013-09-25 | 独立行政法人物質・材料研究機構 | Ｎｉ基超合金及びその製造方法 |
-
2009
- 2009-11-30 US US12/626,973 patent/US8038764B2/en active Active
-
2010
- 2010-11-18 CA CA2721780A patent/CA2721780C/en not_active Expired - Fee Related
- 2010-11-18 EP EP10191754.0A patent/EP2339036B1/en active Active
- 2010-11-22 JP JP2010259753A patent/JP5802382B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2339036A1 (en) | 2011-06-29 |
| JP2011117080A (ja) | 2011-06-16 |
| US8038764B2 (en) | 2011-10-18 |
| CA2721780A1 (en) | 2011-05-30 |
| US20110126673A1 (en) | 2011-06-02 |
| JP5802382B2 (ja) | 2015-10-28 |
| EP2339036B1 (en) | 2018-10-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20150918 |
|
| MKLA | Lapsed |
Effective date: 20201118 |